JPS60218349A - ベンズアルデヒド類の製造法 - Google Patents
ベンズアルデヒド類の製造法Info
- Publication number
- JPS60218349A JPS60218349A JP59075116A JP7511684A JPS60218349A JP S60218349 A JPS60218349 A JP S60218349A JP 59075116 A JP59075116 A JP 59075116A JP 7511684 A JP7511684 A JP 7511684A JP S60218349 A JPS60218349 A JP S60218349A
- Authority
- JP
- Japan
- Prior art keywords
- chloride
- catalyst
- benzal
- benzaldehyde
- hydrolyzing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 150000003935 benzaldehydes Chemical class 0.000 title description 6
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims abstract description 18
- -1 benzal halide Chemical class 0.000 claims abstract description 13
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims abstract description 9
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 9
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 9
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 9
- 230000003301 hydrolyzing effect Effects 0.000 claims abstract description 6
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 238000003756 stirring Methods 0.000 abstract description 4
- 239000003905 agrochemical Substances 0.000 abstract description 2
- 125000003545 alkoxy group Chemical group 0.000 abstract description 2
- 125000000217 alkyl group Chemical group 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 abstract description 2
- 239000003814 drug Substances 0.000 abstract description 2
- 239000000975 dye Substances 0.000 abstract description 2
- 125000005843 halogen group Chemical group 0.000 abstract description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 abstract description 2
- 150000004820 halides Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 10
- CAHQGWAXKLQREW-UHFFFAOYSA-N Benzal chloride Chemical class ClC(Cl)C1=CC=CC=C1 CAHQGWAXKLQREW-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 229960003280 cupric chloride Drugs 0.000 description 5
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- GHPYJLCQYMAXGG-WCCKRBBISA-N (2R)-2-amino-3-(2-boronoethylsulfanyl)propanoic acid hydrochloride Chemical compound Cl.N[C@@H](CSCCB(O)O)C(O)=O GHPYJLCQYMAXGG-WCCKRBBISA-N 0.000 description 1
- ZQNQSIPAAGRZAU-UHFFFAOYSA-N 1-(dibromomethyl)-4-fluorobenzene Chemical compound FC1=CC=C(C(Br)Br)C=C1 ZQNQSIPAAGRZAU-UHFFFAOYSA-N 0.000 description 1
- LRQSJOUIUVTBAJ-UHFFFAOYSA-N 1-(dibromomethyl)-4-methoxybenzene Chemical compound COC1=CC=C(C(Br)Br)C=C1 LRQSJOUIUVTBAJ-UHFFFAOYSA-N 0.000 description 1
- HQHJZSCJOXQOAY-UHFFFAOYSA-N 1-(dibromomethyl)-4-methylbenzene Chemical compound CC1=CC=C(C(Br)Br)C=C1 HQHJZSCJOXQOAY-UHFFFAOYSA-N 0.000 description 1
- GDZMMXXMEMTSJY-UHFFFAOYSA-N 1-(dichloromethyl)-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(C(Cl)Cl)C=C1 GDZMMXXMEMTSJY-UHFFFAOYSA-N 0.000 description 1
- PWKUMFYUILTTMD-UHFFFAOYSA-N 1-(dichloromethyl)-4-ethylbenzene Chemical compound CCC1=CC=C(C(Cl)Cl)C=C1 PWKUMFYUILTTMD-UHFFFAOYSA-N 0.000 description 1
- MFIOEEWGBMJNGG-UHFFFAOYSA-N 1-(dichloromethyl)-4-fluorobenzene Chemical compound FC1=CC=C(C(Cl)Cl)C=C1 MFIOEEWGBMJNGG-UHFFFAOYSA-N 0.000 description 1
- UKVWNSDFMYZNKC-UHFFFAOYSA-N 1-(dichloromethyl)-4-methoxybenzene Chemical compound COC1=CC=C(C(Cl)Cl)C=C1 UKVWNSDFMYZNKC-UHFFFAOYSA-N 0.000 description 1
- RGDYIHSZBVIIND-UHFFFAOYSA-N 1-(dichloromethyl)-4-methylbenzene Chemical compound CC1=CC=C(C(Cl)Cl)C=C1 RGDYIHSZBVIIND-UHFFFAOYSA-N 0.000 description 1
- GAUQRPKIMSLERN-UHFFFAOYSA-N 1-(dichloromethyl)-4-phenoxybenzene Chemical compound C1=CC(C(Cl)Cl)=CC=C1OC1=CC=CC=C1 GAUQRPKIMSLERN-UHFFFAOYSA-N 0.000 description 1
- JHUHEBLQVJNTOC-UHFFFAOYSA-N 1-chloro-4-(dibromomethyl)benzene Chemical compound ClC1=CC=C(C(Br)Br)C=C1 JHUHEBLQVJNTOC-UHFFFAOYSA-N 0.000 description 1
- VWHNJDGWDOQJRM-UHFFFAOYSA-N 1-chloro-4-(dichloromethyl)benzene Chemical compound ClC(Cl)C1=CC=C(Cl)C=C1 VWHNJDGWDOQJRM-UHFFFAOYSA-N 0.000 description 1
- FEWDXGMBVQULLN-UHFFFAOYSA-N 1-hydroxy-2-phenyl-1,5,6,7-tetrahydro-4H-benzimidazol-4-one Chemical compound ON1C=2CCCC(=O)C=2N=C1C1=CC=CC=C1 FEWDXGMBVQULLN-UHFFFAOYSA-N 0.000 description 1
- OUOHINWZCBGQDY-UHFFFAOYSA-N 1-tert-butyl-4-(dibromomethyl)benzene Chemical compound CC(C)(C)C1=CC=C(C(Br)Br)C=C1 OUOHINWZCBGQDY-UHFFFAOYSA-N 0.000 description 1
- UZTQWZWUTLLANF-UHFFFAOYSA-N 1-tert-butyl-4-(dichloromethyl)benzene Chemical compound CC(C)(C)C1=CC=C(C(Cl)Cl)C=C1 UZTQWZWUTLLANF-UHFFFAOYSA-N 0.000 description 1
- GYQNIXGSKFFVIK-UHFFFAOYSA-N 4-(dibromomethyl)benzonitrile Chemical compound BrC(Br)C1=CC=C(C#N)C=C1 GYQNIXGSKFFVIK-UHFFFAOYSA-N 0.000 description 1
- NMXMVMJWZDVFMH-UHFFFAOYSA-N 4-(dichloromethyl)benzonitrile Chemical compound ClC(Cl)C1=CC=C(C#N)C=C1 NMXMVMJWZDVFMH-UHFFFAOYSA-N 0.000 description 1
- 241000861718 Chloris <Aves> Species 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- HGFVOZQVKMBMQH-UHFFFAOYSA-N O(C1=CC=CC=C1)C1=CC=C(C(Br)Br)C=C1 Chemical compound O(C1=CC=CC=C1)C1=CC=C(C(Br)Br)C=C1 HGFVOZQVKMBMQH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 229940045803 cuprous chloride Drugs 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000003580 lung surfactant Substances 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59075116A JPS60218349A (ja) | 1984-04-16 | 1984-04-16 | ベンズアルデヒド類の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59075116A JPS60218349A (ja) | 1984-04-16 | 1984-04-16 | ベンズアルデヒド類の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60218349A true JPS60218349A (ja) | 1985-11-01 |
| JPH0461861B2 JPH0461861B2 (enrdf_load_stackoverflow) | 1992-10-02 |
Family
ID=13566894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59075116A Granted JPS60218349A (ja) | 1984-04-16 | 1984-04-16 | ベンズアルデヒド類の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60218349A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0599214A1 (de) * | 1992-11-26 | 1994-06-01 | Hoechst Aktiengesellschaft | Verfahren zur kontinuierlichen Herstellung von aromatischen Aldehyden |
| EP0599241A1 (de) * | 1992-11-26 | 1994-06-01 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung aromatischer Aldehyde |
| CN114456049A (zh) * | 2022-01-24 | 2022-05-10 | 连云港市工投集团利海化工有限公司 | 一种苯甲醛的制备方法及装置 |
-
1984
- 1984-04-16 JP JP59075116A patent/JPS60218349A/ja active Granted
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0599214A1 (de) * | 1992-11-26 | 1994-06-01 | Hoechst Aktiengesellschaft | Verfahren zur kontinuierlichen Herstellung von aromatischen Aldehyden |
| EP0599241A1 (de) * | 1992-11-26 | 1994-06-01 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung aromatischer Aldehyde |
| US5347054A (en) * | 1992-11-26 | 1994-09-13 | Hoechst Aktiengesellschaft | Process for preparing aromatic aldehydes |
| US5382694A (en) * | 1992-11-26 | 1995-01-17 | Hoechst Aktiengesellschaft | Process for the continuous production of aromatic aldehydes |
| EP0599241B2 (de) † | 1992-11-26 | 2001-01-24 | Clariant GmbH | Verfahren zur Herstellung aromatischer Aldehyde |
| CN114456049A (zh) * | 2022-01-24 | 2022-05-10 | 连云港市工投集团利海化工有限公司 | 一种苯甲醛的制备方法及装置 |
| CN114456049B (zh) * | 2022-01-24 | 2023-02-17 | 连云港市工投集团利海化工有限公司 | 一种苯甲醛的制备装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0461861B2 (enrdf_load_stackoverflow) | 1992-10-02 |
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