JPS5869890A - オルガノハロシランの加水分解法 - Google Patents
オルガノハロシランの加水分解法Info
- Publication number
- JPS5869890A JPS5869890A JP57151831A JP15183182A JPS5869890A JP S5869890 A JPS5869890 A JP S5869890A JP 57151831 A JP57151831 A JP 57151831A JP 15183182 A JP15183182 A JP 15183182A JP S5869890 A JPS5869890 A JP S5869890A
- Authority
- JP
- Japan
- Prior art keywords
- hydrolyzate
- hydrolysis
- water
- organohalosilane
- moles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000007062 hydrolysis Effects 0.000 title claims description 31
- 238000006460 hydrolysis reaction Methods 0.000 title claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 15
- 229920001296 polysiloxane Polymers 0.000 claims description 14
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical group C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 8
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- 150000001367 organochlorosilanes Chemical class 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims 1
- 125000005375 organosiloxane group Chemical group 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 239000012071 phase Substances 0.000 description 14
- -1 cyclic siloxane Chemical class 0.000 description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 238000003869 coulometry Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 3
- 235000011167 hydrochloric acid Nutrition 0.000 description 3
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000005046 Chlorosilane Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical group 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229920005645 diorganopolysiloxane polymer Polymers 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000004045 organic chlorine compounds Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 125000004469 siloxy group Chemical class [SiH3]O* 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0874—Reactions involving a bond of the Si-O-Si linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Silicon Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/298,663 US4382145A (en) | 1981-09-02 | 1981-09-02 | Method of hydrolyzing organochlorosilanes |
| US298663 | 1981-09-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5869890A true JPS5869890A (ja) | 1983-04-26 |
| JPS64956B2 JPS64956B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-01-10 |
Family
ID=23151492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57151831A Granted JPS5869890A (ja) | 1981-09-02 | 1982-09-02 | オルガノハロシランの加水分解法 |
Country Status (5)
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60172991A (ja) * | 1983-12-14 | 1985-09-06 | ゼネラル・エレクトリツク・カンパニイ | クロロシランの加水分解方法 |
| JPH028223A (ja) * | 1988-06-27 | 1990-01-11 | Toshiba Silicone Co Ltd | オルガノクロロシランの加水分解方法 |
| JPH06172534A (ja) * | 1992-07-31 | 1994-06-21 | Dow Corning Corp | 有機官能シロキサンの調製のための縮合方法 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4578494A (en) * | 1985-06-14 | 1986-03-25 | Dow Corning Corporation | Preparation of polysiloxanes from halosilanes |
| US4950779A (en) * | 1989-12-04 | 1990-08-21 | General Electric Company | Nonaqueous method for making silicone oligomers |
| US5075479A (en) * | 1991-05-20 | 1991-12-24 | Dow Corning Corporation | Anhydrous hydrogen chloride evolving one-step process for producing siloxanes |
| DE4343033A1 (de) * | 1993-12-16 | 1995-06-29 | Wacker Chemie Gmbh | Verfahren zur Herstellung von Polydimethylsiloxanen |
| US5739370A (en) * | 1997-04-02 | 1998-04-14 | General Electric Company | Process the production of octaphenylcyclotetrasiloxane |
| DE19828390A1 (de) * | 1998-06-25 | 1999-12-30 | Wacker Chemie Gmbh | Verfahren zur Herstellung von Hydrogenmethylpolysiloxanen mit Trimethylsilyl-Endgruppen |
| DE19918406A1 (de) * | 1999-04-22 | 2000-10-26 | Wacker Chemie Gmbh | Verfahren zur kontinuierlichen Aufarbeitung des bei der Herstellung von Siliconharzen anfallenden Abwassers |
| US7208617B2 (en) * | 2004-10-05 | 2007-04-24 | Dow Corning Corporation | Hydrolysis of chlorosilanes |
| BRPI0519857A2 (pt) * | 2005-01-13 | 2009-03-24 | Dow Corning | método de neutralizar um hidrolisado de polisiloxano |
| US7479567B2 (en) * | 2005-03-29 | 2009-01-20 | Dow Corning Corporation | Reactive distillation of chlorosilanes |
| KR101617762B1 (ko) * | 2008-08-27 | 2016-05-18 | 다우 코닝 코포레이션 | 폴리실록산 재분배 방법 |
| CN104284920A (zh) * | 2012-05-23 | 2015-01-14 | 道康宁公司 | 使用纤维反应器生产有机硅 |
| CN113248710A (zh) * | 2021-06-29 | 2021-08-13 | 山东硅科新材料有限公司 | 一种(2,4,4-三甲基戊基)硅烷低聚物及其制备方法和应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1058334A (en) * | 1964-02-27 | 1967-02-08 | Bayer Ag | Process and apparatus for the continuous hydrolysis of organo-chlorosilanes |
| JPS5231086A (en) * | 1975-08-29 | 1977-03-09 | Union Carbide Corp | Preparation method of circular syloxane |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2769829A (en) * | 1953-12-29 | 1956-11-06 | Union Carbide & Carbon Corp | Process for preparing octaethylcyclotetrasiloxane |
| US3070617A (en) * | 1957-09-09 | 1962-12-25 | Dow Corning | Cyclic bistrifluoropropyl siloxanes |
| US2911427A (en) * | 1957-12-11 | 1959-11-03 | Dow Corning | Chlorosiloxanes |
| GB1231448A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1968-12-11 | 1971-05-12 |
-
1981
- 1981-09-02 US US06/298,663 patent/US4382145A/en not_active Expired - Lifetime
-
1982
- 1982-07-08 GB GB08219838A patent/GB2104906A/en not_active Withdrawn
- 1982-08-21 DE DE19823231196 patent/DE3231196A1/de not_active Withdrawn
- 1982-08-30 FR FR8214799A patent/FR2512028A1/fr active Pending
- 1982-09-02 JP JP57151831A patent/JPS5869890A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1058334A (en) * | 1964-02-27 | 1967-02-08 | Bayer Ag | Process and apparatus for the continuous hydrolysis of organo-chlorosilanes |
| JPS5231086A (en) * | 1975-08-29 | 1977-03-09 | Union Carbide Corp | Preparation method of circular syloxane |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60172991A (ja) * | 1983-12-14 | 1985-09-06 | ゼネラル・エレクトリツク・カンパニイ | クロロシランの加水分解方法 |
| JPH028223A (ja) * | 1988-06-27 | 1990-01-11 | Toshiba Silicone Co Ltd | オルガノクロロシランの加水分解方法 |
| JPH06172534A (ja) * | 1992-07-31 | 1994-06-21 | Dow Corning Corp | 有機官能シロキサンの調製のための縮合方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3231196A1 (de) | 1983-04-21 |
| JPS64956B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-01-10 |
| FR2512028A1 (fr) | 1983-03-04 |
| GB2104906A (en) | 1983-03-16 |
| US4382145A (en) | 1983-05-03 |
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