JPS5940057B2 - エタノ−ルからのエチレン製造用触媒 - Google Patents
エタノ−ルからのエチレン製造用触媒Info
- Publication number
- JPS5940057B2 JPS5940057B2 JP54068362A JP6836279A JPS5940057B2 JP S5940057 B2 JPS5940057 B2 JP S5940057B2 JP 54068362 A JP54068362 A JP 54068362A JP 6836279 A JP6836279 A JP 6836279A JP S5940057 B2 JPS5940057 B2 JP S5940057B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- alumina
- ethanol
- catalysts
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 53
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims description 24
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 14
- 239000005977 Ethylene Substances 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 32
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 229910001463 metal phosphate Inorganic materials 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000004898 kneading Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- MHJAJDCZWVHCPF-UHFFFAOYSA-L dimagnesium phosphate Chemical compound [Mg+2].OP([O-])([O-])=O MHJAJDCZWVHCPF-UHFFFAOYSA-L 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
- C07C2527/16—Phosphorus; Compounds thereof containing oxygen
- C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54068362A JPS5940057B2 (ja) | 1979-05-31 | 1979-05-31 | エタノ−ルからのエチレン製造用触媒 |
| US06/142,910 US4302357A (en) | 1979-05-31 | 1980-04-23 | Catalyst for production of ethylene from ethanol |
| GB8014552A GB2049645B (en) | 1979-05-31 | 1980-05-01 | Activated alumina catalyst for the conversion of ethanol to ethylene |
| IN505/CAL/80A IN153076B (index.php) | 1979-05-31 | 1980-05-02 | |
| DE3017501A DE3017501C2 (de) | 1979-05-31 | 1980-05-07 | Verwendung von hochreinem, aktiviertem Aluminiumoxid als Katalysator für die Herstellung von Äthylen |
| DE3050706A DE3050706C2 (de) | 1979-05-31 | 1980-05-07 | Katalysator für die Herstellung von Äthylen |
| BR8003367A BR8003367A (pt) | 1979-05-31 | 1980-05-29 | Catalisador para a producao de etileno pela desidratacao de etanol |
| FR8012052A FR2457848A1 (fr) | 1979-05-31 | 1980-05-30 | Catalyseur pour la production d'ethylene a partir d'ethanol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54068362A JPS5940057B2 (ja) | 1979-05-31 | 1979-05-31 | エタノ−ルからのエチレン製造用触媒 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55159840A JPS55159840A (en) | 1980-12-12 |
| JPS5940057B2 true JPS5940057B2 (ja) | 1984-09-27 |
Family
ID=13371598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54068362A Expired JPS5940057B2 (ja) | 1979-05-31 | 1979-05-31 | エタノ−ルからのエチレン製造用触媒 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4302357A (index.php) |
| JP (1) | JPS5940057B2 (index.php) |
| BR (1) | BR8003367A (index.php) |
| DE (2) | DE3017501C2 (index.php) |
| FR (1) | FR2457848A1 (index.php) |
| GB (1) | GB2049645B (index.php) |
| IN (1) | IN153076B (index.php) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60176734U (ja) * | 1984-04-27 | 1985-11-22 | オルゴ株式会社 | ポツトの提げ手 |
| US9968914B2 (en) | 2012-12-26 | 2018-05-15 | Kao Corporation | Method for producing olefin |
| WO2019053956A1 (ja) | 2017-09-12 | 2019-03-21 | 花王株式会社 | オレフィンの製造方法 |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE141579T1 (de) * | 1991-02-04 | 1996-09-15 | Mitsui Petrochemical Ind | Verfahren zur herstellung von propylene |
| US20060149109A1 (en) * | 2004-12-30 | 2006-07-06 | Ruziska Philip A | Converting methanol and ethanol to light olefins |
| MX2009000712A (es) | 2006-07-21 | 2009-03-23 | Xyleco Inc | Sistemas para conversion de biomasa. |
| CN101121624B (zh) * | 2006-08-11 | 2010-09-08 | 中国石油化工股份有限公司 | 乙醇脱水制乙烯的方法 |
| CN100582066C (zh) * | 2007-10-16 | 2010-01-20 | 南京工业大学 | 一种乙醇脱水生产乙烯的工艺 |
| EP2108636A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Dehydration of alcohols in the presence of an inert component. |
| EP2108635A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol |
| EP2108637A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol. |
| EP2090561A1 (en) | 2008-02-07 | 2009-08-19 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| EP2108634A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| JP5071175B2 (ja) * | 2008-03-11 | 2012-11-14 | 東ソー株式会社 | エチレンの製造法 |
| JP5071174B2 (ja) * | 2008-03-11 | 2012-11-14 | 東ソー株式会社 | エチレンの製法 |
| MY154353A (en) | 2008-11-28 | 2015-05-29 | Total Petrochemicals Res Feluy | Purfication of alcohols prior to their use in the presence of an acid catalyst |
| EP2192101A1 (en) | 2008-11-28 | 2010-06-02 | Total Petrochemicals Research Feluy | Purification of alcohols prior to their use in the presence of an acid catalyst |
| RU2438775C1 (ru) * | 2010-04-30 | 2012-01-10 | Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН | Катализатор, способ его приготовления и способ получения этилена |
| EA023440B1 (ru) * | 2010-06-23 | 2016-06-30 | Тотал Ресерч Энд Текнолоджи Фелюи | Дегидратация спиртов на отравленных кислотных катализаторах |
| EP3080059B1 (en) | 2013-12-13 | 2023-12-13 | Dow Global Technologies LLC | Alkanol to alkylene conversion using at least two different catalysts in sequential order |
| RU2609263C1 (ru) * | 2015-09-03 | 2017-01-31 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук | Катализатор процесса дегидратации этанола в этилен, способ его приготовления и способ получения этилена |
| US11260367B2 (en) | 2018-12-12 | 2022-03-01 | Instituto Nacional De Tecnologia | Catalytic system and process for the production of light olefins from ethanol |
| EP4038040A4 (en) | 2019-09-30 | 2024-01-10 | GEVO, Inc. | SIMULTANEOUS DEHYDRATION, DIMERIZATION AND METATHESIS OF C2-C5 ALCOHOLS |
| JP2024515717A (ja) | 2021-04-23 | 2024-04-10 | ジーヴォ，インコーポレイテッド | Ｃ１～ｃ５アルコールをｃ２～ｃ５オレフィン混合物に触媒転化させるためのシステムおよび方法 |
| WO2024091452A1 (en) | 2022-10-27 | 2024-05-02 | Gevo, Inc. | Processes for catalytic conversion of c1-c5 alcohols to c2-c5 olefin mixtures |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA457938A (en) * | 1949-07-05 | Shell Development Company | Process for producing monoolefins | |
| US1913938A (en) * | 1929-06-11 | 1933-06-13 | Air Reduction | Catalytic material and method of producing same |
| US2204157A (en) * | 1938-08-16 | 1940-06-11 | Goodrich Co B F | Catalyst and method of producing the same |
| GB586494A (en) * | 1944-10-27 | 1947-03-20 | Frederick Joseph Leigh Bentley | Improvements in or relating to alumina catalysts |
| BE498292A (index.php) * | 1949-09-23 | |||
| DE1142343B (de) * | 1958-01-29 | 1963-01-17 | Pechiney Prod Chimiques Sa | Verfahren zur Herstellung von aus aktiver Tonerde bestehenden Dehydratisierungskatalysatoren aus dem beim Bayerverfahren anfallenden rohen Tonerdealphatrihydrat |
| US3249557A (en) * | 1962-06-25 | 1966-05-03 | Socony Mobil Oil Co Inc | Process for producing an alumina catalyst base |
| FR2087011A5 (index.php) * | 1970-04-16 | 1971-12-31 | Raffinage Cie Francaise | |
| US3637406A (en) * | 1970-12-23 | 1972-01-25 | American Lava Corp | Ultrapure alumina ceramics formed by coprecipitation |
| US4207424A (en) * | 1978-08-09 | 1980-06-10 | Halcon Research & Development Corporation | Catalytic process for dehydration of alcohols |
-
1979
- 1979-05-31 JP JP54068362A patent/JPS5940057B2/ja not_active Expired
-
1980
- 1980-04-23 US US06/142,910 patent/US4302357A/en not_active Expired - Lifetime
- 1980-05-01 GB GB8014552A patent/GB2049645B/en not_active Expired
- 1980-05-02 IN IN505/CAL/80A patent/IN153076B/en unknown
- 1980-05-07 DE DE3017501A patent/DE3017501C2/de not_active Expired
- 1980-05-07 DE DE3050706A patent/DE3050706C2/de not_active Expired
- 1980-05-29 BR BR8003367A patent/BR8003367A/pt not_active IP Right Cessation
- 1980-05-30 FR FR8012052A patent/FR2457848A1/fr active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60176734U (ja) * | 1984-04-27 | 1985-11-22 | オルゴ株式会社 | ポツトの提げ手 |
| US9968914B2 (en) | 2012-12-26 | 2018-05-15 | Kao Corporation | Method for producing olefin |
| WO2019053956A1 (ja) | 2017-09-12 | 2019-03-21 | 花王株式会社 | オレフィンの製造方法 |
| US11078129B2 (en) | 2017-09-12 | 2021-08-03 | Kao Corporation | Method for producing olefin |
Also Published As
| Publication number | Publication date |
|---|---|
| IN153076B (index.php) | 1984-05-26 |
| DE3017501C2 (de) | 1985-03-28 |
| GB2049645A (en) | 1980-12-31 |
| GB2049645B (en) | 1983-05-25 |
| FR2457848A1 (fr) | 1980-12-26 |
| JPS55159840A (en) | 1980-12-12 |
| DE3017501A1 (de) | 1980-12-18 |
| US4302357A (en) | 1981-11-24 |
| DE3050706C2 (de) | 1987-02-05 |
| FR2457848B1 (index.php) | 1983-01-21 |
| BR8003367A (pt) | 1980-12-30 |
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