CN1121417C - 乳液均聚物和共聚物的制备及其设备 - Google Patents

乳液均聚物和共聚物的制备及其设备 Download PDF

Info

Publication number
CN1121417C
CN1121417C CN97121466A CN97121466A CN1121417C CN 1121417 C CN1121417 C CN 1121417C CN 97121466 A CN97121466 A CN 97121466A CN 97121466 A CN97121466 A CN 97121466A CN 1121417 C CN1121417 C CN 1121417C
Authority
CN
China
Prior art keywords
monomer
methyl
add
weight
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN97121466A
Other languages
English (en)
Chinese (zh)
Other versions
CN1184819A (zh
Inventor
H·克洛纳
W·克拉尼格
B·R·莫里森
R·克洛斯特曼
H·肖普科
W·卡斯坦休伯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN1184819A publication Critical patent/CN1184819A/zh
Application granted granted Critical
Publication of CN1121417C publication Critical patent/CN1121417C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1881—Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/92—Apparatus for use in addition polymerization processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/922—Polymerization process of ethylenic monomers using manipulative technique

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Adhesives Or Adhesive Processes (AREA)
CN97121466A 1996-10-02 1997-09-30 乳液均聚物和共聚物的制备及其设备 Expired - Lifetime CN1121417C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19640793.1 1996-10-02
DE19640793A DE19640793A1 (de) 1996-10-02 1996-10-02 Verfahren und Vorrichtung zur Herstellung von Homo- und Copolymeren in Emulsionspolymerisationstechnik

Publications (2)

Publication Number Publication Date
CN1184819A CN1184819A (zh) 1998-06-17
CN1121417C true CN1121417C (zh) 2003-09-17

Family

ID=7807765

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97121466A Expired - Lifetime CN1121417C (zh) 1996-10-02 1997-09-30 乳液均聚物和共聚物的制备及其设备

Country Status (11)

Country Link
US (1) US6660814B1 (enExample)
EP (1) EP0834518B1 (enExample)
JP (1) JPH10120710A (enExample)
KR (1) KR19980032518A (enExample)
CN (1) CN1121417C (enExample)
AU (1) AU746031B2 (enExample)
CA (1) CA2215556A1 (enExample)
DE (2) DE19640793A1 (enExample)
ES (1) ES2154438T3 (enExample)
ID (1) ID17248A (enExample)
MX (1) MX9707559A (enExample)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3639858B2 (ja) * 1997-09-12 2005-04-20 日本甜菜製糖株式会社 ラフィノースの結晶を製造する方法及び装置
EP0926161B1 (en) * 1997-12-19 2003-02-05 Rohm And Haas Company A continuous process for preparing polymers
US6380324B1 (en) 1999-01-26 2002-04-30 Rohm And Haas Company Reduction of polymer fouling on reactor surface in a continuous process for preparing polymers
US6320000B1 (en) 1999-04-21 2001-11-20 Jeanine Lee Hurry Process for preparing polymers
US6852797B2 (en) 2000-04-26 2005-02-08 Basf Aktiengesellschaft Method for producing polybutadiene latex with an optimized thermal current profile
DE10103709A1 (de) * 2001-01-26 2002-08-01 Basf Ag Verfahren zur Herstellung einer wässrigen Polymerisatdispersion durch radikalisch initiierte wässrige Emulsionspolymerisation
DE10134023A1 (de) * 2001-07-12 2003-01-23 Basf Ag Verfahren und Vorrichtung zur Herstellung von Polymerdispersionen
JP5022546B2 (ja) * 2001-08-28 2012-09-12 出光興産株式会社 α−オレフィン低重合体の製造方法
CN100455610C (zh) * 2002-09-03 2009-01-28 沈阳化工股份有限公司 一种共聚糊树脂及其制备方法
CN1294326C (zh) * 2005-01-11 2007-01-10 东阳市野风塑胶有限公司 饮料过滤袋绵纸涂布用胶乳及其制备方法
DE602006001135D1 (de) 2005-03-24 2008-06-26 Rohm & Haas Polymerisationsverfahren
ATE459655T1 (de) 2005-08-31 2010-03-15 Nippon Catalytic Chem Ind Kontinuierliches herstellungsverfahren für wasserlösliches polymer und wasserlösliches polymer
CN100429246C (zh) * 2006-07-04 2008-10-29 中国石油天然气集团公司 丁苯胶乳的制备方法
DE102006036177B4 (de) * 2006-07-21 2013-05-08 Evonik Degussa Gmbh Vorrichtung und Verfahren zur Herstellung von Acrylsäure mit verminderter Autoxidationsneigung
DE102007038332A1 (de) * 2007-08-14 2009-02-19 Wacker Chemie Ag Kontinuierliches Polymerisationsverfahren
DE102007040850A1 (de) * 2007-08-29 2009-03-05 Wacker Chemie Ag Verfahren zur Herstellung von Schutzkolloid-stabilisierten Polymerisaten und Vorrichtung zur Durchführung des Verfahrens
EP2106849B2 (en) * 2008-04-03 2014-02-12 Rohm and Haas Company Method of emulsion polymerization
US8247585B2 (en) * 2009-07-14 2012-08-21 Ceramatec, Inc Systems and methods for removing catalyst and recovering free carboxylic acids after transesterification reaction
CN101812152B (zh) * 2010-03-31 2011-11-16 上海东升新材料有限公司 涂布纸底涂涂料用细粒径丙苯胶乳及其制备方法和应用
CN102311515A (zh) * 2010-07-09 2012-01-11 新疆石河子中发化工有限责任公司 共聚树脂悬浮法生产中加料及温度控制方法
DE102011005388A1 (de) 2011-03-10 2012-09-13 Wacker Chemie Ag Verfahren zur Herstellung von Polymerisaten mittels Emulsions- oder Suspensionspolymerisation
DE102011087138A1 (de) 2011-11-25 2013-05-29 Wacker Chemie Ag Verfahren zur Herstellung von wässrigen Polymerdispersionen
KR101394405B1 (ko) * 2011-12-09 2014-05-15 금호석유화학 주식회사 종이 코팅용 스티렌 부타디엔계 라텍스와 그 제조방법
US9156920B2 (en) 2012-09-26 2015-10-13 Wacker Chemical Corporation Process for the preparation of an aqueous emulsifier-stabilized vinyl acetate-ethylene copolymer dispersion with fine particle size
KR101524306B1 (ko) * 2013-06-25 2015-06-01 한국신발피혁연구원 프리폴리머 자동 중합 생산설비
CN104513143A (zh) 2013-09-26 2015-04-15 陶氏技术投资有限责任公司 加氢甲酰化方法
WO2015101621A1 (en) 2013-12-30 2015-07-09 Averis As Process for the preparation of solid particulate vinyl aromatic polymer compositions
CN104369282B (zh) * 2014-09-26 2016-08-17 安徽安利材料科技股份有限公司 一种大规模高效自动配料系统
BR112017007648A2 (pt) 2014-10-13 2017-12-19 Avery Dennison Corp emulsões de acetato de etileno vinila/polímero acrílico e produtos e métodos relacionados às mesmas
ES2827824T3 (es) * 2016-08-31 2021-05-24 Exxonmobil Chemical Patents Inc Intercambiador de calor en espiral como precalentador en los procedimientos de desvolatilización de polímeros
US10718571B2 (en) * 2016-08-31 2020-07-21 Exxonmobil Chemical Patents Inc. Spiral heat exchanger as preheater in polymer devolatilization processes
CN111164107B (zh) 2017-10-04 2022-05-24 瓦克化学股份公司 采用外部冷却的聚合方法
CN109517313A (zh) * 2018-10-12 2019-03-26 安徽优丽普科技有限公司 一种高韧性增塑pvc护墙板及其制备方法
KR102256402B1 (ko) * 2018-10-15 2021-05-25 한화솔루션 주식회사 회분식 반응기
CN110327852B (zh) * 2019-07-06 2022-07-12 江西奕方农业科技有限公司 溶胶设备和其制造方法
CN115215962B (zh) * 2022-09-15 2022-12-06 拓迪化学(上海)有限公司 用于锂电池正极极片边缘保护的粘结剂树脂的制备方法、及粘结剂树脂和绝缘胶

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4727110A (en) * 1984-04-19 1988-02-23 Union Carbide Corporation Process for the polymerization of shear-stable water-in-oil emulsions

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1495145B2 (de) * 1963-10-10 1971-05-06 Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen Verfahren zum abfuehren der reaktionswaerme bei der polymerisation in dispersion bzw loesung
IT1094930B (it) * 1978-04-24 1985-08-10 Montedison Spa Procedimento di polimerizzazione sotto pressione in apparecchiatura di tipo anolare
US4182820A (en) * 1978-06-08 1980-01-08 Borg-Warner Corporation Process for polymerization of styrene and acrylonitrile
US4273904A (en) * 1979-07-20 1981-06-16 The B. F. Goodrich Company Process for producing homopolymers or copolymers of vinyl or vinylidene monomers by emulsion polymerization
US4482685A (en) * 1982-09-30 1984-11-13 Allied Corporation Copolymerization of ethylene and chlorotrifluoroethylene in an aqueous emulsion
AT382629B (de) * 1984-11-21 1987-03-25 Hans Dipl Ing Dr Te Bukowiecki Verfahren zur emulsionspolymerisation
US5216065A (en) * 1990-11-29 1993-06-01 The Mead Corporation Emulsion polymerization with large particle size
DE4220610C2 (de) * 1992-06-24 1996-01-25 Buna Gmbh Verfahren und Vorrichtung zur kontinuierlichen Emulsionspolymerisation von Vinylchlorid
JP3608625B2 (ja) * 1994-05-15 2005-01-12 アメルシャム・バイオサイエンシーズ・アクチボラグ 粒子の製造方法、及び該方法によって製造され得る粒子
US5502105A (en) * 1994-08-25 1996-03-26 Dow Corning Corporation Method of emulsion polymerization
DE4442577A1 (de) * 1994-11-30 1996-06-05 Hoechst Ag Verfahren zur Herstellung von Emulsionspolymerisaten

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4727110A (en) * 1984-04-19 1988-02-23 Union Carbide Corporation Process for the polymerization of shear-stable water-in-oil emulsions

Also Published As

Publication number Publication date
DE59702949D1 (de) 2001-03-01
AU3990497A (en) 1998-04-09
CN1184819A (zh) 1998-06-17
KR19980032518A (ko) 1998-07-25
CA2215556A1 (en) 1998-04-02
US6660814B1 (en) 2003-12-09
AU746031B2 (en) 2002-04-11
DE19640793A1 (de) 1998-04-16
EP0834518B1 (de) 2001-01-24
EP0834518A1 (de) 1998-04-08
JPH10120710A (ja) 1998-05-12
MX9707559A (es) 1998-04-30
ID17248A (id) 1997-12-11
ES2154438T3 (es) 2001-04-01

Similar Documents

Publication Publication Date Title
CN1121417C (zh) 乳液均聚物和共聚物的制备及其设备
US4130523A (en) High solids latexes
MXPA97007559A (es) Homopolimeros y copolimeros preparados por emulsion y dispositivo para dicha preparacion
JP4052661B2 (ja) 改良されたポリマー形成方法
US6252016B1 (en) Continuous polymerization in a non-cylindrical channel with temperature control
US3458467A (en) Continuous emulsion polymerization
CA2088129A1 (en) Continuous polymerization of vinyl monomers
EP0443609B1 (en) Method and apparatus of suspension polymerization
CN109021161A (zh) 一种微通道反应合成gma丙烯酸树脂的方法
AU752487B2 (en) Continuous process for preparing polymers
CA2149577A1 (en) Process for preparing acrylic polymers
CN109369839A (zh) 一种自交联型氯乙烯共聚物乳液及其制备方法
CN1269848C (zh) 半连续双峰乳液聚合
DE19531515A1 (de) Herstellung von Polyvinylester-Dispersionen
KR20000076461A (ko) 반응기 표면상의 중합체 오염이 감소되는 중합체의연속제조방법
CN111978461B (zh) 一种水性功能性丙烯酸树脂及其制备方法
US5777049A (en) Polymerisation processes and reactors
CN103755865A (zh) 无皂聚合丙烯酸乳液及制备方法
AU2005201143B2 (en) A continuous process for preparing polymers
US7858715B2 (en) Loop reactor for emulsion polymerisation
JPH04150934A (ja) エマルジョン樹脂の製造方法
CN117089009A (zh) 一种氯乙烯-丙烯酸酯共聚树脂及其连续性生产方法
JPS61205A (ja) ペ−スト用塩化ビニル樹脂の製造法
BG62657B1 (bg) Метод за получаване на хомо- и съполимерни водни дисперсии
JPH01289802A (ja) ポリマービーズの製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20030917