JPS60221702A - 透明被覆層を有する成形体 - Google Patents
透明被覆層を有する成形体Info
- Publication number
- JPS60221702A JPS60221702A JP60009247A JP924785A JPS60221702A JP S60221702 A JPS60221702 A JP S60221702A JP 60009247 A JP60009247 A JP 60009247A JP 924785 A JP924785 A JP 924785A JP S60221702 A JPS60221702 A JP S60221702A
- Authority
- JP
- Japan
- Prior art keywords
- coating layer
- transparent
- transparent coating
- layer
- molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011247 coating layer Substances 0.000 title claims abstract description 33
- 238000000465 moulding Methods 0.000 title abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 30
- 229920003023 plastic Polymers 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 11
- 238000002834 transmittance Methods 0.000 claims abstract description 11
- 239000011521 glass Substances 0.000 claims abstract description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 7
- 229920001558 organosilicon polymer Polymers 0.000 claims abstract 2
- 239000010410 layer Substances 0.000 claims description 17
- 229910010272 inorganic material Inorganic materials 0.000 claims description 15
- 239000011147 inorganic material Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 7
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 229920000620 organic polymer Polymers 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 19
- 239000011248 coating agent Substances 0.000 abstract description 14
- 239000000758 substrate Substances 0.000 abstract description 10
- 239000002344 surface layer Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 229920000642 polymer Polymers 0.000 abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 229910052719 titanium Inorganic materials 0.000 abstract description 3
- 229910052726 zirconium Inorganic materials 0.000 abstract description 3
- 238000001704 evaporation Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 description 23
- 239000002585 base Substances 0.000 description 15
- 239000000126 substance Substances 0.000 description 14
- 239000004033 plastic Substances 0.000 description 13
- 239000012780 transparent material Substances 0.000 description 10
- -1 etc.) Polymers 0.000 description 8
- 238000001723 curing Methods 0.000 description 7
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000002612 dispersion medium Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 229910000077 silane Inorganic materials 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
- 150000003961 organosilicon compounds Chemical group 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- ZLNAFSPCNATQPQ-UHFFFAOYSA-N ethenyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C=C ZLNAFSPCNATQPQ-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- HEXHLHNCJVXPNU-UHFFFAOYSA-N 2-(trimethoxysilylmethyl)butane-1,4-diamine Chemical compound CO[Si](OC)(OC)CC(CN)CCN HEXHLHNCJVXPNU-UHFFFAOYSA-N 0.000 description 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
- XBIUWALDKXACEA-UHFFFAOYSA-N 3-[bis(2,4-dioxopentan-3-yl)alumanyl]pentane-2,4-dione Chemical compound CC(=O)C(C(C)=O)[Al](C(C(C)=O)C(C)=O)C(C(C)=O)C(C)=O XBIUWALDKXACEA-UHFFFAOYSA-N 0.000 description 1
- ZYAASQNKCWTPKI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propan-1-amine Chemical compound CO[Si](C)(OC)CCCN ZYAASQNKCWTPKI-UHFFFAOYSA-N 0.000 description 1
- IKYAJDOSWUATPI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propane-1-thiol Chemical compound CO[Si](C)(OC)CCCS IKYAJDOSWUATPI-UHFFFAOYSA-N 0.000 description 1
- LZMNXXQIQIHFGC-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical compound CO[Si](C)(OC)CCCOC(=O)C(C)=C LZMNXXQIQIHFGC-UHFFFAOYSA-N 0.000 description 1
- KSCAZPYHLGGNPZ-UHFFFAOYSA-N 3-chloropropyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CCCCl KSCAZPYHLGGNPZ-UHFFFAOYSA-N 0.000 description 1
- PLXLQGPXPXIVKM-UHFFFAOYSA-N 3-chloropropyl(tripropoxy)silane Chemical compound CCCO[Si](CCCCl)(OCCC)OCCC PLXLQGPXPXIVKM-UHFFFAOYSA-N 0.000 description 1
- KNTKCYKJRSMRMZ-UHFFFAOYSA-N 3-chloropropyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)CCCCl KNTKCYKJRSMRMZ-UHFFFAOYSA-N 0.000 description 1
- ONLPKGMCOFNAJA-UHFFFAOYSA-N 3-methoxysilylpropane-1-thiol Chemical compound CO[SiH2]CCCS ONLPKGMCOFNAJA-UHFFFAOYSA-N 0.000 description 1
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- OTCOSAMIXUWQOA-UHFFFAOYSA-N COC(OC)(OC)CO[SiH2]C Chemical compound COC(OC)(OC)CO[SiH2]C OTCOSAMIXUWQOA-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 208000032544 Cicatrix Diseases 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- RQVFGTYFBUVGOP-UHFFFAOYSA-N [acetyloxy(dimethyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(C)OC(C)=O RQVFGTYFBUVGOP-UHFFFAOYSA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- TVJPBVNWVPUZBM-UHFFFAOYSA-N [diacetyloxy(methyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(OC(C)=O)OC(C)=O TVJPBVNWVPUZBM-UHFFFAOYSA-N 0.000 description 1
- VLFKGWCMFMCFRM-UHFFFAOYSA-N [diacetyloxy(phenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C1=CC=CC=C1 VLFKGWCMFMCFRM-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 208000003464 asthenopia Diseases 0.000 description 1
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 description 1
- SYFOAKAXGNMQAX-UHFFFAOYSA-N bis(prop-2-enyl) carbonate;2-(2-hydroxyethoxy)ethanol Chemical compound OCCOCCO.C=CCOC(=O)OCC=C SYFOAKAXGNMQAX-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 1
- VDCSZEZNBODVRT-UHFFFAOYSA-N dimethoxy-[3-(oxiran-2-ylmethoxy)propyl]-phenylsilane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)CCCOCC1CO1 VDCSZEZNBODVRT-UHFFFAOYSA-N 0.000 description 1
- WHGNXNCOTZPEEK-UHFFFAOYSA-N dimethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](C)(OC)CCCOCC1CO1 WHGNXNCOTZPEEK-UHFFFAOYSA-N 0.000 description 1
- CVQVSVBUMVSJES-UHFFFAOYSA-N dimethoxy-methyl-phenylsilane Chemical compound CO[Si](C)(OC)C1=CC=CC=C1 CVQVSVBUMVSJES-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- RJMRIDVWCWSWFR-UHFFFAOYSA-N methyl(tripropoxy)silane Chemical compound CCCO[Si](C)(OCCC)OCCC RJMRIDVWCWSWFR-UHFFFAOYSA-N 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002894 organic compounds Chemical group 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 230000037387 scars Effects 0.000 description 1
- 229940082569 selenite Drugs 0.000 description 1
- MCAHWIHFGHIESP-UHFFFAOYSA-L selenite(2-) Chemical compound [O-][Se]([O-])=O MCAHWIHFGHIESP-UHFFFAOYSA-L 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- ZUEKXCXHTXJYAR-UHFFFAOYSA-N tetrapropan-2-yl silicate Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)OC(C)C ZUEKXCXHTXJYAR-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XROWMBWRMNHXMF-UHFFFAOYSA-J titanium tetrafluoride Chemical compound [F-].[F-].[F-].[F-].[Ti+4] XROWMBWRMNHXMF-UHFFFAOYSA-J 0.000 description 1
- GYZQBXUDWTVJDF-UHFFFAOYSA-N tributoxy(methyl)silane Chemical compound CCCCO[Si](C)(OCCCC)OCCCC GYZQBXUDWTVJDF-UHFFFAOYSA-N 0.000 description 1
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/111—Anti-reflection coatings using layers comprising organic materials
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60009247A JPS60221702A (ja) | 1985-01-23 | 1985-01-23 | 透明被覆層を有する成形体 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60009247A JPS60221702A (ja) | 1985-01-23 | 1985-01-23 | 透明被覆層を有する成形体 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54146485A Division JPS6059250B2 (ja) | 1979-11-14 | 1979-11-14 | 反射防止性透明材料およびその製造方法 |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1136545A Division JPH0277434A (ja) | 1989-05-29 | 1989-05-29 | 透明被覆層を有する成形体 |
| JP1136544A Division JPH0222340A (ja) | 1989-05-29 | 1989-05-29 | 透明被覆層を有する成形体 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60221702A true JPS60221702A (ja) | 1985-11-06 |
| JPS6337142B2 JPS6337142B2 (enrdf_load_stackoverflow) | 1988-07-22 |
Family
ID=11715074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60009247A Granted JPS60221702A (ja) | 1985-01-23 | 1985-01-23 | 透明被覆層を有する成形体 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60221702A (enrdf_load_stackoverflow) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6381033A (ja) * | 1986-09-25 | 1988-04-11 | Toray Ind Inc | 反射防止物品およびその製造方法 |
| JPS63197635A (ja) * | 1987-02-13 | 1988-08-16 | Toray Ind Inc | 反射防止効果を有するプラスチツク光学物品 |
| JPS63225635A (ja) * | 1987-03-16 | 1988-09-20 | Toray Ind Inc | 透明被覆成形体 |
| JPH0222340A (ja) * | 1989-05-29 | 1990-01-25 | Toray Ind Inc | 透明被覆層を有する成形体 |
| JPH0277434A (ja) * | 1989-05-29 | 1990-03-16 | Toray Ind Inc | 透明被覆層を有する成形体 |
| WO1990005315A1 (en) * | 1988-10-31 | 1990-05-17 | Sumitomo Cement Co., Ltd. | Antireflection articles, process for their production and coating composition |
| JPH0578508A (ja) * | 1992-02-13 | 1993-03-30 | Toray Ind Inc | 反射防止効果を有するプラスチツク光学物品の製造方法 |
| JPH06118203A (ja) * | 1992-10-08 | 1994-04-28 | Kureha Chem Ind Co Ltd | プラスチックレンズ |
| JPH10292135A (ja) * | 1997-04-18 | 1998-11-04 | Seiko Epson Corp | コーティング用組成物、その製造方法および積層体 |
| US6013372A (en) * | 1995-03-20 | 2000-01-11 | Toto, Ltd. | Method for photocatalytically rendering a surface of a substrate superhydrophilic, a substrate with superhydrophilic photocatalytic surface, and method of making thereof |
| US6090489A (en) * | 1995-12-22 | 2000-07-18 | Toto, Ltd. | Method for photocatalytically hydrophilifying surface and composite material with photocatalytically hydrophilifiable surface |
| JP2000329903A (ja) * | 1999-05-18 | 2000-11-30 | Asahi Denka Kogyo Kk | 反射防止膜用剤および反射防止膜製造方法 |
| US6165256A (en) * | 1996-07-19 | 2000-12-26 | Toto Ltd. | Photocatalytically hydrophilifiable coating composition |
| US6337129B1 (en) | 1997-06-02 | 2002-01-08 | Toto Ltd. | Antifouling member and antifouling coating composition |
| US6524664B1 (en) | 1996-03-21 | 2003-02-25 | Toto Ltd. | Photocatalytically hydrophilifying and hydrophobifying material |
| WO2004024444A1 (ja) * | 2002-09-12 | 2004-03-25 | Nippon Sheet Glass Company, Limited | 発光膜被覆物品 |
| JP2004122772A (ja) * | 2002-09-12 | 2004-04-22 | Nippon Sheet Glass Co Ltd | 発光膜被覆物品 |
| US6830785B1 (en) | 1995-03-20 | 2004-12-14 | Toto Ltd. | Method for photocatalytically rendering a surface of a substrate superhydrophilic, a substrate with a superhydrophilic photocatalytic surface, and method of making thereof |
| JP2006057106A (ja) * | 2005-10-05 | 2006-03-02 | Seiko Epson Corp | コーティング用組成物、その製造方法および積層体 |
| US7193781B2 (en) | 2002-10-02 | 2007-03-20 | Bridgestone Corporation | Optical substrate and antireflective film |
| WO2015005333A1 (ja) * | 2013-07-11 | 2015-01-15 | 日産化学工業株式会社 | 高屈折率膜形成組成物 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02168911A (ja) * | 1988-12-22 | 1990-06-29 | Toshiba Corp | コーヒー抽出器 |
| WO1998039253A1 (fr) | 1997-03-03 | 1998-09-11 | Nissan Chemical Industries, Ltd. | Procede de production de sols de composites, de composition de revetement et d'elements optiques |
| JP4247585B2 (ja) | 1999-03-30 | 2009-04-02 | 日産化学工業株式会社 | 変性された酸化第二スズ−酸化ジルコニウム複合ゾル及びその製造法 |
| JP4730487B2 (ja) * | 1999-08-16 | 2011-07-20 | 日産化学工業株式会社 | 変性金属酸化物ゾル及びその製造方法 |
| US7556682B2 (en) | 2005-08-09 | 2009-07-07 | Nissan Chemical Industries, Ltd. | Zirconium oxide-tin oxide composite sol, coating composition and optical member |
| JP2010270191A (ja) * | 2009-05-20 | 2010-12-02 | Tokuyama Corp | コーティング組成物および光学物品 |
Citations (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2601123A (en) * | 1947-04-05 | 1952-06-17 | American Optical Corp | Composition for reducing the reflection of light |
| US2743192A (en) * | 1956-04-24 | He same | ||
| US3007878A (en) * | 1956-11-01 | 1961-11-07 | Du Pont | Aquasols of positively-charged coated silica particles and their production |
| US3412063A (en) * | 1965-09-07 | 1968-11-19 | Plas Chem Corp | Low temperature cured ceramic coating composition |
| US3751326A (en) * | 1971-07-14 | 1973-08-07 | A Marks | Hard transparent sheet-like material or coating |
| JPS4878094A (enrdf_load_stackoverflow) * | 1971-12-27 | 1973-10-19 | ||
| JPS51118728A (en) * | 1975-04-11 | 1976-10-18 | Dow Corning | Process for manufacturing silicone resin |
| JPS51126222A (en) * | 1975-03-07 | 1976-11-04 | Minnesota Mining & Mfg | Abrasionnresisting coated material |
| JPS52138564A (en) * | 1975-12-24 | 1977-11-18 | Suwa Seikosha Kk | Protective coating layer on plastic goods |
| US4084021A (en) * | 1974-10-08 | 1978-04-11 | Minnesota Mining And Manufacturing Company | Method for rendering substrates resistant to abrasion |
| JPS53130732A (en) * | 1977-03-18 | 1978-11-15 | Rohm & Haas | Weatherproof and wearrresistant coating composition and method of bonding same |
| JPS5487735A (en) * | 1977-12-23 | 1979-07-12 | Dow Corning | Aqueous coating composition free of pigment |
| JPS5487736A (en) * | 1977-12-23 | 1979-07-12 | Dow Corning | Aqueous coating composition free of pigment |
| JPS54127319A (en) * | 1978-03-13 | 1979-10-03 | Minnesota Mining & Mfg | Transparent film having video |
| JPS5510621A (en) * | 1978-07-07 | 1980-01-25 | Copyer Co Ltd | Method and device for discrimination between inside and outside bordering closed curve |
| JPS55106261A (en) * | 1979-01-15 | 1980-08-14 | Dow Corning | Composition made of dispersed body of colloid silica and colloid titania |
| JPS5684729A (en) * | 1979-11-14 | 1981-07-10 | Toray Ind Inc | Production of transparent material having excellent reflection-preventing effect |
| JPS5699236A (en) * | 1980-01-09 | 1981-08-10 | Suuedoroo Inc | Transparent antiabrasive coating composition |
| JPS5798578A (en) * | 1980-12-12 | 1982-06-18 | Mitsubishi Petrochem Co Ltd | Surface coating type waterdrop preventing agent |
-
1985
- 1985-01-23 JP JP60009247A patent/JPS60221702A/ja active Granted
Patent Citations (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2743192A (en) * | 1956-04-24 | He same | ||
| US2601123A (en) * | 1947-04-05 | 1952-06-17 | American Optical Corp | Composition for reducing the reflection of light |
| US3007878A (en) * | 1956-11-01 | 1961-11-07 | Du Pont | Aquasols of positively-charged coated silica particles and their production |
| US3412063A (en) * | 1965-09-07 | 1968-11-19 | Plas Chem Corp | Low temperature cured ceramic coating composition |
| US3751326A (en) * | 1971-07-14 | 1973-08-07 | A Marks | Hard transparent sheet-like material or coating |
| JPS4878094A (enrdf_load_stackoverflow) * | 1971-12-27 | 1973-10-19 | ||
| US4084021A (en) * | 1974-10-08 | 1978-04-11 | Minnesota Mining And Manufacturing Company | Method for rendering substrates resistant to abrasion |
| JPS51126222A (en) * | 1975-03-07 | 1976-11-04 | Minnesota Mining & Mfg | Abrasionnresisting coated material |
| JPS51118728A (en) * | 1975-04-11 | 1976-10-18 | Dow Corning | Process for manufacturing silicone resin |
| JPS52138564A (en) * | 1975-12-24 | 1977-11-18 | Suwa Seikosha Kk | Protective coating layer on plastic goods |
| JPS53130732A (en) * | 1977-03-18 | 1978-11-15 | Rohm & Haas | Weatherproof and wearrresistant coating composition and method of bonding same |
| JPS5487735A (en) * | 1977-12-23 | 1979-07-12 | Dow Corning | Aqueous coating composition free of pigment |
| JPS5487736A (en) * | 1977-12-23 | 1979-07-12 | Dow Corning | Aqueous coating composition free of pigment |
| JPS54127319A (en) * | 1978-03-13 | 1979-10-03 | Minnesota Mining & Mfg | Transparent film having video |
| JPS5510621A (en) * | 1978-07-07 | 1980-01-25 | Copyer Co Ltd | Method and device for discrimination between inside and outside bordering closed curve |
| JPS55106261A (en) * | 1979-01-15 | 1980-08-14 | Dow Corning | Composition made of dispersed body of colloid silica and colloid titania |
| JPS5684729A (en) * | 1979-11-14 | 1981-07-10 | Toray Ind Inc | Production of transparent material having excellent reflection-preventing effect |
| JPS5699236A (en) * | 1980-01-09 | 1981-08-10 | Suuedoroo Inc | Transparent antiabrasive coating composition |
| JPS5798578A (en) * | 1980-12-12 | 1982-06-18 | Mitsubishi Petrochem Co Ltd | Surface coating type waterdrop preventing agent |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6381033A (ja) * | 1986-09-25 | 1988-04-11 | Toray Ind Inc | 反射防止物品およびその製造方法 |
| JPS63197635A (ja) * | 1987-02-13 | 1988-08-16 | Toray Ind Inc | 反射防止効果を有するプラスチツク光学物品 |
| JPS63225635A (ja) * | 1987-03-16 | 1988-09-20 | Toray Ind Inc | 透明被覆成形体 |
| WO1990005315A1 (en) * | 1988-10-31 | 1990-05-17 | Sumitomo Cement Co., Ltd. | Antireflection articles, process for their production and coating composition |
| JPH0222340A (ja) * | 1989-05-29 | 1990-01-25 | Toray Ind Inc | 透明被覆層を有する成形体 |
| JPH0277434A (ja) * | 1989-05-29 | 1990-03-16 | Toray Ind Inc | 透明被覆層を有する成形体 |
| JPH0578508A (ja) * | 1992-02-13 | 1993-03-30 | Toray Ind Inc | 反射防止効果を有するプラスチツク光学物品の製造方法 |
| JPH06118203A (ja) * | 1992-10-08 | 1994-04-28 | Kureha Chem Ind Co Ltd | プラスチックレンズ |
| US6830785B1 (en) | 1995-03-20 | 2004-12-14 | Toto Ltd. | Method for photocatalytically rendering a surface of a substrate superhydrophilic, a substrate with a superhydrophilic photocatalytic surface, and method of making thereof |
| US6013372A (en) * | 1995-03-20 | 2000-01-11 | Toto, Ltd. | Method for photocatalytically rendering a surface of a substrate superhydrophilic, a substrate with superhydrophilic photocatalytic surface, and method of making thereof |
| US6090489A (en) * | 1995-12-22 | 2000-07-18 | Toto, Ltd. | Method for photocatalytically hydrophilifying surface and composite material with photocatalytically hydrophilifiable surface |
| US6524664B1 (en) | 1996-03-21 | 2003-02-25 | Toto Ltd. | Photocatalytically hydrophilifying and hydrophobifying material |
| US6165256A (en) * | 1996-07-19 | 2000-12-26 | Toto Ltd. | Photocatalytically hydrophilifiable coating composition |
| JPH10292135A (ja) * | 1997-04-18 | 1998-11-04 | Seiko Epson Corp | コーティング用組成物、その製造方法および積層体 |
| US6337129B1 (en) | 1997-06-02 | 2002-01-08 | Toto Ltd. | Antifouling member and antifouling coating composition |
| JP2000329903A (ja) * | 1999-05-18 | 2000-11-30 | Asahi Denka Kogyo Kk | 反射防止膜用剤および反射防止膜製造方法 |
| WO2004024444A1 (ja) * | 2002-09-12 | 2004-03-25 | Nippon Sheet Glass Company, Limited | 発光膜被覆物品 |
| JP2004122772A (ja) * | 2002-09-12 | 2004-04-22 | Nippon Sheet Glass Co Ltd | 発光膜被覆物品 |
| US7279236B2 (en) | 2002-09-12 | 2007-10-09 | Nippon Sheet Glass Co., Ltd. | Luminescent-film-coated product |
| US7193781B2 (en) | 2002-10-02 | 2007-03-20 | Bridgestone Corporation | Optical substrate and antireflective film |
| JP2006057106A (ja) * | 2005-10-05 | 2006-03-02 | Seiko Epson Corp | コーティング用組成物、その製造方法および積層体 |
| WO2015005333A1 (ja) * | 2013-07-11 | 2015-01-15 | 日産化学工業株式会社 | 高屈折率膜形成組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6337142B2 (enrdf_load_stackoverflow) | 1988-07-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS60221702A (ja) | 透明被覆層を有する成形体 | |
| US4374158A (en) | Process for producing transparent shaped article having enhanced anti-reflective effect | |
| JP4745324B2 (ja) | プラスチックレンズ | |
| JP2008163205A (ja) | 透明被膜形成用塗料および透明被膜付基材 | |
| JP3196558B2 (ja) | ハードコーティング剤及びハードコート膜が形成された物品 | |
| JPS6059250B2 (ja) | 反射防止性透明材料およびその製造方法 | |
| WO2016088901A1 (ja) | コーティング組成物、及び該コーティング組成物よりなるコート層を有する光学物品 | |
| JPH08295846A (ja) | コーティング用組成物および積層体 | |
| CA2302924C (en) | An optical element having cured film | |
| JPH049281B2 (enrdf_load_stackoverflow) | ||
| JP4828066B2 (ja) | コーティング組成物及びその製造方法 | |
| JPS5949501A (ja) | 反射防止膜を有する透明材料 | |
| EP0573304B1 (en) | Coating composition and lens coated therewith | |
| JPH10292135A (ja) | コーティング用組成物、その製造方法および積層体 | |
| EP0922501B1 (en) | Method of removing hard coating from plastic lens | |
| JPH06102776B2 (ja) | 硬化膜およびその硬化膜を有する光学部材 | |
| JPH0277434A (ja) | 透明被覆層を有する成形体 | |
| JPS6191601A (ja) | 反射防止性透明材料の製造方法 | |
| JPS6193402A (ja) | 反射防止性を有する染色光学物品 | |
| JPS6381033A (ja) | 反射防止物品およびその製造方法 | |
| JPS6068319A (ja) | 反射防止レンズの製造方法 | |
| JP2003292896A (ja) | コーティング用組成物および積層体 | |
| JPH0222340A (ja) | 透明被覆層を有する成形体 | |
| JPS60203679A (ja) | 反射防止性透明材料の製造方法 | |
| JPH036276A (ja) | コーティング用組成物 |