KR19980032518A - 단독- 및 공중합체의 유화 중합 제조 방법 및 그를 위한 장치 - Google Patents
단독- 및 공중합체의 유화 중합 제조 방법 및 그를 위한 장치 Download PDFInfo
- Publication number
- KR19980032518A KR19980032518A KR1019970050948A KR19970050948A KR19980032518A KR 19980032518 A KR19980032518 A KR 19980032518A KR 1019970050948 A KR1019970050948 A KR 1019970050948A KR 19970050948 A KR19970050948 A KR 19970050948A KR 19980032518 A KR19980032518 A KR 19980032518A
- Authority
- KR
- South Korea
- Prior art keywords
- meth
- monomer
- reaction
- polymerization
- heat exchanger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 13
- 238000007720 emulsion polymerization reaction Methods 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- 239000000178 monomer Substances 0.000 claims abstract description 62
- 238000000034 method Methods 0.000 claims abstract description 26
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 18
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011541 reaction mixture Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 13
- 239000006185 dispersion Substances 0.000 claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 12
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 9
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003999 initiator Substances 0.000 claims abstract description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000007870 radical polymerization initiator Substances 0.000 claims abstract description 4
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000012442 inert solvent Substances 0.000 claims abstract description 3
- 239000000376 reactant Substances 0.000 claims abstract description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 24
- 238000001816 cooling Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 239000002671 adjuvant Substances 0.000 claims description 4
- 230000007246 mechanism Effects 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 239000000047 product Substances 0.000 description 10
- 238000009826 distribution Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N alpha-Methyl-n-butyl acrylate Natural products CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- 239000002826 coolant Substances 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000002902 bimodal effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- -1 2-ethylhexyl Chemical group 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 125000005385 peroxodisulfate group Chemical group 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical compound OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- VSVCAMGKPRPGQR-UHFFFAOYSA-N propan-2-one;sulfurous acid Chemical compound CC(C)=O.OS(O)=O VSVCAMGKPRPGQR-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
- B01J19/1881—Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/92—Apparatus for use in addition polymerization processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/922—Polymerization process of ethylenic monomers using manipulative technique
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19640793.1 | 1996-10-02 | ||
| DE19640793A DE19640793A1 (de) | 1996-10-02 | 1996-10-02 | Verfahren und Vorrichtung zur Herstellung von Homo- und Copolymeren in Emulsionspolymerisationstechnik |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR19980032518A true KR19980032518A (ko) | 1998-07-25 |
Family
ID=7807765
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019970050948A Withdrawn KR19980032518A (ko) | 1996-10-02 | 1997-10-02 | 단독- 및 공중합체의 유화 중합 제조 방법 및 그를 위한 장치 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6660814B1 (enExample) |
| EP (1) | EP0834518B1 (enExample) |
| JP (1) | JPH10120710A (enExample) |
| KR (1) | KR19980032518A (enExample) |
| CN (1) | CN1121417C (enExample) |
| AU (1) | AU746031B2 (enExample) |
| CA (1) | CA2215556A1 (enExample) |
| DE (2) | DE19640793A1 (enExample) |
| ES (1) | ES2154438T3 (enExample) |
| ID (1) | ID17248A (enExample) |
| MX (1) | MX9707559A (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3639858B2 (ja) * | 1997-09-12 | 2005-04-20 | 日本甜菜製糖株式会社 | ラフィノースの結晶を製造する方法及び装置 |
| EP0926161B1 (en) * | 1997-12-19 | 2003-02-05 | Rohm And Haas Company | A continuous process for preparing polymers |
| US6380324B1 (en) | 1999-01-26 | 2002-04-30 | Rohm And Haas Company | Reduction of polymer fouling on reactor surface in a continuous process for preparing polymers |
| US6320000B1 (en) | 1999-04-21 | 2001-11-20 | Jeanine Lee Hurry | Process for preparing polymers |
| US6852797B2 (en) | 2000-04-26 | 2005-02-08 | Basf Aktiengesellschaft | Method for producing polybutadiene latex with an optimized thermal current profile |
| DE10103709A1 (de) * | 2001-01-26 | 2002-08-01 | Basf Ag | Verfahren zur Herstellung einer wässrigen Polymerisatdispersion durch radikalisch initiierte wässrige Emulsionspolymerisation |
| DE10134023A1 (de) * | 2001-07-12 | 2003-01-23 | Basf Ag | Verfahren und Vorrichtung zur Herstellung von Polymerdispersionen |
| JP5022546B2 (ja) * | 2001-08-28 | 2012-09-12 | 出光興産株式会社 | α−オレフィン低重合体の製造方法 |
| CN100455610C (zh) * | 2002-09-03 | 2009-01-28 | 沈阳化工股份有限公司 | 一种共聚糊树脂及其制备方法 |
| CN1294326C (zh) * | 2005-01-11 | 2007-01-10 | 东阳市野风塑胶有限公司 | 饮料过滤袋绵纸涂布用胶乳及其制备方法 |
| DE602006001135D1 (de) | 2005-03-24 | 2008-06-26 | Rohm & Haas | Polymerisationsverfahren |
| ATE459655T1 (de) | 2005-08-31 | 2010-03-15 | Nippon Catalytic Chem Ind | Kontinuierliches herstellungsverfahren für wasserlösliches polymer und wasserlösliches polymer |
| CN100429246C (zh) * | 2006-07-04 | 2008-10-29 | 中国石油天然气集团公司 | 丁苯胶乳的制备方法 |
| DE102006036177B4 (de) * | 2006-07-21 | 2013-05-08 | Evonik Degussa Gmbh | Vorrichtung und Verfahren zur Herstellung von Acrylsäure mit verminderter Autoxidationsneigung |
| DE102007038332A1 (de) * | 2007-08-14 | 2009-02-19 | Wacker Chemie Ag | Kontinuierliches Polymerisationsverfahren |
| DE102007040850A1 (de) * | 2007-08-29 | 2009-03-05 | Wacker Chemie Ag | Verfahren zur Herstellung von Schutzkolloid-stabilisierten Polymerisaten und Vorrichtung zur Durchführung des Verfahrens |
| EP2106849B2 (en) * | 2008-04-03 | 2014-02-12 | Rohm and Haas Company | Method of emulsion polymerization |
| US8247585B2 (en) * | 2009-07-14 | 2012-08-21 | Ceramatec, Inc | Systems and methods for removing catalyst and recovering free carboxylic acids after transesterification reaction |
| CN101812152B (zh) * | 2010-03-31 | 2011-11-16 | 上海东升新材料有限公司 | 涂布纸底涂涂料用细粒径丙苯胶乳及其制备方法和应用 |
| CN102311515A (zh) * | 2010-07-09 | 2012-01-11 | 新疆石河子中发化工有限责任公司 | 共聚树脂悬浮法生产中加料及温度控制方法 |
| DE102011005388A1 (de) | 2011-03-10 | 2012-09-13 | Wacker Chemie Ag | Verfahren zur Herstellung von Polymerisaten mittels Emulsions- oder Suspensionspolymerisation |
| DE102011087138A1 (de) | 2011-11-25 | 2013-05-29 | Wacker Chemie Ag | Verfahren zur Herstellung von wässrigen Polymerdispersionen |
| KR101394405B1 (ko) * | 2011-12-09 | 2014-05-15 | 금호석유화학 주식회사 | 종이 코팅용 스티렌 부타디엔계 라텍스와 그 제조방법 |
| US9156920B2 (en) | 2012-09-26 | 2015-10-13 | Wacker Chemical Corporation | Process for the preparation of an aqueous emulsifier-stabilized vinyl acetate-ethylene copolymer dispersion with fine particle size |
| KR101524306B1 (ko) * | 2013-06-25 | 2015-06-01 | 한국신발피혁연구원 | 프리폴리머 자동 중합 생산설비 |
| CN104513143A (zh) | 2013-09-26 | 2015-04-15 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
| WO2015101621A1 (en) | 2013-12-30 | 2015-07-09 | Averis As | Process for the preparation of solid particulate vinyl aromatic polymer compositions |
| CN104369282B (zh) * | 2014-09-26 | 2016-08-17 | 安徽安利材料科技股份有限公司 | 一种大规模高效自动配料系统 |
| BR112017007648A2 (pt) | 2014-10-13 | 2017-12-19 | Avery Dennison Corp | emulsões de acetato de etileno vinila/polímero acrílico e produtos e métodos relacionados às mesmas |
| ES2827824T3 (es) * | 2016-08-31 | 2021-05-24 | Exxonmobil Chemical Patents Inc | Intercambiador de calor en espiral como precalentador en los procedimientos de desvolatilización de polímeros |
| US10718571B2 (en) * | 2016-08-31 | 2020-07-21 | Exxonmobil Chemical Patents Inc. | Spiral heat exchanger as preheater in polymer devolatilization processes |
| CN111164107B (zh) | 2017-10-04 | 2022-05-24 | 瓦克化学股份公司 | 采用外部冷却的聚合方法 |
| CN109517313A (zh) * | 2018-10-12 | 2019-03-26 | 安徽优丽普科技有限公司 | 一种高韧性增塑pvc护墙板及其制备方法 |
| KR102256402B1 (ko) * | 2018-10-15 | 2021-05-25 | 한화솔루션 주식회사 | 회분식 반응기 |
| CN110327852B (zh) * | 2019-07-06 | 2022-07-12 | 江西奕方农业科技有限公司 | 溶胶设备和其制造方法 |
| CN115215962B (zh) * | 2022-09-15 | 2022-12-06 | 拓迪化学(上海)有限公司 | 用于锂电池正极极片边缘保护的粘结剂树脂的制备方法、及粘结剂树脂和绝缘胶 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1495145B2 (de) * | 1963-10-10 | 1971-05-06 | Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen | Verfahren zum abfuehren der reaktionswaerme bei der polymerisation in dispersion bzw loesung |
| IT1094930B (it) * | 1978-04-24 | 1985-08-10 | Montedison Spa | Procedimento di polimerizzazione sotto pressione in apparecchiatura di tipo anolare |
| US4182820A (en) * | 1978-06-08 | 1980-01-08 | Borg-Warner Corporation | Process for polymerization of styrene and acrylonitrile |
| US4273904A (en) * | 1979-07-20 | 1981-06-16 | The B. F. Goodrich Company | Process for producing homopolymers or copolymers of vinyl or vinylidene monomers by emulsion polymerization |
| US4482685A (en) * | 1982-09-30 | 1984-11-13 | Allied Corporation | Copolymerization of ethylene and chlorotrifluoroethylene in an aqueous emulsion |
| US4727110A (en) * | 1984-04-19 | 1988-02-23 | Union Carbide Corporation | Process for the polymerization of shear-stable water-in-oil emulsions |
| AT382629B (de) * | 1984-11-21 | 1987-03-25 | Hans Dipl Ing Dr Te Bukowiecki | Verfahren zur emulsionspolymerisation |
| US5216065A (en) * | 1990-11-29 | 1993-06-01 | The Mead Corporation | Emulsion polymerization with large particle size |
| DE4220610C2 (de) * | 1992-06-24 | 1996-01-25 | Buna Gmbh | Verfahren und Vorrichtung zur kontinuierlichen Emulsionspolymerisation von Vinylchlorid |
| JP3608625B2 (ja) * | 1994-05-15 | 2005-01-12 | アメルシャム・バイオサイエンシーズ・アクチボラグ | 粒子の製造方法、及び該方法によって製造され得る粒子 |
| US5502105A (en) * | 1994-08-25 | 1996-03-26 | Dow Corning Corporation | Method of emulsion polymerization |
| DE4442577A1 (de) * | 1994-11-30 | 1996-06-05 | Hoechst Ag | Verfahren zur Herstellung von Emulsionspolymerisaten |
-
1996
- 1996-10-02 DE DE19640793A patent/DE19640793A1/de not_active Withdrawn
-
1997
- 1997-09-30 US US08/940,996 patent/US6660814B1/en not_active Expired - Lifetime
- 1997-09-30 CN CN97121466A patent/CN1121417C/zh not_active Expired - Lifetime
- 1997-10-01 DE DE59702949T patent/DE59702949D1/de not_active Expired - Lifetime
- 1997-10-01 EP EP97117059A patent/EP0834518B1/de not_active Expired - Lifetime
- 1997-10-01 CA CA002215556A patent/CA2215556A1/en not_active Abandoned
- 1997-10-01 ES ES97117059T patent/ES2154438T3/es not_active Expired - Lifetime
- 1997-10-02 ID IDP973346A patent/ID17248A/id unknown
- 1997-10-02 JP JP9270138A patent/JPH10120710A/ja not_active Withdrawn
- 1997-10-02 MX MX9707559A patent/MX9707559A/es not_active IP Right Cessation
- 1997-10-02 KR KR1019970050948A patent/KR19980032518A/ko not_active Withdrawn
- 1997-10-02 AU AU39904/97A patent/AU746031B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| DE59702949D1 (de) | 2001-03-01 |
| AU3990497A (en) | 1998-04-09 |
| CN1184819A (zh) | 1998-06-17 |
| CA2215556A1 (en) | 1998-04-02 |
| US6660814B1 (en) | 2003-12-09 |
| AU746031B2 (en) | 2002-04-11 |
| DE19640793A1 (de) | 1998-04-16 |
| EP0834518B1 (de) | 2001-01-24 |
| EP0834518A1 (de) | 1998-04-08 |
| JPH10120710A (ja) | 1998-05-12 |
| CN1121417C (zh) | 2003-09-17 |
| MX9707559A (es) | 1998-04-30 |
| ID17248A (id) | 1997-12-11 |
| ES2154438T3 (es) | 2001-04-01 |
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