JPS59185770A - 化学ニツケルめつき浴の廃液からニツケルを回収する方法 - Google Patents
化学ニツケルめつき浴の廃液からニツケルを回収する方法Info
- Publication number
- JPS59185770A JPS59185770A JP58060422A JP6042283A JPS59185770A JP S59185770 A JPS59185770 A JP S59185770A JP 58060422 A JP58060422 A JP 58060422A JP 6042283 A JP6042283 A JP 6042283A JP S59185770 A JPS59185770 A JP S59185770A
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- oxalate
- waste
- acid
- soln
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 44
- 239000002699 waste material Substances 0.000 title claims abstract description 24
- 238000007747 plating Methods 0.000 title claims abstract description 19
- 239000000126 substance Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 11
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910001453 nickel ion Inorganic materials 0.000 claims abstract description 19
- DOLZKNFSRCEOFV-UHFFFAOYSA-L nickel(2+);oxalate Chemical compound [Ni+2].[O-]C(=O)C([O-])=O DOLZKNFSRCEOFV-UHFFFAOYSA-L 0.000 claims abstract description 19
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000008139 complexing agent Substances 0.000 claims abstract description 11
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 9
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 8
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims abstract description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 12
- 239000011574 phosphorus Substances 0.000 claims description 12
- 150000007524 organic acids Chemical class 0.000 claims description 7
- 230000032683 aging Effects 0.000 claims description 5
- 239000002351 wastewater Substances 0.000 claims description 4
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 21
- 239000007788 liquid Substances 0.000 description 18
- 238000011282 treatment Methods 0.000 description 11
- 239000002244 precipitate Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000005868 electrolysis reaction Methods 0.000 description 5
- XWKBMOUUGHARTI-UHFFFAOYSA-N tricalcium;diphosphite Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])[O-].[O-]P([O-])[O-] XWKBMOUUGHARTI-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 3
- 239000001354 calcium citrate Substances 0.000 description 3
- 239000002659 electrodeposit Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 235000013337 tricalcium citrate Nutrition 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000007743 anodising Methods 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229960002713 calcium chloride Drugs 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- QXDMQSPYEZFLGF-UHFFFAOYSA-L calcium oxalate Chemical compound [Ca+2].[O-]C(=O)C([O-])=O QXDMQSPYEZFLGF-UHFFFAOYSA-L 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- -1 hypophosphite ions Chemical class 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 2
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 1
- DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical compound O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229940000488 arsenic acid Drugs 0.000 description 1
- 239000003788 bath preparation Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- LLSDKQJKOVVTOJ-UHFFFAOYSA-L calcium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ca+2] LLSDKQJKOVVTOJ-UHFFFAOYSA-L 0.000 description 1
- 229940052299 calcium chloride dihydrate Drugs 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940116298 l- malic acid Drugs 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/32—Carboxylic acids
- C22B3/322—Oxalic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Chemically Coating (AREA)
- Removal Of Specific Substances (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58060422A JPS59185770A (ja) | 1983-04-05 | 1983-04-05 | 化学ニツケルめつき浴の廃液からニツケルを回収する方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58060422A JPS59185770A (ja) | 1983-04-05 | 1983-04-05 | 化学ニツケルめつき浴の廃液からニツケルを回収する方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59185770A true JPS59185770A (ja) | 1984-10-22 |
| JPH0223236B2 JPH0223236B2 (enrdf_load_stackoverflow) | 1990-05-23 |
Family
ID=13141754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58060422A Granted JPS59185770A (ja) | 1983-04-05 | 1983-04-05 | 化学ニツケルめつき浴の廃液からニツケルを回収する方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59185770A (enrdf_load_stackoverflow) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4954265A (en) * | 1989-02-01 | 1990-09-04 | Environmental Recovery Systems, Inc. | Method of processing spent electroless bath and bath for use therein |
| JPH0834604A (ja) * | 1994-07-27 | 1996-02-06 | Taihei Kagaku Sangyo Kk | 有価物の回収方法 |
| US6659171B2 (en) * | 2001-03-27 | 2003-12-09 | Nippon Paint Co., Ltd. | Hydrophilic modification method and heat exchanger treated thereby |
| CN102409178A (zh) * | 2011-11-28 | 2012-04-11 | 镇江中孚复合材料有限公司 | 一种从高温合金废料中回收铁钴镍金属产品的方法 |
| JP2016005825A (ja) * | 2014-06-20 | 2016-01-14 | 住友金属鉱山株式会社 | 有機酸含有廃液の処理方法 |
| CN106148709A (zh) * | 2016-08-12 | 2016-11-23 | 星特殊化学品（新加坡）有限公司 | 化学镀镍废液中的镍回收处理方法 |
| JP2017119891A (ja) * | 2015-12-28 | 2017-07-06 | 国立大学法人山形大学 | シュウ酸塩の分解方法、及びシュウ酸塩の分解のための錯化合物 |
| RU2644471C2 (ru) * | 2016-06-28 | 2018-02-12 | Акционерное общество "Калужский научно-исследовательский институт телемеханических устройств" | Способ утилизации отработанного раствора анодного оксидирования алюминия и его сплавов |
| JP2019137879A (ja) * | 2018-02-07 | 2019-08-22 | 上田石灰製造株式会社 | 有価金属の回収方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51125606A (en) * | 1975-02-25 | 1976-11-02 | Toray Ind Inc | A method of fractional recovery of heavy metals |
-
1983
- 1983-04-05 JP JP58060422A patent/JPS59185770A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51125606A (en) * | 1975-02-25 | 1976-11-02 | Toray Ind Inc | A method of fractional recovery of heavy metals |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4954265A (en) * | 1989-02-01 | 1990-09-04 | Environmental Recovery Systems, Inc. | Method of processing spent electroless bath and bath for use therein |
| JPH0834604A (ja) * | 1994-07-27 | 1996-02-06 | Taihei Kagaku Sangyo Kk | 有価物の回収方法 |
| US6659171B2 (en) * | 2001-03-27 | 2003-12-09 | Nippon Paint Co., Ltd. | Hydrophilic modification method and heat exchanger treated thereby |
| CN102409178A (zh) * | 2011-11-28 | 2012-04-11 | 镇江中孚复合材料有限公司 | 一种从高温合金废料中回收铁钴镍金属产品的方法 |
| JP2016005825A (ja) * | 2014-06-20 | 2016-01-14 | 住友金属鉱山株式会社 | 有機酸含有廃液の処理方法 |
| JP2017119891A (ja) * | 2015-12-28 | 2017-07-06 | 国立大学法人山形大学 | シュウ酸塩の分解方法、及びシュウ酸塩の分解のための錯化合物 |
| RU2644471C2 (ru) * | 2016-06-28 | 2018-02-12 | Акционерное общество "Калужский научно-исследовательский институт телемеханических устройств" | Способ утилизации отработанного раствора анодного оксидирования алюминия и его сплавов |
| CN106148709A (zh) * | 2016-08-12 | 2016-11-23 | 星特殊化学品（新加坡）有限公司 | 化学镀镍废液中的镍回收处理方法 |
| CN106148709B (zh) * | 2016-08-12 | 2018-01-05 | 星特殊化学品（新加坡）有限公司 | 化学镀镍废液中的镍回收处理方法 |
| JP2019137879A (ja) * | 2018-02-07 | 2019-08-22 | 上田石灰製造株式会社 | 有価金属の回収方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0223236B2 (enrdf_load_stackoverflow) | 1990-05-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101636353B (zh) | 化学镀镍废物的回收方法 | |
| US3770630A (en) | Treatment of electroless process and stripping solutions | |
| JPS5948155B2 (ja) | 廃液の処理方法 | |
| JPS59185770A (ja) | 化学ニツケルめつき浴の廃液からニツケルを回収する方法 | |
| US4789484A (en) | Treatment of electroless nickel plating baths | |
| US2845330A (en) | Method of recovering cyanides from waste aqueous solutions containing metal cyanides | |
| US4698162A (en) | Method for prevention of metallic precipitate reoxidation/redissolution in aqueous systems | |
| CN113562877B (zh) | 一种含EDTA-Ni废水的处理方法 | |
| KR20090069231A (ko) | 구리 소지용 치환 금도금액 및 이를 이용한 금도금 방법 | |
| JPS62243776A (ja) | 無電解銅メッキ浴の再生方法 | |
| US4238300A (en) | Gold electroplating process | |
| CN119392343B (zh) | 一种电镀镍磷合金废液的再生方法 | |
| CN111039459A (zh) | 一种含间-硝基苯磺酸钠的退镀镍废水的处理工艺 | |
| JPS6141774A (ja) | 水性・無電解ニツケル改良浴及び方法 | |
| US2861927A (en) | Process for adjusting the components in aqueous alkali cyanide electrolytes | |
| JP3111614B2 (ja) | 無電解ニッケルめっき浴の再生方法 | |
| JPH0361380A (ja) | 無電解すずめっき浴 | |
| JPH06173024A (ja) | ぶりき材表面処理液及び表面処理方法 | |
| JPS637894A (ja) | 廃液の処理方法 | |
| JPH08158060A (ja) | アルミニウムの無電解ニッケルめっき方法 | |
| JPS5854629B2 (ja) | 重金属錯塩を含有する廃液の処理方法 | |
| JPS60145378A (ja) | 無電解メツキ老化液の再生方法 | |
| JPS622879B2 (enrdf_load_stackoverflow) | ||
| JP3448730B2 (ja) | 次亜リン酸及び亜リン酸廃液の処理法 | |
| JP2902335B2 (ja) | 無電解ニッケルめっき浴または無電解ニッケル合金めっき浴の再生方法 |