JPS58206615A - 柔軟性を有するふつ素樹脂の製造方法 - Google Patents
柔軟性を有するふつ素樹脂の製造方法Info
- Publication number
- JPS58206615A JPS58206615A JP8805382A JP8805382A JPS58206615A JP S58206615 A JPS58206615 A JP S58206615A JP 8805382 A JP8805382 A JP 8805382A JP 8805382 A JP8805382 A JP 8805382A JP S58206615 A JPS58206615 A JP S58206615A
- Authority
- JP
- Japan
- Prior art keywords
- fluorine
- copolymer
- monomer
- peroxy
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 229920002313 fluoropolymer Polymers 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 claims abstract description 29
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 25
- 239000011737 fluorine Substances 0.000 claims abstract description 25
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000178 monomer Substances 0.000 claims abstract description 21
- 229920000642 polymer Polymers 0.000 claims abstract description 19
- 238000002844 melting Methods 0.000 claims abstract description 6
- 230000008018 melting Effects 0.000 claims abstract description 6
- 125000000864 peroxy group Chemical group O(O*)* 0.000 claims abstract description 6
- 230000009477 glass transition Effects 0.000 claims abstract description 4
- 239000006185 dispersion Substances 0.000 claims abstract 3
- 239000000839 emulsion Substances 0.000 claims abstract 3
- 239000002904 solvent Substances 0.000 claims description 5
- 239000002243 precursor Substances 0.000 claims 3
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 abstract description 16
- 239000011347 resin Substances 0.000 abstract description 16
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 abstract description 7
- 238000007334 copolymerization reaction Methods 0.000 abstract description 7
- -1 t-butylperoxy allyl carbonate Chemical compound 0.000 abstract description 6
- 238000004132 cross linking Methods 0.000 abstract description 5
- 238000000465 moulding Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 18
- 239000000203 mixture Substances 0.000 description 9
- 150000002978 peroxides Chemical class 0.000 description 9
- 229920001971 elastomer Polymers 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 7
- 229920006038 crystalline resin Polymers 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 229920000578 graft copolymer Polymers 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 229920001973 fluoroelastomer Polymers 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229920005570 flexible polymer Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 150000004978 peroxycarbonates Chemical class 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NFPBWZOKGZKYRE-UHFFFAOYSA-N 2-propan-2-ylperoxypropane Chemical group CC(C)OOC(C)C NFPBWZOKGZKYRE-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical class Cl* 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008241 heterogeneous mixture Substances 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- ZUHAKVLHBJLXGV-UHFFFAOYSA-N tert-butyl 2-methylprop-2-eneperoxoate Chemical compound CC(=C)C(=O)OOC(C)(C)C ZUHAKVLHBJLXGV-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Landscapes
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8805382A JPS58206615A (ja) | 1982-05-26 | 1982-05-26 | 柔軟性を有するふつ素樹脂の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8805382A JPS58206615A (ja) | 1982-05-26 | 1982-05-26 | 柔軟性を有するふつ素樹脂の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58206615A true JPS58206615A (ja) | 1983-12-01 |
| JPS6234324B2 JPS6234324B2 (enrdf_load_stackoverflow) | 1987-07-27 |
Family
ID=13932090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8805382A Granted JPS58206615A (ja) | 1982-05-26 | 1982-05-26 | 柔軟性を有するふつ素樹脂の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58206615A (enrdf_load_stackoverflow) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62193824A (ja) * | 1986-02-20 | 1987-08-26 | セントラル硝子株式会社 | 柔軟性のあるガラス繊維強化フツ素樹脂複合材料 |
| JPS6443514A (en) * | 1987-08-10 | 1989-02-15 | Central Glass Co Ltd | Preparation of soft fluororesin |
| JPH01292013A (ja) * | 1988-05-19 | 1989-11-24 | Central Glass Co Ltd | 軟質ふっ素樹脂の製造方法 |
| US5134213A (en) * | 1989-12-14 | 1992-07-28 | Tomei Sangyo Kabushiki Kaisha | Polymer-type polymerization initiator |
| JPH05287683A (ja) * | 1992-04-09 | 1993-11-02 | Kanebo Ltd | スエード調立毛布帛の製造方法 |
| US6124404A (en) * | 1997-12-19 | 2000-09-26 | Nippon Mektron Limited | Process for producing fluorine-containing graft copolymer |
| US6166141A (en) * | 1996-06-11 | 2000-12-26 | Central Glass Company, Limited | Fluorine-containing resin for preparing paint |
| US6281312B1 (en) | 1998-12-25 | 2001-08-28 | Nippon Mektron, Ltd. | Process for producing fluorinated copolymer, fluorinated copolymer, crosslinkable composition containing same and sealant |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102089339A (zh) | 2008-02-01 | 2011-06-08 | 旭硝子株式会社 | 热塑性氟树脂及其制造方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5219794A (en) * | 1975-06-25 | 1977-02-15 | Inst Himichiesukoi Fuijiki Aka | Method of reprocessing waste polyfluoroethylene |
| JPS5234794A (en) * | 1975-09-12 | 1977-03-16 | Kansai Paint Co Ltd | Apparatus for measuring sol-gel change and transfer in the couse of drying (hardening) of paint films |
| JPS54132695A (en) * | 1978-04-07 | 1979-10-15 | Nippon Oil & Fats Co Ltd | Preparation of graft copolymer |
-
1982
- 1982-05-26 JP JP8805382A patent/JPS58206615A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5219794A (en) * | 1975-06-25 | 1977-02-15 | Inst Himichiesukoi Fuijiki Aka | Method of reprocessing waste polyfluoroethylene |
| JPS5234794A (en) * | 1975-09-12 | 1977-03-16 | Kansai Paint Co Ltd | Apparatus for measuring sol-gel change and transfer in the couse of drying (hardening) of paint films |
| JPS54132695A (en) * | 1978-04-07 | 1979-10-15 | Nippon Oil & Fats Co Ltd | Preparation of graft copolymer |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62193824A (ja) * | 1986-02-20 | 1987-08-26 | セントラル硝子株式会社 | 柔軟性のあるガラス繊維強化フツ素樹脂複合材料 |
| JPS6443514A (en) * | 1987-08-10 | 1989-02-15 | Central Glass Co Ltd | Preparation of soft fluororesin |
| FR2619384A1 (fr) * | 1987-08-10 | 1989-02-17 | Central Glass Co Ltd | Procede de production d'une resine fluoree souple polymerisee par greffe |
| US4910258A (en) * | 1987-08-10 | 1990-03-20 | Central Glass Company, Limited | Method of producing graft polymerized soft fluororesin |
| JPH01292013A (ja) * | 1988-05-19 | 1989-11-24 | Central Glass Co Ltd | 軟質ふっ素樹脂の製造方法 |
| US5134213A (en) * | 1989-12-14 | 1992-07-28 | Tomei Sangyo Kabushiki Kaisha | Polymer-type polymerization initiator |
| JPH05287683A (ja) * | 1992-04-09 | 1993-11-02 | Kanebo Ltd | スエード調立毛布帛の製造方法 |
| US6166141A (en) * | 1996-06-11 | 2000-12-26 | Central Glass Company, Limited | Fluorine-containing resin for preparing paint |
| US6124404A (en) * | 1997-12-19 | 2000-09-26 | Nippon Mektron Limited | Process for producing fluorine-containing graft copolymer |
| US6281312B1 (en) | 1998-12-25 | 2001-08-28 | Nippon Mektron, Ltd. | Process for producing fluorinated copolymer, fluorinated copolymer, crosslinkable composition containing same and sealant |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6234324B2 (enrdf_load_stackoverflow) | 1987-07-27 |
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