JPS61282430A - 活性炭素繊維の製造法 - Google Patents
活性炭素繊維の製造法Info
- Publication number
- JPS61282430A JPS61282430A JP60121589A JP12158985A JPS61282430A JP S61282430 A JPS61282430 A JP S61282430A JP 60121589 A JP60121589 A JP 60121589A JP 12158985 A JP12158985 A JP 12158985A JP S61282430 A JPS61282430 A JP S61282430A
- Authority
- JP
- Japan
- Prior art keywords
- activation
- surface area
- specific surface
- fiber
- acf
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title description 4
- 230000004913 activation Effects 0.000 claims abstract description 55
- 239000011148 porous material Substances 0.000 claims abstract description 31
- 230000001590 oxidative effect Effects 0.000 claims abstract description 10
- 239000012298 atmosphere Substances 0.000 claims abstract description 9
- 229920002972 Acrylic fiber Polymers 0.000 claims abstract description 7
- 230000003213 activating effect Effects 0.000 claims description 2
- 239000007789 gas Substances 0.000 abstract description 22
- 239000000835 fiber Substances 0.000 abstract description 19
- 239000000203 mixture Substances 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 8
- -1 acrylic activated carbon fiber Chemical class 0.000 abstract description 2
- 238000001994 activation Methods 0.000 description 46
- 238000001179 sorption measurement Methods 0.000 description 14
- 230000003647 oxidation Effects 0.000 description 12
- 238000007254 oxidation reaction Methods 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 230000007423 decrease Effects 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- 239000003570 air Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical class NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical class O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical class ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- VMSBGXAJJLPWKV-UHFFFAOYSA-N 2-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1C=C VMSBGXAJJLPWKV-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical class C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920006282 Phenolic fiber Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical class ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229930003270 Vitamin B Natural products 0.000 description 1
- 229930003779 Vitamin B12 Natural products 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- AGVAZMGAQJOSFJ-WZHZPDAFSA-M cobalt(2+);[(2r,3s,4r,5s)-5-(5,6-dimethylbenzimidazol-1-yl)-4-hydroxy-2-(hydroxymethyl)oxolan-3-yl] [(2r)-1-[3-[(1r,2r,3r,4z,7s,9z,12s,13s,14z,17s,18s,19r)-2,13,18-tris(2-amino-2-oxoethyl)-7,12,17-tris(3-amino-3-oxopropyl)-3,5,8,8,13,15,18,19-octamethyl-2 Chemical compound [Co+2].N#[C-].[N-]([C@@H]1[C@H](CC(N)=O)[C@@]2(C)CCC(=O)NC[C@@H](C)OP(O)(=O)O[C@H]3[C@H]([C@H](O[C@@H]3CO)N3C4=CC(C)=C(C)C=C4N=C3)O)\C2=C(C)/C([C@H](C\2(C)C)CCC(N)=O)=N/C/2=C\C([C@H]([C@@]/2(CC(N)=O)C)CCC(N)=O)=N\C\2=C(C)/C2=N[C@]1(C)[C@@](C)(CC(N)=O)[C@@H]2CCC(N)=O AGVAZMGAQJOSFJ-WZHZPDAFSA-M 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 239000002052 molecular layer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Substances 0.000 description 1
- 239000011715 vitamin B12 Substances 0.000 description 1
- 235000019163 vitamin B12 Nutrition 0.000 description 1
Landscapes
- Inorganic Fibers (AREA)
- Carbon And Carbon Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60121589A JPS61282430A (ja) | 1985-06-06 | 1985-06-06 | 活性炭素繊維の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60121589A JPS61282430A (ja) | 1985-06-06 | 1985-06-06 | 活性炭素繊維の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61282430A true JPS61282430A (ja) | 1986-12-12 |
| JPS64486B2 JPS64486B2 (enrdf_load_stackoverflow) | 1989-01-06 |
Family
ID=14814984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60121589A Granted JPS61282430A (ja) | 1985-06-06 | 1985-06-06 | 活性炭素繊維の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61282430A (enrdf_load_stackoverflow) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61295217A (ja) * | 1985-06-22 | 1986-12-26 | Unitika Ltd | 繊維状活性炭 |
| JPS6227315A (ja) * | 1985-07-24 | 1987-02-05 | Osaka Gas Co Ltd | 活性炭繊維の製造方法 |
| US4921686A (en) * | 1986-05-29 | 1990-05-01 | Matsushita Electric Industrial Co., Ltd. | Method of carbonizing and activating fiber materials |
| US5618510A (en) * | 1994-04-12 | 1997-04-08 | New Oji Paper Co., Ltd. | Process for producing silicon carbide material |
| JP2004138097A (ja) * | 2002-10-15 | 2004-05-13 | Ishizuka Kenkyusho:Kk | 水素吸蔵媒体及びその製造方法 |
| WO2008139747A1 (ja) * | 2007-05-14 | 2008-11-20 | Hi-Van Corporation | 炭素アルミニウム複合化合物及び炭素アルミニウム複合化合物被覆無機化合物 |
| CN102140709A (zh) * | 2011-01-27 | 2011-08-03 | 济南大学 | 一种多微孔活性炭纤维及其制备方法 |
| CN102140708A (zh) * | 2011-01-27 | 2011-08-03 | 济南大学 | 一种活性炭纤维及其制备方法 |
| KR20160125388A (ko) | 2014-02-26 | 2016-10-31 | 도레이 카부시키가이샤 | 다공질 탄소 재료, 탄소 재료 강화 복합 재료, 다공질 탄소 재료 전구체, 다공질 탄소 재료 전구체의 제조 방법, 및 다공질 탄소 재료의 제조 방법 |
| CN109082880A (zh) * | 2018-07-05 | 2018-12-25 | 王伟霞 | 功能活性碳纤维、制备方法及其应用 |
-
1985
- 1985-06-06 JP JP60121589A patent/JPS61282430A/ja active Granted
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61295217A (ja) * | 1985-06-22 | 1986-12-26 | Unitika Ltd | 繊維状活性炭 |
| JPS6227315A (ja) * | 1985-07-24 | 1987-02-05 | Osaka Gas Co Ltd | 活性炭繊維の製造方法 |
| US4921686A (en) * | 1986-05-29 | 1990-05-01 | Matsushita Electric Industrial Co., Ltd. | Method of carbonizing and activating fiber materials |
| US5618510A (en) * | 1994-04-12 | 1997-04-08 | New Oji Paper Co., Ltd. | Process for producing silicon carbide material |
| JP2004138097A (ja) * | 2002-10-15 | 2004-05-13 | Ishizuka Kenkyusho:Kk | 水素吸蔵媒体及びその製造方法 |
| JPWO2008139747A1 (ja) * | 2007-05-14 | 2010-07-29 | 株式会社Ｈｉ−Ｖａｎ | 炭素アルミニウム複合化合物及び炭素アルミニウム複合化合物被覆無機化合物 |
| WO2008139747A1 (ja) * | 2007-05-14 | 2008-11-20 | Hi-Van Corporation | 炭素アルミニウム複合化合物及び炭素アルミニウム複合化合物被覆無機化合物 |
| JP2012140322A (ja) * | 2007-05-14 | 2012-07-26 | Hi-Van:Kk | 炭素アルミニウム複合化合物及び炭素アルミニウム複合化合物被覆無機化合物 |
| CN102140709A (zh) * | 2011-01-27 | 2011-08-03 | 济南大学 | 一种多微孔活性炭纤维及其制备方法 |
| CN102140708A (zh) * | 2011-01-27 | 2011-08-03 | 济南大学 | 一种活性炭纤维及其制备方法 |
| KR20160125388A (ko) | 2014-02-26 | 2016-10-31 | 도레이 카부시키가이샤 | 다공질 탄소 재료, 탄소 재료 강화 복합 재료, 다공질 탄소 재료 전구체, 다공질 탄소 재료 전구체의 제조 방법, 및 다공질 탄소 재료의 제조 방법 |
| US10131770B2 (en) | 2014-02-26 | 2018-11-20 | Toray Industries, Inc. | Porous carbon material, composite material reinforced with carbon material, porous carbon material precursor, porous carbon material precursor production method, and porous carbon material production method |
| CN109082880A (zh) * | 2018-07-05 | 2018-12-25 | 王伟霞 | 功能活性碳纤维、制备方法及其应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS64486B2 (enrdf_load_stackoverflow) | 1989-01-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |