JPS5923860B2 - 触媒支持体及びその製造方法 - Google Patents
触媒支持体及びその製造方法Info
- Publication number
- JPS5923860B2 JPS5923860B2 JP52101029A JP10102977A JPS5923860B2 JP S5923860 B2 JPS5923860 B2 JP S5923860B2 JP 52101029 A JP52101029 A JP 52101029A JP 10102977 A JP10102977 A JP 10102977A JP S5923860 B2 JPS5923860 B2 JP S5923860B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- aqueous solution
- precipitate
- pores
- catalyst support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 35
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 239000011148 porous material Substances 0.000 claims description 91
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 39
- 239000000243 solution Substances 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 30
- 229910001868 water Inorganic materials 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 229910052698 phosphorus Inorganic materials 0.000 claims description 22
- 239000011574 phosphorus Substances 0.000 claims description 22
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 18
- 239000002244 precipitate Substances 0.000 claims description 17
- 238000009826 distribution Methods 0.000 claims description 14
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 150000004645 aluminates Chemical class 0.000 claims description 9
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 9
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 8
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 8
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 8
- -1 aluminum aluminate Chemical class 0.000 claims description 8
- 239000000908 ammonium hydroxide Substances 0.000 claims description 8
- 239000000174 gluconic acid Substances 0.000 claims description 8
- 235000012208 gluconic acid Nutrition 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 7
- 229910052753 mercury Inorganic materials 0.000 claims description 7
- 238000001179 sorption measurement Methods 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- 229910052593 corundum Inorganic materials 0.000 claims description 5
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 2
- 150000003017 phosphorus Chemical class 0.000 claims description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 5
- 230000002378 acidificating effect Effects 0.000 claims 3
- 229910001387 inorganic aluminate Inorganic materials 0.000 claims 3
- 238000007493 shaping process Methods 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 235000019837 monoammonium phosphate Nutrition 0.000 claims 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 239000000499 gel Substances 0.000 description 16
- 239000000843 powder Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 8
- 239000002002 slurry Substances 0.000 description 7
- 239000007921 spray Substances 0.000 description 6
- 235000012438 extruded product Nutrition 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000006477 desulfuration reaction Methods 0.000 description 4
- 230000023556 desulfurization Effects 0.000 description 4
- 238000004455 differential thermal analysis Methods 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000006187 pill Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007613 slurry method Methods 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 description 2
- 238000002411 thermogravimetry Methods 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 229910019670 (NH4)H2PO4 Inorganic materials 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 101000965313 Legionella pneumophila subsp. pneumophila (strain Philadelphia 1 / ATCC 33152 / DSM 7513) Aconitate hydratase A Proteins 0.000 description 1
- 229910017974 NH40H Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 1
- 238000002003 electron diffraction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
- B01J35/67—Pore distribution monomodal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US000000731128 | 1976-10-12 | ||
| US05/731,128 US4066572A (en) | 1976-10-12 | 1976-10-12 | Phospha-alumina gel and method of preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5347390A JPS5347390A (en) | 1978-04-27 |
| JPS5923860B2 true JPS5923860B2 (ja) | 1984-06-05 |
Family
ID=24938186
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52101029A Expired JPS5923860B2 (ja) | 1976-10-12 | 1977-08-23 | 触媒支持体及びその製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4066572A (Direct) |
| JP (1) | JPS5923860B2 (Direct) |
| BE (1) | BE857931A (Direct) |
| DE (1) | DE2737380C3 (Direct) |
| FR (1) | FR2367534A1 (Direct) |
| GB (1) | GB1547347A (Direct) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61178203U (Direct) * | 1985-04-24 | 1986-11-07 | ||
| JP2005169232A (ja) * | 2003-12-10 | 2005-06-30 | Petroleum Energy Center | 炭化水素油の水素化脱硫触媒及びその製造方法 |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4233184A (en) * | 1979-01-18 | 1980-11-11 | Exxon Research & Engineering Co. | Aluminum phosphate-alumina compositions and catalysts comprising the same |
| JPS5941663B2 (ja) * | 1979-07-20 | 1984-10-08 | 住友化学工業株式会社 | 樹脂組成物の製造法 |
| FR2486094B1 (Direct) * | 1980-07-02 | 1985-03-22 | Catalyse Soc Prod Francais | |
| US4310440A (en) * | 1980-07-07 | 1982-01-12 | Union Carbide Corporation | Crystalline metallophosphate compositions |
| US4456699A (en) * | 1981-06-17 | 1984-06-26 | Standard Oil Company (Indiana) | Catalyst and support, and their methods of preparation |
| CA1187864A (en) * | 1981-06-17 | 1985-05-28 | Standard Oil Company | Catalyst and support, their methods of preparation, and processes employing same |
| US4395328A (en) * | 1981-06-17 | 1983-07-26 | Standard Oil Company (Indiana) | Catalyst and support, their methods of preparation, and processes employing same |
| US4399057A (en) * | 1981-06-17 | 1983-08-16 | Standard Oil Company (Indiana) | Catalyst and support, their methods of preparation, and processes employing same |
| US4382878A (en) * | 1981-06-22 | 1983-05-10 | Gulf Research & Development Company | Catalytic supports with controlled pore properties |
| US4407730A (en) * | 1981-06-22 | 1983-10-04 | Gulf Research & Development Co. | Catalytic supports with controlled pore properties |
| US4382877A (en) * | 1981-06-22 | 1983-05-10 | Gulf Research & Development Company | Catalytic supports with controlled pore properties |
| US4407732A (en) * | 1981-06-22 | 1983-10-04 | Gulf Research & Development Company | Catalytic supports with controlled pore properties |
| US4473663A (en) * | 1983-03-31 | 1984-09-25 | Union Carbide Corporation | Crystalline aluminophosphate compositions |
| US4818743A (en) * | 1983-04-07 | 1989-04-04 | Union Oil Company Of California | Desulfurization catalyst and the catalyst prepared by a method |
| DE3330944C1 (de) * | 1983-08-27 | 1985-02-21 | Boehringer Ingelheim International GmbH, 6507 Ingelheim | Basisches Aluminiumphosphat-Gel,seine Herstellung und Verwendung |
| US4845069A (en) * | 1983-09-29 | 1989-07-04 | The Dow Chemical Company | Porous amorphous metallo phosphates process for preparing porous amorphous metallo phosphates |
| US4837192A (en) * | 1983-10-18 | 1989-06-06 | Phillips Petroleum Company | Catalyst composition |
| US4965236A (en) * | 1983-10-18 | 1990-10-23 | Phillips Petroleum Company | Process for producing a catalyst |
| US4520128A (en) * | 1983-12-19 | 1985-05-28 | Intevep, S.A. | Catalyst having high metal retention capacity and good stability for use in the demetallization of heavy crudes and method of preparation of same |
| US4629716A (en) * | 1985-04-15 | 1986-12-16 | Shell Oil Company | Process for producing narrow-pore catalyst supports |
| US4624938A (en) * | 1985-04-26 | 1986-11-25 | Shell Oil Company | Process for producing wide-pore catalyst supports |
| US4629717A (en) * | 1985-06-11 | 1986-12-16 | Uop Inc. | Phosphorus-modified alumina composite, method of manufacture and use thereof |
| US4758544A (en) * | 1985-07-17 | 1988-07-19 | Chevron Research Company | Catalyst composition and hydroprocessing of oils using same |
| JPH0685875B2 (ja) * | 1985-08-05 | 1994-11-02 | 触媒化成工業株式会社 | 炭化水素油の接触分解用触媒と接触分解法 |
| DE3683816D1 (de) * | 1985-08-29 | 1992-03-19 | Grace W R & Co | Aluminiumphosphat mit einem hohen porenvolumen. |
| US5292701A (en) * | 1985-08-29 | 1994-03-08 | W. R. Grace & Co.-Conn. | High pore volume and pore diameter aluminum phosphate and method of making the same |
| US4861460A (en) * | 1986-10-28 | 1989-08-29 | Shell Oil Company | Hydrotreating with wide-pore hydrogel-derived catalysts |
| US4832827A (en) * | 1986-10-28 | 1989-05-23 | Shell Oil Company | Hydrotreating with catalysts prepared from hydrogels |
| US4716141A (en) * | 1986-10-28 | 1987-12-29 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
| US4717706A (en) * | 1986-10-28 | 1988-01-05 | Shell Oil Company | Wide-pore hydrogel-derived catalysts |
| US4717698A (en) * | 1986-10-28 | 1988-01-05 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
| US4738945A (en) * | 1986-10-28 | 1988-04-19 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
| US4717707A (en) * | 1986-10-28 | 1988-01-05 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
| US4839028A (en) * | 1986-10-28 | 1989-06-13 | Shell Oil Company | Hydrotreating with catalysts prepared from hydrogels |
| CA1304347C (en) * | 1986-10-28 | 1992-06-30 | Richard Alan Kemp | Process for the preparation of hydrotreating catalysts from hydrogels |
| CA1312595C (en) * | 1986-10-28 | 1993-01-12 | Richard Alan Kemp | Process for the preparation of hydrotreating catalysts from hydrogels |
| US4717705A (en) * | 1986-10-28 | 1988-01-05 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
| US4786404A (en) * | 1986-10-28 | 1988-11-22 | Shell Oil Company | Process for hydrotreating hydrocarbon feeds |
| US4786403A (en) * | 1986-10-28 | 1988-11-22 | Shell Oil Company | Process for hydrotreating hydro carbon feeds |
| US4716140A (en) * | 1986-10-28 | 1987-12-29 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
| US4717704A (en) * | 1986-10-28 | 1988-01-05 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
| US4754099A (en) * | 1987-05-27 | 1988-06-28 | Shell Oil Company | Disproportionation of olefins |
| US4853108A (en) * | 1987-06-29 | 1989-08-01 | Shell Oil Company | Process for hydrotreating hydrocarbon feeds |
| US4880524A (en) * | 1987-11-20 | 1989-11-14 | Shell Oil Company | Process for hydrotreating hydrocarbon feeds |
| US4820679A (en) * | 1987-11-20 | 1989-04-11 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
| DE68913781T2 (de) * | 1988-03-30 | 1994-07-14 | Sumitomo Chemical Co | Thermoplastische Harzmasse. |
| US5175211A (en) * | 1988-04-14 | 1992-12-29 | Sumitomo Chemical Co., Ltd. | Thermoplastic resin composition |
| DE3813354A1 (de) * | 1988-04-21 | 1989-11-02 | Huels Chemische Werke Ag | Thermoplastische formmassen auf basis von funktionalisierten polyphenylenethern und polyamiden |
| US5039644A (en) * | 1989-01-10 | 1991-08-13 | Corning Incorporated | Phosphate-containing ceramic structures for catalyst support and fluid filtering |
| US5124302A (en) * | 1989-01-10 | 1992-06-23 | Corning Incorporated | Phosphate-containing structures with catalytic material distributed throughout |
| CA2093412C (en) * | 1992-04-20 | 2002-12-31 | Gerald Verdell Nelson | Novel hydroconversion process employing catalyst with specified pore size distribution |
| US5260241A (en) * | 1992-08-12 | 1993-11-09 | Corning Incorporated | Controlled pore size phosphate-alumina material and method for producing same |
| US5397456A (en) * | 1993-02-19 | 1995-03-14 | Texaco Inc. | Hydroconversion process employing catalyst with specified pore size distribution |
| US5753716A (en) * | 1997-02-21 | 1998-05-19 | Air Products And Chemicals, Inc. | Use of aluminum phosphate as the dehydration catalyst in single step dimethyl ether process |
| DE69925580D1 (de) * | 1998-12-08 | 2005-07-07 | Japan Energy Corp | Katalysator zur hydrodesulforierung und verfahren zu seiner herstellung |
| JP4472556B2 (ja) * | 2004-03-26 | 2010-06-02 | コスモ石油株式会社 | 炭化水素油の水素化処理触媒及びその製造方法並びに炭化水素油の水素化処理方法 |
| WO2014102388A2 (en) * | 2012-12-31 | 2014-07-03 | M-I Drilling Fluids Uk Limited | Shale hydration inhibitor complex for aqueous wellbore fluids |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2938874A (en) * | 1956-06-20 | 1960-05-31 | Socony Mobil Oil Co Inc | Preparation of phosphate-containing alumina gels |
| NL255524A (Direct) * | 1959-09-03 | |||
| US3342750A (en) * | 1965-04-01 | 1967-09-19 | Exxon Research Engineering Co | Compositions containing stable aluminum phosphate gel and methods of making and using same |
| US3664968A (en) * | 1967-11-16 | 1972-05-23 | Goodrich Co B F | Catalyst for preparing unsaturated acids and aldehydes |
| US3974233A (en) * | 1972-08-17 | 1976-08-10 | Bp Chemicals International Limited | Process for the production of a rhenium heptoxide/alumina disproportionation catalyst |
| US3904550A (en) * | 1973-10-19 | 1975-09-09 | Exxon Research Engineering Co | Hydrocarbon conversion catalyst comprising alumina and aluminum phosphate |
| US3969273A (en) * | 1975-04-24 | 1976-07-13 | W. R. Grace & Co. | Process for preparing phosphated alumina extrudates |
-
1976
- 1976-10-12 US US05/731,128 patent/US4066572A/en not_active Expired - Lifetime
-
1977
- 1977-07-27 GB GB31607/77A patent/GB1547347A/en not_active Expired
- 1977-08-16 DE DE2737380A patent/DE2737380C3/de not_active Expired
- 1977-08-18 FR FR7725271A patent/FR2367534A1/fr active Granted
- 1977-08-19 BE BE1008333A patent/BE857931A/xx not_active IP Right Cessation
- 1977-08-23 JP JP52101029A patent/JPS5923860B2/ja not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61178203U (Direct) * | 1985-04-24 | 1986-11-07 | ||
| JP2005169232A (ja) * | 2003-12-10 | 2005-06-30 | Petroleum Energy Center | 炭化水素油の水素化脱硫触媒及びその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1547347A (en) | 1979-06-13 |
| FR2367534A1 (fr) | 1978-05-12 |
| DE2737380C3 (de) | 1982-03-18 |
| US4066572A (en) | 1978-01-03 |
| FR2367534B1 (Direct) | 1981-11-27 |
| DE2737380B2 (de) | 1981-03-12 |
| DE2737380A1 (de) | 1978-04-13 |
| JPS5347390A (en) | 1978-04-27 |
| BE857931A (fr) | 1978-02-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS5923860B2 (ja) | 触媒支持体及びその製造方法 | |
| CA1073435A (en) | Thermally stable phosphate containing alumina precipitates and their method of preparation | |
| US4629717A (en) | Phosphorus-modified alumina composite, method of manufacture and use thereof | |
| US3287280A (en) | Hydrodesulfurization catalyst and process for preparing the same | |
| CN100368076C (zh) | 非常均匀的非晶形氧化硅-氧化铝组合物的制备方法 | |
| CA1233810A (en) | Catalyst composition suitable for synthesis of methanol | |
| US3544452A (en) | Fluorine and metal phosphate-containing catalysts and preparation and use thereof | |
| US4727209A (en) | Hydrocarbon alkylation processes employing a phosphorus-modified alumina composite | |
| CN104884166B (zh) | 烃转化催化剂的制备 | |
| JPS594182B2 (ja) | 重質炭化水素油の水素化処理用触媒およびその製造法 | |
| US10807076B2 (en) | Mesoporous FCC catalysts with excellent attrition resistance | |
| JPS61254254A (ja) | 広い細孔の触媒支持体の製造方法 | |
| JPS595011B2 (ja) | 重質炭化水素油の水素化処理用触媒ならびにその製法 | |
| JP2000515844A (ja) | ゼオライトの製造 | |
| US3726790A (en) | Hydrotreating high-nitrogen feedstocks with hydrodenitrogenation and hydrocracking catalyst | |
| CN115805099A (zh) | 一种最大化丙烯辛烷值助剂及其制备方法 | |
| KR20000068567A (ko) | 촉매 담체용 의사 베마이트 분말 및 그 제조 방법 | |
| CN109312238A (zh) | 具有衍生自结晶勃姆石的氧化铝的fcc催化剂 | |
| JPH01171640A (ja) | 流動層反応に適する鉄・アンチモン・リン含有触媒の製法 | |
| JP2949346B2 (ja) | ヒドロゲルからの水素化処理用触媒の製造方法 | |
| JP3881162B2 (ja) | 水素化処理成形触媒およびその製造方法 | |
| US3682836A (en) | Metal phosphate-containing catalysts and preparation | |
| US4699893A (en) | Fluid cracking catalyst and method of making same from waste catalyst manufacture fines | |
| CN109641193A (zh) | 具有多于一种二氧化硅的fcc催化剂、其制备和使用 | |
| JP2822044B2 (ja) | ヒドロゲルからの水素化処理用触媒の製造方法 |