JPH10120710A - エマルジョン単独重合体および共重合体の製造法およびこれに用いられる装置 - Google Patents
エマルジョン単独重合体および共重合体の製造法およびこれに用いられる装置Info
- Publication number
- JPH10120710A JPH10120710A JP9270138A JP27013897A JPH10120710A JP H10120710 A JPH10120710 A JP H10120710A JP 9270138 A JP9270138 A JP 9270138A JP 27013897 A JP27013897 A JP 27013897A JP H10120710 A JPH10120710 A JP H10120710A
- Authority
- JP
- Japan
- Prior art keywords
- meth
- reactor
- monomer
- polymerization
- heat exchanger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 13
- 239000000839 emulsion Substances 0.000 title claims abstract description 12
- 229920001519 homopolymer Polymers 0.000 title claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 title abstract description 8
- 239000000178 monomer Substances 0.000 claims abstract description 54
- 238000000034 method Methods 0.000 claims abstract description 25
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000006185 dispersion Substances 0.000 claims abstract description 7
- 239000003999 initiator Substances 0.000 claims abstract description 6
- 230000000379 polymerizing effect Effects 0.000 claims abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 17
- 239000011541 reaction mixture Substances 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 3
- 239000007870 radical polymerization initiator Substances 0.000 claims description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims 1
- 238000010556 emulsion polymerization method Methods 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 7
- 238000010008 shearing Methods 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 description 9
- 238000009826 distribution Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 238000009529 body temperature measurement Methods 0.000 description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 description 5
- 239000000498 cooling water Substances 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- -1 n- butyl Chemical group 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- RALRVIPTUXSBPO-UHFFFAOYSA-N 4-[4-chloro-3-(trifluoromethyl)phenyl]piperidin-4-ol Chemical compound C=1C=C(Cl)C(C(F)(F)F)=CC=1C1(O)CCNCC1 RALRVIPTUXSBPO-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000002902 bimodal effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004815 dispersion polymer Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical compound OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical group CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- WAGRIKSHWXFXHV-UHFFFAOYSA-N 1-hydroxybutyl prop-2-enoate Chemical compound CCCC(O)OC(=O)C=C WAGRIKSHWXFXHV-UHFFFAOYSA-N 0.000 description 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical class CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical group OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
- B01J19/1881—Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/92—Apparatus for use in addition polymerization processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/922—Polymerization process of ethylenic monomers using manipulative technique
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19640793.1 | 1996-10-02 | ||
| DE19640793A DE19640793A1 (de) | 1996-10-02 | 1996-10-02 | Verfahren und Vorrichtung zur Herstellung von Homo- und Copolymeren in Emulsionspolymerisationstechnik |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH10120710A true JPH10120710A (ja) | 1998-05-12 |
| JPH10120710A5 JPH10120710A5 (enExample) | 2005-06-23 |
Family
ID=7807765
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9270138A Withdrawn JPH10120710A (ja) | 1996-10-02 | 1997-10-02 | エマルジョン単独重合体および共重合体の製造法およびこれに用いられる装置 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6660814B1 (enExample) |
| EP (1) | EP0834518B1 (enExample) |
| JP (1) | JPH10120710A (enExample) |
| KR (1) | KR19980032518A (enExample) |
| CN (1) | CN1121417C (enExample) |
| AU (1) | AU746031B2 (enExample) |
| CA (1) | CA2215556A1 (enExample) |
| DE (2) | DE19640793A1 (enExample) |
| ES (1) | ES2154438T3 (enExample) |
| ID (1) | ID17248A (enExample) |
| MX (1) | MX9707559A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101524306B1 (ko) * | 2013-06-25 | 2015-06-01 | 한국신발피혁연구원 | 프리폴리머 자동 중합 생산설비 |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3639858B2 (ja) * | 1997-09-12 | 2005-04-20 | 日本甜菜製糖株式会社 | ラフィノースの結晶を製造する方法及び装置 |
| EP0926161B1 (en) * | 1997-12-19 | 2003-02-05 | Rohm And Haas Company | A continuous process for preparing polymers |
| US6380324B1 (en) | 1999-01-26 | 2002-04-30 | Rohm And Haas Company | Reduction of polymer fouling on reactor surface in a continuous process for preparing polymers |
| US6320000B1 (en) | 1999-04-21 | 2001-11-20 | Jeanine Lee Hurry | Process for preparing polymers |
| US6852797B2 (en) | 2000-04-26 | 2005-02-08 | Basf Aktiengesellschaft | Method for producing polybutadiene latex with an optimized thermal current profile |
| DE10103709A1 (de) * | 2001-01-26 | 2002-08-01 | Basf Ag | Verfahren zur Herstellung einer wässrigen Polymerisatdispersion durch radikalisch initiierte wässrige Emulsionspolymerisation |
| DE10134023A1 (de) * | 2001-07-12 | 2003-01-23 | Basf Ag | Verfahren und Vorrichtung zur Herstellung von Polymerdispersionen |
| JP5022546B2 (ja) * | 2001-08-28 | 2012-09-12 | 出光興産株式会社 | α−オレフィン低重合体の製造方法 |
| CN100455610C (zh) * | 2002-09-03 | 2009-01-28 | 沈阳化工股份有限公司 | 一种共聚糊树脂及其制备方法 |
| CN1294326C (zh) * | 2005-01-11 | 2007-01-10 | 东阳市野风塑胶有限公司 | 饮料过滤袋绵纸涂布用胶乳及其制备方法 |
| DE602006001135D1 (de) | 2005-03-24 | 2008-06-26 | Rohm & Haas | Polymerisationsverfahren |
| ATE459655T1 (de) | 2005-08-31 | 2010-03-15 | Nippon Catalytic Chem Ind | Kontinuierliches herstellungsverfahren für wasserlösliches polymer und wasserlösliches polymer |
| CN100429246C (zh) * | 2006-07-04 | 2008-10-29 | 中国石油天然气集团公司 | 丁苯胶乳的制备方法 |
| DE102006036177B4 (de) * | 2006-07-21 | 2013-05-08 | Evonik Degussa Gmbh | Vorrichtung und Verfahren zur Herstellung von Acrylsäure mit verminderter Autoxidationsneigung |
| DE102007038332A1 (de) * | 2007-08-14 | 2009-02-19 | Wacker Chemie Ag | Kontinuierliches Polymerisationsverfahren |
| DE102007040850A1 (de) * | 2007-08-29 | 2009-03-05 | Wacker Chemie Ag | Verfahren zur Herstellung von Schutzkolloid-stabilisierten Polymerisaten und Vorrichtung zur Durchführung des Verfahrens |
| EP2106849B2 (en) * | 2008-04-03 | 2014-02-12 | Rohm and Haas Company | Method of emulsion polymerization |
| US8247585B2 (en) * | 2009-07-14 | 2012-08-21 | Ceramatec, Inc | Systems and methods for removing catalyst and recovering free carboxylic acids after transesterification reaction |
| CN101812152B (zh) * | 2010-03-31 | 2011-11-16 | 上海东升新材料有限公司 | 涂布纸底涂涂料用细粒径丙苯胶乳及其制备方法和应用 |
| CN102311515A (zh) * | 2010-07-09 | 2012-01-11 | 新疆石河子中发化工有限责任公司 | 共聚树脂悬浮法生产中加料及温度控制方法 |
| DE102011005388A1 (de) | 2011-03-10 | 2012-09-13 | Wacker Chemie Ag | Verfahren zur Herstellung von Polymerisaten mittels Emulsions- oder Suspensionspolymerisation |
| DE102011087138A1 (de) | 2011-11-25 | 2013-05-29 | Wacker Chemie Ag | Verfahren zur Herstellung von wässrigen Polymerdispersionen |
| KR101394405B1 (ko) * | 2011-12-09 | 2014-05-15 | 금호석유화학 주식회사 | 종이 코팅용 스티렌 부타디엔계 라텍스와 그 제조방법 |
| US9156920B2 (en) | 2012-09-26 | 2015-10-13 | Wacker Chemical Corporation | Process for the preparation of an aqueous emulsifier-stabilized vinyl acetate-ethylene copolymer dispersion with fine particle size |
| CN104513143A (zh) | 2013-09-26 | 2015-04-15 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
| WO2015101621A1 (en) | 2013-12-30 | 2015-07-09 | Averis As | Process for the preparation of solid particulate vinyl aromatic polymer compositions |
| CN104369282B (zh) * | 2014-09-26 | 2016-08-17 | 安徽安利材料科技股份有限公司 | 一种大规模高效自动配料系统 |
| BR112017007648A2 (pt) | 2014-10-13 | 2017-12-19 | Avery Dennison Corp | emulsões de acetato de etileno vinila/polímero acrílico e produtos e métodos relacionados às mesmas |
| ES2827824T3 (es) * | 2016-08-31 | 2021-05-24 | Exxonmobil Chemical Patents Inc | Intercambiador de calor en espiral como precalentador en los procedimientos de desvolatilización de polímeros |
| US10718571B2 (en) * | 2016-08-31 | 2020-07-21 | Exxonmobil Chemical Patents Inc. | Spiral heat exchanger as preheater in polymer devolatilization processes |
| CN111164107B (zh) | 2017-10-04 | 2022-05-24 | 瓦克化学股份公司 | 采用外部冷却的聚合方法 |
| CN109517313A (zh) * | 2018-10-12 | 2019-03-26 | 安徽优丽普科技有限公司 | 一种高韧性增塑pvc护墙板及其制备方法 |
| KR102256402B1 (ko) * | 2018-10-15 | 2021-05-25 | 한화솔루션 주식회사 | 회분식 반응기 |
| CN110327852B (zh) * | 2019-07-06 | 2022-07-12 | 江西奕方农业科技有限公司 | 溶胶设备和其制造方法 |
| CN115215962B (zh) * | 2022-09-15 | 2022-12-06 | 拓迪化学(上海)有限公司 | 用于锂电池正极极片边缘保护的粘结剂树脂的制备方法、及粘结剂树脂和绝缘胶 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE1495145B2 (de) * | 1963-10-10 | 1971-05-06 | Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen | Verfahren zum abfuehren der reaktionswaerme bei der polymerisation in dispersion bzw loesung |
| IT1094930B (it) * | 1978-04-24 | 1985-08-10 | Montedison Spa | Procedimento di polimerizzazione sotto pressione in apparecchiatura di tipo anolare |
| US4182820A (en) * | 1978-06-08 | 1980-01-08 | Borg-Warner Corporation | Process for polymerization of styrene and acrylonitrile |
| US4273904A (en) * | 1979-07-20 | 1981-06-16 | The B. F. Goodrich Company | Process for producing homopolymers or copolymers of vinyl or vinylidene monomers by emulsion polymerization |
| US4482685A (en) * | 1982-09-30 | 1984-11-13 | Allied Corporation | Copolymerization of ethylene and chlorotrifluoroethylene in an aqueous emulsion |
| US4727110A (en) * | 1984-04-19 | 1988-02-23 | Union Carbide Corporation | Process for the polymerization of shear-stable water-in-oil emulsions |
| AT382629B (de) * | 1984-11-21 | 1987-03-25 | Hans Dipl Ing Dr Te Bukowiecki | Verfahren zur emulsionspolymerisation |
| US5216065A (en) * | 1990-11-29 | 1993-06-01 | The Mead Corporation | Emulsion polymerization with large particle size |
| DE4220610C2 (de) * | 1992-06-24 | 1996-01-25 | Buna Gmbh | Verfahren und Vorrichtung zur kontinuierlichen Emulsionspolymerisation von Vinylchlorid |
| JP3608625B2 (ja) * | 1994-05-15 | 2005-01-12 | アメルシャム・バイオサイエンシーズ・アクチボラグ | 粒子の製造方法、及び該方法によって製造され得る粒子 |
| US5502105A (en) * | 1994-08-25 | 1996-03-26 | Dow Corning Corporation | Method of emulsion polymerization |
| DE4442577A1 (de) * | 1994-11-30 | 1996-06-05 | Hoechst Ag | Verfahren zur Herstellung von Emulsionspolymerisaten |
-
1996
- 1996-10-02 DE DE19640793A patent/DE19640793A1/de not_active Withdrawn
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1997
- 1997-09-30 US US08/940,996 patent/US6660814B1/en not_active Expired - Lifetime
- 1997-09-30 CN CN97121466A patent/CN1121417C/zh not_active Expired - Lifetime
- 1997-10-01 DE DE59702949T patent/DE59702949D1/de not_active Expired - Lifetime
- 1997-10-01 EP EP97117059A patent/EP0834518B1/de not_active Expired - Lifetime
- 1997-10-01 CA CA002215556A patent/CA2215556A1/en not_active Abandoned
- 1997-10-01 ES ES97117059T patent/ES2154438T3/es not_active Expired - Lifetime
- 1997-10-02 ID IDP973346A patent/ID17248A/id unknown
- 1997-10-02 JP JP9270138A patent/JPH10120710A/ja not_active Withdrawn
- 1997-10-02 MX MX9707559A patent/MX9707559A/es not_active IP Right Cessation
- 1997-10-02 KR KR1019970050948A patent/KR19980032518A/ko not_active Withdrawn
- 1997-10-02 AU AU39904/97A patent/AU746031B2/en not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101524306B1 (ko) * | 2013-06-25 | 2015-06-01 | 한국신발피혁연구원 | 프리폴리머 자동 중합 생산설비 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE59702949D1 (de) | 2001-03-01 |
| AU3990497A (en) | 1998-04-09 |
| CN1184819A (zh) | 1998-06-17 |
| KR19980032518A (ko) | 1998-07-25 |
| CA2215556A1 (en) | 1998-04-02 |
| US6660814B1 (en) | 2003-12-09 |
| AU746031B2 (en) | 2002-04-11 |
| DE19640793A1 (de) | 1998-04-16 |
| EP0834518B1 (de) | 2001-01-24 |
| EP0834518A1 (de) | 1998-04-08 |
| CN1121417C (zh) | 2003-09-17 |
| MX9707559A (es) | 1998-04-30 |
| ID17248A (id) | 1997-12-11 |
| ES2154438T3 (es) | 2001-04-01 |
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