JPS61111140A - 炭化水素合成用触媒 - Google Patents
炭化水素合成用触媒Info
- Publication number
- JPS61111140A JPS61111140A JP59234697A JP23469784A JPS61111140A JP S61111140 A JPS61111140 A JP S61111140A JP 59234697 A JP59234697 A JP 59234697A JP 23469784 A JP23469784 A JP 23469784A JP S61111140 A JPS61111140 A JP S61111140A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- carrier
- cobalt
- cerium oxide
- supported
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 52
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 25
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 25
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 14
- 230000015572 biosynthetic process Effects 0.000 title claims description 12
- 238000003786 synthesis reaction Methods 0.000 title claims description 12
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 29
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000010941 cobalt Substances 0.000 claims abstract description 26
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 16
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 10
- 239000011148 porous material Substances 0.000 claims abstract description 10
- 239000001257 hydrogen Substances 0.000 claims abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000002194 synthesizing effect Effects 0.000 claims abstract description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 9
- 230000003197 catalytic effect Effects 0.000 abstract description 8
- 229910052596 spinel Inorganic materials 0.000 abstract description 8
- 239000011029 spinel Substances 0.000 abstract description 8
- 229910052684 Cerium Inorganic materials 0.000 abstract description 7
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 3
- 239000004113 Sepiolite Substances 0.000 abstract description 2
- UAMZXLIURMNTHD-UHFFFAOYSA-N dialuminum;magnesium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Mg+2].[Al+3].[Al+3] UAMZXLIURMNTHD-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052624 sepiolite Inorganic materials 0.000 abstract description 2
- 235000019355 sepiolite Nutrition 0.000 abstract description 2
- 238000000151 deposition Methods 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 229910002090 carbon oxide Inorganic materials 0.000 description 4
- 239000000969 carrier Substances 0.000 description 4
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 241000206761 Bacillariophyta Species 0.000 description 1
- 241000264877 Hippospongia communis Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- FQMNUIZEFUVPNU-UHFFFAOYSA-N cobalt iron Chemical compound [Fe].[Co].[Co] FQMNUIZEFUVPNU-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with rare earths or actinides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59234697A JPS61111140A (ja) | 1984-11-06 | 1984-11-06 | 炭化水素合成用触媒 |
| US06/912,216 US4801620A (en) | 1984-11-06 | 1986-09-26 | Catalyst for hydrocarbon synthesis |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59234697A JPS61111140A (ja) | 1984-11-06 | 1984-11-06 | 炭化水素合成用触媒 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61111140A true JPS61111140A (ja) | 1986-05-29 |
| JPH0510133B2 JPH0510133B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-02-08 |
Family
ID=16974991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59234697A Granted JPS61111140A (ja) | 1984-11-06 | 1984-11-06 | 炭化水素合成用触媒 |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4801620A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
| JP (1) | JPS61111140A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001348207A (ja) * | 2000-03-02 | 2001-12-18 | Boc Group Inc:The | 炭化水素を部分酸化して水素と一酸化炭素を製造する方法 |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3803122C1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1988-02-03 | 1989-07-13 | Degussa Ag, 6000 Frankfurt, De | |
| US6479428B1 (en) | 1998-07-27 | 2002-11-12 | Battelle Memorial Institute | Long life hydrocarbon conversion catalyst and method of making |
| US6440895B1 (en) * | 1998-07-27 | 2002-08-27 | Battelle Memorial Institute | Catalyst, method of making, and reactions using the catalyst |
| US6616909B1 (en) | 1998-07-27 | 2003-09-09 | Battelle Memorial Institute | Method and apparatus for obtaining enhanced production rate of thermal chemical reactions |
| US6262132B1 (en) * | 1999-05-21 | 2001-07-17 | Energy International Corporation | Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems |
| US6488838B1 (en) * | 1999-08-17 | 2002-12-03 | Battelle Memorial Institute | Chemical reactor and method for gas phase reactant catalytic reactions |
| US6607678B2 (en) | 1999-08-17 | 2003-08-19 | Battelle Memorial Institute | Catalyst and method of steam reforming |
| US6451864B1 (en) | 1999-08-17 | 2002-09-17 | Battelle Memorial Institute | Catalyst structure and method of Fischer-Tropsch synthesis |
| CA2381221C (en) * | 1999-08-17 | 2012-01-17 | Battelle Memorial Institute | Catalyst structure and method of fischer-tropsch synthesis |
| EP1206508B1 (en) * | 1999-08-17 | 2005-11-30 | Battelle Memorial Institute | Catalyst structure and method of fischer-tropsch synthesis |
| JP3407031B2 (ja) * | 2000-03-09 | 2003-05-19 | 東北大学長 | 一酸化炭素の水素化反応触媒および水素化生成物の製造方法 |
| US7125540B1 (en) * | 2000-06-06 | 2006-10-24 | Battelle Memorial Institute | Microsystem process networks |
| GB0030170D0 (en) * | 2000-12-11 | 2001-01-24 | Norske Stats Oljeselskap | Fischer-tropsch catalyst |
| EP1378289A3 (en) * | 2002-04-18 | 2004-02-04 | Ford Global Technologies, LLC, A subsidary of Ford Motor Company | Platinum-group-metal free catalytic washcoats for particulate exhaust gas filter applications |
| US20050203195A1 (en) * | 2003-08-05 | 2005-09-15 | Yong Wang | Tailored Fischer-Tropsch synthesis product distribution |
| GB2410449B (en) * | 2004-01-28 | 2008-05-21 | Statoil Asa | Fischer-Tropsch catalysts |
| FR2879478B1 (fr) * | 2004-12-17 | 2007-10-26 | Inst Francais Du Petrole | Catalyseur a base de cobalt pour la synthese fisher-tropsch |
| FR2879477A1 (fr) * | 2004-12-17 | 2006-06-23 | Inst Francais Du Petrole | Catalyseur a base de cobalt pour la synthese fischer-tropsch |
| GB2446127A (en) * | 2007-01-30 | 2008-08-06 | Gtl F1 Ag | Preparation of Fischer-Tropsch Catalysts |
| CN102307660A (zh) * | 2009-02-09 | 2012-01-04 | 巴斯夫欧洲公司 | 氢化催化剂及其制备和用途 |
| JP2012517333A (ja) * | 2009-02-09 | 2012-08-02 | ビーエーエスエフ ソシエタス・ヨーロピア | モノリス触媒の触媒活性を改善する方法 |
| GB2473071B (en) | 2009-09-01 | 2013-09-11 | Gtl F1 Ag | Fischer-tropsch catalysts |
| GB2475492B (en) | 2009-11-18 | 2014-12-31 | Gtl F1 Ag | Fischer-Tropsch synthesis |
| EP2603316B1 (en) | 2010-08-09 | 2017-04-19 | Gtl. F1 Ag | Fischer-tropsch catalysts |
| WO2014158095A1 (en) | 2013-03-28 | 2014-10-02 | Agency For Science, Technology And Research | Methanation catalyst |
| SG2013050877A (en) | 2013-06-28 | 2015-01-29 | Agency Science Tech & Res | Methanation catalyst |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5881440A (ja) * | 1981-11-09 | 1983-05-16 | Toyota Central Res & Dev Lab Inc | 炭化水素合成用触媒 |
| JPS58139744A (ja) * | 1982-02-12 | 1983-08-19 | Toyota Central Res & Dev Lab Inc | 炭化水素合成用触媒 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3322491A (en) * | 1963-07-31 | 1967-05-30 | Grace W R & Co | Method of treating exhaust gases |
| US3888792A (en) * | 1970-06-26 | 1975-06-10 | African Explosives & Chem | Catalyst of cobalt oxide and a rare earth metal oxide and its method of preparation |
| US4256653A (en) * | 1976-11-03 | 1981-03-17 | The United States Of America As Represented By The Secretary Of The Interior | Preparation and use of high surface area transition metal catalysts |
| US4177163A (en) * | 1978-03-08 | 1979-12-04 | Mobil Oil Corporation | Supported catalyst for demetalation and desulfurization of hydrocarbon oils |
| US4235755A (en) * | 1979-02-21 | 1980-11-25 | Uop Inc. | Hydrocarbon dehydrogenation method and nonacidic multimetallic catalytic composite for use therein |
| SU895491A1 (ru) * | 1980-02-04 | 1982-01-07 | Институт новых химических проблем АН СССР | Катализатор дл синтеза метана из окиси углерода и водорода и способ его приготовлени |
| CA1173064A (en) * | 1981-07-17 | 1984-08-21 | Malcolm P. Heyward | Catalyst composition for conversion of synthesis gas to hydrocarbons |
| US4613624A (en) * | 1981-10-13 | 1986-09-23 | Chevron Research Company | Conversion of synthesis gas to diesel fuel and catalyst therefor |
-
1984
- 1984-11-06 JP JP59234697A patent/JPS61111140A/ja active Granted
-
1986
- 1986-09-26 US US06/912,216 patent/US4801620A/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5881440A (ja) * | 1981-11-09 | 1983-05-16 | Toyota Central Res & Dev Lab Inc | 炭化水素合成用触媒 |
| JPS58139744A (ja) * | 1982-02-12 | 1983-08-19 | Toyota Central Res & Dev Lab Inc | 炭化水素合成用触媒 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001348207A (ja) * | 2000-03-02 | 2001-12-18 | Boc Group Inc:The | 炭化水素を部分酸化して水素と一酸化炭素を製造する方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US4801620A (en) | 1989-01-31 |
| JPH0510133B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-02-08 |
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