JPS58160344A - ガスバリア−性の優れたポリエステル中空成形体 - Google Patents
ガスバリア−性の優れたポリエステル中空成形体Info
- Publication number
- JPS58160344A JPS58160344A JP4342982A JP4342982A JPS58160344A JP S58160344 A JPS58160344 A JP S58160344A JP 4342982 A JP4342982 A JP 4342982A JP 4342982 A JP4342982 A JP 4342982A JP S58160344 A JPS58160344 A JP S58160344A
- Authority
- JP
- Japan
- Prior art keywords
- gas barrier
- polyester resin
- barrier properties
- resin
- hollow molded
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000004888 barrier function Effects 0.000 title claims abstract description 17
- 229920000728 polyester Polymers 0.000 title claims abstract description 9
- 238000000465 moulding Methods 0.000 title abstract description 9
- 229920006230 thermoplastic polyester resin Polymers 0.000 claims abstract description 17
- 229920006122 polyamide resin Polymers 0.000 claims abstract description 9
- 229920001225 polyester resin Polymers 0.000 claims abstract description 9
- 239000004645 polyester resin Substances 0.000 claims abstract description 9
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical group C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 abstract description 12
- -1 m-xylylene Chemical group 0.000 abstract description 11
- 229920001577 copolymer Polymers 0.000 abstract description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract description 3
- 229910001882 dioxygen Inorganic materials 0.000 abstract description 3
- 229920001519 homopolymer Polymers 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 230000002542 deteriorative effect Effects 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 13
- 239000011347 resin Substances 0.000 description 13
- 238000000071 blow moulding Methods 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 2
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- UUAGPGQUHZVJBQ-UHFFFAOYSA-N Bisphenol A bis(2-hydroxyethyl)ether Chemical compound C=1C=C(OCCO)C=CC=1C(C)(C)C1=CC=C(OCCO)C=C1 UUAGPGQUHZVJBQ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BHHGXPLMPWCGHP-UHFFFAOYSA-N Phenethylamine Chemical compound NCCC1=CC=CC=C1 BHHGXPLMPWCGHP-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- QCTBMLYLENLHLA-UHFFFAOYSA-N aminomethylbenzoic acid Chemical compound NCC1=CC=C(C(O)=O)C=C1 QCTBMLYLENLHLA-UHFFFAOYSA-N 0.000 description 1
- 229960003375 aminomethylbenzoic acid Drugs 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920006038 crystalline resin Polymers 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Landscapes
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4342982A JPS58160344A (ja) | 1982-03-17 | 1982-03-17 | ガスバリア−性の優れたポリエステル中空成形体 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4342982A JPS58160344A (ja) | 1982-03-17 | 1982-03-17 | ガスバリア−性の優れたポリエステル中空成形体 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58160344A true JPS58160344A (ja) | 1983-09-22 |
| JPH0454702B2 JPH0454702B2 (enrdf_load_stackoverflow) | 1992-09-01 |
Family
ID=12663448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4342982A Granted JPS58160344A (ja) | 1982-03-17 | 1982-03-17 | ガスバリア−性の優れたポリエステル中空成形体 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58160344A (enrdf_load_stackoverflow) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01139334A (ja) * | 1987-11-27 | 1989-05-31 | Mitsubishi Gas Chem Co Inc | パリソンおよびブロー成形容器 |
| US5202052A (en) * | 1990-09-12 | 1993-04-13 | Aquanautics Corporation | Amino polycarboxylic acid compounds as oxygen scavengers |
| US5364555A (en) * | 1991-04-30 | 1994-11-15 | Advanced Oxygen Technologies, Inc. | Polymer compositions containing salicylic acid chelates as oxygen scavengers |
| EP1046674A3 (en) * | 1999-04-19 | 2001-06-13 | Mitsubishi Gas Chemical Company, Inc. | Polyester resin composition |
| EP1239008A1 (en) * | 2001-03-05 | 2002-09-11 | Mitsubishi Gas Chemical Company, Inc. | Polyester-based resin composition and shaped articles |
| JP2002294055A (ja) * | 2001-04-02 | 2002-10-09 | Mitsui Chemicals Inc | ポリエステル組成物、その製造方法および該組成物からなる成形体 |
| US6709724B1 (en) | 1990-05-02 | 2004-03-23 | W. R. Grace & Co.-Conn. | Metal catalyzed ascorbate compounds as oxygen scavengers |
| JP2005297344A (ja) * | 2004-04-12 | 2005-10-27 | Mitsubishi Gas Chem Co Inc | 多層容器 |
| JP2005344123A (ja) * | 2002-06-03 | 2005-12-15 | Toyobo Co Ltd | ポリエステル組成物およびそれからなるポリエステル包装材料 |
| US8097662B2 (en) | 1998-02-03 | 2012-01-17 | Graham Packaging Pet Technologies, Inc. | Enhanced oxygen-scavenging polymers, and packaging made therefrom |
| WO2013133352A1 (ja) | 2012-03-09 | 2013-09-12 | 三菱瓦斯化学株式会社 | ポリエステル系樹脂組成物及びその製造方法、並びに該樹脂組成物を用いた成形体 |
| WO2020059749A1 (ja) * | 2018-09-21 | 2020-03-26 | 三菱瓦斯化学株式会社 | 延伸体、ペットボトルおよび容器の製造方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4880651A (enrdf_load_stackoverflow) * | 1972-01-24 | 1973-10-29 | ||
| JPS51124162A (en) * | 1975-04-23 | 1976-10-29 | Mitsubishi Plastics Ind | Manufacturing of elongated mat films |
-
1982
- 1982-03-17 JP JP4342982A patent/JPS58160344A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4880651A (enrdf_load_stackoverflow) * | 1972-01-24 | 1973-10-29 | ||
| JPS51124162A (en) * | 1975-04-23 | 1976-10-29 | Mitsubishi Plastics Ind | Manufacturing of elongated mat films |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01139334A (ja) * | 1987-11-27 | 1989-05-31 | Mitsubishi Gas Chem Co Inc | パリソンおよびブロー成形容器 |
| US6709724B1 (en) | 1990-05-02 | 2004-03-23 | W. R. Grace & Co.-Conn. | Metal catalyzed ascorbate compounds as oxygen scavengers |
| US5202052A (en) * | 1990-09-12 | 1993-04-13 | Aquanautics Corporation | Amino polycarboxylic acid compounds as oxygen scavengers |
| US5364555A (en) * | 1991-04-30 | 1994-11-15 | Advanced Oxygen Technologies, Inc. | Polymer compositions containing salicylic acid chelates as oxygen scavengers |
| US8097662B2 (en) | 1998-02-03 | 2012-01-17 | Graham Packaging Pet Technologies, Inc. | Enhanced oxygen-scavenging polymers, and packaging made therefrom |
| US8309622B2 (en) | 1998-02-03 | 2012-11-13 | Graham Packaging Pet Technologies Inc. | Enhanced oxygen-scavenging polymers, and packaging made therefrom |
| EP1046674A3 (en) * | 1999-04-19 | 2001-06-13 | Mitsubishi Gas Chemical Company, Inc. | Polyester resin composition |
| EP1239008A1 (en) * | 2001-03-05 | 2002-09-11 | Mitsubishi Gas Chemical Company, Inc. | Polyester-based resin composition and shaped articles |
| JP2002294055A (ja) * | 2001-04-02 | 2002-10-09 | Mitsui Chemicals Inc | ポリエステル組成物、その製造方法および該組成物からなる成形体 |
| JP2005344123A (ja) * | 2002-06-03 | 2005-12-15 | Toyobo Co Ltd | ポリエステル組成物およびそれからなるポリエステル包装材料 |
| JP2005297344A (ja) * | 2004-04-12 | 2005-10-27 | Mitsubishi Gas Chem Co Inc | 多層容器 |
| WO2013133352A1 (ja) | 2012-03-09 | 2013-09-12 | 三菱瓦斯化学株式会社 | ポリエステル系樹脂組成物及びその製造方法、並びに該樹脂組成物を用いた成形体 |
| KR20140135970A (ko) | 2012-03-09 | 2014-11-27 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 폴리에스테르계 수지 조성물 및 그 제조 방법, 그리고 이 수지 조성물을 이용한 성형체 |
| WO2020059749A1 (ja) * | 2018-09-21 | 2020-03-26 | 三菱瓦斯化学株式会社 | 延伸体、ペットボトルおよび容器の製造方法 |
| JPWO2020059749A1 (ja) * | 2018-09-21 | 2021-09-30 | 三菱瓦斯化学株式会社 | 延伸体、ペットボトルおよび容器の製造方法 |
| US11981809B2 (en) | 2018-09-21 | 2024-05-14 | Mitsubishi Gas Chemical Company, Inc. | Stretched body, PET bottle, and method for producing container |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0454702B2 (enrdf_load_stackoverflow) | 1992-09-01 |
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