KR960704623A - 향상된 용해 속도를 가지는 블럭 공중합체와 음이온성 계면 활성제의 혼합물(Blends of Block Copolymers with Anionic Surfactants Having Improved Dissolution Rates) - Google Patents

향상된 용해 속도를 가지는 블럭 공중합체와 음이온성 계면 활성제의 혼합물(Blends of Block Copolymers with Anionic Surfactants Having Improved Dissolution Rates)

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Publication number
KR960704623A
KR960704623A KR1019960701435A KR19960701435A KR960704623A KR 960704623 A KR960704623 A KR 960704623A KR 1019960701435 A KR1019960701435 A KR 1019960701435A KR 19960701435 A KR19960701435 A KR 19960701435A KR 960704623 A KR960704623 A KR 960704623A
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surfactant
polymer mixture
amount
dissolution rate
block copolymer
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KR1019960701435A
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KR100373966B1 (ko
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크리스토퍼 지. 유티제트
레베카 피. 홀리스
조니 엠. 세크미스트르쯔
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로버트 엠. 쇼우·토마스 와이. 올맨
바스프 코포레이션
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules
    • A01N25/14Powders or granules wettable
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/661,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/681,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • C08K5/42Sulfonic acids; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/43Compounds containing sulfur bound to nitrogen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017Mixtures of compounds

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Zoology (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

본 발명은 70%이상의 EO를 함유하는 EO/PO 블록 공중합체 85 내지 95%, 1종 이상의 폴리카르복실레이트 5 내지 15% 및 1종 이상의 직쇄 알킬벤젠 슬포네이트 0.1 내지 5%를 함유하는 물 중에서의용해 속도가 6.5분이하인 계면 활성제/중합체 혼합물을 제공한다.

Description

향상된 용해 속도를 가지는 블럭 공중합체와 음이온성 계면 활성제의 혼합물(Blends of Block copolymers with Anionic Sufactants Having Improved Dissolution Rates)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. a) 약 70% 이상의 EO를 함유하는 EO/PO 블록 공중합체 약 85 내지 약 95%; b) 1종 이상의 폴리카르복실레이트 약 5 내지 약 15%; 및 c) 1종 이상의 직쇄 알킬벤젠 슬포네이트 약 0.1 내지 약 5%로 이루어지는, 물 중에서의 용해 속도가 약 6.5분이하인 계면 활성제/중합체 혼합물.
  2. 제1항에 있어서, 1종 이상의 직쇄 알킬벤젠 슬포네이트를 약 0.5 내지 약 5%를 함유하는 계면 활성제/중합체 혼합물.
  3. 제2항에 있어서, 상기 EO/PO 블록 공중합체의 분자량이 약 6000 이상인 계면 활성제/중합체 혼합물.
  4. 제3항에 있어서, 상기 폴리카르복실레이트가 약 1200 내지 약 12000 범위내의 분자량을 갖는 폴리아크릴레이트인 계면 활성제/중합체 혼합물.
  5. 제4항에 있어서, 상기 직쇄 알킬벤젠술포네이트가 C8내지 C18알킬기를 갖는 것인 계면 활성제/중합체 혼합물.
  6. 제5항에 있어서, 상기 EO/PO 블록 공중합체가 약 88 내지 92%의 양으로 존재하는 것인 계면 활성제/중합체 혼합물.
  7. 제6항에 있어서, 상기 폴리아크릴레이트가 약 8 내지 약 12%의 양으로 존재하는 것인 계면 활성제/중합체 혼합물.
  8. 제7항에 있어서, 상기 직쇄 알킬벤젠술포네이트가 약 0.,1 내지 2.5%의 양으로 존재하는 것인 계면 활성제/중합체 혼합물.
  9. 제8항에 있어서, 상기 혼합물의 용해 속도가 약 6분이하인 계면 활성제/중합체 혼합물.
  10. 제9항에 있어서, EO/PO 블록 공중합체가 분자량이 약 8400 이고, 약 89 내지 약 90%의 양으로 존재하는 것인 계면 활성제/중합체 혼합물.
  11. 제10항에 있어서, 상기 폴리아크릴레이트가 분자량이 약 4000 이고, 약 10%의 양으로 존재하는 것인 계면 활성제/중합체 혼합물.
  12. 제11항에 있어서, 상기 직쇄 알킬벤젠술포네이트가 C12내지 C15의 기를 가지고, 약 0.5 내지 약 1.5%의 양으로 존재하는 것인 계면 활성제/중합체 혼합물.
  13. 제12항에 있어서, 상기 계면 활성제 혼합물의 용해 속도가 약 5.5분이하인 계면 활성제/중합체 혼합물.
  14. a) 살충제; 및 b) 약 70% 내지 80%의 EO를 함유하는 EO/PO 블록 공중합체 약 85 내지 약 95%, 1종 이상의 폴리아크릴레이트 약 5 내지 약 15%, 및 1종 이상의 직쇄 알킬벤젠 술포네이트 약 0.1 내지 약 5%로 이루어지는 물 중에서 용해 속도가 약 6.5분이하인 계면 활성제/중합체 혼합물 분산제로 이루어지는 농업용 살충 조성물.
  15. 폴리카르복실레이트 및 직쇄 알킬벤젠술포네이트로 구성되는 군으로부터 선택된 1종 이상의 화합물의 유효량을 첨가시키는 것으로 이루어진, 에틸렌 옥사이드/프로필렌 옥사이드 블록 공중합체의 용해 속도를 증가시키는 방법.
  16. 제15항에 있어서, 상기 용해 속도가 약 50% 이상 증가되는 방법.
  17. 제16항에 있어서, 상기 폴리카르복실레이트가 약 1200 내지 약 8000 범위내의 분자량을 갖는 폴리아크릴레이트인 방법.
  18. 제17항에 있어서, 직쇄 알킬벤젠 술포네이트가 C12내지 C15알킬벤젠 술포네이트 및 그의 혼합물인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960701435A 1993-09-21 1994-09-16 향상된 용해속도를 가지는 블럭공중합체와 음이온성 계면활성제의 혼합물 KR100373966B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/124,413 1993-09-21
US08/124,413 US5500219A (en) 1993-09-21 1993-09-21 Pesticide compositions containing blends of block copolymers with anionic surfactants having improved dissolution rates
US08/124413 1993-09-21

Publications (2)

Publication Number Publication Date
KR960704623A true KR960704623A (ko) 1996-10-09
KR100373966B1 KR100373966B1 (ko) 2003-04-23

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US (1) US5500219A (ko)
EP (1) EP0720511B1 (ko)
JP (1) JP3781427B2 (ko)
KR (1) KR100373966B1 (ko)
AU (1) AU682062B2 (ko)
BR (1) BR9407577A (ko)
CA (1) CA2132508C (ko)
CO (1) CO4340716A1 (ko)
DE (1) DE69411574T2 (ko)
ES (1) ES2118436T3 (ko)
RU (1) RU2134153C1 (ko)
TW (1) TW326464B (ko)
WO (1) WO1995008389A1 (ko)

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Publication number Publication date
RU2134153C1 (ru) 1999-08-10
JP3781427B2 (ja) 2006-05-31
AU682062B2 (en) 1997-09-18
BR9407577A (pt) 1996-07-16
DE69411574T2 (de) 1998-11-05
WO1995008389A1 (en) 1995-03-30
TW326464B (en) 1998-02-11
DE69411574D1 (de) 1998-08-13
AU7697194A (en) 1995-04-10
US5500219A (en) 1996-03-19
JPH09506029A (ja) 1997-06-17
KR100373966B1 (ko) 2003-04-23
CA2132508A1 (en) 1995-03-22
EP0720511A1 (en) 1996-07-10
EP0720511B1 (en) 1998-07-08
ES2118436T3 (es) 1998-09-16
CO4340716A1 (es) 1996-07-30
CA2132508C (en) 2000-08-22

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