JPS59167969A - 非水電解液電池 - Google Patents

Info

Publication number

JPS59167969A

JPS59167969A JP58041095A JP4109583A JPS59167969A JP S59167969 A JPS59167969 A JP S59167969A JP 58041095 A JP58041095 A JP 58041095A JP 4109583 A JP4109583 A JP 4109583A JP S59167969 A JPS59167969 A JP S59167969A

Authority

JP

Japan

Prior art keywords

lithium

solvent

nonaqueous electrolyte

solute

temperature storage

Prior art date

1983-03-11

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Granted

Links

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• 239000011255 nonaqueous electrolyte Substances 0.000 title claims abstract description 13
• 239000002904 solvent Substances 0.000 claims abstract description 27
• WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 18
• 229910052744 lithium Inorganic materials 0.000 claims abstract description 18
• 239000011149 active material Substances 0.000 claims description 4
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
• 229910052751 metal Inorganic materials 0.000 claims description 3
• 239000002184 metal Substances 0.000 claims description 3
• 239000012046 mixed solvent Substances 0.000 claims description 3
• 229910052708 sodium Inorganic materials 0.000 claims description 3
• 239000011734 sodium Substances 0.000 claims description 3
• 229910045601 alloy Inorganic materials 0.000 claims description 2
• 239000000956 alloy Substances 0.000 claims description 2
• 239000000203 mixture Substances 0.000 abstract description 4
• MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 abstract description 3
• 238000009835 boiling Methods 0.000 abstract description 2
• IKLFYZKCSVGMPU-UHFFFAOYSA-N B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+] Chemical compound B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].B(OCl)([O-])[O-].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+].[Li+] IKLFYZKCSVGMPU-UHFFFAOYSA-N 0.000 abstract 5
• PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 abstract 2
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
• XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 4
• 239000007788 liquid Substances 0.000 description 3
• MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical group [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 3
• 229910001486 lithium perchlorate Inorganic materials 0.000 description 3
• RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 3
• YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
• BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
• 239000007864 aqueous solution Substances 0.000 description 2
• 238000010586 diagram Methods 0.000 description 2
• 238000001704 evaporation Methods 0.000 description 2
• 230000008020 evaporation Effects 0.000 description 2
• KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
• NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
• BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
• 229910013470 LiC1 Inorganic materials 0.000 description 1
• 241001185311 Lyticum Species 0.000 description 1
• 239000011230 binding agent Substances 0.000 description 1
• 239000006258 conductive agent Substances 0.000 description 1
• 238000007599 discharging Methods 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• 238000005868 electrolysis reaction Methods 0.000 description 1
• 150000004820 halides Chemical class 0.000 description 1
• -1 lithium and sodium Chemical class 0.000 description 1
• 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
• 229910044991 metal oxide Inorganic materials 0.000 description 1
• 150000004706 metal oxides Chemical class 0.000 description 1
• 150000002739 metals Chemical class 0.000 description 1
• 238000000034 method Methods 0.000 description 1
• 239000000843 powder Substances 0.000 description 1
• 230000002285 radioactive effect Effects 0.000 description 1
• YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
• 150000003568 thioethers Chemical class 0.000 description 1

Cited By (1)