JPS5832653A - 優れた耐酸敗ガソリン性を有する加硫用ゴム組成物 - Google Patents
優れた耐酸敗ガソリン性を有する加硫用ゴム組成物Info
- Publication number
- JPS5832653A JPS5832653A JP56131047A JP13104781A JPS5832653A JP S5832653 A JPS5832653 A JP S5832653A JP 56131047 A JP56131047 A JP 56131047A JP 13104781 A JP13104781 A JP 13104781A JP S5832653 A JPS5832653 A JP S5832653A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- calcium
- rubber composition
- rancidity
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 14
- 239000004636 vulcanized rubber Substances 0.000 title 1
- 229920001971 elastomer Polymers 0.000 claims description 31
- 239000005060 rubber Substances 0.000 claims description 31
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 6
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 5
- 238000004073 vulcanization Methods 0.000 claims description 5
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229940043430 calcium compound Drugs 0.000 claims description 3
- 150000001674 calcium compounds Chemical class 0.000 claims description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- 239000000378 calcium silicate Substances 0.000 claims description 2
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 2
- 229920006027 ternary co-polymer Polymers 0.000 claims description 2
- 241001122767 Theaceae Species 0.000 claims 1
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 241000238557 Decapoda Species 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000370 acceptor Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920005558 epichlorohydrin rubber Polymers 0.000 description 2
- 150000002118 epoxides Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- XUNLTYLWCMUZFO-UHFFFAOYSA-N 1,4-dihydropyrazine-2,3-dithione Chemical compound S=C1NC=CNC1=S XUNLTYLWCMUZFO-UHFFFAOYSA-N 0.000 description 1
- YFBUDXNMBTUSOC-UHFFFAOYSA-N 1,4-dihydroquinoxaline-2,3-dithione Chemical compound C1=CC=C2NC(=S)C(=S)NC2=C1 YFBUDXNMBTUSOC-UHFFFAOYSA-N 0.000 description 1
- OIXNFJTTYAIBNF-UHFFFAOYSA-N 2-(chloromethyl)oxirane;oxirane Chemical compound C1CO1.ClCC1CO1 OIXNFJTTYAIBNF-UHFFFAOYSA-N 0.000 description 1
- RHKIIBWXBRKZSF-UHFFFAOYSA-N 5-methyl-1,4-dihydropyrazine-2,3-dithione Chemical compound CC1=CNC(=S)C(=S)N1 RHKIIBWXBRKZSF-UHFFFAOYSA-N 0.000 description 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 description 1
- LLEGRYYUNARWKW-UHFFFAOYSA-N 6,7-dibutyl-1,4-dihydroquinoxaline-2,3-dithione Chemical compound N1C(=S)C(=S)NC2=C1C=C(CCCC)C(CCCC)=C2 LLEGRYYUNARWKW-UHFFFAOYSA-N 0.000 description 1
- PKDMPVRCVTYMPA-UHFFFAOYSA-N 6-bromo-1,4-dihydroquinoxaline-2,3-dithione Chemical compound N1C(=S)C(=S)NC2=CC(Br)=CC=C21 PKDMPVRCVTYMPA-UHFFFAOYSA-N 0.000 description 1
- VCNVWAGJKXBURV-UHFFFAOYSA-N 6-ethyl-1,4-dihydroquinoxaline-2,3-dithione Chemical compound N1C(=S)C(=S)NC2=CC(CC)=CC=C21 VCNVWAGJKXBURV-UHFFFAOYSA-N 0.000 description 1
- WPIVYVMXORGSSY-UHFFFAOYSA-N 6-nitro-1,4-dihydroquinoxaline-2,3-dithione Chemical compound N1=C(S)C(S)=NC2=CC([N+](=O)[O-])=CC=C21 WPIVYVMXORGSSY-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000004450 alkenylene group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- -1 cyclo Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000002611 lead compounds Chemical class 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56131047A JPS5832653A (ja) | 1981-08-20 | 1981-08-20 | 優れた耐酸敗ガソリン性を有する加硫用ゴム組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56131047A JPS5832653A (ja) | 1981-08-20 | 1981-08-20 | 優れた耐酸敗ガソリン性を有する加硫用ゴム組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5832653A true JPS5832653A (ja) | 1983-02-25 |
| JPS6129618B2 JPS6129618B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1986-07-08 |
Family
ID=15048769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56131047A Granted JPS5832653A (ja) | 1981-08-20 | 1981-08-20 | 優れた耐酸敗ガソリン性を有する加硫用ゴム組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5832653A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62177063A (ja) * | 1986-01-29 | 1987-08-03 | Osaka Soda Co Ltd | エピクロルヒドリン−プロピレンオキサイド系ゴム組成物 |
| JPS63284259A (ja) * | 1987-05-18 | 1988-11-21 | Osaka Soda Co Ltd | マイクロ波加硫用ゴム組成物 |
| JPS63284258A (ja) * | 1987-05-18 | 1988-11-21 | Osaka Soda Co Ltd | マイクロ波加硫用ゴム組成物 |
| WO2015098911A1 (ja) * | 2013-12-25 | 2015-07-02 | 日本ゼオン株式会社 | 架橋性アクリルゴム組成物およびゴム架橋物 |
-
1981
- 1981-08-20 JP JP56131047A patent/JPS5832653A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62177063A (ja) * | 1986-01-29 | 1987-08-03 | Osaka Soda Co Ltd | エピクロルヒドリン−プロピレンオキサイド系ゴム組成物 |
| JPS63284259A (ja) * | 1987-05-18 | 1988-11-21 | Osaka Soda Co Ltd | マイクロ波加硫用ゴム組成物 |
| JPS63284258A (ja) * | 1987-05-18 | 1988-11-21 | Osaka Soda Co Ltd | マイクロ波加硫用ゴム組成物 |
| WO2015098911A1 (ja) * | 2013-12-25 | 2015-07-02 | 日本ゼオン株式会社 | 架橋性アクリルゴム組成物およびゴム架橋物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6129618B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1986-07-08 |