JPS58187402A - 共役ジオレフインの重合または共重合用触媒組成物 - Google Patents
共役ジオレフインの重合または共重合用触媒組成物Info
- Publication number
- JPS58187402A JPS58187402A JP58065749A JP6574983A JPS58187402A JP S58187402 A JPS58187402 A JP S58187402A JP 58065749 A JP58065749 A JP 58065749A JP 6574983 A JP6574983 A JP 6574983A JP S58187402 A JPS58187402 A JP S58187402A
- Authority
- JP
- Japan
- Prior art keywords
- component
- catalyst composition
- composition according
- group
- molar ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims description 37
- 239000000203 mixture Substances 0.000 title claims description 21
- 238000006116 polymerization reaction Methods 0.000 title claims description 12
- 150000001993 dienes Chemical class 0.000 title claims description 9
- 238000007334 copolymerization reaction Methods 0.000 title claims 2
- 150000001875 compounds Chemical class 0.000 claims description 13
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- 229910052779 Neodymium Inorganic materials 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 150000002484 inorganic compounds Chemical class 0.000 claims description 2
- 229910010272 inorganic material Inorganic materials 0.000 claims description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 2
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- 229910052777 Praseodymium Inorganic materials 0.000 claims 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 125000000000 cycloalkoxy group Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 33
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 22
- 229920000642 polymer Polymers 0.000 description 19
- 229910001868 water Inorganic materials 0.000 description 17
- 239000000243 solution Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000000178 monomer Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000005062 Polybutadiene Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920002857 polybutadiene Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- -1 organometallic aluminum compound Chemical class 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- KTOQRRDVVIDEAA-UHFFFAOYSA-N 2-methylpropane Chemical compound [CH2]C(C)C KTOQRRDVVIDEAA-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- 241000755266 Kathetostoma giganteum Species 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000190020 Zelkova serrata Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 125000004490 chloroalkoxy group Chemical group 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT20746A/82 | 1982-04-15 | ||
| IT20746/82A IT1151542B (it) | 1982-04-15 | 1982-04-15 | Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58187402A true JPS58187402A (ja) | 1983-11-01 |
| JPH0322887B2 JPH0322887B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-03-27 |
Family
ID=11171451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58065749A Granted JPS58187402A (ja) | 1982-04-15 | 1983-04-15 | 共役ジオレフインの重合または共重合用触媒組成物 |
Country Status (20)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61268705A (ja) * | 1985-05-15 | 1986-11-28 | エニ−ケム・エラストメ−リ・エセ・ピ・ア | ブタジエン重合体又は共重合体の製法 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1164238B (it) * | 1983-05-25 | 1987-04-08 | Anic Spa | Procedimento per la polimerizzazione del butadiene |
| IT1191614B (it) * | 1985-05-15 | 1988-03-23 | Enichem Elastomers | Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene |
| IT1186730B (it) * | 1985-06-05 | 1987-12-16 | Enichem Elastomers | Procedimento per la polimerizzazione di isoprene |
| IT1186747B (it) * | 1985-07-01 | 1987-12-16 | Enichem Elastomers | Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene |
| IT1230756B (it) * | 1989-02-17 | 1991-10-29 | Enichem Elastomers | Metodo per la preparazione di polibutadiene a lavorabilita' migliorata. |
| US5405815A (en) * | 1993-06-17 | 1995-04-11 | The Goodyear Tire & Rubber Company | Process for preparing a catalyst system useful in the synthesis of isoprene-butadiene rubber |
| DE19746266A1 (de) | 1997-10-20 | 1999-04-22 | Bayer Ag | Katalysator auf Basis von Verbindungen der seltenen Erdmetalle für die Polymerisation von ungesättigten organischen Verbindungen |
| RU2141382C1 (ru) * | 1998-06-08 | 1999-11-20 | Государственное унитарное предприятие Научно-исследовательский институт синтетического каучука им.акад.С.В.Лебедева | Способ получения катализатора полимеризации и сополимеризации ненасыщенных углеводородов |
| KR100352764B1 (ko) * | 2000-03-16 | 2002-09-16 | 금호석유화학 주식회사 | 신규한 단분자 니오디뮴 카르복실레이트 화합물 및 이를포함하는 디엔 중합용 촉매 |
| DE10115106A1 (de) | 2001-03-27 | 2002-10-10 | Bayer Ag | Blockcopolymerisat auf Basis von konjugierten Diolefinen und polaren Monomeren |
| KR100553249B1 (ko) | 2003-05-15 | 2006-02-20 | 금호석유화학 주식회사 | 고 1,4-시스 폴리부타디엔-폴리우레탄 공중합체 및 그 제조방법 |
| US7094849B2 (en) * | 2003-12-15 | 2006-08-22 | Bridgestone Corporation | Bulk polymerization process for producing polydienes |
| RU2437895C1 (ru) * | 2010-06-21 | 2011-12-27 | Открытое акционерное общество "Воронежский синтетический каучук" | Способ получения модифицированного 1,4-цис полибутадиена |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3297667A (en) * | 1963-02-28 | 1967-01-10 | Union Carbide Corp | Production of cis-1, 4-polydienes by polymerization of 1, 3-dienes |
| US3803053A (en) * | 1968-05-08 | 1974-04-09 | Atlantic Richfield Co | Lanthanide oligomerization catalyst |
| CA1087596A (en) * | 1976-05-14 | 1980-10-14 | Battelle Memorial Institute | Process for the preparation of olefine polymerization catalysts |
| DE2830080A1 (de) * | 1978-07-08 | 1980-01-17 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
| US4384982A (en) * | 1981-05-18 | 1983-05-24 | Phillips Petroleum Company | Process and catalyst for olefin polymerization |
-
1982
- 1982-04-15 IT IT20746/82A patent/IT1151542B/it active
-
1983
- 1983-04-06 BR BR8301824A patent/BR8301824A/pt not_active IP Right Cessation
- 1983-04-08 AU AU13283/83A patent/AU565051B2/en not_active Expired
- 1983-04-11 MX MX196897A patent/MX162409A/es unknown
- 1983-04-11 DE DE8383200504T patent/DE3366688D1/de not_active Expired
- 1983-04-11 ZA ZA832520A patent/ZA832520B/xx unknown
- 1983-04-11 EP EP83200504A patent/EP0092270B1/en not_active Expired
- 1983-04-12 CA CA000425661A patent/CA1205446A/en not_active Expired
- 1983-04-13 EG EG234/83A patent/EG15942A/xx active
- 1983-04-14 US US06/484,956 patent/US4525549A/en not_active Expired - Lifetime
- 1983-04-14 SU SU833584516A patent/SU1396959A3/ru active
- 1983-04-14 IN IN437/CAL/83A patent/IN161008B/en unknown
- 1983-04-14 IE IE846/83A patent/IE56761B1/en not_active IP Right Cessation
- 1983-04-14 PT PT76555A patent/PT76555B/pt unknown
- 1983-04-15 CS CS832713A patent/CS240958B2/cs unknown
- 1983-04-15 DD DD83249907A patent/DD209582A5/de not_active IP Right Cessation
- 1983-04-15 JP JP58065749A patent/JPS58187402A/ja active Granted
- 1983-04-15 YU YU855/83A patent/YU44738B/xx unknown
- 1983-04-15 PL PL1983241513A patent/PL140562B1/pl unknown
- 1983-04-15 ES ES521800A patent/ES8502131A1/es not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61268705A (ja) * | 1985-05-15 | 1986-11-28 | エニ−ケム・エラストメ−リ・エセ・ピ・ア | ブタジエン重合体又は共重合体の製法 |
Also Published As
| Publication number | Publication date |
|---|---|
| PL140562B1 (en) | 1987-05-30 |
| EP0092270B1 (en) | 1986-10-08 |
| AU1328383A (en) | 1983-10-20 |
| DE3366688D1 (en) | 1986-11-13 |
| IN161008B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1987-09-12 |
| PT76555B (en) | 1986-03-12 |
| IE830846L (en) | 1983-10-15 |
| EG15942A (en) | 1986-12-30 |
| PT76555A (en) | 1983-05-01 |
| CS240958B2 (en) | 1986-03-13 |
| PL241513A1 (en) | 1984-04-24 |
| YU85583A (en) | 1986-02-28 |
| IT1151542B (it) | 1986-12-24 |
| CA1205446A (en) | 1986-06-03 |
| CS271383A2 (en) | 1985-06-13 |
| ES521800A0 (es) | 1984-12-16 |
| AU565051B2 (en) | 1987-09-03 |
| ZA832520B (en) | 1983-12-28 |
| DD209582A5 (de) | 1984-05-16 |
| EP0092270A1 (en) | 1983-10-26 |
| IT8220746A0 (it) | 1982-04-15 |
| SU1396959A3 (ru) | 1988-05-15 |
| US4525549A (en) | 1985-06-25 |
| ES8502131A1 (es) | 1984-12-16 |
| JPH0322887B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-03-27 |
| YU44738B (en) | 1991-02-28 |
| IE56761B1 (en) | 1991-12-04 |
| BR8301824A (pt) | 1983-12-20 |
| MX162409A (es) | 1991-05-07 |
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