JPH0542366B2 - - Google Patents
Info
- Publication number
- JPH0542366B2 JPH0542366B2 JP59275020A JP27502084A JPH0542366B2 JP H0542366 B2 JPH0542366 B2 JP H0542366B2 JP 59275020 A JP59275020 A JP 59275020A JP 27502084 A JP27502084 A JP 27502084A JP H0542366 B2 JPH0542366 B2 JP H0542366B2
- Authority
- JP
- Japan
- Prior art keywords
- sio
- crystalline
- reaction
- silicic acid
- mmol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000012239 silicon dioxide Nutrition 0.000 claims description 56
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 55
- 239000011734 sodium Substances 0.000 claims description 43
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 39
- 238000006243 chemical reaction Methods 0.000 claims description 37
- 238000005342 ion exchange Methods 0.000 claims description 30
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 24
- 239000011541 reaction mixture Substances 0.000 claims description 23
- 239000004115 Sodium Silicate Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 20
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 238000002441 X-ray diffraction Methods 0.000 claims description 18
- 238000004448 titration Methods 0.000 claims description 18
- 239000013078 crystal Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 159000000000 sodium salts Chemical class 0.000 claims description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 229910052681 coesite Inorganic materials 0.000 claims description 6
- 229910052906 cristobalite Inorganic materials 0.000 claims description 6
- 229910052682 stishovite Inorganic materials 0.000 claims description 6
- 229910052905 tridymite Inorganic materials 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 4
- -1 alkali metal salt Chemical class 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000010586 diagram Methods 0.000 claims description 3
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 239000000047 product Substances 0.000 description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 15
- 239000002253 acid Substances 0.000 description 15
- 238000007792 addition Methods 0.000 description 14
- 230000035484 reaction time Effects 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 10
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 125000005624 silicic acid group Chemical class 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 150000004760 silicates Chemical class 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 238000002425 crystallisation Methods 0.000 description 6
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- 235000019353 potassium silicate Nutrition 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000000921 elemental analysis Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000002083 X-ray spectrum Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 229910052680 mordenite Inorganic materials 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 229910052615 phyllosilicate Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910006358 SiâOH Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000004455 differential thermal analysis Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 238000000954 titration curve Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910009112 xH2O Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Silicon Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
æ¬çºæã¯å±€æ§é ãæããæ°èŠãªçµæ¶æ§ã±ã€é
žã
ãã®æ°èŠãªçµæ¶æ§ãããªãŠã å¡©ããã³ãããã®å
åç©ãæ°Žæ§åªè³ªäžã§è£œé ããæ¹æ³ã«é¢ããã ç¡å®åœ¢ã®ã±ã€é žãšå ±ã«ãè¥å¹²ã®çµæ¶è³ªã±ã€é žã
ãŸãç¥ãããŠããããã®éãéªšæ Œæ§é ãæããã±
ã€é žãšå±€æ§é ãæããã±ã€é žãšãåºå¥ããããšã
ã§ãããã¢ã«ãããŠã ãå«ãŸãªããããŸãã¯ã¢ã«
ãããŠã å«éã®æ¥µããŠäœããæ°ŽçŽ åã®ãŒãªã©ã€ã
ã¯ãéªšæ Œæ§é ãæããã±ã€é žã®ãã¡ã«ç®ããã
ããããã«ã¯ããŒãªã©ã€ãZSMâïŒã®æ¥µããŠã¢
ã«ãããŠã å«éã®äœã代衚äŸãšããŠã®ã·ãªã«ã©ã€
ãïŒSilicalitïŒïŒç±³åœç¹èš±ç¬¬4061724å·åç §ïŒãŸã
ã¯ããªãŒãžã€ãµã€ãåãŸãã¯ã¢ã«ããã€ãåã®è±
ã¢ã«ãããŠã ããããŒãªã©ã€ããå±ããã æŽã«ãè¥å¹²ã®å±€ç¶ã±ã€é žããããã®ã¢ã«ã«ãªå¡©
ã倩ç¶ç£ãšããŠèŠåºãããŠããããšãç¥ãããŠã
ãïŒH.P.EugsterãScienceã157ã1177â1180ïŒ
T.P.Rooney et al.ãAmer.Mineral.ã54ã1034
â1043ïŒ1969ïŒïŒG.Maglioneããã³M.Servantã
C.R.Acad.Sci.ãSer.ãD.ã277ã1721â1724
ïŒ1973ïŒïŒJ.L.McAteeãJr.et al.ãAmer.
Mineral.ã53ïŒ1968ïŒã2061â2069åç §ïŒãããã
ã®å¡©ã¯ããŸãåæã«ãã€ãŠãåŸãããïŒL.Mc
CullochãJ.Amer.Chem.Soc.ã74ã2453â2456
ïŒ1952ïŒïŒG.LagalyãK.Beneckeããã³A.Weissã
Proc.Int.Clay Conf.ãMadrid1972ã663â673
ïŒ1973ïŒãR.K.Ilerâ²J.Colloid Sci.19ã648â657
ïŒ1964ïŒããã€ãç¹èš±ç¬¬2742912å·ãG.Lagaly et
al.ãZ.Naturforsch.28bã234â238ïŒ1973ïŒãZ.
Naturforsch.34bã666â674ïŒ1979ïŒK.Benekeã
ãã³G.LagalyãAmer.Mineral.ã68ïŒ1983ïŒ818
â826åç §ïŒã ã¢ã«ã«ãªã±ã€é žå¡©ããé žæ§ã€ãªã³äº€æã«ãã€ãŠ
éé¢ã®ã±ã€é žãåŸãããããã®éãååç©ã®å±€æ§
é ããã®ãŸãŸã§åŸãããããã®åã®ã±ã€é žãŸãã¯
ã±ã€é žå¡©ã«ãšã€ãŠç¹åŸŽçãªããšã«ã¯ãçµæ¶æ§ã®å«
æ°Žäºé žåã±ã€çŽ ã®å±€ã®éã«å€æ¥ååãçµèŸŒãèœå
ã§ããããã®éãç·åæå³ããå±€ã®æ¡å€§ãæšè«
ããããã ãã€ãç¹èš±ç¬¬2742912å·ã«èšèŒãããå±€æ§é ã
æããã±ã€é žã¯ãçŽç²ãªåœ¢ãŸãã¯ãã®ä»å ååç©
ã®åœ¢ã§åžçå€ãšããŠäœ¿çšããããã 容æã«å ¥æãããåºçºçæç©ããç°¡åãªæ¹æ³ã§
é¡äŒŒã®ã±ã€é žããã³å±€ç¶ã®ã¢ã«ã«ãªéå±ã±ã€é žå¡©
ã補é ãããæ¹æ³ãèŠåºããšãã課é¡ããã€ãã
äœå»ãªå·¥æ¥ç補é ãå¯èœã«ããããã«ããã®æ¹æ³
ã¯ãæ倧éïŒæ¥éãšããçããåå¿æéã§å®æœã§
ããªããã°ãªããªããããã¯ãæŽã«ç³è±ããã³ç¡
å®åœ¢éšåãã§ããéãå«æããªãçæç©ãããã
ããªããã°ãªããªãã æ¬çºæã¯ãäžèšã®èª²é¡ã解決ãããã®ã§ããã
æ¬çºæã¯ãå±€æ§é ãæããããŠ83ãªãã130ããª
ã¢ã«Na+ïŒã¢ã«SiO2ã®ã€ãªã³äº€æ容éãæãã
çµæ¶æ§ã±ã€é žãããªãŠã ã補é ãã¹ãã3.9ïŒïŒ
ãªãã15ïŒïŒã®SiO2ïŒNa2Oã®ã¢ã«æ¯ããã³ïŒïŒ
ïŒãªãã80ïŒïŒã®H2OïŒïŒNa2OïŒSiO2ïŒã®ã¢ã«
æ¯ãæãã䜿çšããåå¿æ··åç©ã®SiO2å«æéã«
é¢ããŠææã®çµæ¶æ§ã±ã€é žãããªãŠã ã®çš®åçµæ¶
ã®0.01ãªãã30ééïŒ ãå«æãããã±ã€é žãããª
ãŠã å«ææ°Žæ§åå¿æ··åç©ãçšæããããã160ãª
ãã250âã®æž©åºŠã«å ç±ãããããŠå°ããšããåž
åŒéãããããŠ120âã«ãããŠä¹Ÿç¥ãããè©Šæ
ãç·åæå³ã«ãã㊠d1ïŒïŒ20±ïŒïŒã»10-8cmã®æ Œåé¢éè·é¢ã«ããã
åå°åŒ·åºŠå¯Ÿd2ïŒïŒ15.5±1.5ïŒã»10-8cmã®æ Œåééé
ã«ãããåå°ã®åŒ·ãã®æ¯ãå°ããšãïŒïŒïŒã瀺ã
ã«è³ããŸã§å°ããšãåå¿ãå®æœãããããŠd3ïŒ
ïŒ3.34±0.04ïŒã»10-8cmã®æ Œåéééã«ãããåå°
ã®åŒ·ããd4ïŒïŒ3.44±0.04ïŒã»10-8cmã®æ Œåé¢éé
ã«ãããåå°ã®åŒ·ãã«éããããŸãã¯ãããè¶ ã
ãåã«åå¿ãçµäºãããããšãç¹åŸŽãšãããåèš
çµæ¶æ§ã±ã€é žãããªãŠã ã®è£œé æ¹æ³ã«é¢ããã åºçºçæç©ãšããŠã¯ãæ°Žé žåãããªãŠã ãšæ²æ®¿
ã±ã€é žãã·ãªã«ã²ã«ãŸãã¯ã·ãªã«ãŸã«ãšã®æ··åç©
ã䜿çšããããããããªããããœãŒãæ°Žã¬ã©ã¹ã
ç¹ã«SiO221ãªãã30ééïŒ ããã³Na2O5ãªãã
10ééïŒ ãå«æããæ°Žã¬ã©ã¹ã䜿çšããããšã奜
ãŸããããããã®æ°Žã¬ã©ã¹ã¯ãäœå»ã§ãåæ±ãæ
ããããé«ãåå¿æ§ã瀺ãã ãã®éãé žæ§ååç©ã®æ·»å ã«ãã€ãŠSiO2ïŒ
Na2Oã®æ¯ãé«ããããšãå¿ èŠã§ãããããã
ãšããã®ããã«ããŠäžåãããéã¯ãSiO2ïŒ
Na2Oã®æ¯ã«æŽã«å¯äžããããšã¯ãªãã åå¿æéã¯ãåå¿æž©åºŠã«åŒ·ãäŸåãããããã¯
200ãªãã250âã®æž©åºŠã«ãããŠã¯ïŒæé以äžã§ã
ãããããïŒããäœã枩床ããã³SiO2ïŒNa2Oã®
ããäœãæ¯ã®å Žåã«ãããŠïŒ48æéãŸã§ã§ããã
ããåå¿æéã¯ãåå¿äžçš®ã ã®æç¹ã«ãããŠè©Šæ
ãæ¡åããããŠããããç·åæã«ãã€ãŠããã
ãè©Šéšããããšã«ãã€ãŠãéžæãããåå¿æž©åºŠã«
ã€ããŠæ±ºå®ãããããããã¯ã奜ãŸããã¯ãŸãå°
èŠæš¡ã®ã¢ãã«ããããçšããŠå®æœããããæ Œåé¢
ééd1ããã³d4ã«ãããåå°ã¯ãå±€æ§é ïŒïŒã
æããææã®ã±ã€é žãããªãŠã ã«åž°ãããããåŸ
ã€ãŠãããã®åŒ·ãïŒããªãã¡çæç©æ··åç©äžã«ç
æããçµæ¶æ§ã±ã€é žãããªãŠã ã®éïŒã¯ãã§ãã
ã ãé«ããã¹ãã§ãããæ Œåé¢ééd2ã«ãããå
å°ã¯ãåãããé©åœãªåå¿æ¡ä»¶ãéžæãããå Žå
ã«ã¯èªããããªãããã®å Žåã«ã¯ãd1ããã³d2ã«
ãããåå°ã®åŒ·ãã¯ãå®è³ªçã«ïŒããé«ããd2ã«
ãããåå°ã¯ãäžéçæç©ãšããŠãã¬ãžã¢ã€ã
ïŒmagadiiteïŒãçæãããšãã«èªãããããã
ãããªããããã¬ãžã¢ã€ãã¯ãåå¿æ¡ä»¶äžã§ã¯å®
å®ã§ãªãã®ã§ãd2ã®åŒ·ãã¯æ倧å€ãééãããã
åå¿æéã¯ãæå©ã«ã¯éåžžã«å»¶é·ãããã®ã§ãd2
ã«ãããŠã¯ããã¯ãåå°ãèµ·ããªããåæ§ãªçµæ
ã¯ãåãåå¿æéã«ãããŠæž©åºŠãé«ããããšã«ã
ã€ãŠãéæãããããæ Œåé¢ééd3ã«ãããåå°
ã®åŒ·ãã¯ãããé·ãåå°æéã«ãããŠäžéšã¯ç³è±
ïŒã¹ãã¯ãã«ã«ãããéãããŒã¯ïŒã«ãããŠå€§éš
åã¯ãææã®ã±ã€é žå¡©ïŒã¹ãã¯ãã«ã«ãããŠäžæ
çãªæ¥µå€§å€ïŒã«åž°ããããã SiO2ïŒNa2OïŒäžåãããŠããªããã®ïŒã®ã¢ã«
æ¯ã¯ã奜ãŸããã¯ïŒïŒïŒãªãã10ïŒïŒã§ããã
H2OïŒïŒNa2OïŒSiO2ïŒã®ã¢ã«æ¯ã¯ã奜ãŸããã¯
ïŒïŒïŒãªãã40ïŒïŒã§ãããåå¿æž©åºŠã¯ã奜ãŸã
ãã¯175ãªãã230âãç¹ã«180ãªãã210âã§ã
ãã ãããªãŠã ã€ãªã³ã«å ããã«ãè¿œå çã«ä»ã®é
å±ã€ãªã³ãäŸãã°ã²ã«ãããŠã ãã¢ã«ãããŠã ã
ã€ã³ãžãŠã ããçŽ ããã³ã¢ã³ãã¢ã³ã®ã€ãªã³ãªã
ã³ã«ééå±ã®ãªã³ããã³ããŠçŽ ããŸãåæã®éã«
䜿çšããããããããã®æåã®éããããªãŠã ã®
å«éã«é¢ããŠ10ïŒ ãè¶ ããªãéããåæã¯å ãã
ã圱é¿ãåããªããçŽç²ãªå±€ç¶ã±ã€é žãããªãŠã
ïŒïŒãŸãã¯éé¢ã®é žïŒïŒã補é ããããã«ã¯ã
åæã®éã«ç°çš®ã®éå±ã®æ·»å ãçç¥ããããšãæ
å©ã§ãããã¢ã«ã«ãªéå±ïŒIAïŒä»¥å€ã®ä»ã®éœã€
ãªã³ãå«æããçŽç²ãªå±€ç¶ã±ã€é žå¡©ã¯ããããªãŠ
ã å¡©ïŒïŒããã€ãªã³äº€æã«ãã€ãŠããŸãã¯å¯Ÿå¿
ããéé¢é žïŒïŒããäžåã«ãã€ãŠåŸãããã åºçºæ··åç©äžã®ã¢ã«ãããŠã ã®å€§éšåã¯ããŒãª
ã©ã€ãç³»å¯çæç©ã倧æµZSMâïŒâåãŸãã¯ã¢
ã«ããã€ãåã®ãããã®çæãããããããšãã§
ãããããã«å¯ŸããŠå·¥æ¥çšæ°Žã¬ã©ã¹äžã«ååšãã
ãããªãæ¯èŒçå å°ãªã¢ã«ãããŠã å«éã¯ãæªåœ±
é¿ãåãŒããªãã åå¿ã®éã«çããé«ãæ°Žèžæ°åå§ã®ããã«ãå
å¿ã¯å§å容åšå ã§ã奜ãŸããæ¹æäžã«å®æœãã
ããçš®åçµæ¶ã®æ·»å ã¯ãæ¯éãšãå¿ èŠã§ãããã
ãããªãããæ¯èŒçé·ãåå¿æéã«ãããŠã¯åæ§
ãªã±ã€é žå¡©ïŒäœãçŽåºŠãæãããã®ïŒã¯ãçš®åã®
çµæ¶ã®æ·»å ãªãã§ãçæããã çš®åçµæ¶ã®éã¯ãéé£ç¶çãªåå¿ã®å®æœã®éã«
ã¯äœ¿çšãããåå¿æ··åç©ã®SiO2å«éã«é¢ããŠå¥œ
ãŸããã¯0.5ã10ééïŒ ã§ããã0.01ééïŒ ä»¥äž
ã®çš®åçµæ¶ã®æ·»å ã¯ãèªããããçšã®å¹æããã¯
ããããããªããçš®åçµæ¶ãæ·»å ãã代ãã«ãå
ã®ãããããã®å°éã®æ®éšãåå¿å®¹åšå ã«æ®ã€ãŠ
ããå Žåã«ã¯ãããã§å åã§ãããé£ç¶çåå¿æ
äœã®å Žåã«ã¯ãçµæ¶æ žã®æ¯èŒçã«é«ãæ¿åºŠïŒå®åžž
ç平衡ã«ãããŠïŒããŸãæå©ã§ããããšãç«èšŒã
ãããçš®åçµæ¶ã®æ·»å ã¯ãçæç©ã®çŽåºŠã«æå©ã«
äœçšãããŸãåå¿æéãèããççž®ããã æ¬çºæã«ããæ¹æ³ã¯ãæµã管âãæ¹æ槜âãŸã
ã¯ã«ã¹ã±ãŒãã®ç¹åŸŽãæããè£ çœ®ã«ãããŠããã
ãåŒãåé£ç¶åŒãŸãã¯é£ç¶åŒã«å®æœãããããå ¬
ç¥ã®æ¹æ³ã«æ¯èŒããŠåå¿æéã極ããŠçãããšã
ãå©ç¹ãããããããŸãåæã«æ¥µããŠããããç
æç©ã®å質ãžãšå°ããã©ã¹ã¿ãŒé»åé¡åŸ®é¡åç
ã¯ãæ¬çºæã«ããæ¹æ³ã«åŸã€ãŠè£œé ãããçæç©
ã¯ãç¡å®åœ¢ã®æåãç³è±å«ææåãå«æããªãã
ãšã瀺ããŠããã æ¬çºæã«ããæ¹æ³ã«åŸã€ãŠåŸãããçµæ¶æ§ãã
ãªãŠã å¡©ïŒïŒïŒããã¯NaâSKSâïŒïŒå±€ç¶ã±ã€
é žïŒã®ãããªãŠã å¡©ãšåŒã°ããïŒã¯ãå±€æ§é ãæ
ããç·åæå³ã«ãããŠïŒ3.42±0.15ïŒã»10-8cmã«
ãããŠå°ããšãïŒåã®æ¥µããŠåŒ·ãç·ã瀺ããããŠ
0.083ãªãã0.13ã®ãããªãŠã ïŒã±ã€çŽ ã®ååæ¯
ãæãããããã¯å®éšåŒNa2SixO2x+1ïŒããã«ïœ
ã¯15ãªãã24ã®æ°ã§ããïŒã«çžåœããã åŸããããããªãŠã å¡©ïŒïŒã¯ãéœã€ãªã³äº€æ
äœãšããŠã®æåã瀺ããã€ãªã³äº€æ容éã¯ãïŒç¡
æ°Žã®çæç©ã«æç®ããŠïŒ132ãªãã203ããªã¢ã«
NaïŒ100ïœã®ç¯å²å ãç¹ã«132ãªãã173ããªã¢
ã«ïŒ100ïœã®ç¯å²å ã«ãããããã¯é žã«ãããã
ãªãŠã å¡©ã®æ»Žå®ãªãã³ã«èæ§ã¢ã«ã«ãªæ¶²ã«ããåŸ
ãããé žã®é滎å®ã«ãã€ãŠæ±ºå®ããããåæãã¬
ãžã¢ã€ãïŒè©Šéšç©è³ªãšããŠã®ïŒã«ã€ããŠã®åæ§ãª
枬å®æ¹æ³ã¯ãæç®ã«ããå ¬ç¥ãšãªã€ãŠããNaïŒ
Siâæ¯ããããããäžèšã®ç¯å²ã®åºãã¯ãäžéšã¯
åçŸæ§ã«ãããäžéšã¯çµæ¶æ§ã±ã€é žãããªãŠã äž
ã®å¯çæç©ã®éã®å°ãªãããšã«ãã€ãŠæ¡ä»¶ã¥ãã
ããã çŽç²ãªçæç©ïŒïŒã¯ã145ããªã¢ã«NaïŒ100
ïœã®ã€ãªã³äº€æ容éã瀺ãããŸãNa2Si22O45ã®
çæ³çµæãæãããã®ãšèããããŠããã ãããªãŠã å¡©ïŒïŒã®ïŒžç·ã¹ãã¯ãã«ã¯â第ïŒ
è¡šããæãããªããã«âã±ãã¢ã€ãã®ãSiO2â
ïŒHeydemannãBeitr.Min.Petrog.10ã242â
259ïŒ1964ïŒåç §ïŒã®ã極ããŠäœã亀æ容éãæã
ãé«å§åæã«ããåŸãããã±ã€é žå¡©ã§ãã
âSiO2ïŒX2âçžïŒâïŒB.Mitsyuk et al.ãGeochem.
Int.13ã202ïŒ1976ïŒåç §ïŒã®ãããã³K2Si8O17ã»
xH2OïŒãã€ãç¹èš±ç¬¬2742912å·å ¬å ±åç §ïŒã®ãã
ããã®ã¹ãã¯ãã«ã«é¡äŒŒããããã®ããšãããå±€
ç¶ã¢ã«ã«ãªéå±ã±ã€é žå¡©ããNa2Si22O45ã»xH2O
ïŒã±ãã¢ã€ãïŒãSiO2âãSiO2ïŒX2âçžïŒã
K2SiO17ã»xH2Oããã³NaâSKSâïŒã«ãããŠ
ã¯ãæ§é äžã®é¡äŒŒæ§ãååšããã«ã¡ãããªããšæš
å®ããããšãã§ããäžèšã®ãã¹ãŠã®å±€ç¶ã±ã€é žå¡©
ã¯ããããã®ïŒžç·åæå³ã«é¢ããŠã±ãã¢ã€ãç³»ã®
ã±ã€é žå¡©ãšããŠææ¡ããããšãã§ãããSiO2â
ãšK2Si8O17ã»xH2OãŸãã¯å¯Ÿå¿ããéé¢ã®é žãš
ã®éã®åŒ·ãé¡äŒŒæ§ãããããã±ïŒBeneckeïŒãã
ã³ã©ã¬ãªãŒïŒLagalyïŒã«ãã€ãŠææãããŠãã
ïŒZ.Naturforsch.34bã648â649ïŒ1979ïŒåç §ïŒãå
çŽ åæã«ããNaâSKSâïŒã®çµæããŸãæ¬çºæ
ã«ãããããªãŠã å¡©ãšé±ç©ã±ãã¢ã€ããšã®é¡äŒŒæ§
ã瀺ããŠãããããããªãããé žãçšãã滎å®ç¹
æ§ã«ãããŠãæãããªçžç°ã瀺ããŠãããNaâ
SKSâïŒã¯ã83ã130ããªã¢ã«Na+ïŒã¢ã«SiO2ã€
ãªã³äº€æ容éãæããããŠã»ãŒåœéã®å¡©é žã«ãã€
ãŠéé¢ã®é žïŒïŒšâSKSâïŒïŒã«å€æãããããã
é±ç©ã±ãã¢ã€ãã¯åžèé žãšåå¿ããŠ333ããªã¢ã«
H+ïŒã¢ã«SiO2ã®å¯Ÿå¿ããé žã®ïŒçè«äžã®ïŒã€ãª
ã³äº€æ容éãæãã6SiO2ã»H2Oãšãªããããã
ãªããããã®æ°ŽåãããSiO2ã¯ããã®ã€ãªã³äº€
æèœã«ãããŠã®ã¿ãªããããŸããã®ïŒžç·åæãã¿
ãŒã³ã«ãããŠãããã®å Žåã«çæãããå±€æ§é ã
æããéé¢ã®ã±ã€é žïŒšâSKSâïŒãšã¯æããã«
çžéãããé žãšã¯ç°ãªããã®æåã¯ããªã€ã°ã¹ã¿
ãŒïŒEugsterïŒã«ãã€ãŠçºèŠããã倩ç¶ç£ã®å±€ç¶
ã±ã€é žãããªãŠã ã§ããã±ãã¢ã€ãã¯ãNaâ
SKSâïŒãšåäžã§ãªãããšã瀺ããŠããã ãã€ãç¹èš±ç¬¬2742912å·ã«ããã°ãK2Si8O17ã»
xH2Oã¯ã250ããªã¢ã«K+ïŒã¢ã«SiO2ã®ã€ãªã³äº€
æèœãæãããSiO2ïŒX2âçžïŒã«ã€ããŠã¯ãæç®
äžã«SiO2âX2100ïœåœã100ã130mgNa+ã®ã€ãªã³
亀æ容éãèšèŒãããŠãããããã¯èšç®ã«ããã°
çŽ62ã81ããªã¢ã«Na+ïŒã¢ã«SiO2ã®äº€æ容éã«
çžåœããããã®æ¯èŒã¯ãç·åæå³ã«ãããå®è³ª
çãªåå°ã«å ããŠãæŽã«ã€ãªã³äº€æ容éã«é¢ãã
èšèŒããŸãçµæ¶æ§ã±ã€é žã®æ確ãªç¹åŸŽä»ãã«ãšã€
ãŠå¿ èŠã§ããããšã瀺ããŠããã å±€æ§é ãæããã±ã€é žã®ä»ã®çµæ¶æ§ã¢ã«ã«ãªé
å±å¡©ïŒIaïŒãäŸãã°ã«ãªãŠã ããã³ãªããŠã å¡©ã¯ã
åæ§ã«ïŒ3.42±0.15ïŒã»10-8cmã«ãããŠæ¥µããŠåŒ·ã
ç·ã瀺ãããããŠ0.083ãªãã0.13ã®ã¢ã«ã«ãªé
å±ïŒã±ã€çŽ ã®ååæ¯ãæããããããã¯ããããª
ãŠã å¡©ïŒïŒããã€ãªã³äº€æã«ããããŸãã¯å±€æ§
é ãæããéé¢ã®ã±ã€é žïŒïŒããã¢ã«ã«ãªéå±
æ°Žé žåç©ã§äžåããããšã«ãã€ãŠåŸãããã éé¢ã®çµæ¶æ§ã±ã€é žïŒšâSKSâïŒïŒïŒãåŸã
ããã«ã¯ãåžèãªæ°Žæ§ç¡æ©é žãçšããŠæã奜éœå
ã«å®æœããããå®å šãªå€æã®ããã«ã¯ããããã³
ã®éã¯ãé€å»ãããã¹ãã¢ã«ã«ãªéå±ã€ãªã³ã®é
ã®å°ããšãçã¢ã«éã§ãªããã°ãªããªããéå°ã®
é žã䜿çšããããšã奜ãŸãããåŠçãã¹ãã¢ã«ã«
ãªéå±ã±ã€é žå¡©ïŒïŒãå°éã¥ã€é žãšæ··åããã¢
ã«ã«ãªã€ãªã³ãå«æããåå¿æº¶æ¶²ãæ®æž£ããåé¢
ããããŠãã®æ¹æ³ãæ°åå埩ããããšãç¹ã«æå©
ã§ãããã€ãªã³äº€æãå®äºããããã®æéãççž®
ããããã«ã¯ãåå¿æ··åç©ãæ¹æããããšãæšå¥š
ãããããã®éãåå¿äžã®PHå€ãçŽ2.0ã«ãããš
æå©ã§ããã çæããã±ã€é žïŒšâSKSâïŒã¯ãå¥ããã
ãããŠå¿ èŠãªå Žåã«ã¯ãäŸãã°ä¹Ÿç¥åšå ã§140â
ã«ãããŠä¹Ÿç¥ãããããé žãäŸãã°ã«ãªãŠã å¡©ã«
å€æãããã¹ãå Žåã®ããã«ãæŽã«åŠçãããã¹
ãå Žåã«ã¯ã也ç¥ã¯ãå¿ èŠã§ã¯ãªãã æ¬çºæã«ããæ¹æ³ã«åŸã€ãŠåŸãããçµæ¶æ§ã±ã€
é žïŒšâSKSâïŒã¯ãæ°èŠã§ãããããã¯ãå®éš
åŒH2SixO2x+1ïŒããã«ïœã¯15ãªãã24ã®æ°ã§ããïŒ
ãæãããäžèšåŒã«ãããŠã¯ãååšããããšãã
ãæ°Žã¯ãèæ ®ã«å ¥ããããŠããªããæ°ãã«è£œé ã
ããçµæ¶æ§ã±ã€é žã¯ã也ç¥åã«ã¯çŽ10ãªãã60é
éïŒ ã®æ°Žãå«æããã也ç¥æäœäžããã®æ°Žã¯ãé£
ç¶çã«é€å»ãããæçµçã«ã¯ïŒïŒ ã«è¿ã¥ãããã®
çµæ¶æ§ã±ã€é žã¯ãç·åæå³ã«ãã㊠ïœïŒïŒ3.42±0.1ïŒã»10-8cmã«ãããŠæ¥µããŠåŒ·ã第
äžã®ç·ãããããŠïœïŒïŒ18±ïŒïŒã»10-8cmã«ãã
ãŠã第äžã®ç·ã®åŒ·åºŠã®ãããã75ïŒ ã®åŒ·åºŠãæã
ã第äºã®ç·ãæããããšã«ãã€ãŠéç«ã€ãŠããã
ããã¯æŽã«åæã®æ§é åŒã«äžèŽãã83ãªãã130
ããªã¢ã«H+ïŒã¢ã«SiO2ã®æ»Žå®ãããé žæ§åºŠã瀺
ããäžè¬ã«ã芳å¯ãããé žæ§åºŠã¯ã83ãªãã105
ããªã¢ã«H+ïŒã¢ã«SiO2ã®ç¯å²å ã«ããã æ°èŠãªçµæ¶æ§ã±ã€é žïŒšâSKSâïŒã®ïŒžç·åæ
ãã¿ãŒã³ã¯ãå°æ°ã®ç·ãã瀺ããªãããã®çæç©
ã¯ãçŽ3.42ã»10-8cmã®æ Œåé¢ééã«ãããå·Ÿåºã
匷ãç·ã«ãã€ãŠç¡å®åœ¢ã®ã±ã€é žãšã¯æããã«åºå¥
ããããæç®ã«ããã°ãïŒ3.2ã3.6ïŒã»10-8cmãã
ã³ïŒ11ã21ïŒã»10-8cmã®ç¯å²å ã®ç·ã¯ãå±€æ§é ã
æããã±ã€é žã«ãšã€ãŠå žåçãªãã®ã§ãããåŸã€
ãŠãæ¬çºæã«ããã±ã€é žããŸãå±€ç¶ã®çµæ¶æ§é ã
æããããšãæšå®ããããè¥å¹²ã®ïŒžç·åå°ã®åŒ·
ããç¹ã«ïœïŒïŒ18±ïŒïŒã»10-8cmã«ãããåå°ã®åŒ·
ãã¯ãã±ã€é žã®å«æ°Žéã«äŸåãããããããªã
ããç¹åŸŽçãªããšã¯ãïœïŒïŒ18±ïŒïŒã»10-8cmã«ã
ããåå°ã®åŒ·ããçŽ3.42ã»10-8cmã«ãããåå°ã®
ããã®ãããã75ïŒ ã§ãããšããäºå®ã§ãããæ¬
çºæã«ããæ°èŠãªã±ã€é žã¯ããã®ïŒžç·åæãã¿ãŒ
ã³ããã³ïŒãŸãã¯ãã®ç¹å®ã®ã€ãªã³äº€æ容éã«ã
ã€ãŠå ¬ç¥ã®çµæ¶æ§ã±ã€é žããåºå¥ããããã 第ïŒè¡šã«ãããŠãæ°èŠãªã±ã€é žïŒïŒããã®ïŒž
ç·åæãã¿ãŒã³ã«é¢ããŠãïŒçš®ã®å ¬ç¥ã®ã±ã€é žã
ããªãã¡ãH2Si8O17ã»xH2OïŒãã€ãç¹èš±ç¬¬
2742912å·åç §ïŒãH2Si14O29ã»xH2OïŒLagaly et
al.Z.Naturforsch.28bïŒ1973ïŒã234â238åç §ïŒ
ããã³é±ç©ãã¬ãžã¢ã€ãããã³ã±ãã¢ã€ãã®é žæ§
åã«ãã€ãŠåŸãããã±ã€é žSHïŒEugsterã
Science157ïŒ1967ïŒã1177â1180åç §ïŒãšæ¯èŒã
ããŠãããæ°èŠãªã±ã€é žïŒšâSKSâïŒã¯ãç·
åæãã¿ãŒã³ã«ãããŠH2Si8O17ã»xH2Oãšã®é¡äŒŒ
æ§ã瀺ããããããªãããããã¯ã€ãªã³äº€æ容é
ã«ãããŠãã®é žãšã¯æããã«çžéããŠããã H2Si8O17ã»xH2Oã¯ãSiO21ã¢ã«åœãçŽ250ããª
ã¢ã«ã®äº€æããããããã³ãæããããæ¬çºæã«
ããæ°èŠãªã±ã€é žã¯ãæããã«ããäœãã€ãªã³äº€
æ容éã瀺ããããã¯ãæé«130ããªã¢ã«H+ïŒã¢
ã«SiO2ã§ããããããŠäžè¬ã«83ããªã¢ã«H+ïŒã
ãªã¢ã«SiO2ãã倧ãããå žåçãªæ°å€ã¯ãSiO21
ã¢ã«åœã亀æãããH+83ãªãã105ããªã¢ã«ïŒç¹
ã«88ãªãã99ããªã¢ã«ïŒã§ãããåŸã€ãŠã
H2Si22O45ã®çæ³çµæãæšå®ãããããæ¬çºæã«
ããæ°èŠãªçæç©ã¯ããã§ã«å ¬ç¥ã®å±€ç¶ã±ã€é žå¡©
ãšåæ§ã«ãäŸãã°åžçå€ãšããŠäœ¿çšããããã
ãã®æ°èŠãªçµæ¶æ§ãããªãŠã å¡©ããã³ãããã®å
åç©ãæ°Žæ§åªè³ªäžã§è£œé ããæ¹æ³ã«é¢ããã ç¡å®åœ¢ã®ã±ã€é žãšå ±ã«ãè¥å¹²ã®çµæ¶è³ªã±ã€é žã
ãŸãç¥ãããŠããããã®éãéªšæ Œæ§é ãæããã±
ã€é žãšå±€æ§é ãæããã±ã€é žãšãåºå¥ããããšã
ã§ãããã¢ã«ãããŠã ãå«ãŸãªããããŸãã¯ã¢ã«
ãããŠã å«éã®æ¥µããŠäœããæ°ŽçŽ åã®ãŒãªã©ã€ã
ã¯ãéªšæ Œæ§é ãæããã±ã€é žã®ãã¡ã«ç®ããã
ããããã«ã¯ããŒãªã©ã€ãZSMâïŒã®æ¥µããŠã¢
ã«ãããŠã å«éã®äœã代衚äŸãšããŠã®ã·ãªã«ã©ã€
ãïŒSilicalitïŒïŒç±³åœç¹èš±ç¬¬4061724å·åç §ïŒãŸã
ã¯ããªãŒãžã€ãµã€ãåãŸãã¯ã¢ã«ããã€ãåã®è±
ã¢ã«ãããŠã ããããŒãªã©ã€ããå±ããã æŽã«ãè¥å¹²ã®å±€ç¶ã±ã€é žããããã®ã¢ã«ã«ãªå¡©
ã倩ç¶ç£ãšããŠèŠåºãããŠããããšãç¥ãããŠã
ãïŒH.P.EugsterãScienceã157ã1177â1180ïŒ
T.P.Rooney et al.ãAmer.Mineral.ã54ã1034
â1043ïŒ1969ïŒïŒG.Maglioneããã³M.Servantã
C.R.Acad.Sci.ãSer.ãD.ã277ã1721â1724
ïŒ1973ïŒïŒJ.L.McAteeãJr.et al.ãAmer.
Mineral.ã53ïŒ1968ïŒã2061â2069åç §ïŒãããã
ã®å¡©ã¯ããŸãåæã«ãã€ãŠãåŸãããïŒL.Mc
CullochãJ.Amer.Chem.Soc.ã74ã2453â2456
ïŒ1952ïŒïŒG.LagalyãK.Beneckeããã³A.Weissã
Proc.Int.Clay Conf.ãMadrid1972ã663â673
ïŒ1973ïŒãR.K.Ilerâ²J.Colloid Sci.19ã648â657
ïŒ1964ïŒããã€ãç¹èš±ç¬¬2742912å·ãG.Lagaly et
al.ãZ.Naturforsch.28bã234â238ïŒ1973ïŒãZ.
Naturforsch.34bã666â674ïŒ1979ïŒK.Benekeã
ãã³G.LagalyãAmer.Mineral.ã68ïŒ1983ïŒ818
â826åç §ïŒã ã¢ã«ã«ãªã±ã€é žå¡©ããé žæ§ã€ãªã³äº€æã«ãã€ãŠ
éé¢ã®ã±ã€é žãåŸãããããã®éãååç©ã®å±€æ§
é ããã®ãŸãŸã§åŸãããããã®åã®ã±ã€é žãŸãã¯
ã±ã€é žå¡©ã«ãšã€ãŠç¹åŸŽçãªããšã«ã¯ãçµæ¶æ§ã®å«
æ°Žäºé žåã±ã€çŽ ã®å±€ã®éã«å€æ¥ååãçµèŸŒãèœå
ã§ããããã®éãç·åæå³ããå±€ã®æ¡å€§ãæšè«
ããããã ãã€ãç¹èš±ç¬¬2742912å·ã«èšèŒãããå±€æ§é ã
æããã±ã€é žã¯ãçŽç²ãªåœ¢ãŸãã¯ãã®ä»å ååç©
ã®åœ¢ã§åžçå€ãšããŠäœ¿çšããããã 容æã«å ¥æãããåºçºçæç©ããç°¡åãªæ¹æ³ã§
é¡äŒŒã®ã±ã€é žããã³å±€ç¶ã®ã¢ã«ã«ãªéå±ã±ã€é žå¡©
ã補é ãããæ¹æ³ãèŠåºããšãã課é¡ããã€ãã
äœå»ãªå·¥æ¥ç補é ãå¯èœã«ããããã«ããã®æ¹æ³
ã¯ãæ倧éïŒæ¥éãšããçããåå¿æéã§å®æœã§
ããªããã°ãªããªããããã¯ãæŽã«ç³è±ããã³ç¡
å®åœ¢éšåãã§ããéãå«æããªãçæç©ãããã
ããªããã°ãªããªãã æ¬çºæã¯ãäžèšã®èª²é¡ã解決ãããã®ã§ããã
æ¬çºæã¯ãå±€æ§é ãæããããŠ83ãªãã130ããª
ã¢ã«Na+ïŒã¢ã«SiO2ã®ã€ãªã³äº€æ容éãæãã
çµæ¶æ§ã±ã€é žãããªãŠã ã補é ãã¹ãã3.9ïŒïŒ
ãªãã15ïŒïŒã®SiO2ïŒNa2Oã®ã¢ã«æ¯ããã³ïŒïŒ
ïŒãªãã80ïŒïŒã®H2OïŒïŒNa2OïŒSiO2ïŒã®ã¢ã«
æ¯ãæãã䜿çšããåå¿æ··åç©ã®SiO2å«æéã«
é¢ããŠææã®çµæ¶æ§ã±ã€é žãããªãŠã ã®çš®åçµæ¶
ã®0.01ãªãã30ééïŒ ãå«æãããã±ã€é žãããª
ãŠã å«ææ°Žæ§åå¿æ··åç©ãçšæããããã160ãª
ãã250âã®æž©åºŠã«å ç±ãããããŠå°ããšããåž
åŒéãããããŠ120âã«ãããŠä¹Ÿç¥ãããè©Šæ
ãç·åæå³ã«ãã㊠d1ïŒïŒ20±ïŒïŒã»10-8cmã®æ Œåé¢éè·é¢ã«ããã
åå°åŒ·åºŠå¯Ÿd2ïŒïŒ15.5±1.5ïŒã»10-8cmã®æ Œåééé
ã«ãããåå°ã®åŒ·ãã®æ¯ãå°ããšãïŒïŒïŒã瀺ã
ã«è³ããŸã§å°ããšãåå¿ãå®æœãããããŠd3ïŒ
ïŒ3.34±0.04ïŒã»10-8cmã®æ Œåéééã«ãããåå°
ã®åŒ·ããd4ïŒïŒ3.44±0.04ïŒã»10-8cmã®æ Œåé¢éé
ã«ãããåå°ã®åŒ·ãã«éããããŸãã¯ãããè¶ ã
ãåã«åå¿ãçµäºãããããšãç¹åŸŽãšãããåèš
çµæ¶æ§ã±ã€é žãããªãŠã ã®è£œé æ¹æ³ã«é¢ããã åºçºçæç©ãšããŠã¯ãæ°Žé žåãããªãŠã ãšæ²æ®¿
ã±ã€é žãã·ãªã«ã²ã«ãŸãã¯ã·ãªã«ãŸã«ãšã®æ··åç©
ã䜿çšããããããããªããããœãŒãæ°Žã¬ã©ã¹ã
ç¹ã«SiO221ãªãã30ééïŒ ããã³Na2O5ãªãã
10ééïŒ ãå«æããæ°Žã¬ã©ã¹ã䜿çšããããšã奜
ãŸããããããã®æ°Žã¬ã©ã¹ã¯ãäœå»ã§ãåæ±ãæ
ããããé«ãåå¿æ§ã瀺ãã ãã®éãé žæ§ååç©ã®æ·»å ã«ãã€ãŠSiO2ïŒ
Na2Oã®æ¯ãé«ããããšãå¿ èŠã§ãããããã
ãšããã®ããã«ããŠäžåãããéã¯ãSiO2ïŒ
Na2Oã®æ¯ã«æŽã«å¯äžããããšã¯ãªãã åå¿æéã¯ãåå¿æž©åºŠã«åŒ·ãäŸåãããããã¯
200ãªãã250âã®æž©åºŠã«ãããŠã¯ïŒæé以äžã§ã
ãããããïŒããäœã枩床ããã³SiO2ïŒNa2Oã®
ããäœãæ¯ã®å Žåã«ãããŠïŒ48æéãŸã§ã§ããã
ããåå¿æéã¯ãåå¿äžçš®ã ã®æç¹ã«ãããŠè©Šæ
ãæ¡åããããŠããããç·åæã«ãã€ãŠããã
ãè©Šéšããããšã«ãã€ãŠãéžæãããåå¿æž©åºŠã«
ã€ããŠæ±ºå®ãããããããã¯ã奜ãŸããã¯ãŸãå°
èŠæš¡ã®ã¢ãã«ããããçšããŠå®æœããããæ Œåé¢
ééd1ããã³d4ã«ãããåå°ã¯ãå±€æ§é ïŒïŒã
æããææã®ã±ã€é žãããªãŠã ã«åž°ãããããåŸ
ã€ãŠãããã®åŒ·ãïŒããªãã¡çæç©æ··åç©äžã«ç
æããçµæ¶æ§ã±ã€é žãããªãŠã ã®éïŒã¯ãã§ãã
ã ãé«ããã¹ãã§ãããæ Œåé¢ééd2ã«ãããå
å°ã¯ãåãããé©åœãªåå¿æ¡ä»¶ãéžæãããå Žå
ã«ã¯èªããããªãããã®å Žåã«ã¯ãd1ããã³d2ã«
ãããåå°ã®åŒ·ãã¯ãå®è³ªçã«ïŒããé«ããd2ã«
ãããåå°ã¯ãäžéçæç©ãšããŠãã¬ãžã¢ã€ã
ïŒmagadiiteïŒãçæãããšãã«èªãããããã
ãããªããããã¬ãžã¢ã€ãã¯ãåå¿æ¡ä»¶äžã§ã¯å®
å®ã§ãªãã®ã§ãd2ã®åŒ·ãã¯æ倧å€ãééãããã
åå¿æéã¯ãæå©ã«ã¯éåžžã«å»¶é·ãããã®ã§ãd2
ã«ãããŠã¯ããã¯ãåå°ãèµ·ããªããåæ§ãªçµæ
ã¯ãåãåå¿æéã«ãããŠæž©åºŠãé«ããããšã«ã
ã€ãŠãéæãããããæ Œåé¢ééd3ã«ãããåå°
ã®åŒ·ãã¯ãããé·ãåå°æéã«ãããŠäžéšã¯ç³è±
ïŒã¹ãã¯ãã«ã«ãããéãããŒã¯ïŒã«ãããŠå€§éš
åã¯ãææã®ã±ã€é žå¡©ïŒã¹ãã¯ãã«ã«ãããŠäžæ
çãªæ¥µå€§å€ïŒã«åž°ããããã SiO2ïŒNa2OïŒäžåãããŠããªããã®ïŒã®ã¢ã«
æ¯ã¯ã奜ãŸããã¯ïŒïŒïŒãªãã10ïŒïŒã§ããã
H2OïŒïŒNa2OïŒSiO2ïŒã®ã¢ã«æ¯ã¯ã奜ãŸããã¯
ïŒïŒïŒãªãã40ïŒïŒã§ãããåå¿æž©åºŠã¯ã奜ãŸã
ãã¯175ãªãã230âãç¹ã«180ãªãã210âã§ã
ãã ãããªãŠã ã€ãªã³ã«å ããã«ãè¿œå çã«ä»ã®é
å±ã€ãªã³ãäŸãã°ã²ã«ãããŠã ãã¢ã«ãããŠã ã
ã€ã³ãžãŠã ããçŽ ããã³ã¢ã³ãã¢ã³ã®ã€ãªã³ãªã
ã³ã«ééå±ã®ãªã³ããã³ããŠçŽ ããŸãåæã®éã«
䜿çšããããããããã®æåã®éããããªãŠã ã®
å«éã«é¢ããŠ10ïŒ ãè¶ ããªãéããåæã¯å ãã
ã圱é¿ãåããªããçŽç²ãªå±€ç¶ã±ã€é žãããªãŠã
ïŒïŒãŸãã¯éé¢ã®é žïŒïŒã補é ããããã«ã¯ã
åæã®éã«ç°çš®ã®éå±ã®æ·»å ãçç¥ããããšãæ
å©ã§ãããã¢ã«ã«ãªéå±ïŒIAïŒä»¥å€ã®ä»ã®éœã€
ãªã³ãå«æããçŽç²ãªå±€ç¶ã±ã€é žå¡©ã¯ããããªãŠ
ã å¡©ïŒïŒããã€ãªã³äº€æã«ãã€ãŠããŸãã¯å¯Ÿå¿
ããéé¢é žïŒïŒããäžåã«ãã€ãŠåŸãããã åºçºæ··åç©äžã®ã¢ã«ãããŠã ã®å€§éšåã¯ããŒãª
ã©ã€ãç³»å¯çæç©ã倧æµZSMâïŒâåãŸãã¯ã¢
ã«ããã€ãåã®ãããã®çæãããããããšãã§
ãããããã«å¯ŸããŠå·¥æ¥çšæ°Žã¬ã©ã¹äžã«ååšãã
ãããªãæ¯èŒçå å°ãªã¢ã«ãããŠã å«éã¯ãæªåœ±
é¿ãåãŒããªãã åå¿ã®éã«çããé«ãæ°Žèžæ°åå§ã®ããã«ãå
å¿ã¯å§å容åšå ã§ã奜ãŸããæ¹æäžã«å®æœãã
ããçš®åçµæ¶ã®æ·»å ã¯ãæ¯éãšãå¿ èŠã§ãããã
ãããªãããæ¯èŒçé·ãåå¿æéã«ãããŠã¯åæ§
ãªã±ã€é žå¡©ïŒäœãçŽåºŠãæãããã®ïŒã¯ãçš®åã®
çµæ¶ã®æ·»å ãªãã§ãçæããã çš®åçµæ¶ã®éã¯ãéé£ç¶çãªåå¿ã®å®æœã®éã«
ã¯äœ¿çšãããåå¿æ··åç©ã®SiO2å«éã«é¢ããŠå¥œ
ãŸããã¯0.5ã10ééïŒ ã§ããã0.01ééïŒ ä»¥äž
ã®çš®åçµæ¶ã®æ·»å ã¯ãèªããããçšã®å¹æããã¯
ããããããªããçš®åçµæ¶ãæ·»å ãã代ãã«ãå
ã®ãããããã®å°éã®æ®éšãåå¿å®¹åšå ã«æ®ã€ãŠ
ããå Žåã«ã¯ãããã§å åã§ãããé£ç¶çåå¿æ
äœã®å Žåã«ã¯ãçµæ¶æ žã®æ¯èŒçã«é«ãæ¿åºŠïŒå®åžž
ç平衡ã«ãããŠïŒããŸãæå©ã§ããããšãç«èšŒã
ãããçš®åçµæ¶ã®æ·»å ã¯ãçæç©ã®çŽåºŠã«æå©ã«
äœçšãããŸãåå¿æéãèããççž®ããã æ¬çºæã«ããæ¹æ³ã¯ãæµã管âãæ¹æ槜âãŸã
ã¯ã«ã¹ã±ãŒãã®ç¹åŸŽãæããè£ çœ®ã«ãããŠããã
ãåŒãåé£ç¶åŒãŸãã¯é£ç¶åŒã«å®æœãããããå ¬
ç¥ã®æ¹æ³ã«æ¯èŒããŠåå¿æéã極ããŠçãããšã
ãå©ç¹ãããããããŸãåæã«æ¥µããŠããããç
æç©ã®å質ãžãšå°ããã©ã¹ã¿ãŒé»åé¡åŸ®é¡åç
ã¯ãæ¬çºæã«ããæ¹æ³ã«åŸã€ãŠè£œé ãããçæç©
ã¯ãç¡å®åœ¢ã®æåãç³è±å«ææåãå«æããªãã
ãšã瀺ããŠããã æ¬çºæã«ããæ¹æ³ã«åŸã€ãŠåŸãããçµæ¶æ§ãã
ãªãŠã å¡©ïŒïŒïŒããã¯NaâSKSâïŒïŒå±€ç¶ã±ã€
é žïŒã®ãããªãŠã å¡©ãšåŒã°ããïŒã¯ãå±€æ§é ãæ
ããç·åæå³ã«ãããŠïŒ3.42±0.15ïŒã»10-8cmã«
ãããŠå°ããšãïŒåã®æ¥µããŠåŒ·ãç·ã瀺ããããŠ
0.083ãªãã0.13ã®ãããªãŠã ïŒã±ã€çŽ ã®ååæ¯
ãæãããããã¯å®éšåŒNa2SixO2x+1ïŒããã«ïœ
ã¯15ãªãã24ã®æ°ã§ããïŒã«çžåœããã åŸããããããªãŠã å¡©ïŒïŒã¯ãéœã€ãªã³äº€æ
äœãšããŠã®æåã瀺ããã€ãªã³äº€æ容éã¯ãïŒç¡
æ°Žã®çæç©ã«æç®ããŠïŒ132ãªãã203ããªã¢ã«
NaïŒ100ïœã®ç¯å²å ãç¹ã«132ãªãã173ããªã¢
ã«ïŒ100ïœã®ç¯å²å ã«ãããããã¯é žã«ãããã
ãªãŠã å¡©ã®æ»Žå®ãªãã³ã«èæ§ã¢ã«ã«ãªæ¶²ã«ããåŸ
ãããé žã®é滎å®ã«ãã€ãŠæ±ºå®ããããåæãã¬
ãžã¢ã€ãïŒè©Šéšç©è³ªãšããŠã®ïŒã«ã€ããŠã®åæ§ãª
枬å®æ¹æ³ã¯ãæç®ã«ããå ¬ç¥ãšãªã€ãŠããNaïŒ
Siâæ¯ããããããäžèšã®ç¯å²ã®åºãã¯ãäžéšã¯
åçŸæ§ã«ãããäžéšã¯çµæ¶æ§ã±ã€é žãããªãŠã äž
ã®å¯çæç©ã®éã®å°ãªãããšã«ãã€ãŠæ¡ä»¶ã¥ãã
ããã çŽç²ãªçæç©ïŒïŒã¯ã145ããªã¢ã«NaïŒ100
ïœã®ã€ãªã³äº€æ容éã瀺ãããŸãNa2Si22O45ã®
çæ³çµæãæãããã®ãšèããããŠããã ãããªãŠã å¡©ïŒïŒã®ïŒžç·ã¹ãã¯ãã«ã¯â第ïŒ
è¡šããæãããªããã«âã±ãã¢ã€ãã®ãSiO2â
ïŒHeydemannãBeitr.Min.Petrog.10ã242â
259ïŒ1964ïŒåç §ïŒã®ã極ããŠäœã亀æ容éãæã
ãé«å§åæã«ããåŸãããã±ã€é žå¡©ã§ãã
âSiO2ïŒX2âçžïŒâïŒB.Mitsyuk et al.ãGeochem.
Int.13ã202ïŒ1976ïŒåç §ïŒã®ãããã³K2Si8O17ã»
xH2OïŒãã€ãç¹èš±ç¬¬2742912å·å ¬å ±åç §ïŒã®ãã
ããã®ã¹ãã¯ãã«ã«é¡äŒŒããããã®ããšãããå±€
ç¶ã¢ã«ã«ãªéå±ã±ã€é žå¡©ããNa2Si22O45ã»xH2O
ïŒã±ãã¢ã€ãïŒãSiO2âãSiO2ïŒX2âçžïŒã
K2SiO17ã»xH2Oããã³NaâSKSâïŒã«ãããŠ
ã¯ãæ§é äžã®é¡äŒŒæ§ãååšããã«ã¡ãããªããšæš
å®ããããšãã§ããäžèšã®ãã¹ãŠã®å±€ç¶ã±ã€é žå¡©
ã¯ããããã®ïŒžç·åæå³ã«é¢ããŠã±ãã¢ã€ãç³»ã®
ã±ã€é žå¡©ãšããŠææ¡ããããšãã§ãããSiO2â
ãšK2Si8O17ã»xH2OãŸãã¯å¯Ÿå¿ããéé¢ã®é žãš
ã®éã®åŒ·ãé¡äŒŒæ§ãããããã±ïŒBeneckeïŒãã
ã³ã©ã¬ãªãŒïŒLagalyïŒã«ãã€ãŠææãããŠãã
ïŒZ.Naturforsch.34bã648â649ïŒ1979ïŒåç §ïŒãå
çŽ åæã«ããNaâSKSâïŒã®çµæããŸãæ¬çºæ
ã«ãããããªãŠã å¡©ãšé±ç©ã±ãã¢ã€ããšã®é¡äŒŒæ§
ã瀺ããŠãããããããªãããé žãçšãã滎å®ç¹
æ§ã«ãããŠãæãããªçžç°ã瀺ããŠãããNaâ
SKSâïŒã¯ã83ã130ããªã¢ã«Na+ïŒã¢ã«SiO2ã€
ãªã³äº€æ容éãæããããŠã»ãŒåœéã®å¡©é žã«ãã€
ãŠéé¢ã®é žïŒïŒšâSKSâïŒïŒã«å€æãããããã
é±ç©ã±ãã¢ã€ãã¯åžèé žãšåå¿ããŠ333ããªã¢ã«
H+ïŒã¢ã«SiO2ã®å¯Ÿå¿ããé žã®ïŒçè«äžã®ïŒã€ãª
ã³äº€æ容éãæãã6SiO2ã»H2Oãšãªããããã
ãªããããã®æ°ŽåãããSiO2ã¯ããã®ã€ãªã³äº€
æèœã«ãããŠã®ã¿ãªããããŸããã®ïŒžç·åæãã¿
ãŒã³ã«ãããŠãããã®å Žåã«çæãããå±€æ§é ã
æããéé¢ã®ã±ã€é žïŒšâSKSâïŒãšã¯æããã«
çžéãããé žãšã¯ç°ãªããã®æåã¯ããªã€ã°ã¹ã¿
ãŒïŒEugsterïŒã«ãã€ãŠçºèŠããã倩ç¶ç£ã®å±€ç¶
ã±ã€é žãããªãŠã ã§ããã±ãã¢ã€ãã¯ãNaâ
SKSâïŒãšåäžã§ãªãããšã瀺ããŠããã ãã€ãç¹èš±ç¬¬2742912å·ã«ããã°ãK2Si8O17ã»
xH2Oã¯ã250ããªã¢ã«K+ïŒã¢ã«SiO2ã®ã€ãªã³äº€
æèœãæãããSiO2ïŒX2âçžïŒã«ã€ããŠã¯ãæç®
äžã«SiO2âX2100ïœåœã100ã130mgNa+ã®ã€ãªã³
亀æ容éãèšèŒãããŠãããããã¯èšç®ã«ããã°
çŽ62ã81ããªã¢ã«Na+ïŒã¢ã«SiO2ã®äº€æ容éã«
çžåœããããã®æ¯èŒã¯ãç·åæå³ã«ãããå®è³ª
çãªåå°ã«å ããŠãæŽã«ã€ãªã³äº€æ容éã«é¢ãã
èšèŒããŸãçµæ¶æ§ã±ã€é žã®æ確ãªç¹åŸŽä»ãã«ãšã€
ãŠå¿ èŠã§ããããšã瀺ããŠããã å±€æ§é ãæããã±ã€é žã®ä»ã®çµæ¶æ§ã¢ã«ã«ãªé
å±å¡©ïŒIaïŒãäŸãã°ã«ãªãŠã ããã³ãªããŠã å¡©ã¯ã
åæ§ã«ïŒ3.42±0.15ïŒã»10-8cmã«ãããŠæ¥µããŠåŒ·ã
ç·ã瀺ãããããŠ0.083ãªãã0.13ã®ã¢ã«ã«ãªé
å±ïŒã±ã€çŽ ã®ååæ¯ãæããããããã¯ããããª
ãŠã å¡©ïŒïŒããã€ãªã³äº€æã«ããããŸãã¯å±€æ§
é ãæããéé¢ã®ã±ã€é žïŒïŒããã¢ã«ã«ãªéå±
æ°Žé žåç©ã§äžåããããšã«ãã€ãŠåŸãããã éé¢ã®çµæ¶æ§ã±ã€é žïŒšâSKSâïŒïŒïŒãåŸã
ããã«ã¯ãåžèãªæ°Žæ§ç¡æ©é žãçšããŠæã奜éœå
ã«å®æœããããå®å šãªå€æã®ããã«ã¯ããããã³
ã®éã¯ãé€å»ãããã¹ãã¢ã«ã«ãªéå±ã€ãªã³ã®é
ã®å°ããšãçã¢ã«éã§ãªããã°ãªããªããéå°ã®
é žã䜿çšããããšã奜ãŸãããåŠçãã¹ãã¢ã«ã«
ãªéå±ã±ã€é žå¡©ïŒïŒãå°éã¥ã€é žãšæ··åããã¢
ã«ã«ãªã€ãªã³ãå«æããåå¿æº¶æ¶²ãæ®æž£ããåé¢
ããããŠãã®æ¹æ³ãæ°åå埩ããããšãç¹ã«æå©
ã§ãããã€ãªã³äº€æãå®äºããããã®æéãççž®
ããããã«ã¯ãåå¿æ··åç©ãæ¹æããããšãæšå¥š
ãããããã®éãåå¿äžã®PHå€ãçŽ2.0ã«ãããš
æå©ã§ããã çæããã±ã€é žïŒšâSKSâïŒã¯ãå¥ããã
ãããŠå¿ èŠãªå Žåã«ã¯ãäŸãã°ä¹Ÿç¥åšå ã§140â
ã«ãããŠä¹Ÿç¥ãããããé žãäŸãã°ã«ãªãŠã å¡©ã«
å€æãããã¹ãå Žåã®ããã«ãæŽã«åŠçãããã¹
ãå Žåã«ã¯ã也ç¥ã¯ãå¿ èŠã§ã¯ãªãã æ¬çºæã«ããæ¹æ³ã«åŸã€ãŠåŸãããçµæ¶æ§ã±ã€
é žïŒšâSKSâïŒã¯ãæ°èŠã§ãããããã¯ãå®éš
åŒH2SixO2x+1ïŒããã«ïœã¯15ãªãã24ã®æ°ã§ããïŒ
ãæãããäžèšåŒã«ãããŠã¯ãååšããããšãã
ãæ°Žã¯ãèæ ®ã«å ¥ããããŠããªããæ°ãã«è£œé ã
ããçµæ¶æ§ã±ã€é žã¯ã也ç¥åã«ã¯çŽ10ãªãã60é
éïŒ ã®æ°Žãå«æããã也ç¥æäœäžããã®æ°Žã¯ãé£
ç¶çã«é€å»ãããæçµçã«ã¯ïŒïŒ ã«è¿ã¥ãããã®
çµæ¶æ§ã±ã€é žã¯ãç·åæå³ã«ãã㊠ïœïŒïŒ3.42±0.1ïŒã»10-8cmã«ãããŠæ¥µããŠåŒ·ã第
äžã®ç·ãããããŠïœïŒïŒ18±ïŒïŒã»10-8cmã«ãã
ãŠã第äžã®ç·ã®åŒ·åºŠã®ãããã75ïŒ ã®åŒ·åºŠãæã
ã第äºã®ç·ãæããããšã«ãã€ãŠéç«ã€ãŠããã
ããã¯æŽã«åæã®æ§é åŒã«äžèŽãã83ãªãã130
ããªã¢ã«H+ïŒã¢ã«SiO2ã®æ»Žå®ãããé žæ§åºŠã瀺
ããäžè¬ã«ã芳å¯ãããé žæ§åºŠã¯ã83ãªãã105
ããªã¢ã«H+ïŒã¢ã«SiO2ã®ç¯å²å ã«ããã æ°èŠãªçµæ¶æ§ã±ã€é žïŒšâSKSâïŒã®ïŒžç·åæ
ãã¿ãŒã³ã¯ãå°æ°ã®ç·ãã瀺ããªãããã®çæç©
ã¯ãçŽ3.42ã»10-8cmã®æ Œåé¢ééã«ãããå·Ÿåºã
匷ãç·ã«ãã€ãŠç¡å®åœ¢ã®ã±ã€é žãšã¯æããã«åºå¥
ããããæç®ã«ããã°ãïŒ3.2ã3.6ïŒã»10-8cmãã
ã³ïŒ11ã21ïŒã»10-8cmã®ç¯å²å ã®ç·ã¯ãå±€æ§é ã
æããã±ã€é žã«ãšã€ãŠå žåçãªãã®ã§ãããåŸã€
ãŠãæ¬çºæã«ããã±ã€é žããŸãå±€ç¶ã®çµæ¶æ§é ã
æããããšãæšå®ããããè¥å¹²ã®ïŒžç·åå°ã®åŒ·
ããç¹ã«ïœïŒïŒ18±ïŒïŒã»10-8cmã«ãããåå°ã®åŒ·
ãã¯ãã±ã€é žã®å«æ°Žéã«äŸåãããããããªã
ããç¹åŸŽçãªããšã¯ãïœïŒïŒ18±ïŒïŒã»10-8cmã«ã
ããåå°ã®åŒ·ããçŽ3.42ã»10-8cmã«ãããåå°ã®
ããã®ãããã75ïŒ ã§ãããšããäºå®ã§ãããæ¬
çºæã«ããæ°èŠãªã±ã€é žã¯ããã®ïŒžç·åæãã¿ãŒ
ã³ããã³ïŒãŸãã¯ãã®ç¹å®ã®ã€ãªã³äº€æ容éã«ã
ã€ãŠå ¬ç¥ã®çµæ¶æ§ã±ã€é žããåºå¥ããããã 第ïŒè¡šã«ãããŠãæ°èŠãªã±ã€é žïŒïŒããã®ïŒž
ç·åæãã¿ãŒã³ã«é¢ããŠãïŒçš®ã®å ¬ç¥ã®ã±ã€é žã
ããªãã¡ãH2Si8O17ã»xH2OïŒãã€ãç¹èš±ç¬¬
2742912å·åç §ïŒãH2Si14O29ã»xH2OïŒLagaly et
al.Z.Naturforsch.28bïŒ1973ïŒã234â238åç §ïŒ
ããã³é±ç©ãã¬ãžã¢ã€ãããã³ã±ãã¢ã€ãã®é žæ§
åã«ãã€ãŠåŸãããã±ã€é žSHïŒEugsterã
Science157ïŒ1967ïŒã1177â1180åç §ïŒãšæ¯èŒã
ããŠãããæ°èŠãªã±ã€é žïŒšâSKSâïŒã¯ãç·
åæãã¿ãŒã³ã«ãããŠH2Si8O17ã»xH2Oãšã®é¡äŒŒ
æ§ã瀺ããããããªãããããã¯ã€ãªã³äº€æ容é
ã«ãããŠãã®é žãšã¯æããã«çžéããŠããã H2Si8O17ã»xH2Oã¯ãSiO21ã¢ã«åœãçŽ250ããª
ã¢ã«ã®äº€æããããããã³ãæããããæ¬çºæã«
ããæ°èŠãªã±ã€é žã¯ãæããã«ããäœãã€ãªã³äº€
æ容éã瀺ããããã¯ãæé«130ããªã¢ã«H+ïŒã¢
ã«SiO2ã§ããããããŠäžè¬ã«83ããªã¢ã«H+ïŒã
ãªã¢ã«SiO2ãã倧ãããå žåçãªæ°å€ã¯ãSiO21
ã¢ã«åœã亀æãããH+83ãªãã105ããªã¢ã«ïŒç¹
ã«88ãªãã99ããªã¢ã«ïŒã§ãããåŸã€ãŠã
H2Si22O45ã®çæ³çµæãæšå®ãããããæ¬çºæã«
ããæ°èŠãªçæç©ã¯ããã§ã«å ¬ç¥ã®å±€ç¶ã±ã€é žå¡©
ãšåæ§ã«ãäŸãã°åžçå€ãšããŠäœ¿çšããããã
ãè¡šã
ãè¡šã
æ°èŠãªã±ã€é
žïŒšâSKSâïŒã®ã€ãªã³äº€æ容é
ã¯ãèæ§ãœãŒã溶液ãçšãã滎å®ïŒæãæå©ã«ã¯
å¡©åãããªãŠã 氎溶液ã®æ·»å åŸã®ïŒã«ãã€ãŠæ±ºå®
ããããããããããã滎å®æ²ç·ã®å±æ²ç¹ã¯ãPH
ïŒãªãã11ã®ç¯å²å ã«ãããŠåœéå€ã瀺ãã察å¿
ããã¢ã«ã«ãªéå±å¡©ïŒïŒ©ããã³IaïŒã®å¡©é žã«ãã
滎å®ïŒPHïŒãªããïŒã®ç¯å²å ã®å±æ²ç¹ïŒã¯ãå¯Ÿç §
ãšããŠçšãããããããŠé¡äŒŒã®æ°å€ãäžãããå¡©
é žãçšããåæ§ãªæ»Žå®ãå ¬ç¥ã®ãã¬ãžã¢ã€ãç³»ã®
ã±ã€é žå¡©ãçšããŠå®æœãããšãå®è³ªçã«ããé«ã
ãããã®å±€ç¶ã±ã€é žå¡©ã«ãšã€ãŠäºæ³ãããã€ãªã³
亀æ容éããããããããããŠãã®æž¬å®æ¹æ³ã®é©
çšå¯èœæ§ã確èªããããã ã€ãªã³äº€æ容éã¯ãçŒç±æžéïŒ1000â以äžã«ã
ããïŒã枬å®ããããšã«ãã€ãŠç¡æ°Žã®åœ¢ã«æç®ã
ããããçµæ¶æ°Žãå«æããªãæ°èŠãªã±ã€é žïŒïŒ
ã«ã€ããŠã¯ãããã¯137ãªãã212ããªã¢ã«H+ïŒ
100ïœã±ã€é žããŸãã¯137ãªãã172ããªã¢ã«H+ïŒ
100ïœãããŠç¹ã«145ãªãã162ããªã¢ã«H+ïŒ100
ïœã®ã€ãªã³äº€æ容éã«çžåœããããã®å Žåã«ãã
ãŠããçµæã¯ãçæç©äžã®äžçŽç©ããã³æž¬å®æ¹æ³
ã®æ£ç¢ºåºŠã«ãã€ãŠåœ±é¿ãããã SiO2ã®çž®å床ãH2Si8O17ã«æ¯èŒããŠããé«ã
ãŸãé žæ§SiâOHåºã®å«éãããã«å¯Ÿå¿ããŠäœã
ãšããäºå®ããç°ã€ãååŠçããã³ç©ççæ§è³ªã
ãããããH2Si8O17ã»xH2Oã¯é žã«ææã§ãŸãç±
çã«äžå®å®ã§ãããåŸã€ãŠäœæž©åºŠã§è²¯èµããªãã
ã°ãªããªããããã®ããšã¯æ°èŠãªã±ã€é žïŒïŒšâ
SKSâïŒïŒã«ã¯åœãŠã¯ãŸããªãã滎å®äžãªãã³
ã«è±æ°Žäžã®æåã«ããŸãè¥å¹²ã®çžç°ç¹ãèŠåºãã
ãã 以äžã«çµæ¶æ§å±€ç¶ã±ã€é žãããªãŠã ïŒïŒã®ã
æ¹æ容åšãŸãã¯ã«ã¹ã±ãŒãåŒæ¹æ容åšçŸ€ã«ããã
åé£ç¶åŒããã³å šé£ç¶åŒè£œé ã詳现ã«èª¬æããã äžè¬ã«ãæ¬çºæã«ããæ¹æ³ã®é£ç¶çå®æœæ æ§
ã¯ã175â以äžã«ãããŠè¡ãªããããæ°Žæ§åå¿æ··
åç©äžã§çããå§åã®ããã«ããªãŒãã¯ã¬ãŒãã
å¿ èŠã§ãããäžæŽ»æ§ã¬ã¹ã®æ·»å ã«ããå§åã®ãã
以äžã®äžæã¯ããªããã®å©çãããããããªãã
åå¿æåã®æ·»å äžã§ããåå¿æ··åç©ã®æž©åºŠã¯ã
130ãªãã230âãç¹ã«160ãªãã210âã®ç¯å²å ãš
ãã¹ãã§ãããããã¯ãæ·»å ãã¹ãç©è³ªããã§ã«
å ç±ãããŠããå Žåã«ã¯ãç¹ã«å®¹æã«ã§ãããå
å¿å®¹åšå ã®å§åã¯ã100ããŒã«ä»¥äžãäžè¬ã«ïŒãª
ãã25ããŒã«ã®ç¯å²å ãšãã¹ãã§ããã åå¿å®¹åšäžãžã®åå¿æåã®é éã®ããã«ããã³
ããå¿ èŠã§ããããã®ç®çã§ã¯åäžã®ãã³ãã§å
åã§ããããåã ã®æåãå¥ã ã«ãåŸã€ãŠãªãŒã
ã¯ã¬ãŒãã®ç°ãªã€ãäŸçµŠç¹ã«ãããŠïŒåãŸãã¯ïŒ
åã®ãã³ããå¿ èŠãšããããåå¿å®¹åšå€ã§ã®ã²ã«
圢æãé¿ããããã«ãé žæ§ååç©ïŒäŸãã°ãç¡«
é žããªã³é žïŒããã³å¡©åºæ§åå¿æåïŒæ°Žæº¶æ§ã®ã¢
ã«ã«ãªéå±ã±ã€é žå¡©ãŸãã¯ã¢ã«ã«ãªæº¶æ¶²ïŒãå¥ã
ã«é éããããšã奜ãŸãããé žæ§ååç©ãéå°ã«
é éããå Žåã«ã¯ãã¢ã«ã«ãªæº¶æ¶²ãæ·»å ããããš
ãå¿ èŠã§ããããã åºçºçæç©ã¯ã次ã ãšæ·»å ããããšãã§ãã
ããåæã«æ·»å ããããšã奜ãŸãããæ°åã®çŽå
ã«é£çµãããåå¿å®¹åšã䜿çšãããå Žåã«ã¯ãå
æåã®æ·»å æéã第ïŒã®æ¹æ容åšå ã§ã®æ»çæé
ã®10ãªãã100ïŒ ãç¹ã«20ãªãã80ïŒ ã§ãããªã
ã°æå©ã§ããã ããæ·»å äžã«çæç©ãåæã«ååºããªããã°ã
æ¹æ容åšã®å 容éãå¢å ããããã®å Žåã«ã¯ãæ·»
å ã¯ãæé«æ¶²é¢ã«éãããŸã§ã«çµäºããªããã°ãª
ããªããåæåãéåžžã«æ¥éã«æ·»å ãããå Žåã«
ã¯ãåŸçµæ¶åã«ãã€ãŠçµæ¶æ§ã±ã€é žå¡©ã®å åãªç
æãéæããããã«ãåå¿å®¹åšå ã§ãªãæŽã«æ¹æ
ãç¶ããªããã°ãªããªãã次ãã§ãçæç©ã¯ããª
ãç±ããªãŒãã¯ã¬ãŒã¶ããååºããããããããª
ããããã®åŸçµæ¶åããå Žåã«ãã€ãŠã¯åæ§ã«æ¹
ææ©ãåããããäžã€ã®å®¹åšãŸãã¯å®¹åšçŸ€ã®äžã§
å®æœããåŸã€ãŠïŒæ¹æ容åšïŒã«ã¹ã±ãŒãã圢æã
ãããããšãæå©ã§ããããšããããåŸçµæ¶åã®
æéã¯ã第äžã®æ¹æ容åšå ã®å¹³åæ»çæéã®æé«
99åã奜ãŸããã¯æé«20åãããŠç¹ã«ïŒ200â以
äžã®é«ã枩床ã«ãããŠïŒïŒåã奜ãŸããã¯ïŒå以
äžãšãã¹ãã§ããããã®éã第ïŒã®æ¹æ容åšãã
ãæããã«äœã枩床ã«ãããŠåŸçµæ¶åãå®æœãã
ããšãå¯èœã§ããã é£ç¶çåå¿æäœã«ãããŠã¯ããªãŒãã¯ã¬ãŒãã
å®å šã«ç©ºã«ããªãã§ãåŸçµæ¶åãããã±ã€é žå¡©ã
æ¯æ¶²ããã³æªåå¿ã®åºçºçæç©ãããªãçæç©æ··
åç©ãåžžã«å°ããšãäžéšå å¡«ããŠããããšãæå©
ã§ãããããã«ãã€ãŠããªãŒãã¯ã¬ãŒãå ã«é«å²
åã®ã±ã€é žå¡©çµæ¶ãæ®çãããããçµæ¶æ§ã±ã€é ž
å¡©ã®ãã以äžã®çæãä¿é²ããã é£ç¶çåå¿æäœã«ãããŠã¯ãçš®åçµæ¶ã¯ãé転
éå§æã®éã®ã¿ãïŒå¹³è¡¡ã®èª¿æŽã®ããã«ïŒæ·»å ã
ãããåå¿äžãåå¿æ··åç©äžã®ã¢ã«ã«ãªéå±ã±ã€
é žå¡©ã®çµæ¶å¯Ÿæº¶è§£ãããSiO2ã®ééæ¯ã¯ã0.05以
äžå¥œãŸããã¯0.1以äžãããŠç¹ã«0.2以äžãšãã¹ã
ã§ããããã®å Žåãå šé£ç¶åŒåå¿æäœã«ãããŠ
ã¯ãäžè¬ã«1.0以äžã®äžå®å€ã«ä¿ãããã åé£ç¶åŒåå¿æäœã«ãããŠã¯ãæ°å€ã¯ãå®æç
ã«å¹³åå€ãè¶ ãããŠãŸããããäžå»»ãã å šé£ç¶åŒåå¿æäœããã³çæ³çæ··åã®å Žåã«
ã¯ãæ¹æ容åšããã³ååºãããçæç©ã®äž¡æ¹ã«æº¶
解ãããã±ã€é žå¡©ãããå®è³ªçã«ããå€ãã®çµæ¶
æ§ã±ã€é žå¡©ãååšããããããšãã§ããã ãªãå å§äžã«ãããªãŒãã¯ã¬ãŒãããçæç©ã
ååºãã¹ãå Žåã«ã¯ãããã¯é©åœãªåºéšæåºåŒã«
ãã€ãŠéæããããå®å šã«ç©ºã«ããããšãææã
ããªãå Žåã«ã¯ãåå¿æ··åç©äžã«æµžãããŠããã
ããŠåŒã«ãã€ãŠééãããŠãããµã€ããªã³ç®¡ãä»
ããŠçæç©ãååºãããšãæå©ã§ãããååºãã
ããçæç©ã®æ倧éã¯ãµã€ããªã³ç®¡ã®é·ãã«ãã€
ãŠæ±ºå®ãããã æ¬çºæã«ããæ¹æ³ã¯ãæå©ã«ã¯å šé£ç¶åŒã«å®æœ
ãããããã®ããã«ã¯ãåºçºæåã®é£ç¶çäŸçµŠãš
å ±ã«ãåå¿çæç©ã®é£ç¶çãªæåºãå¿ èŠãšããã
ããã¯ãäŸãã°ãµã€ããªã³ç®¡ã«ãã€ãŠè¡ãªãã
ããåå¿å®¹åšã®ç£èŠã®ããã«ã¯ã液é¢èšã«ããã
ãŸãã¯è£ 眮ã®ééã枬å®ããããšã«ãã€ãŠæ¶²é¢ã
ç£èŠããå¿ èŠãããã çµæžäžã®çç±ããããããåŒæäœããã³é£ç¶åŒ
æäœã®äž¡æ¹ã«ãããŠãåå¿æéã¯ãäžè¬ã«ãæ·»å
ãããã¢ã«ã«ãªéå±ã±ã€é žå¡©ã®å°ããšã10ïŒ ãå±€
ç¶ã¢ã«ã«ãªéå±ã±ã€é žå¡©ã«å€æããããããªãã®
ãšããããåå¿æž©åºŠãããé«ãå Žåã«ã¯ãããç
ãåå¿æéãå¿ èŠãšãããã180â以äžã®æž©åºŠã«
ãããŠã¯ãïŒæé以äžã®æéã§å åã§ããããã
ããªãããæ°æ¥éã®åå¿æéãå¿ èŠãªããšãã
ããç¹å®ã®åå¿æ¡ä»¶ã«äŸåããå¿ èŠãªåå¿æé
ã¯ãåã ã®è©Šæã®ïŒžç·åæãã¿ãŒã³ãã決å®ãã
ãããæ¬çºæã«ããæ¹æ³ã䜿çšããããšã«ããã
çµæ¶æ§å±€ç¶ã±ã€é žå¡©ã«ãããŠå žåçãªïŒžç·åæã
ãã€ã±ã瀺ãã±ã€é žå¡©ã補é ããããšãã§ããã ïŒçæãããïŒçµæ¶æ§ã®ã±ã€é žå¡©å¯ŸïŒæ·»å ãã
ãïŒæº¶è§£ãããã±ã€é žå¡©ã®æ¯ã¯ãäž»ãšããŠå¹³åæ»
çæéããã³çµæïŒç¹ã«Na2OïŒSiO2ïŒã®ã¢ã«
æ¯ïŒã«ãã€ãŠå®ãŸããå¹³åæ»çæéã®å¢å ã¯ãçµ
æ¶æ§ç©è³ªã®éãå¢å ãããçµæã«ãªãããå Žåã«
ãã€ãŠã¯ãŸãå¯çæç©ã®çæãä¿é²ãããçµæžç
çç±ãããããçãæ»çæéãçšããããŠæ¯èŒç
å°éã®çµæ¶æ§çæç©ãåå ¥ããããšãå®éçã§ã
ããã å±€ç¶ã±ã€é žå¡©ãåé¢ããããã«ã¯ãåå¿æ··åç©
ãåå¿åŸã«éãããããŠæ®æž£ãæ°ŽãŸãã¯åžèãª
ã¢ã«ã«ãªéå±æº¶æ¶²ïŒã¢ã«ã«ãªéå±ã±ã€é žå¡©ã«å¿ã
ãŠïŒã§æŽæ»ãããããŠå¿ èŠãªãã°ä¹Ÿç¥ããããã
ããªãããæŽã«åŠçããããã«ã¯ãäŸãã°ã¢ã«ã«
ãªéå±ã€ãªã³ã塩溶液ã§åŠçãããšãã«ãã€ãŠä»
ã®æã€ãªã³ãšäº€æããããã«ããã€ã«ã¿ãŒããå
åºããã湿最ããçæç©ãçŽæ¥åŠçããããšããŸ
ãæå©ã§ãããã äŸ ïŒ ãœãŒãæ°Žã¬ã©ã¹ïŒSiO227ïŒ ãNa2O8.43ïŒ ã
Al2O30.24ïŒ ïŒ83.5éééšãæ°Ž149éšã«æ·»å ãã
ããšã«ããã次ã®ã¢ã«çµæïŒ Na2O0.303ïŒAl2O30.0052ïŒSiO2ïŒXH2Oãæ
ããåå¿æ··åç©ããŸã調補ããããã®åŸã§ãäºã
è¡ã€ãå®éšããã®ãã€ã«ã¿ãŒããåŸã湿最ããçµ
æ¶æ§ã±ã€é žãããªãŠã ïŒ1200âãžã®å ç±ã«ãã71
ïŒ ã®ééæžïŒã¢ã«çµæã®èšç®ã«åœã€ãŠã¯æ°Žã®éã®
ã¿ãèæ ®ã«å ¥ããïŒãæ·»å ããã次ãã§ã96ïŒ ã®
ç¡«é ž4.93éšãæ¹æäžã«åŸã ã«å ããããã®æåå¿
æ··åç©ã¯ã次ã®ã¢ã«çµæãæããïŒ Na2O0.174ïŒAl2O30.0052ïŒSiO2ïŒ
Na2SO40.129ïŒH2O30ã äžèšã®åå¿æ··åç©ãã¹ãã³ã¬ã³éŒè£œã®ãªãŒãã¯
ã¬ãŒãå ã§205âã§1.5æéå ç±ããããŠãã®æž©åºŠ
ã«ä¿ã€ãæã ãè©ŠæãååºããŠè©Šéšãè¡ãªãã
205âã§2.5æéå ç±ããåŸãåŸã ã«å·åŽãããã
ãã®æç¹ã§ååºããè©Šæã¯ã120âã«ãããŠä¹Ÿç¥
ããåŸã«ãd1ïŒ20.5ã»10-8cmã®æ Œåé¢ééã«ãã
ãŠ56ã®çžå¯ŸåŒ·ããæããåå°ã瀺ããd2ïŒ15.5ã»
10-8cmã«ãããŠã¯åå°ã瀺ãããd3ïŒ3.34ã»10-8
cmã«ãããŠ46ã®çžå¯ŸåŒ·ããæããåå°ãããããŠ
d43.44ã»10-8cmã«ãããŠ100ã®çžå¯ŸåŒ·ããæãã
åå°ããããã瀺ããå·åŽåŸã«åå¿æ··åç©ãé
ããæ°Žã§æŽæ»ããããŠåžåŒæŒæã§åžåŒä¹Ÿç¥ããã
ãã€ã«ã¿ãŒããååºããã湿最ããçæç©ã¯ã55
ïŒ ã®çŒç±æžéã瀺ãã空æ°ã§çæé也ç¥ããçæ
ç©ãç±ééåæã«ããè©ŠéšãããçŽ140âã®æž©åºŠ
ã«éãããŸã§ã«43ïŒ ã®ééæžãçãããçŽ1000â
ãŸã§ã«ã¯ããã以äžé質çãªééæžã¯èŠ³å¯ãããª
ãã120âã«ãããŠäžå®ééãŸã§ä¹Ÿç¥ãããçæ
ç©ïŒïŒã¯ãå çŽ åæã«ãã次ã®çµæã瀺ãïŒ Na3.8ïŒ ãAl0.24ïŒ ãSi41.5ïŒ ããã³Fe0.003
ïŒ ã ãããã17.9ã®SiO2ïŒNa2Oã®ã¢ã«æ¯ãç®åºã
ããã332ã®SiO2ïŒAl2O3ã®ã¢ã«æ¯ã¯ãåå¿æ··å
ç©äžã®æº¶è§£ãããAl2O3ã®ååšã«ããããããã
ããã¯æçµçæç©äžã«æ¥µããŠå°éããçµèŸŒãŸããª
ããšããããšã瀺ãã空æ°ä¹Ÿç¥ãããã±ã€é žãã
ãªãŠã ïŒïŒã®ïŒžç·åæãã¿ãŒã³ã第ïŒè¡šã«ç€º
ãã
ã¯ãèæ§ãœãŒã溶液ãçšãã滎å®ïŒæãæå©ã«ã¯
å¡©åãããªãŠã 氎溶液ã®æ·»å åŸã®ïŒã«ãã€ãŠæ±ºå®
ããããããããããã滎å®æ²ç·ã®å±æ²ç¹ã¯ãPH
ïŒãªãã11ã®ç¯å²å ã«ãããŠåœéå€ã瀺ãã察å¿
ããã¢ã«ã«ãªéå±å¡©ïŒïŒ©ããã³IaïŒã®å¡©é žã«ãã
滎å®ïŒPHïŒãªããïŒã®ç¯å²å ã®å±æ²ç¹ïŒã¯ãå¯Ÿç §
ãšããŠçšãããããããŠé¡äŒŒã®æ°å€ãäžãããå¡©
é žãçšããåæ§ãªæ»Žå®ãå ¬ç¥ã®ãã¬ãžã¢ã€ãç³»ã®
ã±ã€é žå¡©ãçšããŠå®æœãããšãå®è³ªçã«ããé«ã
ãããã®å±€ç¶ã±ã€é žå¡©ã«ãšã€ãŠäºæ³ãããã€ãªã³
亀æ容éããããããããããŠãã®æž¬å®æ¹æ³ã®é©
çšå¯èœæ§ã確èªããããã ã€ãªã³äº€æ容éã¯ãçŒç±æžéïŒ1000â以äžã«ã
ããïŒã枬å®ããããšã«ãã€ãŠç¡æ°Žã®åœ¢ã«æç®ã
ããããçµæ¶æ°Žãå«æããªãæ°èŠãªã±ã€é žïŒïŒ
ã«ã€ããŠã¯ãããã¯137ãªãã212ããªã¢ã«H+ïŒ
100ïœã±ã€é žããŸãã¯137ãªãã172ããªã¢ã«H+ïŒ
100ïœãããŠç¹ã«145ãªãã162ããªã¢ã«H+ïŒ100
ïœã®ã€ãªã³äº€æ容éã«çžåœããããã®å Žåã«ãã
ãŠããçµæã¯ãçæç©äžã®äžçŽç©ããã³æž¬å®æ¹æ³
ã®æ£ç¢ºåºŠã«ãã€ãŠåœ±é¿ãããã SiO2ã®çž®å床ãH2Si8O17ã«æ¯èŒããŠããé«ã
ãŸãé žæ§SiâOHåºã®å«éãããã«å¯Ÿå¿ããŠäœã
ãšããäºå®ããç°ã€ãååŠçããã³ç©ççæ§è³ªã
ãããããH2Si8O17ã»xH2Oã¯é žã«ææã§ãŸãç±
çã«äžå®å®ã§ãããåŸã€ãŠäœæž©åºŠã§è²¯èµããªãã
ã°ãªããªããããã®ããšã¯æ°èŠãªã±ã€é žïŒïŒšâ
SKSâïŒïŒã«ã¯åœãŠã¯ãŸããªãã滎å®äžãªãã³
ã«è±æ°Žäžã®æåã«ããŸãè¥å¹²ã®çžç°ç¹ãèŠåºãã
ãã 以äžã«çµæ¶æ§å±€ç¶ã±ã€é žãããªãŠã ïŒïŒã®ã
æ¹æ容åšãŸãã¯ã«ã¹ã±ãŒãåŒæ¹æ容åšçŸ€ã«ããã
åé£ç¶åŒããã³å šé£ç¶åŒè£œé ã詳现ã«èª¬æããã äžè¬ã«ãæ¬çºæã«ããæ¹æ³ã®é£ç¶çå®æœæ æ§
ã¯ã175â以äžã«ãããŠè¡ãªããããæ°Žæ§åå¿æ··
åç©äžã§çããå§åã®ããã«ããªãŒãã¯ã¬ãŒãã
å¿ èŠã§ãããäžæŽ»æ§ã¬ã¹ã®æ·»å ã«ããå§åã®ãã
以äžã®äžæã¯ããªããã®å©çãããããããªãã
åå¿æåã®æ·»å äžã§ããåå¿æ··åç©ã®æž©åºŠã¯ã
130ãªãã230âãç¹ã«160ãªãã210âã®ç¯å²å ãš
ãã¹ãã§ãããããã¯ãæ·»å ãã¹ãç©è³ªããã§ã«
å ç±ãããŠããå Žåã«ã¯ãç¹ã«å®¹æã«ã§ãããå
å¿å®¹åšå ã®å§åã¯ã100ããŒã«ä»¥äžãäžè¬ã«ïŒãª
ãã25ããŒã«ã®ç¯å²å ãšãã¹ãã§ããã åå¿å®¹åšäžãžã®åå¿æåã®é éã®ããã«ããã³
ããå¿ èŠã§ããããã®ç®çã§ã¯åäžã®ãã³ãã§å
åã§ããããåã ã®æåãå¥ã ã«ãåŸã€ãŠãªãŒã
ã¯ã¬ãŒãã®ç°ãªã€ãäŸçµŠç¹ã«ãããŠïŒåãŸãã¯ïŒ
åã®ãã³ããå¿ èŠãšããããåå¿å®¹åšå€ã§ã®ã²ã«
圢æãé¿ããããã«ãé žæ§ååç©ïŒäŸãã°ãç¡«
é žããªã³é žïŒããã³å¡©åºæ§åå¿æåïŒæ°Žæº¶æ§ã®ã¢
ã«ã«ãªéå±ã±ã€é žå¡©ãŸãã¯ã¢ã«ã«ãªæº¶æ¶²ïŒãå¥ã
ã«é éããããšã奜ãŸãããé žæ§ååç©ãéå°ã«
é éããå Žåã«ã¯ãã¢ã«ã«ãªæº¶æ¶²ãæ·»å ããããš
ãå¿ èŠã§ããããã åºçºçæç©ã¯ã次ã ãšæ·»å ããããšãã§ãã
ããåæã«æ·»å ããããšã奜ãŸãããæ°åã®çŽå
ã«é£çµãããåå¿å®¹åšã䜿çšãããå Žåã«ã¯ãå
æåã®æ·»å æéã第ïŒã®æ¹æ容åšå ã§ã®æ»çæé
ã®10ãªãã100ïŒ ãç¹ã«20ãªãã80ïŒ ã§ãããªã
ã°æå©ã§ããã ããæ·»å äžã«çæç©ãåæã«ååºããªããã°ã
æ¹æ容åšã®å 容éãå¢å ããããã®å Žåã«ã¯ãæ·»
å ã¯ãæé«æ¶²é¢ã«éãããŸã§ã«çµäºããªããã°ãª
ããªããåæåãéåžžã«æ¥éã«æ·»å ãããå Žåã«
ã¯ãåŸçµæ¶åã«ãã€ãŠçµæ¶æ§ã±ã€é žå¡©ã®å åãªç
æãéæããããã«ãåå¿å®¹åšå ã§ãªãæŽã«æ¹æ
ãç¶ããªããã°ãªããªãã次ãã§ãçæç©ã¯ããª
ãç±ããªãŒãã¯ã¬ãŒã¶ããååºããããããããª
ããããã®åŸçµæ¶åããå Žåã«ãã€ãŠã¯åæ§ã«æ¹
ææ©ãåããããäžã€ã®å®¹åšãŸãã¯å®¹åšçŸ€ã®äžã§
å®æœããåŸã€ãŠïŒæ¹æ容åšïŒã«ã¹ã±ãŒãã圢æã
ãããããšãæå©ã§ããããšããããåŸçµæ¶åã®
æéã¯ã第äžã®æ¹æ容åšå ã®å¹³åæ»çæéã®æé«
99åã奜ãŸããã¯æé«20åãããŠç¹ã«ïŒ200â以
äžã®é«ã枩床ã«ãããŠïŒïŒåã奜ãŸããã¯ïŒå以
äžãšãã¹ãã§ããããã®éã第ïŒã®æ¹æ容åšãã
ãæããã«äœã枩床ã«ãããŠåŸçµæ¶åãå®æœãã
ããšãå¯èœã§ããã é£ç¶çåå¿æäœã«ãããŠã¯ããªãŒãã¯ã¬ãŒãã
å®å šã«ç©ºã«ããªãã§ãåŸçµæ¶åãããã±ã€é žå¡©ã
æ¯æ¶²ããã³æªåå¿ã®åºçºçæç©ãããªãçæç©æ··
åç©ãåžžã«å°ããšãäžéšå å¡«ããŠããããšãæå©
ã§ãããããã«ãã€ãŠããªãŒãã¯ã¬ãŒãå ã«é«å²
åã®ã±ã€é žå¡©çµæ¶ãæ®çãããããçµæ¶æ§ã±ã€é ž
å¡©ã®ãã以äžã®çæãä¿é²ããã é£ç¶çåå¿æäœã«ãããŠã¯ãçš®åçµæ¶ã¯ãé転
éå§æã®éã®ã¿ãïŒå¹³è¡¡ã®èª¿æŽã®ããã«ïŒæ·»å ã
ãããåå¿äžãåå¿æ··åç©äžã®ã¢ã«ã«ãªéå±ã±ã€
é žå¡©ã®çµæ¶å¯Ÿæº¶è§£ãããSiO2ã®ééæ¯ã¯ã0.05以
äžå¥œãŸããã¯0.1以äžãããŠç¹ã«0.2以äžãšãã¹ã
ã§ããããã®å Žåãå šé£ç¶åŒåå¿æäœã«ãããŠ
ã¯ãäžè¬ã«1.0以äžã®äžå®å€ã«ä¿ãããã åé£ç¶åŒåå¿æäœã«ãããŠã¯ãæ°å€ã¯ãå®æç
ã«å¹³åå€ãè¶ ãããŠãŸããããäžå»»ãã å šé£ç¶åŒåå¿æäœããã³çæ³çæ··åã®å Žåã«
ã¯ãæ¹æ容åšããã³ååºãããçæç©ã®äž¡æ¹ã«æº¶
解ãããã±ã€é žå¡©ãããå®è³ªçã«ããå€ãã®çµæ¶
æ§ã±ã€é žå¡©ãååšããããããšãã§ããã ãªãå å§äžã«ãããªãŒãã¯ã¬ãŒãããçæç©ã
ååºãã¹ãå Žåã«ã¯ãããã¯é©åœãªåºéšæåºåŒã«
ãã€ãŠéæããããå®å šã«ç©ºã«ããããšãææã
ããªãå Žåã«ã¯ãåå¿æ··åç©äžã«æµžãããŠããã
ããŠåŒã«ãã€ãŠééãããŠãããµã€ããªã³ç®¡ãä»
ããŠçæç©ãååºãããšãæå©ã§ãããååºãã
ããçæç©ã®æ倧éã¯ãµã€ããªã³ç®¡ã®é·ãã«ãã€
ãŠæ±ºå®ãããã æ¬çºæã«ããæ¹æ³ã¯ãæå©ã«ã¯å šé£ç¶åŒã«å®æœ
ãããããã®ããã«ã¯ãåºçºæåã®é£ç¶çäŸçµŠãš
å ±ã«ãåå¿çæç©ã®é£ç¶çãªæåºãå¿ èŠãšããã
ããã¯ãäŸãã°ãµã€ããªã³ç®¡ã«ãã€ãŠè¡ãªãã
ããåå¿å®¹åšã®ç£èŠã®ããã«ã¯ã液é¢èšã«ããã
ãŸãã¯è£ 眮ã®ééã枬å®ããããšã«ãã€ãŠæ¶²é¢ã
ç£èŠããå¿ èŠãããã çµæžäžã®çç±ããããããåŒæäœããã³é£ç¶åŒ
æäœã®äž¡æ¹ã«ãããŠãåå¿æéã¯ãäžè¬ã«ãæ·»å
ãããã¢ã«ã«ãªéå±ã±ã€é žå¡©ã®å°ããšã10ïŒ ãå±€
ç¶ã¢ã«ã«ãªéå±ã±ã€é žå¡©ã«å€æããããããªãã®
ãšããããåå¿æž©åºŠãããé«ãå Žåã«ã¯ãããç
ãåå¿æéãå¿ èŠãšãããã180â以äžã®æž©åºŠã«
ãããŠã¯ãïŒæé以äžã®æéã§å åã§ããããã
ããªãããæ°æ¥éã®åå¿æéãå¿ èŠãªããšãã
ããç¹å®ã®åå¿æ¡ä»¶ã«äŸåããå¿ èŠãªåå¿æé
ã¯ãåã ã®è©Šæã®ïŒžç·åæãã¿ãŒã³ãã決å®ãã
ãããæ¬çºæã«ããæ¹æ³ã䜿çšããããšã«ããã
çµæ¶æ§å±€ç¶ã±ã€é žå¡©ã«ãããŠå žåçãªïŒžç·åæã
ãã€ã±ã瀺ãã±ã€é žå¡©ã補é ããããšãã§ããã ïŒçæãããïŒçµæ¶æ§ã®ã±ã€é žå¡©å¯ŸïŒæ·»å ãã
ãïŒæº¶è§£ãããã±ã€é žå¡©ã®æ¯ã¯ãäž»ãšããŠå¹³åæ»
çæéããã³çµæïŒç¹ã«Na2OïŒSiO2ïŒã®ã¢ã«
æ¯ïŒã«ãã€ãŠå®ãŸããå¹³åæ»çæéã®å¢å ã¯ãçµ
æ¶æ§ç©è³ªã®éãå¢å ãããçµæã«ãªãããå Žåã«
ãã€ãŠã¯ãŸãå¯çæç©ã®çæãä¿é²ãããçµæžç
çç±ãããããçãæ»çæéãçšããããŠæ¯èŒç
å°éã®çµæ¶æ§çæç©ãåå ¥ããããšãå®éçã§ã
ããã å±€ç¶ã±ã€é žå¡©ãåé¢ããããã«ã¯ãåå¿æ··åç©
ãåå¿åŸã«éãããããŠæ®æž£ãæ°ŽãŸãã¯åžèãª
ã¢ã«ã«ãªéå±æº¶æ¶²ïŒã¢ã«ã«ãªéå±ã±ã€é žå¡©ã«å¿ã
ãŠïŒã§æŽæ»ãããããŠå¿ èŠãªãã°ä¹Ÿç¥ããããã
ããªãããæŽã«åŠçããããã«ã¯ãäŸãã°ã¢ã«ã«
ãªéå±ã€ãªã³ã塩溶液ã§åŠçãããšãã«ãã€ãŠä»
ã®æã€ãªã³ãšäº€æããããã«ããã€ã«ã¿ãŒããå
åºããã湿最ããçæç©ãçŽæ¥åŠçããããšããŸ
ãæå©ã§ãããã äŸ ïŒ ãœãŒãæ°Žã¬ã©ã¹ïŒSiO227ïŒ ãNa2O8.43ïŒ ã
Al2O30.24ïŒ ïŒ83.5éééšãæ°Ž149éšã«æ·»å ãã
ããšã«ããã次ã®ã¢ã«çµæïŒ Na2O0.303ïŒAl2O30.0052ïŒSiO2ïŒXH2Oãæ
ããåå¿æ··åç©ããŸã調補ããããã®åŸã§ãäºã
è¡ã€ãå®éšããã®ãã€ã«ã¿ãŒããåŸã湿最ããçµ
æ¶æ§ã±ã€é žãããªãŠã ïŒ1200âãžã®å ç±ã«ãã71
ïŒ ã®ééæžïŒã¢ã«çµæã®èšç®ã«åœã€ãŠã¯æ°Žã®éã®
ã¿ãèæ ®ã«å ¥ããïŒãæ·»å ããã次ãã§ã96ïŒ ã®
ç¡«é ž4.93éšãæ¹æäžã«åŸã ã«å ããããã®æåå¿
æ··åç©ã¯ã次ã®ã¢ã«çµæãæããïŒ Na2O0.174ïŒAl2O30.0052ïŒSiO2ïŒ
Na2SO40.129ïŒH2O30ã äžèšã®åå¿æ··åç©ãã¹ãã³ã¬ã³éŒè£œã®ãªãŒãã¯
ã¬ãŒãå ã§205âã§1.5æéå ç±ããããŠãã®æž©åºŠ
ã«ä¿ã€ãæã ãè©ŠæãååºããŠè©Šéšãè¡ãªãã
205âã§2.5æéå ç±ããåŸãåŸã ã«å·åŽãããã
ãã®æç¹ã§ååºããè©Šæã¯ã120âã«ãããŠä¹Ÿç¥
ããåŸã«ãd1ïŒ20.5ã»10-8cmã®æ Œåé¢ééã«ãã
ãŠ56ã®çžå¯ŸåŒ·ããæããåå°ã瀺ããd2ïŒ15.5ã»
10-8cmã«ãããŠã¯åå°ã瀺ãããd3ïŒ3.34ã»10-8
cmã«ãããŠ46ã®çžå¯ŸåŒ·ããæããåå°ãããããŠ
d43.44ã»10-8cmã«ãããŠ100ã®çžå¯ŸåŒ·ããæãã
åå°ããããã瀺ããå·åŽåŸã«åå¿æ··åç©ãé
ããæ°Žã§æŽæ»ããããŠåžåŒæŒæã§åžåŒä¹Ÿç¥ããã
ãã€ã«ã¿ãŒããååºããã湿最ããçæç©ã¯ã55
ïŒ ã®çŒç±æžéã瀺ãã空æ°ã§çæé也ç¥ããçæ
ç©ãç±ééåæã«ããè©ŠéšãããçŽ140âã®æž©åºŠ
ã«éãããŸã§ã«43ïŒ ã®ééæžãçãããçŽ1000â
ãŸã§ã«ã¯ããã以äžé質çãªééæžã¯èŠ³å¯ãããª
ãã120âã«ãããŠäžå®ééãŸã§ä¹Ÿç¥ãããçæ
ç©ïŒïŒã¯ãå çŽ åæã«ãã次ã®çµæã瀺ãïŒ Na3.8ïŒ ãAl0.24ïŒ ãSi41.5ïŒ ããã³Fe0.003
ïŒ ã ãããã17.9ã®SiO2ïŒNa2Oã®ã¢ã«æ¯ãç®åºã
ããã332ã®SiO2ïŒAl2O3ã®ã¢ã«æ¯ã¯ãåå¿æ··å
ç©äžã®æº¶è§£ãããAl2O3ã®ååšã«ããããããã
ããã¯æçµçæç©äžã«æ¥µããŠå°éããçµèŸŒãŸããª
ããšããããšã瀺ãã空æ°ä¹Ÿç¥ãããã±ã€é žãã
ãªãŠã ïŒïŒã®ïŒžç·åæãã¿ãŒã³ã第ïŒè¡šã«ç€º
ãã
ãè¡šã
ãè¡šã
äŸ ïŒ
äŸïŒã«ããçæç©ã«å¡©é
žã宀枩ã«ãããŠ2.0ã®
PHå€ã«éãããŸã§åŸã ã«æ·»å ãããåå¿æ··åç©ã
çŽ15åéæ¹æããéãããã€ã«ã¿ãŒæ®æž£ã«åã³
åžå¡©é žãPHïŒãšãªããŸã§æ·»å ãããçããçµæ¶æ§
ã±ã€é žãéããæ°Žã§ïŒåå åã«æŽæ»ããåã³
éããããŠåžåŒä¹Ÿç¥ããããã€ã«ã¿ãŒããååºã
ãã湿最ããçæç©ã®çŒç±æžéã¯ã34.9ïŒ ã§ã
ãã湿最ããã±ã€é ž100ïœãïŒïŒ ã®NaCl溶液190
ïœãšæ··åãã次ãã§1Mã®NaOHãçšããŠæ»Žå®ã
ãã第ïŒè¡šã¯ã滎å®å€ã瀺ããã°ã©ãã«è¡šããã
å ŽåãPH9.5ã«ãããæ²ç·ã®å±æ²ç¹ãããçŒç±ã
ããçæç©100ïœåœã155ããªåœéã®åœéå€ã決å®
ãããããããããçŽ94ããªã¢ã«H+ïŒã¢ã«SiO2
ã®ã€ãªã³äº€æ容éã枬å®ãããããã¯21ïŒïŒã®
SiO2ïŒ2H+ã®æ¯ãŸãã¯SiO2ïŒNa2Oæ¯ã«çžåœã
ãã äŸ ïŒ äŸïŒã«ããçæç©ãïŒïŒ ã®å¡©é žãçšããŠ80âã«
ãããŠ15åéã®æœåºãïŒåè¡ãªãããã€ã«ã¿ãŒã
ãååºããã湿最ããçæç©ã®ïŒžç·åæãã¿ãŒã³
ã第ïŒè¡šã«ç€ºãã瀺差ç±åæã«ããè©Šéšã®çµæ
ã¯ãçŽ120âã«ãããé¡èãªè»¢ç§»ããã³çŽ1180â
ã«ãããããŸãèãããªãåžç±ç転移ã瀺ããŠã
ãã 第ïŒè¡š ïœïŒ10-8cmïŒ ïŒ©ïŒIo 16.1 19 7.89 ïŒ 5.21 12 3.85 15 3.53(S) 27 3.39 100 3.22(S) 17 ïŒè©éš äŸ ïŒ äŸïŒã«ãããã€ã«ã¿ãŒããååºããã湿最ãã
çæç©ã«éå°ã®èæ§ãœãŒã溶液ãå ãããïŒæé
æ¹æããåžåŒéããããŠå°éã®æ°Žã§æŽæ»ããã
120âã«ãããŠä¹Ÿç¥ãããçæç©ã®ïŒžç·è§£æãã¿
ãŒã³ã第ïŒè¡šã«ç€ºãã 第ïŒè¡š ïœïŒ10-8cmïŒ ïŒ©ïŒIo 19.8 62 9.87 13 7.31 ïŒ 6.37 ïŒ 4.98 11 4.69 10 4.27 ïŒ 3.66 19 3.50 31 3.44 100 3.35 44 3.33 44 3.21 47 2.94 ïŒ äŸ ïŒ äºãçæé空æ°ä¹Ÿç¥ãããããŠ44.2ïŒ ã®çŒç±æž
éãæããäŸïŒããã®çæç©10ïœãæ°Ž190ïœã«æ·»
å ãã0.5Mã®H2So4ã§æ»Žå®ãè¡ãªãããããã
ã®æ·»å åŸãPHãå°æ°ç¹ä»¥äžïŒäœãŸã§å°ããšãïŒå
éäžå®ã«ãªããŸã§åŸ ã¡æéãããããã®çµæã滎
å®ã«æ°æéãããã第ïŒè¡šã¯æ»Žå®å€ã瀺ããã°ã©
ããçšããããšã«ãããPH4.5ã«ãããæ²ç·ã®å±
æ²ç¹ãããçŒç±ãããçæç©100ïœåœãNa+150ã
ãªã¢ã«ã®åœéå€ã決å®ããããã21ïŒïŒã®
SiO2ïŒNa2Oâæ¯ãŸãã¯SiO2ïŒ2H+âïŒäº€æãã
ããããã³ïŒã«çžåœããçŽ95ããªã¢ã«Na+ïŒã¢ã«
SiO2ã®ã€ãªã³äº€æ容éã枬å®ããããé žã§æ»Žå®
ããããŠç©ºæ°äžã§ä¹Ÿç¥ããåŸã®ïŒžç·åæãã¿ãŒã³
ã¯ç¬¬ïŒè¡šã«ç€ºãããŠããã
PHå€ã«éãããŸã§åŸã ã«æ·»å ãããåå¿æ··åç©ã
çŽ15åéæ¹æããéãããã€ã«ã¿ãŒæ®æž£ã«åã³
åžå¡©é žãPHïŒãšãªããŸã§æ·»å ãããçããçµæ¶æ§
ã±ã€é žãéããæ°Žã§ïŒåå åã«æŽæ»ããåã³
éããããŠåžåŒä¹Ÿç¥ããããã€ã«ã¿ãŒããååºã
ãã湿最ããçæç©ã®çŒç±æžéã¯ã34.9ïŒ ã§ã
ãã湿最ããã±ã€é ž100ïœãïŒïŒ ã®NaCl溶液190
ïœãšæ··åãã次ãã§1Mã®NaOHãçšããŠæ»Žå®ã
ãã第ïŒè¡šã¯ã滎å®å€ã瀺ããã°ã©ãã«è¡šããã
å ŽåãPH9.5ã«ãããæ²ç·ã®å±æ²ç¹ãããçŒç±ã
ããçæç©100ïœåœã155ããªåœéã®åœéå€ã決å®
ãããããããããçŽ94ããªã¢ã«H+ïŒã¢ã«SiO2
ã®ã€ãªã³äº€æ容éã枬å®ãããããã¯21ïŒïŒã®
SiO2ïŒ2H+ã®æ¯ãŸãã¯SiO2ïŒNa2Oæ¯ã«çžåœã
ãã äŸ ïŒ äŸïŒã«ããçæç©ãïŒïŒ ã®å¡©é žãçšããŠ80âã«
ãããŠ15åéã®æœåºãïŒåè¡ãªãããã€ã«ã¿ãŒã
ãååºããã湿最ããçæç©ã®ïŒžç·åæãã¿ãŒã³
ã第ïŒè¡šã«ç€ºãã瀺差ç±åæã«ããè©Šéšã®çµæ
ã¯ãçŽ120âã«ãããé¡èãªè»¢ç§»ããã³çŽ1180â
ã«ãããããŸãèãããªãåžç±ç転移ã瀺ããŠã
ãã 第ïŒè¡š ïœïŒ10-8cmïŒ ïŒ©ïŒIo 16.1 19 7.89 ïŒ 5.21 12 3.85 15 3.53(S) 27 3.39 100 3.22(S) 17 ïŒè©éš äŸ ïŒ äŸïŒã«ãããã€ã«ã¿ãŒããååºããã湿最ãã
çæç©ã«éå°ã®èæ§ãœãŒã溶液ãå ãããïŒæé
æ¹æããåžåŒéããããŠå°éã®æ°Žã§æŽæ»ããã
120âã«ãããŠä¹Ÿç¥ãããçæç©ã®ïŒžç·è§£æãã¿
ãŒã³ã第ïŒè¡šã«ç€ºãã 第ïŒè¡š ïœïŒ10-8cmïŒ ïŒ©ïŒIo 19.8 62 9.87 13 7.31 ïŒ 6.37 ïŒ 4.98 11 4.69 10 4.27 ïŒ 3.66 19 3.50 31 3.44 100 3.35 44 3.33 44 3.21 47 2.94 ïŒ äŸ ïŒ äºãçæé空æ°ä¹Ÿç¥ãããããŠ44.2ïŒ ã®çŒç±æž
éãæããäŸïŒããã®çæç©10ïœãæ°Ž190ïœã«æ·»
å ãã0.5Mã®H2So4ã§æ»Žå®ãè¡ãªãããããã
ã®æ·»å åŸãPHãå°æ°ç¹ä»¥äžïŒäœãŸã§å°ããšãïŒå
éäžå®ã«ãªããŸã§åŸ ã¡æéãããããã®çµæã滎
å®ã«æ°æéãããã第ïŒè¡šã¯æ»Žå®å€ã瀺ããã°ã©
ããçšããããšã«ãããPH4.5ã«ãããæ²ç·ã®å±
æ²ç¹ãããçŒç±ãããçæç©100ïœåœãNa+150ã
ãªã¢ã«ã®åœéå€ã決å®ããããã21ïŒïŒã®
SiO2ïŒNa2Oâæ¯ãŸãã¯SiO2ïŒ2H+âïŒäº€æãã
ããããã³ïŒã«çžåœããçŽ95ããªã¢ã«Na+ïŒã¢ã«
SiO2ã®ã€ãªã³äº€æ容éã枬å®ããããé žã§æ»Žå®
ããããŠç©ºæ°äžã§ä¹Ÿç¥ããåŸã®ïŒžç·åæãã¿ãŒã³
ã¯ç¬¬ïŒè¡šã«ç€ºãããŠããã
ãè¡šã
ãè¡šã
äŸ ïŒ
äŸïŒã®æ»Žå®ãç¹°è¿ãããã ãæ°Žã®ä»£ãã«ïŒïŒ
ã®
NaCl溶液190ïœãçšããããã第ïŒè¡šã¯ã滎å®å€
ã瀺ããã°ã©ããçšããããšã«ãããPH3.75ã«ã
ããæ²ç·ã®å±æ²ç¹ãããçŒç±ãããçæç©100ïœ
åœã145ããªã¢ã«ã®åœéå€ã決å®ããããããã
ãã22ïŒïŒã®SiO2ïŒNa2Oâæ¯ãŸãã¯SiO2ïŒ2H+
âæ¯ã«çžåœããSiO21ã¢ã«åœãNa+çŽ91ããªã¢ã«
ã®ã€ãªã³äº€æ容éãç®åºãããã
NaCl溶液190ïœãçšããããã第ïŒè¡šã¯ã滎å®å€
ã瀺ããã°ã©ããçšããããšã«ãããPH3.75ã«ã
ããæ²ç·ã®å±æ²ç¹ãããçŒç±ãããçæç©100ïœ
åœã145ããªã¢ã«ã®åœéå€ã決å®ããããããã
ãã22ïŒïŒã®SiO2ïŒNa2Oâæ¯ãŸãã¯SiO2ïŒ2H+
âæ¯ã«çžåœããSiO21ã¢ã«åœãNa+çŽ91ããªã¢ã«
ã®ã€ãªã³äº€æ容éãç®åºãããã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
äŸ ïŒ
æ²æ®¿ã±ã€é
žïŒã¡ã«ã¯ç€ŸïŒMerck AG.
DarmstadtãCat.No.657ïŒçŒç±æžéçŽ15ïŒ ïŒ
141.44éééšãæ°Ž1479éééšã«å ãã次ãã§
NaOH32éééšãå°å ¥ãããããã¯Na2O0.20ïŒ
SiO2ïŒH2O42ã®ã¢ã«çµæã«çžåœããã æ··åç©ã察å¿ããåã®å®éšããã®çµæ¶æ§ã±ã€é ž
ãããªãŠã ã®æ®æž£ããªãå«æããŠããã¹ãã³ã¬ã¹
éŒè£œã®ãªãŒãã¯ã¬ãŒãäžã§200âã«å ç±ããããŠ
æ¹æãããã±ã€é žã¯ãã±ã€é žãããªãŠã ã®çæäž
ã«æº¶è§£ããã ïŒæéã®å šåå¿æéã®åŸã«ãåå¿æ··åç©ãé
ããæŽæ»ããããŠ100âã«ãããŠä¹Ÿç¥ãããç·
åæã¹ãã¯ãã«ã¯ã第ïŒè¡šã«ç€ºãããŠããããã«
ã»ãŒäžèŽããïŒ3.44ã»10-8cmã«ããã匷ãç·ïŒã 0.5Mã®H2SO4ãçšãã滎å®ã«ãã€ãŠçŒç±ãã
ãçæç©100ïœåœãNa+çŽ142ããªã¢ã«ã®ã€ãªã³äº€
æ容éã枬å®ãããããããããNa2SixO2x+1
ïŒããã«ïœïŒ22.4ïŒã®å®éšçµæããã³0.089ã®NaïŒ
Siã®ååæ¯ãç®åºãããã äŸ ïŒ ïŒæ¯èŒäŸïŒ 以äžã®ïŒã€ã®äŸã«ãããŠãäžè¿°ããæ¬çºæã«ã
ãã±ã€é žå¡©ããã¬ãžã¢ã€ãç³»ã®å±€ç¶ã±ã€é žå¡©ãšæ¯
èŒãããäŸïŒã¯ãçš®åçµæ¶ãæ·»å ããããšã«ãã€
ãŠã±ã€é žãããªãŠã ã®çµæ¶åã匷ã圱é¿ãããã
ãšã瀺ãããã®ãã®ã§ããã ã±ã€é žãããªãŠã ã¯ãäŸïŒã«ããããã®ãšåã
ãšãã¯ãçµæãæããåå¿æ··åç©ãã補é ãã
ããåã«è¡ãªãããå®éšããåŸããããã¬ãžã¢ã€
ãæ§ã±ã€é žå¡©ã®çš®åçµæ¶ãåå¿æ··åç©ã«æ·»å ãã
ããåå¿æ··åç©ã165âã«ãããŠ19æéæ¹æãã
å·åŽåŸéããæ°Žã§æŽããããŠåžåŒæŒæã§åžåŒä¹Ÿ
ç¥ãããæ°Ž250mlã§åžéãããåå¿æ··åç©ããã®
æ¯æ¶²10ïœã¯ã10.4ã®PHå€ãæããã空æ°äžã§çæ
é也ç¥ãããçæç©ã®ïŒžç·åæãã¿ãŒã³ã第ïŒè¡š
ã«ç€ºããçŒç±ïŒ1000â以äžïŒã«ãããã®ééã®
61.3ïŒ ã®æžéã瀺ããã€ã«ã¿ãŒããååºããã湿
最ããçæç©ãäŸïŒãšåæ§ã«ããŠç¡«é žã§æ»Žå®ã
ãã第ïŒè¡šã¯æ»Žå®å€ã瀺ããã°ã©ãã«è¡šãããå Ž
åãPH5.0ã«ãããæ²ç·ã®å±æ²ç¹ããçŒç±ããã
çæç©100ïœåœã215ããªåœéã®åœéå€ãåŸãã
ããè©Šæã®SiO2å«éã«ã€ããŠæ»Žå®ãã決å®ãã
ãçµæãå å«ãããããšã«ããã14.5ïŒïŒã®
SiO2ïŒNa2Oâæ¯ã«çžåœãã138ããªã¢ã«Na+ïŒ
ã¢ã«SiO2ã®ã€ãªã³äº€æ容éã決å®ãããã 第ïŒè¡š ïœïŒ10-8cmïŒ ïŒ©ïŒIo 15.5 100 7.76 13 5.15 20 4.69 ïŒ 4.44 10 4.23 ïŒ 3.63 18 3.54 24 3.44 79 3.30 49 3.14 65 2.81 11 2.58 ïŒ 2.34 ïŒ
DarmstadtãCat.No.657ïŒçŒç±æžéçŽ15ïŒ ïŒ
141.44éééšãæ°Ž1479éééšã«å ãã次ãã§
NaOH32éééšãå°å ¥ãããããã¯Na2O0.20ïŒ
SiO2ïŒH2O42ã®ã¢ã«çµæã«çžåœããã æ··åç©ã察å¿ããåã®å®éšããã®çµæ¶æ§ã±ã€é ž
ãããªãŠã ã®æ®æž£ããªãå«æããŠããã¹ãã³ã¬ã¹
éŒè£œã®ãªãŒãã¯ã¬ãŒãäžã§200âã«å ç±ããããŠ
æ¹æãããã±ã€é žã¯ãã±ã€é žãããªãŠã ã®çæäž
ã«æº¶è§£ããã ïŒæéã®å šåå¿æéã®åŸã«ãåå¿æ··åç©ãé
ããæŽæ»ããããŠ100âã«ãããŠä¹Ÿç¥ãããç·
åæã¹ãã¯ãã«ã¯ã第ïŒè¡šã«ç€ºãããŠããããã«
ã»ãŒäžèŽããïŒ3.44ã»10-8cmã«ããã匷ãç·ïŒã 0.5Mã®H2SO4ãçšãã滎å®ã«ãã€ãŠçŒç±ãã
ãçæç©100ïœåœãNa+çŽ142ããªã¢ã«ã®ã€ãªã³äº€
æ容éã枬å®ãããããããããNa2SixO2x+1
ïŒããã«ïœïŒ22.4ïŒã®å®éšçµæããã³0.089ã®NaïŒ
Siã®ååæ¯ãç®åºãããã äŸ ïŒ ïŒæ¯èŒäŸïŒ 以äžã®ïŒã€ã®äŸã«ãããŠãäžè¿°ããæ¬çºæã«ã
ãã±ã€é žå¡©ããã¬ãžã¢ã€ãç³»ã®å±€ç¶ã±ã€é žå¡©ãšæ¯
èŒãããäŸïŒã¯ãçš®åçµæ¶ãæ·»å ããããšã«ãã€
ãŠã±ã€é žãããªãŠã ã®çµæ¶åã匷ã圱é¿ãããã
ãšã瀺ãããã®ãã®ã§ããã ã±ã€é žãããªãŠã ã¯ãäŸïŒã«ããããã®ãšåã
ãšãã¯ãçµæãæããåå¿æ··åç©ãã補é ãã
ããåã«è¡ãªãããå®éšããåŸããããã¬ãžã¢ã€
ãæ§ã±ã€é žå¡©ã®çš®åçµæ¶ãåå¿æ··åç©ã«æ·»å ãã
ããåå¿æ··åç©ã165âã«ãããŠ19æéæ¹æãã
å·åŽåŸéããæ°Žã§æŽããããŠåžåŒæŒæã§åžåŒä¹Ÿ
ç¥ãããæ°Ž250mlã§åžéãããåå¿æ··åç©ããã®
æ¯æ¶²10ïœã¯ã10.4ã®PHå€ãæããã空æ°äžã§çæ
é也ç¥ãããçæç©ã®ïŒžç·åæãã¿ãŒã³ã第ïŒè¡š
ã«ç€ºããçŒç±ïŒ1000â以äžïŒã«ãããã®ééã®
61.3ïŒ ã®æžéã瀺ããã€ã«ã¿ãŒããååºããã湿
最ããçæç©ãäŸïŒãšåæ§ã«ããŠç¡«é žã§æ»Žå®ã
ãã第ïŒè¡šã¯æ»Žå®å€ã瀺ããã°ã©ãã«è¡šãããå Ž
åãPH5.0ã«ãããæ²ç·ã®å±æ²ç¹ããçŒç±ããã
çæç©100ïœåœã215ããªåœéã®åœéå€ãåŸãã
ããè©Šæã®SiO2å«éã«ã€ããŠæ»Žå®ãã決å®ãã
ãçµæãå å«ãããããšã«ããã14.5ïŒïŒã®
SiO2ïŒNa2Oâæ¯ã«çžåœãã138ããªã¢ã«Na+ïŒ
ã¢ã«SiO2ã®ã€ãªã³äº€æ容éã決å®ãããã 第ïŒè¡š ïœïŒ10-8cmïŒ ïŒ©ïŒIo 15.5 100 7.76 13 5.15 20 4.69 ïŒ 4.44 10 4.23 ïŒ 3.63 18 3.54 24 3.44 79 3.30 49 3.14 65 2.81 11 2.58 ïŒ 2.34 ïŒ
ãè¡šã
ãè¡šã
äŸ ïŒ
ïŒæ¯èŒäŸïŒ
äŸïŒããã®æ¹¿æœ€çæç©100ïœãïŒïŒ
ã®å¡©é
ž200ml
ã«æ·»å ãããããŠå®€æž©ã«ãããŠ1.25æéæ¹æã
ãããã®çæç©ãéããåã³åéã®å¡©é žãšæ··å
ãã25æéæ¹æããéããããŠãã®çæç©ãæ°Ž
ãšå ±ã«æ¹æããããŠéã®éã«æŽãããšã«ãã€ãŠ
æ°Žã§ïŒå培åºçã«æŽæ»ããïŒç©ºæ°äžã§çæé也ç¥
ããçæç©ã®ïŒžç·ã¹ãã¯ãã«ã第10è¡šã«ç€ºãããŠ
ããïŒã次ã«çæç©ãåžåŒä¹Ÿç¥ããã10.0ïœïŒçŒ
ç±æžé57.1ïŒ ïŒãïŒïŒ ã®NaCl溶液190mmã«å ãã
ãããŠæ¬¡ã«1MNaOHã§æ»Žå®ããã第11è¡šã¯æ»Žå®
å€ã瀺ããã°ã©ãã«è¡šãããå ŽåãPH8.3ã«ãã
ãæ²ç·ã®å±æ²ç¹ãããçŒç±ãããçæç©100ïœåœ
ãH+235ããªã¢ã«ã®åœéå€ã決å®ããããããã
ã13.9ïŒïŒã®SiO2ïŒ2H+âæ¯ãŸãã¯SiO2ïŒNa2O
âæ¯ã«çžåœããçŽ144ããªåœéïŒã¢ã«SiO2ã®ã€ãª
ã³äº€æ容éãç®åºãããã 倩ç¶ç£ãªãã³ã«åæã®ãã¬ãžã¢ã€ãã«ã€ããŠã
13.4ãªãã14.1ã®SiO2ïŒNa2Oå çŽ åæã«ããçµ
æã決å®ãããŠããïŒLagaly et al.ãAm.
Mineral.ã60ã642â649ïŒ1975ïŒåç §ïŒãäŸïŒã®ã
ããªãŠã å¡©ã®ããŸãã¯äŸïŒã®éé¢ã®é žã®ãããã
ã®ã€ãªã³äº€æ容éããç®åºããã14.5ïŒïŒãŸãã¯
13.9ïŒïŒã®æ¯ã¯ããããã®æ°å€ãšããäžèŽããã 第10è¡š ïœïŒ10-8cmïŒ ïŒ©ïŒIo 12.1 11 7.42 ïŒ 5.55 ïŒ 4.35 ïŒ 3.69 17 3.62 18 3.62 18 3.43 100 3.25 16 3.21 16 3.18 15
ã«æ·»å ãããããŠå®€æž©ã«ãããŠ1.25æéæ¹æã
ãããã®çæç©ãéããåã³åéã®å¡©é žãšæ··å
ãã25æéæ¹æããéããããŠãã®çæç©ãæ°Ž
ãšå ±ã«æ¹æããããŠéã®éã«æŽãããšã«ãã€ãŠ
æ°Žã§ïŒå培åºçã«æŽæ»ããïŒç©ºæ°äžã§çæé也ç¥
ããçæç©ã®ïŒžç·ã¹ãã¯ãã«ã第10è¡šã«ç€ºãããŠ
ããïŒã次ã«çæç©ãåžåŒä¹Ÿç¥ããã10.0ïœïŒçŒ
ç±æžé57.1ïŒ ïŒãïŒïŒ ã®NaCl溶液190mmã«å ãã
ãããŠæ¬¡ã«1MNaOHã§æ»Žå®ããã第11è¡šã¯æ»Žå®
å€ã瀺ããã°ã©ãã«è¡šãããå ŽåãPH8.3ã«ãã
ãæ²ç·ã®å±æ²ç¹ãããçŒç±ãããçæç©100ïœåœ
ãH+235ããªã¢ã«ã®åœéå€ã決å®ããããããã
ã13.9ïŒïŒã®SiO2ïŒ2H+âæ¯ãŸãã¯SiO2ïŒNa2O
âæ¯ã«çžåœããçŽ144ããªåœéïŒã¢ã«SiO2ã®ã€ãª
ã³äº€æ容éãç®åºãããã 倩ç¶ç£ãªãã³ã«åæã®ãã¬ãžã¢ã€ãã«ã€ããŠã
13.4ãªãã14.1ã®SiO2ïŒNa2Oå çŽ åæã«ããçµ
æã決å®ãããŠããïŒLagaly et al.ãAm.
Mineral.ã60ã642â649ïŒ1975ïŒåç §ïŒãäŸïŒã®ã
ããªãŠã å¡©ã®ããŸãã¯äŸïŒã®éé¢ã®é žã®ãããã
ã®ã€ãªã³äº€æ容éããç®åºããã14.5ïŒïŒãŸãã¯
13.9ïŒïŒã®æ¯ã¯ããããã®æ°å€ãšããäžèŽããã 第10è¡š ïœïŒ10-8cmïŒ ïŒ©ïŒIo 12.1 11 7.42 ïŒ 5.55 ïŒ 4.35 ïŒ 3.69 17 3.62 18 3.62 18 3.43 100 3.25 16 3.21 16 3.18 15
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å±€æ§é ããã³H2SixO2x+1ãŸã㯠Na2SixO2x+1ïŒããã«ïœã¯15ãªãã24ã®æ°ãæ
å³ããïŒã®ç·åçµæãæããçµæ¶æ§ã±ã€é žãŸãã¯
ãã®ãããªãŠã å¡©ã§ãã€ãŠãç·åæå³ã«ãããŠ
ïŒ3.42±0.1ïŒã»10-8cmã«æ¥µããŠåŒ·ã第äžã®ç·ããã
ããŠïŒ18±ïŒïŒã»10-8cmã«ããã®åŒ·åºŠã第äžã®ç·
ã®åŒ·åºŠã®ãããã75ïŒ ã§ãã第äºã®ç·ã瀺ããã
ããŠ83ãªãã130ããªã¢ã«H+ïŒã¢ã«SiO2ã®æ»Žå®ã
ããé žæ§åºŠãæããäžèšçµæ¶æ§ã±ã€é žãŸãã¯ïŒžç·
åæå³ã«ãããŠïŒ3.42±0.15ïŒã»10-8cmã«å°ãªããš
ãïŒæ¬ã®æ¥µããŠåŒ·ãç·ãããããŠïŒ20±ïŒïŒã»
10-8cmã«ãã®åŒ·åºŠã第äžã®ç·ã®åŒ·åºŠã®ãããã75
ïŒ ã§ãã第äºã®ç·ã瀺ãããããŠç¡«é žãçšãã滎
å®ã«ãã€ãŠæ±ºå®ããã83ãªãã130ããªã¢ã«
Na+ïŒã¢ã«SiO2ã®ã€ãªã³äº€æ容éãæãããã®
ãããªãŠã å¡©ã ïŒ ã€ãªã³äº€æ容éã83ãªãã150ããªã¢ã«NaïŒ
ããªã¢ã«SiO2ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒ
ã®ãããªãŠã å¡©ã ïŒ å±€æ§é ããã³H2SixO2x+1ãŸã㯠Na2SixO2x+1ïŒããã«ïœã¯15ãªãã24ã®æ°ãæ
å³ããïŒã®ç·åçµæãæããçµæ¶æ§ã±ã€é žãŸãã¯
ãã®ãããªãŠã å¡©ã®è£œé æ¹æ³ã«ãããŠã83ã130
ããªã¢ã«Na+ïŒã¢ã«SiO2ã®ã€ãªã³äº€æ容éãæ
ããçµæ¶æ§ã±ã€é žãããªãŠã ã補é ãã¹ãã
3.9ïŒïŒãªãã15ïŒïŒã®SiO2ïŒNa2Oã®ã¢ã«æ¯ãã
ã³ïŒïŒïŒãªãã80ïŒïŒã®H2OïŒïŒNa2OïŒSiO2ïŒ
ã®ã¢ã«æ¯ãæããã±ã€é žãããªãŠã å«ææ°Žæ§åå¿
æ··åç©ã§ãã€ãŠãææã®çµæ¶æ§ã±ã€é žãããªãŠã
ã®çš®çµæ¶ãã䜿çšãããåå¿æ··åç©ã®SiO2å«é
ã«é¢ããŠ0.01ãªãã30ééïŒ å«æããäžèšåå¿æ··
åç©ãçšæããããã160ãªãã250âã®æž©åºŠã«å
ç±ããåå¿ãå°ãªããšããåžåŒæ¿ŸéãããããŠ
120âã«ãããŠä¹Ÿç¥ãããè©Šæãç·åæå³ã«ã
ããŠæ Œåé¢ééd1ïŒïŒ20±ïŒïŒã»10-8cmã«ãããå
å°ã®åŒ·ãå¯Ÿæ Œåé¢ééd2ïŒïŒ15.5±1.5ïŒã»10-8cmã«
ãããåå°ã®åŒ·ãã®æ¯ãå°ãªããšãïŒïŒïŒã瀺ã
ã«å°ããŸã§å®æœãããããŠåå¿ããæ Œåé¢ééd3
ïŒïŒ3.34±0.04ïŒã»10-8cmã«ãããåå°ã®åŒ·ããæ Œ
åé¢ééd4ïŒïŒ3.44±0.04ïŒã»10-8cmã«ãããåå°
ã®åŒ·ãã«éããããŸãã¯ãããè¶ ããåã«çµäºã
ããããšãç¹åŸŽãšããäžèšçµæ¶æ§ã±ã€é žãããªãŠ
ã ã®è£œé æ¹æ³ã ïŒ äœ¿çšãããåå¿æ··åç©ãïŒïŒïŒãªãã10ïŒïŒ
ã®SiO2ïŒNa2Oã¢ã«æ¯ãæããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®æ¹æ³ã ïŒ ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµæ¶æ§ã±ã€é žã
補é ãã¹ããçµæ¶æ§ã±ã€é žã®ã¢ã«ã«ãªéå±å¡©ãåž
èãªç¡æ©é žã§åŠçãããããŠçããã±ã€é žãæ¿Ÿå¥
ããããšãç¹åŸŽãšããäžèšçµæ¶æ§ã±ã€é žã®è£œé æ¹
æ³ã
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19843400130 DE3400130A1 (de) | 1984-01-04 | 1984-01-04 | Kristalline kieselsaeure, ihre salze und verfahren zu ihrer herstellung |
DE3400130.1 | 1984-01-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60161319A JPS60161319A (ja) | 1985-08-23 |
JPH0542366B2 true JPH0542366B2 (ja) | 1993-06-28 |
Family
ID=6224321
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59275020A Granted JPS60161319A (ja) | 1984-01-04 | 1984-12-28 | çµæ¶æ§ã±ã€é žããã®å¡©ããã³ãã®è£œé æ¹æ³ |
Country Status (6)
Country | Link |
---|---|
US (1) | US4581213A (ja) |
EP (1) | EP0150442B1 (ja) |
JP (1) | JPS60161319A (ja) |
DE (2) | DE3400130A1 (ja) |
ES (1) | ES539295A0 (ja) |
PT (1) | PT79792B (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3416669A1 (de) * | 1984-05-05 | 1985-11-07 | Hoechst Ag, 6230 Frankfurt | Weichmachendes waschmittel |
DE3440252A1 (de) * | 1984-11-03 | 1986-05-15 | Hoechst Ag, 6230 Frankfurt | Formkoerper aus silikatischem material, verfahren zu ihrer herstellung und verwendung |
US4812228A (en) * | 1985-09-10 | 1989-03-14 | Mobil Oil Corporation | Process for hydrotreating residual petroleum oil |
DE3669490D1 (de) * | 1985-06-13 | 1990-04-19 | Hoechst Ag | Verfahren zur herstellung von kristallinen alkalischichtsilikaten. |
US4626421A (en) * | 1985-06-28 | 1986-12-02 | Chevron Research Company | Preparation of magadiite |
CA1272999A (en) * | 1985-11-12 | 1990-08-21 | Guenter H. Kuehl | Crystalline layered and large pore catalytic material |
ZA867945B (en) * | 1985-11-12 | 1988-05-25 | Mobil Oil Corp | Layered silicates |
DK168988B1 (da) * | 1986-01-24 | 1994-07-25 | Topsoe Haldor As | Krystallinsk aluminosilikat, fremgangsmåde til fremstilling deraf og anveldelse deraf |
DE4308062A1 (de) * | 1993-03-13 | 1994-09-15 | Hoechst Ag | Verfahren zur Herstellung von Gemischen aus synthetischem, kristallinem Kenyait und sauerstoffabspaltenden Salzen sowie deren Verwendung |
DE4308063A1 (de) * | 1993-03-13 | 1994-09-15 | Hoechst Ag | Verfahren zur Herstellung von Gemischen aus synthetischem, kristallinem Magadiit und sauerstoffabspaltenden Salzen sowie deren Verwendung |
DE4318242A1 (de) * | 1993-06-02 | 1994-12-08 | Hoechst Ag | Verfahren zur Herstellung von kristallinem Natriumschichtsilikat mit Kanemitstruktur |
DE4446033C2 (de) * | 1994-12-23 | 1996-11-07 | Heraeus Kulzer Gmbh | Polymerisierbares Dentalmaterial |
DE19603838A1 (de) * | 1996-02-05 | 1997-08-07 | Hoechst Ag | Kristalline KieselsÀuren |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB759611A (en) * | 1952-08-15 | 1956-10-24 | Columbia Southern Chem Corp | Finely divided silica |
US4061724A (en) * | 1975-09-22 | 1977-12-06 | Union Carbide Corporation | Crystalline silica |
US4073865A (en) * | 1976-09-27 | 1978-02-14 | Union Carbide Corporation | Silica polymorph and process for preparing same |
DE2742912C3 (de) * | 1977-09-23 | 1980-05-08 | Lagaly, Gerhard, Prof. Dr., 2300 Kiel | Kristalline KieselsÀure, ihr Kaliumsalz, Verfahren zu ihrer Herstellung und ihre Verwendung |
US4285922A (en) * | 1979-09-10 | 1981-08-25 | Mobil Oil Corporation | Method of preparing crystalline zeolite |
US4430314A (en) * | 1980-06-06 | 1984-02-07 | Mobil Oil Corporation | Method of preparing crystalline zeolite |
EP0042225B1 (en) * | 1980-06-12 | 1984-02-01 | Imperial Chemical Industries Plc | Zeolite synthesis |
DE3211433C2 (de) * | 1982-03-27 | 1984-12-13 | Degussa Ag, 6000 Frankfurt | Kristallines Alumosilikat PZ 1 und Verfahren zu seiner Herstellung |
GB2125390B (en) * | 1982-08-16 | 1985-12-24 | Ici Plc | Preparation of zeolites |
-
1984
- 1984-01-04 DE DE19843400130 patent/DE3400130A1/de not_active Withdrawn
- 1984-12-19 EP EP84115780A patent/EP0150442B1/de not_active Expired
- 1984-12-19 DE DE8484115780T patent/DE3476748D1/de not_active Expired
- 1984-12-28 JP JP59275020A patent/JPS60161319A/ja active Granted
-
1985
- 1985-01-02 ES ES539295A patent/ES539295A0/es active Granted
- 1985-01-02 US US06/688,454 patent/US4581213A/en not_active Expired - Lifetime
- 1985-01-03 PT PT79792A patent/PT79792B/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
PT79792A (en) | 1985-02-01 |
US4581213A (en) | 1986-04-08 |
EP0150442B1 (de) | 1989-02-15 |
EP0150442A1 (de) | 1985-08-07 |
ES8601068A1 (es) | 1985-11-16 |
DE3476748D1 (en) | 1989-03-23 |
PT79792B (en) | 1986-11-14 |
JPS60161319A (ja) | 1985-08-23 |
ES539295A0 (es) | 1985-11-16 |
DE3400130A1 (de) | 1985-07-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4578258A (en) | Process for the preparation of crystalline sheet-type alkali metal silicates | |
US4806327A (en) | Process for the preparation of crystalline sheet-type alkali metal silicates | |
DK167866B1 (da) | Fremgangsmaade til fremstilling af zeolitter | |
JPH0542366B2 (ja) | ||
CA1082161A (en) | Crystalline type-a zeolite powder | |
CA1213872A (en) | Process for preparation of zeolites | |
IE904224A1 (en) | Process for preparing alkali metal silicates | |
JPS5914273B2 (ja) | ã°ãªãããæããªããŒãªã©ã€ãã¢ã¬ããŠã©ã·âããæ°Žã®è»åã«çšããæ¹æ³ | |
SE430245B (sv) | Forfarande for framstellning av ett kristallint natriumaluminium silikat av typen 4a | |
US4749676A (en) | Process for the preparation of a crystalline, swellable sheet silicate of the saponite type | |
JPH1171108A (ja) | åæã±ã€é žãã°ãã·ãŠã | |
JPH0258204B2 (ja) | ||
HU181898B (en) | Semicontinuous industrial process for producing zeolite a | |
GB2041902A (en) | Synthetic zeolites | |
CN109279623A (zh) | äžç§çšåŸ®åäºç£·é žénkx-12䞺éæºåæé«ç¡ éæ¯äžå 沞ç³çæ¹æ³ | |
EP0097512B1 (en) | Aluminosilicates | |
JPH0244771B2 (ja) | ||
GB1571535A (en) | Crystalline zeolite powder of type | |
JPH06345420A (ja) | åæçµæ¶æ§ãã¬ãã£ã¢ã€ããšé žçŽ åé¢æ§å¡©ãšã®æ··åç©ã®è£œé æ¹æ³ | |
IE40516L (en) | Cation exchanging aluminium silicates | |
JPH04202009A (ja) | çµæ¶æ§å±€ç¶çªé žã®éå±çœ®æäœåã³ãã®è£œé æ¹æ³ | |
JPS58156527A (ja) | ç¡å®åœ¢ã¢ã«ããã±ã€é žå¡©ã®è£œé æ¹æ³ | |
JPS6042229A (ja) | ãŒãªã©ã€ãæ§é ãæããã¢ã«ããã±ã€é žå¡©ã®è£œé æ¹æ³ | |
JPH04305010A (ja) | é«èç±æ°Žæ§ãŒãªã©ã€ãã®è£œé æ³ | |
JPH0353251B2 (ja) |