JPH0689469B2 - 水溶液電気分解用陰極 - Google Patents
水溶液電気分解用陰極Info
- Publication number
- JPH0689469B2 JPH0689469B2 JP59127243A JP12724384A JPH0689469B2 JP H0689469 B2 JPH0689469 B2 JP H0689469B2 JP 59127243 A JP59127243 A JP 59127243A JP 12724384 A JP12724384 A JP 12724384A JP H0689469 B2 JPH0689469 B2 JP H0689469B2
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- cathode
- layer
- partial
- coating layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005868 electrolysis reaction Methods 0.000 title claims description 11
- 239000007864 aqueous solution Substances 0.000 title claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 38
- 239000010410 layer Substances 0.000 claims description 31
- 229910052759 nickel Inorganic materials 0.000 claims description 19
- 239000011247 coating layer Substances 0.000 claims description 17
- 229910001925 ruthenium oxide Inorganic materials 0.000 claims description 15
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 claims description 15
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 13
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 13
- 229910000831 Steel Inorganic materials 0.000 claims description 11
- 239000010959 steel Substances 0.000 claims description 11
- 239000003792 electrolyte Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 230000007423 decrease Effects 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229910052707 ruthenium Inorganic materials 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 244000099147 Ananas comosus Species 0.000 description 1
- 235000007119 Ananas comosus Nutrition 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- DUDJJJCZFBPZKW-UHFFFAOYSA-N [Ru]=S Chemical compound [Ru]=S DUDJJJCZFBPZKW-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- XIKYYQJBTPYKSG-UHFFFAOYSA-N nickel Chemical compound [Ni].[Ni] XIKYYQJBTPYKSG-UHFFFAOYSA-N 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- -1 platinum group metals Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003303 ruthenium Chemical class 0.000 description 1
- 150000003304 ruthenium compounds Chemical group 0.000 description 1
- VDRDGQXTSLSKKY-UHFFFAOYSA-K ruthenium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Ru+3] VDRDGQXTSLSKKY-UHFFFAOYSA-K 0.000 description 1
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- PGYWOZWVYYSTKK-UHFFFAOYSA-K trichlororuthenium hydrochloride Chemical compound Cl.Cl[Ru](Cl)Cl PGYWOZWVYYSTKK-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/093—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3322169.3 | 1983-06-21 | ||
DE19833322169 DE3322169A1 (de) | 1983-06-21 | 1983-06-21 | Kathode fuer waesserige elektrolysen |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6017086A JPS6017086A (ja) | 1985-01-28 |
JPH0689469B2 true JPH0689469B2 (ja) | 1994-11-09 |
Family
ID=6201896
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59127243A Expired - Lifetime JPH0689469B2 (ja) | 1983-06-21 | 1984-06-20 | 水溶液電気分解用陰極 |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0129088B1 (enrdf_load_stackoverflow) |
JP (1) | JPH0689469B2 (enrdf_load_stackoverflow) |
DE (1) | DE3322169A1 (enrdf_load_stackoverflow) |
NO (1) | NO161812C (enrdf_load_stackoverflow) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3344416A1 (de) * | 1983-12-08 | 1985-12-05 | Sigri GmbH, 8901 Meitingen | Verfahren zur herstellung einer kathode fuer die waesserige elektrolyse |
FR2579628A1 (fr) * | 1985-03-29 | 1986-10-03 | Atochem | Cathode pour electrolyse et un procede de fabrication de ladite cathode |
FR2596776B1 (fr) * | 1986-04-03 | 1988-06-03 | Atochem | Cathode pour electrolyse et un procede de fabrication de ladite cathode |
DE3612790A1 (de) * | 1986-04-16 | 1987-10-22 | Sigri Gmbh | Kathode fuer waesserige elektrolysen |
US5066380A (en) * | 1990-05-29 | 1991-11-19 | The Dow Chemical Company | Electrocatalytic cathodes and method of preparation |
US5164062A (en) * | 1990-05-29 | 1992-11-17 | The Dow Chemical Company | Electrocatalytic cathodes and method of preparation |
US5035789A (en) * | 1990-05-29 | 1991-07-30 | The Dow Chemical Company | Electrocatalytic cathodes and methods of preparation |
US5227030A (en) * | 1990-05-29 | 1993-07-13 | The Dow Chemical Company | Electrocatalytic cathodes and methods of preparation |
JP2008124855A (ja) * | 2006-11-14 | 2008-05-29 | Funai Electric Co Ltd | スピーカ装置 |
DE102010023418A1 (de) * | 2010-06-11 | 2011-12-15 | Uhde Gmbh | Ein- oder mehrseitige Substratbeschichtung |
CN114643187A (zh) * | 2022-03-10 | 2022-06-21 | 宝鸡宝冶钛镍制造有限责任公司 | 一种离子膜电解槽镍阴极活性涂层及镍阴极表面处理方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1195871A (en) * | 1967-02-10 | 1970-06-24 | Chemnor Ag | Improvements in or relating to the Manufacture of Electrodes. |
US3990957A (en) * | 1975-11-17 | 1976-11-09 | Ppg Industries, Inc. | Method of electrolysis |
DE2734084A1 (de) * | 1976-08-02 | 1978-02-09 | Goodrich Co B F | Verfahren zur herstellung von chlor und phosphatsalzen durch elektrolyse |
DE2811472A1 (de) * | 1977-03-19 | 1978-09-21 | Tokuyama Soda Kk | Kathoden fuer elektrolytische zellen |
US4100049A (en) * | 1977-07-11 | 1978-07-11 | Diamond Shamrock Corporation | Coated cathode for electrolysis cells |
US4544473A (en) * | 1980-05-12 | 1985-10-01 | Energy Conversion Devices, Inc. | Catalytic electrolytic electrode |
JPS6022070B2 (ja) * | 1981-09-22 | 1985-05-30 | ペルメレツク電極株式会社 | 酸性溶液電解用陰極及びその製造方法 |
AU580002B2 (en) * | 1983-05-31 | 1988-12-22 | Dow Chemical Company, The | Preparation and use of electrodes |
-
1983
- 1983-06-21 DE DE19833322169 patent/DE3322169A1/de active Granted
-
1984
- 1984-05-23 EP EP84105859A patent/EP0129088B1/de not_active Expired
- 1984-06-18 NO NO842443A patent/NO161812C/no not_active IP Right Cessation
- 1984-06-20 JP JP59127243A patent/JPH0689469B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE3322169A1 (de) | 1985-01-10 |
EP0129088B1 (de) | 1987-05-20 |
NO161812B (no) | 1989-06-19 |
NO161812C (no) | 1989-09-27 |
JPS6017086A (ja) | 1985-01-28 |
EP0129088A1 (de) | 1984-12-27 |
DE3322169C2 (enrdf_load_stackoverflow) | 1990-06-13 |
NO842443L (no) | 1984-12-27 |
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