JPH09506029A - 改善された溶解速度を有する、ブロック共重合体と陰イオン表面活性剤とのブレンド - Google Patents
改善された溶解速度を有する、ブロック共重合体と陰イオン表面活性剤とのブレンドInfo
- Publication number
- JPH09506029A JPH09506029A JP7509549A JP50954995A JPH09506029A JP H09506029 A JPH09506029 A JP H09506029A JP 7509549 A JP7509549 A JP 7509549A JP 50954995 A JP50954995 A JP 50954995A JP H09506029 A JPH09506029 A JP H09506029A
- Authority
- JP
- Japan
- Prior art keywords
- surfactant
- polymer blend
- present
- amount
- block copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/43—Compounds containing sulfur bound to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.(a)約85から約95%の、EO分を少なくとも約70%重合含有する EO/POブロック共重合体と、 (b)約5から約15%の1種類もしくは複数種類のポリカルボキシラートと 、 (c)約0.1から約5%の1種類もしくは複数種類の線形アルキルベンゼン スルホナートとを含有する、水溶解速度が約6.5分より長くない表面活性剤/ 重合体ブレンド。 2.約0.5から約5%の少なくとも1種類の線形アルキルベンゼンスルホナ ートを含有する、請求項1の表面活性剤/重合体ブレンド。 3.上記EO/POブロック共重合体が、約6000またはそれ以上の分子量 を有する、請求項2の表面活性剤/重合体ブレンド。 4.上記ポリカルボキシラートが、約1200から約12000の範囲の分子 量を有する、請求項3の表面活性剤/重合体ブレンド。 5.上記線形アルキルベンゼンスルホナートが、炭素原子数8から18のアル キル基を有する、請求項4の表面活性剤/重合体ブレンド。 6.上記EO/POブロック共重合体が、約88から約92%の量で存在する 、請求項5の表面活性剤/重合体ブレンド。 7.上記ポリアクリラートが、約8から約12%の量で存在する、請求項6の 表面活性剤/重合体ブレンド。 8.上記線形アルキルベンゼンスルホナートが、約0.1から約2.5%の量 で存在する、請求項7の表面活性剤/重合体ブレンド。 9.約6分より長くない溶解速度を有する請求項8の表面活性剤/重合体ブレ ンド。 10.上記EO/POブロック共重合体が、約8400の分子量を有し、約8 9から約90%の量で存在する、請求項9の表面活性剤/重合体ブレンド。 11.上記ポリアクリラートが約4000の分子量を有し、約10%の量で存 在する、請求項10の表面活性剤/重合体ブレンド。 12.上記線形アルキルベンゼンスルホナートが、炭素原子数12から15の 基を有し、約0.5から約1.5%の量で存在する、請求項11の表面活性剤/ 重合体ブレンド。 13.約5.5分より長くない溶解速度を有する、請求項12の表面活性剤/ 重合体ブレンド。 14.(a)殺虫剤と、 (b)(1)約85から約95%の、EO分を約70から約80%重合含有す るEO/POブロック共重合体、 (2)約5から約15%の1種類もしくは複数種類のポリアクリラート、およ び (3)約0.1から約5%の少なくとも1種類の線形アルキルベンゼンスルフ ァートを含有する、水溶解速度が約6.5分より長くない表面活性剤/重合体ブ レンドとを含有する農業用殺虫剤組成物。 15.ポリカルボキシラートと線形アルキルベンゼンスルホナートから選ばれ た少なくとも1種類の化合物の有効量を添加することにより、エチレンオキシド /プロピレンオキシドブロック共重合体の溶解速度を早くする方法。 16.上記溶解速度を少なくとも約50%早くする請求項15の方法。 17.上記ポリカルボキシラートが約1200から約8000の範囲の分子量 を有するポリアクリラートである、請求項16の方法。 18.上記線形アルキルベンゼンスルホナートが炭素原子数12から15のア ルキルベンゼンスルホナートまたはその混合物である請求項17の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/124,413 US5500219A (en) | 1993-09-21 | 1993-09-21 | Pesticide compositions containing blends of block copolymers with anionic surfactants having improved dissolution rates |
US08/124,413 | 1993-09-21 | ||
PCT/EP1994/003110 WO1995008389A1 (en) | 1993-09-21 | 1994-09-16 | Blends of block copolymers with anionic surfactants having improved dissolution rates |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH09506029A true JPH09506029A (ja) | 1997-06-17 |
JP3781427B2 JP3781427B2 (ja) | 2006-05-31 |
Family
ID=22414731
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP50954995A Expired - Lifetime JP3781427B2 (ja) | 1993-09-21 | 1994-09-16 | 改善された溶解速度を有する,ブロック共重合体と陰イオン表面活性剤とのブレンド |
Country Status (13)
Country | Link |
---|---|
US (1) | US5500219A (ja) |
EP (1) | EP0720511B1 (ja) |
JP (1) | JP3781427B2 (ja) |
KR (1) | KR100373966B1 (ja) |
AU (1) | AU682062B2 (ja) |
BR (1) | BR9407577A (ja) |
CA (1) | CA2132508C (ja) |
CO (1) | CO4340716A1 (ja) |
DE (1) | DE69411574T2 (ja) |
ES (1) | ES2118436T3 (ja) |
RU (1) | RU2134153C1 (ja) |
TW (1) | TW326464B (ja) |
WO (1) | WO1995008389A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009028454A1 (ja) * | 2007-08-31 | 2009-03-05 | Nippon Soda Co., Ltd. | 効力の増強された農薬組成物および農薬活性成分の効力の増強方法 |
JP2021507083A (ja) * | 2017-12-21 | 2021-02-22 | シグマ−アルドリッチ・カンパニー・リミテッド・ライアビリティ・カンパニーSigma−Aldrich Co. LLC | ポロキサマー組成物ならびにその製造方法およびその使用 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5866153A (en) * | 1993-02-09 | 1999-02-02 | Novartis Corporation | Process for the preparation of microcapsules |
GB2306965B (en) | 1995-11-06 | 1999-09-01 | American Cyanamid Co | Aqueous spray compositions |
AU1102899A (en) * | 1997-10-28 | 1999-05-17 | Colgate-Palmolive Company, The | Surfactant system for laundry detergent composition |
US6855327B1 (en) | 1998-07-02 | 2005-02-15 | Cognis Corporation | Pesticide dispersant |
AU765652B2 (en) | 1999-07-12 | 2003-09-25 | Michelin Recherche Et Technique S.A. | Tyre casing whereof the sidewalls can comprise a glazed film |
JP3891571B2 (ja) * | 2002-06-14 | 2007-03-14 | キヤノン株式会社 | 機能性組成物、それを用いた画像形成方法及び画像形成装置 |
US7677315B2 (en) | 2005-05-12 | 2010-03-16 | Halliburton Energy Services, Inc. | Degradable surfactants and methods for use |
US7662753B2 (en) | 2005-05-12 | 2010-02-16 | Halliburton Energy Services, Inc. | Degradable surfactants and methods for use |
US9072294B2 (en) * | 2006-02-15 | 2015-07-07 | Cognis Ip Management Gmbh | Emulsifier system and pesticidal formulations containing the emulsifier system |
EP2686390B1 (de) | 2011-03-16 | 2015-05-13 | Clariant Finance (BVI) Limited | Verzweigte polyalkylenglykolether als entlüftende netz- und dispergiermittel für wässrige dispersionsfarben |
AR085728A1 (es) * | 2011-03-28 | 2013-10-23 | Rhodia Operations | Metodo y composicion para el tratamiento de rastrojos |
WO2013072778A2 (en) * | 2011-10-27 | 2013-05-23 | Basf Se | Water dispersible granules |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61180701A (ja) * | 1985-02-06 | 1986-08-13 | Kao Corp | 水性懸濁状殺生剤組成物およびその製造法 |
JPH0249701A (ja) * | 1988-08-11 | 1990-02-20 | Takemoto Oil & Fat Co Ltd | 農薬粒剤用崩壊助剤及び該崩壊助剤を含有する農薬粒剤 |
JPH02108603A (ja) * | 1988-10-19 | 1990-04-20 | Toho Chem Ind Co Ltd | 保存安定性の良好な水中油型懸濁状農薬組成物 |
JPH04327503A (ja) * | 1991-02-08 | 1992-11-17 | Albright & Wilson Ltd | 殺生剤または農薬の組成物 |
JPH05201807A (ja) * | 1991-09-14 | 1993-08-10 | Hoechst Ag | 濃縮マイクロエマルジョンの形態の選択的除草剤組成物 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1542875A1 (de) * | 1966-05-07 | 1970-06-04 | Hoechst Ag | Emulgiermittel fuer biocide organische Thiophosphorsaeureester |
US4826618A (en) * | 1984-02-22 | 1989-05-02 | Diversey Corporation | Stable detergent emulsions |
US4752298A (en) * | 1985-11-25 | 1988-06-21 | Ciba-Geigy Corporation | Storage-stable formulations of water-insoluble or sparingly water-soluble dyes with electrolyte-sensitive thickeners: polyacrylic acid |
US5049303A (en) * | 1988-11-09 | 1991-09-17 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent compositions containing a mixture of an ethylene oxide/propylene oxide block copolymer and a polycarboxylate |
US5169894A (en) * | 1990-11-16 | 1992-12-08 | Holland Richard J | Lowering of anionic loading of dispersants on pigment slurries by blending with nonionic polymers |
-
1993
- 1993-09-21 US US08/124,413 patent/US5500219A/en not_active Expired - Lifetime
-
1994
- 1994-09-16 EP EP94927622A patent/EP0720511B1/en not_active Expired - Lifetime
- 1994-09-16 ES ES94927622T patent/ES2118436T3/es not_active Expired - Lifetime
- 1994-09-16 JP JP50954995A patent/JP3781427B2/ja not_active Expired - Lifetime
- 1994-09-16 DE DE69411574T patent/DE69411574T2/de not_active Expired - Lifetime
- 1994-09-16 WO PCT/EP1994/003110 patent/WO1995008389A1/en active IP Right Grant
- 1994-09-16 RU RU96108235A patent/RU2134153C1/ru active
- 1994-09-16 KR KR1019960701435A patent/KR100373966B1/ko not_active IP Right Cessation
- 1994-09-16 BR BR9407577A patent/BR9407577A/pt not_active IP Right Cessation
- 1994-09-16 AU AU76971/94A patent/AU682062B2/en not_active Expired
- 1994-09-20 CA CA002132508A patent/CA2132508C/en not_active Expired - Lifetime
- 1994-09-20 CO CO94042614A patent/CO4340716A1/es unknown
- 1994-12-19 TW TW083108665A patent/TW326464B/zh not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61180701A (ja) * | 1985-02-06 | 1986-08-13 | Kao Corp | 水性懸濁状殺生剤組成物およびその製造法 |
JPH0249701A (ja) * | 1988-08-11 | 1990-02-20 | Takemoto Oil & Fat Co Ltd | 農薬粒剤用崩壊助剤及び該崩壊助剤を含有する農薬粒剤 |
JPH02108603A (ja) * | 1988-10-19 | 1990-04-20 | Toho Chem Ind Co Ltd | 保存安定性の良好な水中油型懸濁状農薬組成物 |
JPH04327503A (ja) * | 1991-02-08 | 1992-11-17 | Albright & Wilson Ltd | 殺生剤または農薬の組成物 |
JPH05201807A (ja) * | 1991-09-14 | 1993-08-10 | Hoechst Ag | 濃縮マイクロエマルジョンの形態の選択的除草剤組成物 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009028454A1 (ja) * | 2007-08-31 | 2009-03-05 | Nippon Soda Co., Ltd. | 効力の増強された農薬組成物および農薬活性成分の効力の増強方法 |
JP2021507083A (ja) * | 2017-12-21 | 2021-02-22 | シグマ−アルドリッチ・カンパニー・リミテッド・ライアビリティ・カンパニーSigma−Aldrich Co. LLC | ポロキサマー組成物ならびにその製造方法およびその使用 |
US11891510B2 (en) | 2017-12-21 | 2024-02-06 | Sigma-Aldrich Co. Llc | Poloxamer compositions and methods of making and using same |
Also Published As
Publication number | Publication date |
---|---|
JP3781427B2 (ja) | 2006-05-31 |
RU2134153C1 (ru) | 1999-08-10 |
CO4340716A1 (es) | 1996-07-30 |
DE69411574D1 (de) | 1998-08-13 |
US5500219A (en) | 1996-03-19 |
TW326464B (en) | 1998-02-11 |
KR960704623A (ko) | 1996-10-09 |
EP0720511A1 (en) | 1996-07-10 |
WO1995008389A1 (en) | 1995-03-30 |
AU7697194A (en) | 1995-04-10 |
DE69411574T2 (de) | 1998-11-05 |
AU682062B2 (en) | 1997-09-18 |
KR100373966B1 (ko) | 2003-04-23 |
CA2132508C (en) | 2000-08-22 |
CA2132508A1 (en) | 1995-03-22 |
EP0720511B1 (en) | 1998-07-08 |
ES2118436T3 (es) | 1998-09-16 |
BR9407577A (pt) | 1996-07-16 |
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