JPS58174286A - 重金属錯塩含有廃水の処理法 - Google Patents
重金属錯塩含有廃水の処理法Info
- Publication number
- JPS58174286A JPS58174286A JP5377682A JP5377682A JPS58174286A JP S58174286 A JPS58174286 A JP S58174286A JP 5377682 A JP5377682 A JP 5377682A JP 5377682 A JP5377682 A JP 5377682A JP S58174286 A JPS58174286 A JP S58174286A
- Authority
- JP
- Japan
- Prior art keywords
- heavy metal
- waste water
- added
- hydrogen peroxide
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 42
- 239000002351 wastewater Substances 0.000 title claims abstract description 39
- -1 metal complex salt Chemical class 0.000 title claims abstract description 20
- 238000011282 treatment Methods 0.000 title claims description 21
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 49
- 150000002500 ions Chemical class 0.000 claims abstract description 15
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910001448 ferrous ion Inorganic materials 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims description 13
- 239000010949 copper Substances 0.000 abstract description 13
- 235000003891 ferrous sulphate Nutrition 0.000 abstract description 6
- 239000011790 ferrous sulphate Substances 0.000 abstract description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 abstract description 6
- 229910000359 iron(II) sulfate Inorganic materials 0.000 abstract description 6
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract description 6
- 238000007254 oxidation reaction Methods 0.000 abstract description 5
- 150000003839 salts Chemical class 0.000 abstract description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 4
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 abstract description 4
- 230000003647 oxidation Effects 0.000 abstract description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- 229910002651 NO3 Inorganic materials 0.000 abstract description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052793 cadmium Inorganic materials 0.000 abstract description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052804 chromium Inorganic materials 0.000 abstract description 2
- 239000011651 chromium Substances 0.000 abstract description 2
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 12
- 238000010979 pH adjustment Methods 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000003311 flocculating effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 150000002739 metals Chemical group 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000012476 oxidizable substance Substances 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- JGUQDUKBUKFFRO-CIIODKQPSA-N dimethylglyoxime Chemical compound O/N=C(/C)\C(\C)=N\O JGUQDUKBUKFFRO-CIIODKQPSA-N 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Removal Of Specific Substances (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5377682A JPS58174286A (ja) | 1982-04-02 | 1982-04-02 | 重金属錯塩含有廃水の処理法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5377682A JPS58174286A (ja) | 1982-04-02 | 1982-04-02 | 重金属錯塩含有廃水の処理法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58174286A true JPS58174286A (ja) | 1983-10-13 |
| JPS643552B2 JPS643552B2 (enrdf_load_stackoverflow) | 1989-01-23 |
Family
ID=12952211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5377682A Granted JPS58174286A (ja) | 1982-04-02 | 1982-04-02 | 重金属錯塩含有廃水の処理法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58174286A (enrdf_load_stackoverflow) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61104299A (ja) * | 1984-10-26 | 1986-05-22 | 日揮株式会社 | 放射性除染廃液の処理方法 |
| US4724084A (en) * | 1986-03-28 | 1988-02-09 | The Boeing Company | System for removing toxic organics and metals from manufacturing wastewater |
| JP2000202461A (ja) * | 1999-01-11 | 2000-07-25 | Kurita Water Ind Ltd | 重金属錯体含有排液の処理方法 |
| AT412470B (de) * | 2003-04-30 | 2005-03-25 | Dauser Industrieanlagen Und Ab | Verfahren zur reinigung von abwässern |
| KR100613727B1 (ko) | 2004-10-27 | 2006-08-22 | 한국전력공사 | 비촉매 산화처리법을 이용한 세정 폐액의 연속 처리방법 및 장치 |
| JP2010240587A (ja) * | 2009-04-07 | 2010-10-28 | Taiheiyo Cement Corp | 排水処理方法 |
| WO2015129541A1 (ja) * | 2014-02-27 | 2015-09-03 | 三菱レイヨン株式会社 | 重金属含有排水の処理方法及び処理装置 |
| CN105000652A (zh) * | 2015-07-30 | 2015-10-28 | 奉化市腾远计时器厂 | 一种净水器重金属处理装置 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9044178B2 (en) | 2007-08-30 | 2015-06-02 | Pepex Biomedical, Llc | Electrochemical sensor and method for manufacturing |
-
1982
- 1982-04-02 JP JP5377682A patent/JPS58174286A/ja active Granted
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61104299A (ja) * | 1984-10-26 | 1986-05-22 | 日揮株式会社 | 放射性除染廃液の処理方法 |
| US4724084A (en) * | 1986-03-28 | 1988-02-09 | The Boeing Company | System for removing toxic organics and metals from manufacturing wastewater |
| JP2000202461A (ja) * | 1999-01-11 | 2000-07-25 | Kurita Water Ind Ltd | 重金属錯体含有排液の処理方法 |
| AT412470B (de) * | 2003-04-30 | 2005-03-25 | Dauser Industrieanlagen Und Ab | Verfahren zur reinigung von abwässern |
| KR100613727B1 (ko) | 2004-10-27 | 2006-08-22 | 한국전력공사 | 비촉매 산화처리법을 이용한 세정 폐액의 연속 처리방법 및 장치 |
| JP2010240587A (ja) * | 2009-04-07 | 2010-10-28 | Taiheiyo Cement Corp | 排水処理方法 |
| WO2015129541A1 (ja) * | 2014-02-27 | 2015-09-03 | 三菱レイヨン株式会社 | 重金属含有排水の処理方法及び処理装置 |
| JP6061024B2 (ja) * | 2014-02-27 | 2017-01-18 | 三菱レイヨン株式会社 | 重金属含有排水の処理方法及び処理装置 |
| CN105000652A (zh) * | 2015-07-30 | 2015-10-28 | 奉化市腾远计时器厂 | 一种净水器重金属处理装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS643552B2 (enrdf_load_stackoverflow) | 1989-01-23 |
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