JPH0471427B2 - - Google Patents
Info
- Publication number
- JPH0471427B2 JPH0471427B2 JP63040893A JP4089388A JPH0471427B2 JP H0471427 B2 JPH0471427 B2 JP H0471427B2 JP 63040893 A JP63040893 A JP 63040893A JP 4089388 A JP4089388 A JP 4089388A JP H0471427 B2 JPH0471427 B2 JP H0471427B2
- Authority
- JP
- Japan
- Prior art keywords
- condensation polymer
- filler
- polymer composite
- weight
- composite according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002131 composite material Substances 0.000 claims description 56
- 229920000642 polymer Polymers 0.000 claims description 53
- 238000009833 condensation Methods 0.000 claims description 48
- 230000005494 condensation Effects 0.000 claims description 47
- 239000000945 filler Substances 0.000 claims description 46
- 239000000203 mixture Substances 0.000 claims description 43
- 239000000654 additive Substances 0.000 claims description 34
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 20
- 229920000647 polyepoxide Polymers 0.000 claims description 20
- 239000003822 epoxy resin Substances 0.000 claims description 19
- 230000000996 additive effect Effects 0.000 claims description 18
- -1 oxirane compound Chemical class 0.000 claims description 17
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 15
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 15
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 13
- 239000004927 clay Substances 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 12
- 239000004952 Polyamide Substances 0.000 claims description 11
- 229920002647 polyamide Polymers 0.000 claims description 11
- 229920000728 polyester Polymers 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- LCHWKMAWSZDQRD-UHFFFAOYSA-N silylformonitrile Chemical class [SiH3]C#N LCHWKMAWSZDQRD-UHFFFAOYSA-N 0.000 claims description 6
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- 239000010456 wollastonite Substances 0.000 claims description 5
- 229910052882 wollastonite Inorganic materials 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 4
- 239000004677 Nylon Substances 0.000 claims description 3
- 125000000732 arylene group Chemical group 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 2
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 18
- 229920005989 resin Polymers 0.000 description 14
- 239000011347 resin Substances 0.000 description 14
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 230000003301 hydrolyzing effect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229920002292 Nylon 6 Polymers 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 125000004442 acylamino group Chemical group 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000012262 resinous product Substances 0.000 description 3
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 2
- LVNLBBGBASVLLI-UHFFFAOYSA-N 3-triethoxysilylpropylurea Chemical compound CCO[Si](OCC)(OCC)CCCNC(N)=O LVNLBBGBASVLLI-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 150000003951 lactams Chemical group 0.000 description 2
- 238000010128 melt processing Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000000466 oxiranyl group Chemical group 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- BPILDHPJSYVNAF-UHFFFAOYSA-M sodium;diiodomethanesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(I)I BPILDHPJSYVNAF-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- SKIIKRJAQOSWFT-UHFFFAOYSA-N 2-[3-[1-(2,2-difluoroethyl)piperidin-4-yl]oxy-4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound FC(CN1CCC(CC1)OC1=NN(C=C1C=1C=NC(=NC=1)NC1CC2=CC=CC=C2C1)CC(=O)N1CC2=C(CC1)NN=N2)F SKIIKRJAQOSWFT-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- LLQHSBBZNDXTIV-UHFFFAOYSA-N 6-[5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-4,5-dihydro-1,2-oxazol-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC1CC(=NO1)C1=CC2=C(NC(O2)=O)C=C1 LLQHSBBZNDXTIV-UHFFFAOYSA-N 0.000 description 1
- NHJIDZUQMHKGRE-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-yl 2-(7-oxabicyclo[4.1.0]heptan-4-yl)acetate Chemical compound C1CC2OC2CC1OC(=O)CC1CC2OC2CC1 NHJIDZUQMHKGRE-UHFFFAOYSA-N 0.000 description 1
- ADAHGVUHKDNLEB-UHFFFAOYSA-N Bis(2,3-epoxycyclopentyl)ether Chemical compound C1CC2OC2C1OC1CCC2OC21 ADAHGVUHKDNLEB-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000572 Nylon 6/12 Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000004957 Zytel Substances 0.000 description 1
- 229920006102 Zytel® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GLROGUSVUGSGPO-UHFFFAOYSA-N bis(3-methyl-7-oxabicyclo[4.1.0]heptan-4-yl) hexanedioate Chemical compound C1C2OC2CC(C)C1OC(=O)CCCCC(=O)OC1CC2OC2CC1C GLROGUSVUGSGPO-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- YWJUZWOHLHBWQY-UHFFFAOYSA-N decanedioic acid;hexane-1,6-diamine Chemical compound NCCCCCCN.OC(=O)CCCCCCCCC(O)=O YWJUZWOHLHBWQY-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- ZMUCVNSKULGPQG-UHFFFAOYSA-N dodecanedioic acid;hexane-1,6-diamine Chemical compound NCCCCCCN.OC(=O)CCCCCCCCCCC(O)=O ZMUCVNSKULGPQG-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- PFDVZMRMKCSCBG-UHFFFAOYSA-N n-(3-triethoxysilylpropyl)acetamide Chemical compound CCO[Si](OCC)(OCC)CCCNC(C)=O PFDVZMRMKCSCBG-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000052 poly(p-xylylene) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000012758 reinforcing additive Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- 229920006126 semicrystalline polymer Polymers 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- IYMSIPPWHNIMGE-UHFFFAOYSA-N silylurea Chemical class NC(=O)N[SiH3] IYMSIPPWHNIMGE-UHFFFAOYSA-N 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
- C08K5/5455—Silicon-containing compounds containing nitrogen containing at least one group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Polyethers (AREA)
Description
æ¬çºæã¯ãæ©æ¢°çç¹æ§ãä¿æããããŸãã¯é«ã
ãããã®å ãŠãå€çµæç©åã³çž®åéåäœãããªã
çž®åéåäœè€åç©ã«é¢ãããã®ã§ããã éå±å ãŠããããç±å¯å¡æ§ããªãšã¹ãã«è€åäœ
äžãžã®ãšããã·æš¹èã®é åã¯æ圢ãããæ©æ¢°çç¹
æ§ãæ¹åããããšãå ±åãããŠãããç±³åœç¹èš±ç¬¬
3547872å·ïŒå第3547873å·ïŒå第3886104å·åã³
å第4034013å·åç §ãããªã«ãŒãããŒãåã³ããª
ãšã¹ãã«ã«ãŒãããŒãã«ããããšããã·æš¹èã®ç¹
å®ã®äœ¿çšã¯ãªã©ã³ãåœç¹èš±ç¬¬82028930ââ10å·
åã³å第8202931ââ10å·ã«å ±åãããŠããã
ããããªãããè€åäœãå«ããããã®ãšããã·æš¹
èã®å æ°Žå解å®å®æ§ã¯åæ¥çã«ã¯èš±å®¹ãããªãã ç¹èš±å ¬é第76â30254å·ïŒ1976幎ïŒæ15æ¥ïŒã«
ç¡æ©å ãŠãå€ã«å¯ŸããäºååŠçå€ãšããŠãã¬ã³ã
ãŒã¢ãããããã«ããªãšããã·ã·ã©ã³ã®åŠãã¢ã
ãã·ã©ã³ãšé åãããšããã·æš¹èã®äœ¿çšã瀺ãã
ãŠããããã®åèæç®ã¯ç¡æ©å ãŠãå€ã«å¯ŸããŠ
0.02ãïŒééïŒ ã®ã¢ããã·ã©ã³åã³0.1ã10éé
ïŒ ã®ãšããã·æš¹èã䜿çšããªããã°ãªããªãããš
ã§ç¹æ®ã§ããããã®æç®ã«ãããŠããã®éããå€
ããããŸãã¯å°ãªããçšããå Žåã«ç±å¯å¡æ§ããª
ãšã¹ãã«çµæç©ã«æªåœ±é¿ãåãŒãããšã瀺ãããŠ
ããããã®ããšã¯å æ°Žå解å®å šæ§ã«ä»éããåé¡
ãå æãåŸããããããåŠçã®åæ¥çå®æœã¯äžæ
åã®ãšããã·æš¹èïŒã¢ããã·ã©ã³é åã®ä¹ããå®
å šæ§ã«ããå³ããå¶éããããäºå®ããã®æç®ã«
ãããŠããããç³»ã¯åæ¥çã«å¥œé©ã§ããããäžæ
åç³»ãšããŠäœ¿çšããéã«ç¢ºèªããããšãã§ããª
ãã ãããŠã宀枩ã§å®å šã§ããããããŠå ãŠããã
ãçž®åéåäœè€åç©ã«ãããŠå ãŠããããçž®åé
åäœè€åç©ã®æ©æ¢°çç¹æ§ãæ¹åããäžã€ä¿æãã
æ·»å å€ã«å¯Ÿããå¿ èŠæ§ãååšãããæ®ã«ããã®è€
åäœã¯å æ°Žå解å®å šæ§ã瀺ãã¹ãã§ããã è€åäœã®æ©æ¢°çç¹æ§ãä¿æãããããŸãã¯é«ã
ãå ãŠããããçž®åéåäœè€åç©ã«å¯Ÿããæ°èŠãª
ææ©ã±ã€çŽ ïŒãªãã·ã©ã³æ·»å å€ãå«ãå ãŠãå€çµ
æç©ãæäŸããããšãæ¬çºæã®ç®çã§ããã æŽã«å¢å€§ãããå æ°Žå解å®å šæ§ãæããå ãŠã
ãããçž®åéåäœè€åç©ãæäŸããããšãæ¬çºæ
ã®ç®çã§ããã ææ©ã±ã€çŽ ïŒãªãã·ã©ã³æ·»å å€ã«ããã®å ãŠã
ãããçž®åéåäœè€åç©ã«ããã䜿çšã«éããŠå·¥
çšçã«åé¡ãååšããªãããšãæ¬çºæã®ä»ã®ç®ç
ã§ããã æåŸã«ãææ©ã±ã€çŽ ïŒãªãã·ã©ã³æ·»å å€ãäžæ
åç³»ãšããŠäœ¿çšã§ãããããŠãã®ãŸãŸã§å®€æž©ã§çž
åé¢ãããããŸãã¯ç¡¬ãæš¹èç¶ã®å¡ã«ç¡¬åãã«ã
ãïŒä¿åæéå®å®æ§ïŒããšãæ¬çºæã®ç®çã§ã
ãã æ¬çºæã¯å ãŠããããçž®åéåäœè€åç©ã«ãã
ãå ãŠãå€ãšå ±ã«æçšãªæ°èŠãªææ©ã±ã€çŽ ïŒãªã
ã·ã©ã³æ·»å å€ãæäŸããããã®æ°æãªæ·»å å€ã¯ãª
ãã·ã©ã³æš¹èååç©åã³ã¢ã·ã«ã¢ãããŸãã¯ã·ã¢
ãã·ã©ã³ã®é åç©ã§ããããã®æ°èŠãªæ·»å å€ã¯å®€
æž©ã§å®å®ã§ãããå ãŠãå€ãçž®åéåäœããŸãã¯
å ãŠãå€åã³çž®åéåäœã®é åç©ãšå®å šã«
ïŒintegrallyïŒé åãããããŸãã¯å ãŠãå€äžã«
äºååŠçããŠæ圢ãããæ©æ¢°çç¹æ§ã«ãããæ¹å
åã³åªããå æ°Žå解å®å šæ§ã瀺ãå ãŠããããçž®
åéåäœè€åç©ãçæãããããšãã§ããã æ¬çºæã«ããã°ãå ãŠãå€ã«å¯Ÿããæ°èŠãªææ©
ã±ã€çŽ ïŒãªãã·ã©ã³æ·»å å€ãæäŸãããããã®æ·»
å å€ã¯(1)ãªãã·ã©ã³æš¹èæååã³(2)ã¢ã·ã«ã¢ãã
ãŸãã¯ã·ã¢ãã·ã©ã³ãããªãã ãã®ãªãã·ã©ã³æš¹èæåã¯å°ãªããšãïŒã€ã®ãª
ãã·ã©ã³ç° ïŒãªãã·ã©ã³ç°ïŒ ãå«ã¿ããããŠäžè¬ã«ã¯åŒ åŒäžãR1ãR2ãR3åã³R4ã¯ç¬ç«ããŠã¢ã«ã
ã«ãã¢ãªãŒã«ãã¢ã«ã±ãã«ããšããã·ãææ©ã·ãª
ã«åã³æ°ŽçŽ ã®çŸ€ããéžã°ããåºã§ããã ã§è¡šããããããããç©è³ªã«ã¯ãšããã·æš¹èãã¢
ããšããã·å ±éåäœããšããã·ãåããã倩ç¶æ²¹
ãªã©ãå«ãŸããã 奜ãŸããã¯ãšããã·æš¹èãçšãããäžè¬ã«ããš
ããã·æš¹èã¯ïŒåååœãå¹³åããŠïŒã€ããå€ããª
ãã·ã©ã³ç°ãå«ãååç©ãã調補ããããã®ã®æš¹
èã§ããããšããã·æš¹èã¯ãšãŒãããã«ãããŠã¯
ãšããã·ãæš¹èãšããŠå ¬ç¥ã§ããããã®ååŠçæ§
質ã«äŸåããŠããããã®ãã®ã¯ãšããã·ãåãã
ãããªãªã¬ãã€ã³ãéé ¢é žãšããã·æš¹èããšãã
ã·ãªã¬ãã€ã³éåäœããšãã¯ãããããªã³æš¹èã
ãã¹ããšããŒã«ïŒ¡æš¹èããšãã¯ãããããªã³âã
ã¹ããšããŒã«ïŒ¡çž®åäœããšãâãã¹æš¹èåã³ïŒïŒ
ïŒâãã¹ïŒãã©âããããã·ããšãã«ïŒãããã³
ãžã°ãªã·ãžã«ãšãŒãã«éåäœãšããŠãè¡šããããš
ãã§ããã 代衚çã«ã¯ããªãã·ã©ã³æš¹èæåã¯ãªã¬ãã€ã³
ã®ãšããã·ãåãéããŠèª¿è£œãããããã®ãšãã
ã·æš¹èã¯äžè¬ã«ãšãã¯ãããããªã³ã掻æ§æ°ŽçŽ ä¿
æååç©ãšåå¿ãããããšã«ãã調補ããããã
ããã®ãªãã·ã©ã³æš¹èæåãçšããããšãã§ã
ãã é©åœãªãªãã·ã©ã³çµæç©ã¯ããŒã¿ãŒïŒïŒïŒïŒâ
ãšããã·ã·ã¯ãããã·ã«ïŒâãšãã«ããªã¡ããã·
ã·ã©ã³ãã¬ã³ãâã°ãªã·ããã·ãããã«ããªã¡ã
ãã·ã·ã©ã³ããšããã·ãåãããããªãã¿ãžãš
ã³ãããã«ã·ã¯ããããµã³ãžãªãã·ããïŒïŒïŒâ
ãšããã·ã·ã¯ãããã·ã«ã¡ãã«ïŒïŒïŒâãšããã·
ã·ã¯ããããµã³ã«ã«ããã·ã¬ãŒãããã¹ïŒïŒïŒïŒ
âãšããã·ã·ã¯ããã³ãã«ïŒãšãŒãã«ãïŒâïŒïŒïŒ
ïŒâãšããã·ã·ã¯ããããµã³ïŒâïŒïŒïŒâãšãã
ã·âïŒïŒïŒâãžãªããµã¹ãããïŒïŒïŒãâãŠã³ã
ã«ã³ïŒãã¹ïŒïŒïŒïŒâãšããã·âïŒâã¡ãã«ã·ã¯
ãããã·ã«ïŒã¢ãžããŒãïŒ åã³ ãããããããã«éå®ããããã®ã§ã¯ãªãã ã·ã©ã³æåã«ã¯å°ãªããšãïŒã€ã®ã¢ã·ã«ã¢ãã
ãŸãã¯ã·ã¢ãã·ã©ã³çµå ïŒã¢ããã·ã©ã³çµåïŒ ïŒ®â¡CRSiâ¡ ïŒã·ã¢ãã·ã©ã³çµåïŒ åŒäžãã¯ã¢ã«ãã¬ã³ãŸãã¯ã¢ãªãŒã¬ã³åºã§ã
ãã ãå«ãŸããã é©åœãªã¢ã·ã«ã¢ããã·ã©ã³ã«ã¯ã¬ã³ããŒãŠã¬ã€
ããããã«ããªãšããã·ã·ã©ã³ãã¬ã³ããŒã¢ã»ã
ã«ã¢ãããããã«ããªãšããã·ã·ã©ã³ããã«ã¿ãŒ
ãã³ãŸã€ã«ã¢ããããã«ã¡ãã«ãžãšããã·ã·ã©ã³
ãªã©ãå«ãŸããããããã«éå®ãããªããããã
ã·ã©ã³ã«é¢ããæŽã«è©³çŽ°åã³ãã®èª¿è£œæ³ã«ã€ããŠ
ã¯ç±³åœç¹èš±ç¬¬2928858å·ïŒå第2929829å·ïŒå第
3671562å·ïŒå第3754971å·ïŒå第4046794å·ïŒå
ã³å第4209455å·ãåç §ããããã奜ãŸããã¯ã
ãŠã¬ã€ãã·ã©ã³ãæ®ã«ã¬ã³ããŒãŠã¬ã€ããããã«
ããªãšããã·ã·ã©ã³ã奜é©ã§ããã é©åœãªã·ã¢ãã·ã©ã³ã«ã¯ã·ã¢ããšãã«ããªã¢ã«
ã³ãã·ã·ã©ã³ãã·ã¢ããããã«ããªãŒã¢ã«ã³ãã·
ã·ã©ã³ãã·ã¢ãã€ãœããã«ããªã¢ã«ã³ãã·ã·ã©
ã³ãïŒâã·ã¢ãããã«ããªã¢ã«ã³ãã·ã·ã©ã³ãïŒ
âã·ã¢ãã€ãœããã«ããªã¢ã«ã³ãã·ã·ã©ã³ãã·ã¢
ãããšãã«ããªã¢ã«ã³ãã·ã·ã©ã³ãªã©ãå«ãŸãã
ããããã«éå®ããããã®ã§ã¯ãªãããŸãããã
ã·ã¢ãã·ã©ã³åã³ä»ã®ã·ã¢ãã¢ã«ãã¬ã³ãŸãã¯ã¢
ãªãŒã¬ã³ã·ã©ã³ã®éšåçå æ°Žå解çæç©ãæ¬çºæ
ã«äœ¿çšããéã«é©ããŠããããšãèãããããã·
ã¢ãã·ã©ã³ã®æŽã«å®å šãªèšè¿°ã«ã¯Walter Noll.
Academic Press.1968ã«ããChemistry and
Technology of Silicones 180ã189é ã«èŠåºã
ããšãã§ããã æ°èŠãªææ©ã±ã€çŽ ïŒãªãã·ã©ã³çµæç©ã¯äžè¬ã«
å ãŠãå€ã®ééãåºæºãšããŠ0.02ã20ééïŒ ã奜
ãŸããã¯0.5ãïŒééïŒ ã®ç¯å²ã®éã§çšãããã
ããã®äžè¬çç¯å²ã¯å ãŠãå€ã®å ããéã«äŸå
ããå³ã¡æ¥µããŠé«ãå ãŠãå€ã®éã§ã¯äœãæ·»å å€
ã®ç¯å²ã§ææã®çµæã瀺ãããããŠæ¥µããŠäœãå
ãŠãã®éã§ã¯ææã®çµæãéæãããã«ã¯é«ãæ·»
å å€ã®ç¯å²ãå¿ èŠã§ããåŸããäžè¬ã«ããªãã·ã©
ã³æåã¯ïŒã95ééïŒ ã奜ãŸããã¯25ã75ééïŒ
ã®æ·»å å€ãè¡šããããããŠã·ã©ã³æåã¯95ãïŒé
éïŒ ã奜ãŸããã¯75ã25ééïŒ ã®æ·»å å€ãè¡šã
ãã çž®åéåäœè€åç©ã«çšããå ãŠãå€ã¯æ¬åéã«
粟éããè ã«ã¯å ¬ç¥ã§ããããããŠããããã®é©
åœãªçŽ°ããåå²ããããããŸãç²ç¶ã®ç©è³ªãå«
ããçž®åéåäœè€åç©äžã«é åããæç¹ã§ãæ®ã
ã©ã®å ãŠãå€ã¯çŽ°ããåå²ãããç²åã®ç¶æ ã§ã
ãããšãã§ããããã®ãã®ã¯ããããã®ç«äœé
眮ãäŸãã°æ倧çŽåŸãå³ã¡10ÎŒïœã奜ãŸããã¯5ÎŒ
ïœã®æ倧çŽç·çŽåŸãæããã»ãŒçæ¹æ§ã®ãã®ã§ã
ããïŒãŸãã¯10ÎŒïœãŸãã¯ãã以äžã奜ãŸããã¯
5ÎŒïœãŸãã¯ãã以äžã®åããŸãã¯çŽåŸãæãã
ãã¬ãŒããŸãã¯éç¶ïŒç¹ç¶ïŒã®ãã®ã§ããããšã
ã§ãããå ãŠãå€ç²åã®æå°ã®å€§ããã¯èšççã§
ãªããããã«é¢ããŠã¯é垞䜿çšãããå ãŠãå€ã®
ãããã®ãã®ãé©ããŠãããæ¬çºæã«äœ¿çšãåŸã
ç¹å®ã®å ãŠãå€ã®äžã«ã¯ç³ç¶¿ãããšããã³ã°ãã
ãïŒchoppedïŒã¬ã©ã¹ãã«ãªãªã³åã³ä»ã®ç²åé±
ç©ãã·ãªã«ãã«ã«ã·ãŠã ã·ãªã«ãçé žã«ã«ã·ãŠã
ïŒå¢çœå€ïŒãé žåãã°ãã·ãŠã ãçé žããªãŠã ãç¡«
é žããªãŠã ïŒãã©ã€ãïŒãéå±ç¹ç¶åã³ç²æ«ãã¬
ã©ã¹ç¹ç¶ãèç«ç¹ç¶ãé匷åãŸãã¯åŒ·åã«ãŒãã³
ãã©ãã¯ãé žåã¢ã³ãã¢ã³ãé žåãã¿ã³ãé²æ¯ã
ã¿ã«ã¯ãããšããã³ã°ãããã¬ã©ã¹ãã¢ã«ããã
ç³è±ãã±ã€ç°ç³ïŒã±ã€é žã«ã«ã·ãŠã ïŒã䞊ã³ã«ç¡
æ©çè²é¡æããããææ©å ãŠãå€ã«ã¯ç¶¿ãªã³ã¿ãŒ
åã³ä»ã®ã»ã«ããŒã¹æ§ç©è³ªãæšãããåæç¹ç¶ãª
ã©ãå«ãŸãåŸãã奜é©ãªå ãŠãå€ã°ç²åãé²æ¯ã
ã±ã€ç°ç³åã³ããšããã³ã°ãããã¬ã©ã¹ã§ããã æ·»å å€ãå®å šã«é åããããšã¯äºååŠçããã
å ãŠãå€ã«ã¯å®è³ªçãªçµæžçå©ç¹ããããæéå
ã³ãšãã«ã®ãŒã®ç¯çŽãå«ã¿ããããŠäŸ¿å©ã«äžã€ç°¡
åãªããšã§ãããå ãŠãå€ã®æ·»å å€ãšã®äºååŠç
ã¯åéãé²ãããã®é«ãå転æ°ã§å転ãã匷åãª
æ··åãã¬ãŒããåããHenschelãŸãã¯åã·ãšã«
ïŒtwinâshellïŒåé ååšã®ãããªåŒ·åãªæ··ååšã
å¿ èŠãšããå¥ã®æäœã§ãããæ·»å å€ã¯åéãé²ã
ããã«å®åžžçãªæµéã§åŸã ã«å ããªããã°ãªããª
ããäºååŠçé段äžã«ãå±åšåããé«æž©ãçšãã
è£ çœ®ã®é«éæ··åãã¬ãŒããŸãã¯ãã®è¿åã§çã
ãã ãã®å®å šãªé åæè¡ãå©çšããéã«ãæ·»å å€ã¯
å ãŠãå€ãåæ£ãããããšãã§ããªããã°ãªã
ãããããŠãŸãæ·»å å€ã¯å ãŠãå€äžã«åäžã«åé
ãããããšãã§ããªããã°ãªããªãããã®ããšã
åéãé²æ¢ãããæ¬çºæã«ããå®å šãªé åã«ãã
ãŠãæ·»å å€ã¯è¿ éã«ïŒïŒåã§ïŒå ãŠãå€ãŸãã¯å
ãŠãå€ïŒæš¹èæ··åç©ã«å ããç¶ããŠæž©åã«æ¹æã
ãããšãã§ããã匷åæ·»å å€ã®å©ç¹ãä¿æãã€ã€
äœæ¿åºŠã§æ·»å å€ãçšããããšãæ¬çºæã®å®è³ªçäž
ã€äºæãã¬å©ç¹ã§ãããæŽã«ãæ·»å å€ãå ãŠã
å€ïŒæš¹èæ··åç©ãå«ãåŠçè£ çœ®ïŒäŸãã°Farrelé£
ç¶æ··åæ©åã³æŒåºæ©ïŒäžã«çŽæ¥ã«ãäžã€æº¶è§£è€å
äœã®æµåºåã«æ¬çºæã«ããå®å šã«é åããããšã
ã§ããããããã®çç±ã«ããå®å šé åãæ¬çºæã®
奜é©ãªå ·äœäŸã§ãããããããªãããäºååŠçã¯
æ¬çºæã«é©åããäžã€ããå Žåã«ã¯ç¹å®ã®ç¶æ³ã
å³ã¡çšããçž®åéåäœãå ãŠãå€ãæ·»å å€ãªã©ã«
äŸåããŠå¥œé©ãªæ·»å ã®æ¹æ³ãè¡šããã å ãŠããããçž®åéåäœè€åç©ã«çšããçž®åé
åäœã¯å ãŠãå€ãéåžžé åãããããããã®çž®å
éåäœãŸãã¯éçž®åäœã§ããåŸããéåžžã®ã¿ã€ã
ã®çž®åéåäœã¯ããªãšã¹ãã«ïŒãžã«ã«ãã³é žãŸã
ã¯ãžã«ã«ãã³é žåã³ãžã°ãªã³ãŒã«ã®ãšã¹ãã«ã
ãïŒãåã³ããªã¢ããïŒãžã«ã«ãã³é žåã³ãžã¢ã
ã³ãããããŸãã¯ã©ã¯ãã³ããïŒã§ããããŸãã
ããã®ç©è³ªå士ãããŸãã¯ä»ã®éåäœãå³ã¡ããª
ããã«ã¢ã»ããŒããŸãã¯ã¹ãã¬ã³âç¡æ°Žãã¬ã€ã³
é žå ±éåäœãšã®é åäœãèããããã æŽã«éåžžã®ã¿ã€ãã®ããããªã¢ããçž®åéåäœ
ã®äŸã«ã¯ãã®ãã®ãçæãããéã«çšãã次ã®å
å¿ç³»ã«ãããã®ãå«ãŸããããããã«éå®ããã
ãã®ã§ã¯ãªãã ïŒ ãžã¢ãã³ã®ãžã«ã«ãã³é žãšã®åå¿ã ïŒ Ïâã¢ããé žã®èªå·±çž®åã ïŒ ã©ã¯ã¿ã ç°ã®éç°ã ïŒ ãžã¢ãã³ãšäºé žå¡©åç©ãšã®åå¿ã ããªã¢ããéåäœã¯æ¬åéã§ååå ¬ç¥ã§ããã
ãããŠãã€ãã³ãšããŠç§°ãããåçµæ¶ç¶åã³éæ¶
æ§éåäœã®ãã®ãå«ãŸãããå€æ°ã®ããªã¢ããã
ç±³åœç¹èš±ç¬¬2071250å·ïŒå第2071251å·ïŒå第
2130523å·ïŒå第2130948å·ïŒå第2241322å·ïŒå
第2312966å·ïŒå第2512606å·ïŒåã³å第3393210
å·ã«èšèŒãããŠããã ããªã¢ããã®äŸã«ã¯æ¬¡ã®ãã®ãå«ãŸããããã
ãã«éå®ããããã®ã§ã¯ãªãïŒããªïŒãããµã¡ã
ã¬ã³ã¢ãžãã¢ããïŒïŒãã€ãã³ïŒïŒïŒïŒãããªïŒã
ããµã¡ãã¬ã³ã¢ãŒã©ã¢ããïŒïŒãã€ãã³ïŒïŒïŒïŒã
ããªïŒãããµã¡ãã¬ã³ã»ãã·ã¢ããïŒïŒãã€ãã³
ïŒïŒ10ïŒãããªïŒãããµã¡ãã¬ã³ããã«ãã¢ããïŒ
ïŒãã€ãã³ïŒïŒ12ïŒãã©ã¯ã¿ã ã®éç°ã«ããçæã
ããããªã¢ãããäŸãã°ããªã«ããã©ã¯ã¿ã ïŒã
ã€ãã³ïŒïŒãããªã©ãŠãªã«ã©ã¯ã¿ã ïŒãã€ãã³â
12ïŒåã³ããªïŒ11âã¢ãããŠã³ãã«ãã³é žïŒïŒã
ã€ãã³â11ïŒãä»ã®é©åœãªçž®åéåäœã«ã¯ããª
ïŒãªãã·ã¢ã«ã«ãã€ã«ïŒãããªïŒã¢ã«ãã¬ã³ãªããµ
ã¬ãŒãïŒãããªïŒã¢ã«ãã¬ã³ã¢ãžããŒãïŒãããª
ïŒã¢ã«ãã¬ã³ã»ãã»ãŒãïŒãããªïŒããªã¡ãã¬ã³ã¢
ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒãããªïŒãããµã¡ã
ã¬ã³ã¢ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒãããªïŒãã«
ã¡ãã¬ã³ã¢ã«ã«ã³âãžã«ã«ããã·ã¬ãŒãïŒãããª
ïŒãã©ã³ã¹âïŒïŒïŒâã·ã¯ãããã·ã¬ã³ã¢ã«ã«ã³
ãžã«ã«ããã·ã¬ãŒãïŒãããªïŒïŒïŒïŒâã·ã¯ãã
ããµã³ãžã¡ãã¬ã³ã¢ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒã
ããªïŒã¢ã«ãã¬ã³ãã¬ãã¿ã¬ãŒãïŒãããªïŒã¢ã«
ãã¬ã³ã€ãœãã¿ã¬ãŒãïŒãããªïŒïœâããšãã¬ã³
ã¢ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒãããªïŒã¢ã«ãã¬
ã³ïœâããšãã¬ã³ãžã¢ã»ããŒãïŒãããªïŒïœâã
ã·ãªã¬ã³ã¢ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒãããª
ïŒïœâãã·ãªã¬ã³ã¢ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒã
ããªïŒïœâããšãã¬ã³ãžã¢ã«ãã¬ã³ãã¬ãã¿ã¬ãŒ
ãïŒãããªïŒã¢ã«ãã¬ã³ïŒïŒïŒâãšãã¬ã³ãžãªã
ã·âïŒïŒ4â²âãžãã³ãŸãšãŒãïŒãããªïŒã¢ã«ãã¬
ã³ïŒïŒ4â²âãžãã³ãŸãšãŒãïŒãããªïŒã¢ã«ãã¬ã³
ïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ããã·ã¬ãŒãïŒåã³ã
ãªïŒã¢ã«ãã¬ã³ã¹ã«ããã«âïŒïŒ4â²âãžãã³ãŸãš
ãŒãïŒãå«ãŸãããæ®ã«ããªãšã¹ãã«ã奜ãŸã
ãããããŠãã®äžã§ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒã
ïŒPETïŒåã³ããªããã¬ã³ãã¬ãã¿ã¬ãŒã
ïŒPBTïŒã奜é©ãªããªãšã¹ãã«ã§ããã çž®åéåäœãšé åããææ©ã±ã€çŽ ïŒãªãã·ã©ã³
æ·»å å€ã§åŠçãããå ãŠãå€ã®éã¯ç¹å®ã®ç®ççš
éã«äŸåããŠåºç¯å²ã«å€ããããšãã§ãããæ©æ¢°
çç¹æ§ã«å¯ŸããŠå®è³ªçãªå¹æãåŸãããã«ã¯æ·»å
å€âå ãŠãå€æ··åç©ã¯éåžžå ãŠããããçž®åéå
äœè€åç©ã®å°ãªããšãïŒééïŒ ã§ãããå ãŠãã
ããçž®åéåäœè€åç©ã®85ééïŒ ãè¶ éããæ·»å
å€âå ãŠãå€æ··åç©ã¯æ®ãã©æãŸãããªãããã
ãã®ç¯å²å ã§ã¯ãåã ã®æåã®å¥œé©ãªéã¯äžè¬ç
ã«ã¯å ãŠãå€ã®éžæåã³æ®ã«ã¯ç¹æ§ã®ç®ççšéã«
倧ããäŸåããã§ããããæŽã«ãããã®çç±ã«ã
ããçžäºã®æåã®æ¯ã®éçã¯æ¬çºæã®ç²Ÿç¥ããé¢
ããã«æäŸããããšã¯ã§ããªãã åã«è©³è¿°ããæåã«å ããŠããããè€åäœã«é
åžžçšããä»ã®æåãé åããããšãã§ããããã
ãã®ãã®ã«ã¯é©åœãªãã°å¯å¡å€ãå ç¡«å€ãçé¢
å€ãæ¶æ©å€ãçµæ¶åé床調ç¯æ·»å å€ïŒå éå€åã³
é 延å€ïŒãææãé¡æãªã©ãå«ãŸããã æ¬çºæã®æ£ç¢ºãªç¯å²ã¯ä»å±ã®ç¹èš±è«æ±ã®ç¯å²ã«
è¿°ã¹ããã次ã®ç¹å®ã®å®æœäŸã¯æ¬çºæã®ããç¹åŸŽ
ã説æãããããŠæŽã«è©³çŽ°ã«ã¯ãã®ãã®ã®è©äŸ¡æ¹
æ³ãææãããããããªãããæ¬å®æœäŸã¯èª¬æã®
ããã®ã¿ã«ç€ºããããããŠä»å±ããç¹èš±è«æ±ã®ç¯
å²ã«è¿°ã¹ããã以å€ã¯æ¬çºæãéå®ãããã®ã§ã¯
ãªããç¹èšãã¬éããã¹ãŠã®éšåã³ïŒ ã¯ééã«ã
ããã®ã§ããã çš èª æ¬æ现æžã®å®æœäŸåã³ä»ã®å Žæã§äœ¿çšããã次
ã®å称ã¯æ¬¡ã®æå³ãæããïŒ PBTïŒGafiteTM1400AïŒâ GAF Corp.ããè³Œå ¥ããžã¡ãã«ãã¬ãã¿ã¬ãŒ
ãåã³ïŒïŒïŒâãã¿ã³ãžãªãŒã«ã®åå¿çæç©ãå ¬
称0.8åºæç²åºŠïŒ25âãªã«ãã¯ã«ã«ããšããŒã«
äžïŒã PETïŒCleartufTM7207ïŒâ Goodyear Corp.ããè³Œå ¥ããã¬ãã¿ã«é žãŸã
ã¯ãžã¡ãã«ãã¬ãã¿ã¬ãŒãã®ãšãã¬ã³ã°ãªã³ãŒã«
ã®åå¿çæç©ãå ¬ç§°0.72åºæç²åºŠïŒ30âããªãã«
ãªãé ¢é žäžïŒã ãã€ãã³ïŒZytelTM101ïŒâ Du Pont補ã®ãã€ãã³66ã WhitexTMClayâ FreeportâKaolinãçŒãããç²åã å ¬ç§°å¹³åç²åŸ3ÎŒã ã±ã€ç°ç³ïŒNYADTMïŒâ ã±ã€é žã«ã«ã·ãŠã å ãŠãå€ïŒ15ïŒïŒçžŠæšªæ¯å ¬
称ïŒãNyco Corp.ããè³Œå ¥ã Epon 828â Shell Chemical Co.補ã®ãšããã·æš¹èããã¹
ããšããŒã«ïŒ¡åã³ãšãã¯ãããããªã³ã®åå¿çæ
ç©ãå ¬ç§°åœééé190ã UPTESâ 50ïŒ ã¡ã¿ããŒã«æº¶æ¶²ãšããŠã®ã¬ã³ããŒãŠã¬ã€ã
ãããã«ããªãšããã·ã·ã©ã³ GAPTESâ ã¬ã³ãâã¢ãããããã«ããªãšããã·ã·ã©ã³ DCSâ ç¡æ°Žããªã¡ãªãé žåã³ ïŒCH3OïŒ3SiïŒCH2ïŒ3NHïŒCH2ïŒ3SiïŒOCH3ïŒ3ã®å
å¿ã«ãã調補ããã ã·ã¢ããšãã«ããªã¡ããã·ã©ã³ CNEâ ã·ã¢ããšãã«ããªãšããã·ã·ã©ã³ æŒåºæ©æº¶èåŠçâ ç±å¯å¡æ§çž®åéåäœã®æº¶èç©ãããšããã³ã°ã
ããã¬ã©ã¹ãé±ç©å ãŠãå€ãŸãã¯åã ã®é åç©ã
æŒåºäžãããŸãæŒåºåã®é åããããããŸãã¯æ··
åãããããã«ããããã«å ç±ããæŒåºæ©ã䜿
çšã å®æœäŸïŒãïŒã®è€åç©ã¯Wernerâ Pleiderer ZSKâ30 åã¹ã¯ãªãŠãŒæŒåºæ©äžã§
åŠçããïŒ24ïŒïŒ ïŒïŒ€æ¯ïŒã å®æœäŸïŒã®è€åäœã¯Hartig2ã€ã³ãçŽåŸåã¹ã¯
ãªãŠãŒæŒåºæ©äžã§æº¶è§£åŠçããïŒ24ïŒïŒ ïŒïŒ€
æ¯ïŒã å°åºæ圢â ASTMè©Šéšçã¯Arburg2ãªã³ã¹ã22ãã³ãŠã
ããäžã§æ圢ããã æ圢ããããŸãŸâ Arburgè£ çœ®äžã§æ圢ããASTMè©Šéšçã¯è©Šéš
åã«å®€æž©ã§å°ãªããšã48æé平衡ãããã 72æé氎沞隰詊éšâ ASTMè©Šéšçã沞隰氎ã«72æé浞挬ãã220ã
ã§ïŒæé也ç¥ããè©Šéšåã«å®€æž©ã§å°ãªããšã24æ
é平衡ãããã åŒåŒµåŒ·ãâ ASTM â638ïŒ0.2ã€ã³ãïŒåè©Šéšé床ïŒã æ¹è¯ãããããã³ã°ãããªã ã¢ã€ãŸããè¡æå€â ãããã³ã°ãããªã2.5Ã0.5Ã0.125ã€ã³ãã®è©Š
éšçãè©Šéšçã®1/2ã®é·ããè¡æãåããããã«
é²åºããããã«ã¢ã€ãŸããè¡æè©Šéšæ©äžã«çœ®ãã
è¡æã¯ãã€ãŒãã»ãã³ãïŒã€ã³ãã§èšç®ãããã
ããã¯æ¹è¯ãããASTM â256è©Šéšã§ããã ãããã³ã°ãããã¢ã€ãŸããè¡æå€â ASTM â256ã PSiâŠâŠãã³ãïŒå¹³æ¹ã€ã³ã ïŒ âŠâŠç¹èšãã¬éãééïŒ ïœâŠâŠã°ã©ã wtâŠâŠé é éšâŠâŠç¹èšãã¬éãéééš ptsâŠâŠç¹èšãã¬éãéééš phwâŠâŠéééš ppmâŠâŠ100äžéééšåœãã®éééš ftâ1bsïŒinâŠâŠãã€ãŒãã»ãã³ãïŒã€ã³ã inâ1beïŒinâŠâŠã€ã³ãã»ãã³ãïŒã€ã³ã phrâŠâŠæš¹èïŒéåäœïŒ100éééšåœãã®éš HDTïŒ 264 psi ASTM â648 äºååŠçâ ç±ãã©ã¹ããã¯ã«å ããåã«æ·»å ç©ãïŒéšã®ã¡
ã¿ããŒã«ïŒæ°ŽïŒïŒïŒïŒå®¹éæ¯ïŒã«åžéããããšã«
ãã现ããåå²ãããå ãŠãå€ãåŠçãããããŸ
ãã¯è¢«èŠããããã«æ·»å ç©ãé©çšãããããŠ
PattersonâKellyåã·ãšã«é ååšãçšããŠå ãŠ
ãå€ã«é©çšããæ¹æ³ã105âã§ïŒæéã®ä¹Ÿç¥ãµã€
ã¯ã«ã å®å šæ·»å â 溶èåŠçåã«æ··åç©ãæ¹æããªãã液äœãŸãã¯
åºäœæ·»å å€ãå ãŠãå€ïŒæš¹èã®æ··åç©ãžåã«é
åã代衚çã«ã¯Hobartæ··ååšãHenschelæ··å
åšããªãã³é ååšãŸãã¯ãã©ã ã¿ã³ãã©ãŒãçšã
ãã åèäŸ ïŒ å®€æž©ã§ã®å®å®æ§ãæ±ããããã«äžé£ã®å®éšãé
å§ãããããŠå ãŠããããçž®åéåäœè€åç©ã«å¯Ÿ
ããæå¹ãªäžæåæ·»å å€ã補é ããããšãã§ã
ããã¬ã³ããŒã¢ãããããã«ããªãšããã·ã·ã©ã³
ãšé åãããšããã·æš¹èïŒEpon 828ïŒãããã
ãUPTESãCNMåã³DCSãšã®Epon 828ã®å¥ã
ã®æ··åç©ãšæ¯èŒããå Žåã«æ¯èŒçäžå®å®ã§ããã
ãšãåã€ããå®éšã¯ãããªç¿äžã§ãªãã·ã©ã³ãã·
ã©ã³ãšæ··åãã次ã«ã«ããŒããããããšãããªã€
ãŠãããäžå®æéã«ãããèçŒã§ã®èŠ³å¯ãèšé²ã
ãã硬ãæš¹èç¶ã®å¡ãçµç¹ã®åŸŽåã§ãã€ããäŸã
ã°ãEpon 828 åã³ã¬ã³ããŒã¢ãããããã«ã
ãªãšããã·ã·ã©ã³ãïŒïŒïŒã®ééæ¯ã§äžç·ã«ãã
å Žåã宀枩ïŒæéã§åãŒã©ãã³ç¶çæç©ãã24æ
éã§æè»ãªåºäœã®å¡ãããããŠ48æéã§åºäœæš¹è
ç¶çæç©ãçŸãããã第ïŒè¡šã¯èçŒã®èŠ³å¯ã«ãã
çµç¹ã®åºäœæš¹èç¶çæç©ã®çµæã瀺ããããã«ã
ãEpon 828ãšäžç·ã«ããå Žåã«UPTESãCNM
åã³æäœéã®DCSã®åã ã¯192æéã«åºäœæš¹èç¶
çæç©ãçæãããªãããšãç¥ãããšãã§ããã
ãããã®ç³»ã¯Epon 828ïŒã¬ã³ããŒã¢ããããã
ã«ããªãšããã·ã·ã©ã³ããå®å®ã§ããããšãçµè«
ãããã å®æœäŸïŒâïŒãæ¯èŒäŸïŒ 第ïŒè¡šã¯40ïŒ whitexTMç²åãå ãŠããã
PBTïŒPETïŒïŒïŒïŒæ¯ïŒã®è€åäœã®æ©æ¢°çç¹æ§ã
瀺ããEpon 828ïŒUPTESã®é åãç¹ã«äžå®ã®
Epon 828éã§ã®äœæ¿åºŠã®UPTESã¯æ§èœã«ãããŠ
Epon 828ïŒã¬ã³ããŒã¢ãããããã«ããªãšãã
ã·ã·ã©ã³ã«å¹æµããããšãç¥ãããšãã§ãããäž¡
æ¹ã®è€åäœã¯æ°Žæ²žéš°è©Šéšã®ååã³åŸã§å¯Ÿç §è€åäœ
ããåªããŠããã å®æœäŸ ïŒâïŒ ç¬¬ïŒè¡šã¯40ïŒ ç²åãå ãŠãããPBTïŒPET
ïŒïŒïŒïŒæ¯ïŒã«ãããïŒã€ã®æ¿åºŠã§ã®Epon 828ïŒ
CNMã®æ§èœã瀺ãããããã®è€åäœã®æ©æ¢°çç¹
æ§ã¯72æéã®æ°Žæ²žéš°è©Šéšã®ååã³åŸã§å¯Ÿç §è€åäœ
ããåªããŠããã å®æœäŸ ïŒâïŒ ç¬¬ïŒè¡šã¯40ïŒ ç²åå ãŠããããPBTïŒPET
ïŒïŒïŒïŒæ¯ïŒã«ãããïŒã€ã®å¥ã ã®æ¿åºŠã§ã®Epon
828ïŒDCSã®æ§èœã瀺ããEpon 828ã®äžå®éãšé
åããäœæ¿åºŠã®DCSã¯ç¬¬ïŒè¡šã«èšèŒã®Epon
828ïŒDCSæ¯ã®å®€æž©å®å®æ§ãèæ ®ããå Žåã«å¥œãŸ
ãããDCSãå«ãè€åäœã¯ã¬ã³ããŒã¢ãããã
ãã«ããªãšããã·ã·ã©ã³ãå«ãè€åäœã®æ§èœã«å°
éãïŒãã®ãã®ã¯å¯Ÿç §è€åäœããåªããŠããã å®æœäŸ ïŒâïŒ ããšããã³ã°ãããã¬ã©ã¹ïŒç²åå ãŠãããã
PETè€åäœã第ïŒè¡šã«ç€ºãã15ïŒ ããšããã³ã°
ãããã¬ã©ã¹ïŒ15ïŒ ç²åå ãŠããããPETè€å
äœã«ãããŠUPTESåã³CNEãšå¥ã ã«äžç·ã«ãã
Epon 828ã¯æ圢ãããŸãŸã®ç¹æ§ãããŒã¹ã®ãã
å¯Ÿç §è€åäœããããªãè¯å¥œã®æ§èœã瀺ãã å®æœäŸ 10â11 ïŒïŒïŒééæ¯ã®Pponâ828ïŒUPTESãæ··åãã
ãããŠ75âã«å ç±ãããã®éã«ã¡ã¿ããŒã«ãé€å»
ããããã«ç空ãçšããã宀枩ã§å®å®ãªéæã§ç¥
çè²ã®åäžãªçæç©ãçãããã¡ã¿ããŒã«ãé€å»
ããEponâ828ïŒUPTESã1/8ã«ããšããã³ã°ã
ããã¬ã©ã¹åã³PBTïŒPETïŒïŒïŒïŒæ¯ïŒã®æ··åç©
äžã«å®å šã«é åãããå¯Ÿç §è€åäœã¯EPONâ
828ïŒUPTESãå«ãŸã¬PBTïŒPETïŒïŒïŒïŒæ¯ïŒ
ãšæ··åããïŒïŒïŒã€ã³ãã®ããšããã³ã°ãããã¬
ã©ã¹ãããªã€ãŠãããåã ã®è€åäœã«ãããŠ30ïŒ
äžå®ã®ããšããã³ã°ãããã¬ã©ã¹éãçšãïŒ1.5
ïŒ åã³3.0ïŒ ïŒã¬ã©ã¹ãåºæºïŒã®ã¹ããªããã³ã°
ïŒstrippedïŒEPONâ828ïŒUPTESæ¿åºŠã®ãã®ã
è©Šéšããã 第ïŒè¡šã¯è©Šéšçã®æº¶èæŒåºåã³å°åºæ圢åŸã®è€
åäœç¹æ§ã瀺ããEPONâ828ïŒUPTESãå«ã
è€åäœã¯24æéã®æ°Žæ²žéš°è©ŠéšåŸã«å¯Ÿç §è€åäœãã
åªããŠããããããŠãå¯Ÿç §è€åäœãšæ¯èŒããå Ž
åãé·æå ç±èåïŒ180âã§300æéïŒåŸã®è¡æå€
ã®ä¿æã«åªããŠããã å®æœäŸ 12 æšæºçæ··åãã¬ãŒããåããHobartã¹ãã³ã¬
ã¹ã»ã¹ããŒã«è£œæ··ååšãçšããŠãEpon 828 500
ïœåã³UPTESïŒã¡ã¿ããŒã«äž50ïŒ åºäœïŒ500ïœã
æ··åããŠã«ã«å ããç¶ããŠäœéã§æ¹æãããå¥ã®
å®éšããããã®æ··åç©ã¯ äžåäžæ§ã§ããïŒUPTESåºäœãæéãšå ±ã«æ²
殿ãããããããªãããæ²æ®¿ãçããåã«ãã®æ··
åç©ãç³è±ã¬ã©ã¹è£œç¶ã«ç§»ããããããã³ã«ã¯æ
ããããã®ç¶ã®å 容ç©ã50âã«èšå®ãã氎济äžã«
眮ããããã®æ··åç©ã50âã«ïŒæéæãããç¶ã
ãŠç¶åã³å 容ç©ãå·åŽããã補é ïŒãæåŸã«æ²æ®¿
ã¯å šãçããªãã€ãããã®æ··åç©ã¯éæã§ããã
ãŠåäžã§ãã€ãïŒçæç©ïŒãåç §ïŒã å®æœäŸ 13 å®æœäŸïŒã«èšèŒã®å®éšã«ããçŽ25ïŒ ã®ã¡ã¿ããŒ
ã«ãå«ãéæã§åäžãæ··åç©UPTESãã補é ã
ããå®æœäŸïŒã«èšèŒã®éããç空ãçšããŠ50âã®
å ç±ãµã€ã¯ã«ïŒæéã«ç¶ããŠçŽã¡ã«ã¡ã¿ããŒã«ã®
é€å»ãè¡ã€ããéæã§ãåäžã§ãããç²çš ãªçæ
ç©ãçããã å®æœäŸ 14â15 第ïŒè¡šã¯éæã§äžã€åäžãªå®æœäŸïŒåã³Epon
828ïŒDCSé åäœã®æ··åç©ãå«ã40ïŒ whitexç²å
å ãŠãããããã€ãã³è€åäœã®ç¹æ§ã瀺ããå šäœ
ã«ãããã®è€åäœã¯ç¹ã«æ²žéš°æ°Žã«72æéæããåŸ
ã«å¯Ÿç §è€åäœããåªããŠããããŸããã®å®éšã§ã¯
æ·»å å€ã®å€ç§»æ§ïŒversatilityïŒãææãããã å¯Ÿç §è€åäœãšæ¯èŒããå Žåããšããã·æš¹è
ïŒEpon 828ïŒã¯40ïŒ ã±ã€ç°ç³ïŒNyco Corp.補ã®
NYADGçŽïŒãå ãŠãããPBTïŒPETè€åäœã®
æ圢ç¹æ§ãäºå®æ¹åããããšã確èªãããããã®
ããšã¯40ïŒ ãçŒç²åïŒFreeportâKaolin補ã®
Whitexç²åïŒãå ãŠãããPBTïŒPETã«ããã
ãšããã·æš¹èæ§èœãšå¯Ÿç §çã§ãã€ãããã®å Žåã
æ圢ãããŸãŸã®è€åäœã®è¡æå€ãæ¹åãããã®ã¿
ã§ããããããŠåæ¥çã«ã¯èš±å®¹ãããªãé倧ãªæ¿
ãè²èª¿ã®å€åãè€åäœã«çããã
ãããã®å ãŠãå€çµæç©åã³çž®åéåäœãããªã
çž®åéåäœè€åç©ã«é¢ãããã®ã§ããã éå±å ãŠããããç±å¯å¡æ§ããªãšã¹ãã«è€åäœ
äžãžã®ãšããã·æš¹èã®é åã¯æ圢ãããæ©æ¢°çç¹
æ§ãæ¹åããããšãå ±åãããŠãããç±³åœç¹èš±ç¬¬
3547872å·ïŒå第3547873å·ïŒå第3886104å·åã³
å第4034013å·åç §ãããªã«ãŒãããŒãåã³ããª
ãšã¹ãã«ã«ãŒãããŒãã«ããããšããã·æš¹èã®ç¹
å®ã®äœ¿çšã¯ãªã©ã³ãåœç¹èš±ç¬¬82028930ââ10å·
åã³å第8202931ââ10å·ã«å ±åãããŠããã
ããããªãããè€åäœãå«ããããã®ãšããã·æš¹
èã®å æ°Žå解å®å®æ§ã¯åæ¥çã«ã¯èš±å®¹ãããªãã ç¹èš±å ¬é第76â30254å·ïŒ1976幎ïŒæ15æ¥ïŒã«
ç¡æ©å ãŠãå€ã«å¯ŸããäºååŠçå€ãšããŠãã¬ã³ã
ãŒã¢ãããããã«ããªãšããã·ã·ã©ã³ã®åŠãã¢ã
ãã·ã©ã³ãšé åãããšããã·æš¹èã®äœ¿çšã瀺ãã
ãŠããããã®åèæç®ã¯ç¡æ©å ãŠãå€ã«å¯ŸããŠ
0.02ãïŒééïŒ ã®ã¢ããã·ã©ã³åã³0.1ã10éé
ïŒ ã®ãšããã·æš¹èã䜿çšããªããã°ãªããªãããš
ã§ç¹æ®ã§ããããã®æç®ã«ãããŠããã®éããå€
ããããŸãã¯å°ãªããçšããå Žåã«ç±å¯å¡æ§ããª
ãšã¹ãã«çµæç©ã«æªåœ±é¿ãåãŒãããšã瀺ãããŠ
ããããã®ããšã¯å æ°Žå解å®å šæ§ã«ä»éããåé¡
ãå æãåŸããããããåŠçã®åæ¥çå®æœã¯äžæ
åã®ãšããã·æš¹èïŒã¢ããã·ã©ã³é åã®ä¹ããå®
å šæ§ã«ããå³ããå¶éããããäºå®ããã®æç®ã«
ãããŠããããç³»ã¯åæ¥çã«å¥œé©ã§ããããäžæ
åç³»ãšããŠäœ¿çšããéã«ç¢ºèªããããšãã§ããª
ãã ãããŠã宀枩ã§å®å šã§ããããããŠå ãŠããã
ãçž®åéåäœè€åç©ã«ãããŠå ãŠããããçž®åé
åäœè€åç©ã®æ©æ¢°çç¹æ§ãæ¹åããäžã€ä¿æãã
æ·»å å€ã«å¯Ÿããå¿ èŠæ§ãååšãããæ®ã«ããã®è€
åäœã¯å æ°Žå解å®å šæ§ã瀺ãã¹ãã§ããã è€åäœã®æ©æ¢°çç¹æ§ãä¿æãããããŸãã¯é«ã
ãå ãŠããããçž®åéåäœè€åç©ã«å¯Ÿããæ°èŠãª
ææ©ã±ã€çŽ ïŒãªãã·ã©ã³æ·»å å€ãå«ãå ãŠãå€çµ
æç©ãæäŸããããšãæ¬çºæã®ç®çã§ããã æŽã«å¢å€§ãããå æ°Žå解å®å šæ§ãæããå ãŠã
ãããçž®åéåäœè€åç©ãæäŸããããšãæ¬çºæ
ã®ç®çã§ããã ææ©ã±ã€çŽ ïŒãªãã·ã©ã³æ·»å å€ã«ããã®å ãŠã
ãããçž®åéåäœè€åç©ã«ããã䜿çšã«éããŠå·¥
çšçã«åé¡ãååšããªãããšãæ¬çºæã®ä»ã®ç®ç
ã§ããã æåŸã«ãææ©ã±ã€çŽ ïŒãªãã·ã©ã³æ·»å å€ãäžæ
åç³»ãšããŠäœ¿çšã§ãããããŠãã®ãŸãŸã§å®€æž©ã§çž
åé¢ãããããŸãã¯ç¡¬ãæš¹èç¶ã®å¡ã«ç¡¬åãã«ã
ãïŒä¿åæéå®å®æ§ïŒããšãæ¬çºæã®ç®çã§ã
ãã æ¬çºæã¯å ãŠããããçž®åéåäœè€åç©ã«ãã
ãå ãŠãå€ãšå ±ã«æçšãªæ°èŠãªææ©ã±ã€çŽ ïŒãªã
ã·ã©ã³æ·»å å€ãæäŸããããã®æ°æãªæ·»å å€ã¯ãª
ãã·ã©ã³æš¹èååç©åã³ã¢ã·ã«ã¢ãããŸãã¯ã·ã¢
ãã·ã©ã³ã®é åç©ã§ããããã®æ°èŠãªæ·»å å€ã¯å®€
æž©ã§å®å®ã§ãããå ãŠãå€ãçž®åéåäœããŸãã¯
å ãŠãå€åã³çž®åéåäœã®é åç©ãšå®å šã«
ïŒintegrallyïŒé åãããããŸãã¯å ãŠãå€äžã«
äºååŠçããŠæ圢ãããæ©æ¢°çç¹æ§ã«ãããæ¹å
åã³åªããå æ°Žå解å®å šæ§ã瀺ãå ãŠããããçž®
åéåäœè€åç©ãçæãããããšãã§ããã æ¬çºæã«ããã°ãå ãŠãå€ã«å¯Ÿããæ°èŠãªææ©
ã±ã€çŽ ïŒãªãã·ã©ã³æ·»å å€ãæäŸãããããã®æ·»
å å€ã¯(1)ãªãã·ã©ã³æš¹èæååã³(2)ã¢ã·ã«ã¢ãã
ãŸãã¯ã·ã¢ãã·ã©ã³ãããªãã ãã®ãªãã·ã©ã³æš¹èæåã¯å°ãªããšãïŒã€ã®ãª
ãã·ã©ã³ç° ïŒãªãã·ã©ã³ç°ïŒ ãå«ã¿ããããŠäžè¬ã«ã¯åŒ åŒäžãR1ãR2ãR3åã³R4ã¯ç¬ç«ããŠã¢ã«ã
ã«ãã¢ãªãŒã«ãã¢ã«ã±ãã«ããšããã·ãææ©ã·ãª
ã«åã³æ°ŽçŽ ã®çŸ€ããéžã°ããåºã§ããã ã§è¡šããããããããç©è³ªã«ã¯ãšããã·æš¹èãã¢
ããšããã·å ±éåäœããšããã·ãåããã倩ç¶æ²¹
ãªã©ãå«ãŸããã 奜ãŸããã¯ãšããã·æš¹èãçšãããäžè¬ã«ããš
ããã·æš¹èã¯ïŒåååœãå¹³åããŠïŒã€ããå€ããª
ãã·ã©ã³ç°ãå«ãååç©ãã調補ããããã®ã®æš¹
èã§ããããšããã·æš¹èã¯ãšãŒãããã«ãããŠã¯
ãšããã·ãæš¹èãšããŠå ¬ç¥ã§ããããã®ååŠçæ§
質ã«äŸåããŠããããã®ãã®ã¯ãšããã·ãåãã
ãããªãªã¬ãã€ã³ãéé ¢é žãšããã·æš¹èããšãã
ã·ãªã¬ãã€ã³éåäœããšãã¯ãããããªã³æš¹èã
ãã¹ããšããŒã«ïŒ¡æš¹èããšãã¯ãããããªã³âã
ã¹ããšããŒã«ïŒ¡çž®åäœããšãâãã¹æš¹èåã³ïŒïŒ
ïŒâãã¹ïŒãã©âããããã·ããšãã«ïŒãããã³
ãžã°ãªã·ãžã«ãšãŒãã«éåäœãšããŠãè¡šããããš
ãã§ããã 代衚çã«ã¯ããªãã·ã©ã³æš¹èæåã¯ãªã¬ãã€ã³
ã®ãšããã·ãåãéããŠèª¿è£œãããããã®ãšãã
ã·æš¹èã¯äžè¬ã«ãšãã¯ãããããªã³ã掻æ§æ°ŽçŽ ä¿
æååç©ãšåå¿ãããããšã«ãã調補ããããã
ããã®ãªãã·ã©ã³æš¹èæåãçšããããšãã§ã
ãã é©åœãªãªãã·ã©ã³çµæç©ã¯ããŒã¿ãŒïŒïŒïŒïŒâ
ãšããã·ã·ã¯ãããã·ã«ïŒâãšãã«ããªã¡ããã·
ã·ã©ã³ãã¬ã³ãâã°ãªã·ããã·ãããã«ããªã¡ã
ãã·ã·ã©ã³ããšããã·ãåãããããªãã¿ãžãš
ã³ãããã«ã·ã¯ããããµã³ãžãªãã·ããïŒïŒïŒâ
ãšããã·ã·ã¯ãããã·ã«ã¡ãã«ïŒïŒïŒâãšããã·
ã·ã¯ããããµã³ã«ã«ããã·ã¬ãŒãããã¹ïŒïŒïŒïŒ
âãšããã·ã·ã¯ããã³ãã«ïŒãšãŒãã«ãïŒâïŒïŒïŒ
ïŒâãšããã·ã·ã¯ããããµã³ïŒâïŒïŒïŒâãšãã
ã·âïŒïŒïŒâãžãªããµã¹ãããïŒïŒïŒãâãŠã³ã
ã«ã³ïŒãã¹ïŒïŒïŒïŒâãšããã·âïŒâã¡ãã«ã·ã¯
ãããã·ã«ïŒã¢ãžããŒãïŒ åã³ ãããããããã«éå®ããããã®ã§ã¯ãªãã ã·ã©ã³æåã«ã¯å°ãªããšãïŒã€ã®ã¢ã·ã«ã¢ãã
ãŸãã¯ã·ã¢ãã·ã©ã³çµå ïŒã¢ããã·ã©ã³çµåïŒ ïŒ®â¡CRSiâ¡ ïŒã·ã¢ãã·ã©ã³çµåïŒ åŒäžãã¯ã¢ã«ãã¬ã³ãŸãã¯ã¢ãªãŒã¬ã³åºã§ã
ãã ãå«ãŸããã é©åœãªã¢ã·ã«ã¢ããã·ã©ã³ã«ã¯ã¬ã³ããŒãŠã¬ã€
ããããã«ããªãšããã·ã·ã©ã³ãã¬ã³ããŒã¢ã»ã
ã«ã¢ãããããã«ããªãšããã·ã·ã©ã³ããã«ã¿ãŒ
ãã³ãŸã€ã«ã¢ããããã«ã¡ãã«ãžãšããã·ã·ã©ã³
ãªã©ãå«ãŸããããããã«éå®ãããªããããã
ã·ã©ã³ã«é¢ããæŽã«è©³çŽ°åã³ãã®èª¿è£œæ³ã«ã€ããŠ
ã¯ç±³åœç¹èš±ç¬¬2928858å·ïŒå第2929829å·ïŒå第
3671562å·ïŒå第3754971å·ïŒå第4046794å·ïŒå
ã³å第4209455å·ãåç §ããããã奜ãŸããã¯ã
ãŠã¬ã€ãã·ã©ã³ãæ®ã«ã¬ã³ããŒãŠã¬ã€ããããã«
ããªãšããã·ã·ã©ã³ã奜é©ã§ããã é©åœãªã·ã¢ãã·ã©ã³ã«ã¯ã·ã¢ããšãã«ããªã¢ã«
ã³ãã·ã·ã©ã³ãã·ã¢ããããã«ããªãŒã¢ã«ã³ãã·
ã·ã©ã³ãã·ã¢ãã€ãœããã«ããªã¢ã«ã³ãã·ã·ã©
ã³ãïŒâã·ã¢ãããã«ããªã¢ã«ã³ãã·ã·ã©ã³ãïŒ
âã·ã¢ãã€ãœããã«ããªã¢ã«ã³ãã·ã·ã©ã³ãã·ã¢
ãããšãã«ããªã¢ã«ã³ãã·ã·ã©ã³ãªã©ãå«ãŸãã
ããããã«éå®ããããã®ã§ã¯ãªãããŸãããã
ã·ã¢ãã·ã©ã³åã³ä»ã®ã·ã¢ãã¢ã«ãã¬ã³ãŸãã¯ã¢
ãªãŒã¬ã³ã·ã©ã³ã®éšåçå æ°Žå解çæç©ãæ¬çºæ
ã«äœ¿çšããéã«é©ããŠããããšãèãããããã·
ã¢ãã·ã©ã³ã®æŽã«å®å šãªèšè¿°ã«ã¯Walter Noll.
Academic Press.1968ã«ããChemistry and
Technology of Silicones 180ã189é ã«èŠåºã
ããšãã§ããã æ°èŠãªææ©ã±ã€çŽ ïŒãªãã·ã©ã³çµæç©ã¯äžè¬ã«
å ãŠãå€ã®ééãåºæºãšããŠ0.02ã20ééïŒ ã奜
ãŸããã¯0.5ãïŒééïŒ ã®ç¯å²ã®éã§çšãããã
ããã®äžè¬çç¯å²ã¯å ãŠãå€ã®å ããéã«äŸå
ããå³ã¡æ¥µããŠé«ãå ãŠãå€ã®éã§ã¯äœãæ·»å å€
ã®ç¯å²ã§ææã®çµæã瀺ãããããŠæ¥µããŠäœãå
ãŠãã®éã§ã¯ææã®çµæãéæãããã«ã¯é«ãæ·»
å å€ã®ç¯å²ãå¿ èŠã§ããåŸããäžè¬ã«ããªãã·ã©
ã³æåã¯ïŒã95ééïŒ ã奜ãŸããã¯25ã75ééïŒ
ã®æ·»å å€ãè¡šããããããŠã·ã©ã³æåã¯95ãïŒé
éïŒ ã奜ãŸããã¯75ã25ééïŒ ã®æ·»å å€ãè¡šã
ãã çž®åéåäœè€åç©ã«çšããå ãŠãå€ã¯æ¬åéã«
粟éããè ã«ã¯å ¬ç¥ã§ããããããŠããããã®é©
åœãªçŽ°ããåå²ããããããŸãç²ç¶ã®ç©è³ªãå«
ããçž®åéåäœè€åç©äžã«é åããæç¹ã§ãæ®ã
ã©ã®å ãŠãå€ã¯çŽ°ããåå²ãããç²åã®ç¶æ ã§ã
ãããšãã§ããããã®ãã®ã¯ããããã®ç«äœé
眮ãäŸãã°æ倧çŽåŸãå³ã¡10ÎŒïœã奜ãŸããã¯5ÎŒ
ïœã®æ倧çŽç·çŽåŸãæããã»ãŒçæ¹æ§ã®ãã®ã§ã
ããïŒãŸãã¯10ÎŒïœãŸãã¯ãã以äžã奜ãŸããã¯
5ÎŒïœãŸãã¯ãã以äžã®åããŸãã¯çŽåŸãæãã
ãã¬ãŒããŸãã¯éç¶ïŒç¹ç¶ïŒã®ãã®ã§ããããšã
ã§ãããå ãŠãå€ç²åã®æå°ã®å€§ããã¯èšççã§
ãªããããã«é¢ããŠã¯é垞䜿çšãããå ãŠãå€ã®
ãããã®ãã®ãé©ããŠãããæ¬çºæã«äœ¿çšãåŸã
ç¹å®ã®å ãŠãå€ã®äžã«ã¯ç³ç¶¿ãããšããã³ã°ãã
ãïŒchoppedïŒã¬ã©ã¹ãã«ãªãªã³åã³ä»ã®ç²åé±
ç©ãã·ãªã«ãã«ã«ã·ãŠã ã·ãªã«ãçé žã«ã«ã·ãŠã
ïŒå¢çœå€ïŒãé žåãã°ãã·ãŠã ãçé žããªãŠã ãç¡«
é žããªãŠã ïŒãã©ã€ãïŒãéå±ç¹ç¶åã³ç²æ«ãã¬
ã©ã¹ç¹ç¶ãèç«ç¹ç¶ãé匷åãŸãã¯åŒ·åã«ãŒãã³
ãã©ãã¯ãé žåã¢ã³ãã¢ã³ãé žåãã¿ã³ãé²æ¯ã
ã¿ã«ã¯ãããšããã³ã°ãããã¬ã©ã¹ãã¢ã«ããã
ç³è±ãã±ã€ç°ç³ïŒã±ã€é žã«ã«ã·ãŠã ïŒã䞊ã³ã«ç¡
æ©çè²é¡æããããææ©å ãŠãå€ã«ã¯ç¶¿ãªã³ã¿ãŒ
åã³ä»ã®ã»ã«ããŒã¹æ§ç©è³ªãæšãããåæç¹ç¶ãª
ã©ãå«ãŸãåŸãã奜é©ãªå ãŠãå€ã°ç²åãé²æ¯ã
ã±ã€ç°ç³åã³ããšããã³ã°ãããã¬ã©ã¹ã§ããã æ·»å å€ãå®å šã«é åããããšã¯äºååŠçããã
å ãŠãå€ã«ã¯å®è³ªçãªçµæžçå©ç¹ããããæéå
ã³ãšãã«ã®ãŒã®ç¯çŽãå«ã¿ããããŠäŸ¿å©ã«äžã€ç°¡
åãªããšã§ãããå ãŠãå€ã®æ·»å å€ãšã®äºååŠç
ã¯åéãé²ãããã®é«ãå転æ°ã§å転ãã匷åãª
æ··åãã¬ãŒããåããHenschelãŸãã¯åã·ãšã«
ïŒtwinâshellïŒåé ååšã®ãããªåŒ·åãªæ··ååšã
å¿ èŠãšããå¥ã®æäœã§ãããæ·»å å€ã¯åéãé²ã
ããã«å®åžžçãªæµéã§åŸã ã«å ããªããã°ãªããª
ããäºååŠçé段äžã«ãå±åšåããé«æž©ãçšãã
è£ çœ®ã®é«éæ··åãã¬ãŒããŸãã¯ãã®è¿åã§çã
ãã ãã®å®å šãªé åæè¡ãå©çšããéã«ãæ·»å å€ã¯
å ãŠãå€ãåæ£ãããããšãã§ããªããã°ãªã
ãããããŠãŸãæ·»å å€ã¯å ãŠãå€äžã«åäžã«åé
ãããããšãã§ããªããã°ãªããªãããã®ããšã
åéãé²æ¢ãããæ¬çºæã«ããå®å šãªé åã«ãã
ãŠãæ·»å å€ã¯è¿ éã«ïŒïŒåã§ïŒå ãŠãå€ãŸãã¯å
ãŠãå€ïŒæš¹èæ··åç©ã«å ããç¶ããŠæž©åã«æ¹æã
ãããšãã§ããã匷åæ·»å å€ã®å©ç¹ãä¿æãã€ã€
äœæ¿åºŠã§æ·»å å€ãçšããããšãæ¬çºæã®å®è³ªçäž
ã€äºæãã¬å©ç¹ã§ãããæŽã«ãæ·»å å€ãå ãŠã
å€ïŒæš¹èæ··åç©ãå«ãåŠçè£ çœ®ïŒäŸãã°Farrelé£
ç¶æ··åæ©åã³æŒåºæ©ïŒäžã«çŽæ¥ã«ãäžã€æº¶è§£è€å
äœã®æµåºåã«æ¬çºæã«ããå®å šã«é åããããšã
ã§ããããããã®çç±ã«ããå®å šé åãæ¬çºæã®
奜é©ãªå ·äœäŸã§ãããããããªãããäºååŠçã¯
æ¬çºæã«é©åããäžã€ããå Žåã«ã¯ç¹å®ã®ç¶æ³ã
å³ã¡çšããçž®åéåäœãå ãŠãå€ãæ·»å å€ãªã©ã«
äŸåããŠå¥œé©ãªæ·»å ã®æ¹æ³ãè¡šããã å ãŠããããçž®åéåäœè€åç©ã«çšããçž®åé
åäœã¯å ãŠãå€ãéåžžé åãããããããã®çž®å
éåäœãŸãã¯éçž®åäœã§ããåŸããéåžžã®ã¿ã€ã
ã®çž®åéåäœã¯ããªãšã¹ãã«ïŒãžã«ã«ãã³é žãŸã
ã¯ãžã«ã«ãã³é žåã³ãžã°ãªã³ãŒã«ã®ãšã¹ãã«ã
ãïŒãåã³ããªã¢ããïŒãžã«ã«ãã³é žåã³ãžã¢ã
ã³ãããããŸãã¯ã©ã¯ãã³ããïŒã§ããããŸãã
ããã®ç©è³ªå士ãããŸãã¯ä»ã®éåäœãå³ã¡ããª
ããã«ã¢ã»ããŒããŸãã¯ã¹ãã¬ã³âç¡æ°Žãã¬ã€ã³
é žå ±éåäœãšã®é åäœãèããããã æŽã«éåžžã®ã¿ã€ãã®ããããªã¢ããçž®åéåäœ
ã®äŸã«ã¯ãã®ãã®ãçæãããéã«çšãã次ã®å
å¿ç³»ã«ãããã®ãå«ãŸããããããã«éå®ããã
ãã®ã§ã¯ãªãã ïŒ ãžã¢ãã³ã®ãžã«ã«ãã³é žãšã®åå¿ã ïŒ Ïâã¢ããé žã®èªå·±çž®åã ïŒ ã©ã¯ã¿ã ç°ã®éç°ã ïŒ ãžã¢ãã³ãšäºé žå¡©åç©ãšã®åå¿ã ããªã¢ããéåäœã¯æ¬åéã§ååå ¬ç¥ã§ããã
ãããŠãã€ãã³ãšããŠç§°ãããåçµæ¶ç¶åã³éæ¶
æ§éåäœã®ãã®ãå«ãŸãããå€æ°ã®ããªã¢ããã
ç±³åœç¹èš±ç¬¬2071250å·ïŒå第2071251å·ïŒå第
2130523å·ïŒå第2130948å·ïŒå第2241322å·ïŒå
第2312966å·ïŒå第2512606å·ïŒåã³å第3393210
å·ã«èšèŒãããŠããã ããªã¢ããã®äŸã«ã¯æ¬¡ã®ãã®ãå«ãŸããããã
ãã«éå®ããããã®ã§ã¯ãªãïŒããªïŒãããµã¡ã
ã¬ã³ã¢ãžãã¢ããïŒïŒãã€ãã³ïŒïŒïŒïŒãããªïŒã
ããµã¡ãã¬ã³ã¢ãŒã©ã¢ããïŒïŒãã€ãã³ïŒïŒïŒïŒã
ããªïŒãããµã¡ãã¬ã³ã»ãã·ã¢ããïŒïŒãã€ãã³
ïŒïŒ10ïŒãããªïŒãããµã¡ãã¬ã³ããã«ãã¢ããïŒ
ïŒãã€ãã³ïŒïŒ12ïŒãã©ã¯ã¿ã ã®éç°ã«ããçæã
ããããªã¢ãããäŸãã°ããªã«ããã©ã¯ã¿ã ïŒã
ã€ãã³ïŒïŒãããªã©ãŠãªã«ã©ã¯ã¿ã ïŒãã€ãã³â
12ïŒåã³ããªïŒ11âã¢ãããŠã³ãã«ãã³é žïŒïŒã
ã€ãã³â11ïŒãä»ã®é©åœãªçž®åéåäœã«ã¯ããª
ïŒãªãã·ã¢ã«ã«ãã€ã«ïŒãããªïŒã¢ã«ãã¬ã³ãªããµ
ã¬ãŒãïŒãããªïŒã¢ã«ãã¬ã³ã¢ãžããŒãïŒãããª
ïŒã¢ã«ãã¬ã³ã»ãã»ãŒãïŒãããªïŒããªã¡ãã¬ã³ã¢
ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒãããªïŒãããµã¡ã
ã¬ã³ã¢ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒãããªïŒãã«
ã¡ãã¬ã³ã¢ã«ã«ã³âãžã«ã«ããã·ã¬ãŒãïŒãããª
ïŒãã©ã³ã¹âïŒïŒïŒâã·ã¯ãããã·ã¬ã³ã¢ã«ã«ã³
ãžã«ã«ããã·ã¬ãŒãïŒãããªïŒïŒïŒïŒâã·ã¯ãã
ããµã³ãžã¡ãã¬ã³ã¢ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒã
ããªïŒã¢ã«ãã¬ã³ãã¬ãã¿ã¬ãŒãïŒãããªïŒã¢ã«
ãã¬ã³ã€ãœãã¿ã¬ãŒãïŒãããªïŒïœâããšãã¬ã³
ã¢ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒãããªïŒã¢ã«ãã¬
ã³ïœâããšãã¬ã³ãžã¢ã»ããŒãïŒãããªïŒïœâã
ã·ãªã¬ã³ã¢ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒãããª
ïŒïœâãã·ãªã¬ã³ã¢ã«ã«ã³ãžã«ã«ããã·ã¬ãŒãïŒã
ããªïŒïœâããšãã¬ã³ãžã¢ã«ãã¬ã³ãã¬ãã¿ã¬ãŒ
ãïŒãããªïŒã¢ã«ãã¬ã³ïŒïŒïŒâãšãã¬ã³ãžãªã
ã·âïŒïŒ4â²âãžãã³ãŸãšãŒãïŒãããªïŒã¢ã«ãã¬
ã³ïŒïŒ4â²âãžãã³ãŸãšãŒãïŒãããªïŒã¢ã«ãã¬ã³
ïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ããã·ã¬ãŒãïŒåã³ã
ãªïŒã¢ã«ãã¬ã³ã¹ã«ããã«âïŒïŒ4â²âãžãã³ãŸãš
ãŒãïŒãå«ãŸãããæ®ã«ããªãšã¹ãã«ã奜ãŸã
ãããããŠãã®äžã§ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒã
ïŒPETïŒåã³ããªããã¬ã³ãã¬ãã¿ã¬ãŒã
ïŒPBTïŒã奜é©ãªããªãšã¹ãã«ã§ããã çž®åéåäœãšé åããææ©ã±ã€çŽ ïŒãªãã·ã©ã³
æ·»å å€ã§åŠçãããå ãŠãå€ã®éã¯ç¹å®ã®ç®ççš
éã«äŸåããŠåºç¯å²ã«å€ããããšãã§ãããæ©æ¢°
çç¹æ§ã«å¯ŸããŠå®è³ªçãªå¹æãåŸãããã«ã¯æ·»å
å€âå ãŠãå€æ··åç©ã¯éåžžå ãŠããããçž®åéå
äœè€åç©ã®å°ãªããšãïŒééïŒ ã§ãããå ãŠãã
ããçž®åéåäœè€åç©ã®85ééïŒ ãè¶ éããæ·»å
å€âå ãŠãå€æ··åç©ã¯æ®ãã©æãŸãããªãããã
ãã®ç¯å²å ã§ã¯ãåã ã®æåã®å¥œé©ãªéã¯äžè¬ç
ã«ã¯å ãŠãå€ã®éžæåã³æ®ã«ã¯ç¹æ§ã®ç®ççšéã«
倧ããäŸåããã§ããããæŽã«ãããã®çç±ã«ã
ããçžäºã®æåã®æ¯ã®éçã¯æ¬çºæã®ç²Ÿç¥ããé¢
ããã«æäŸããããšã¯ã§ããªãã åã«è©³è¿°ããæåã«å ããŠããããè€åäœã«é
åžžçšããä»ã®æåãé åããããšãã§ããããã
ãã®ãã®ã«ã¯é©åœãªãã°å¯å¡å€ãå ç¡«å€ãçé¢
å€ãæ¶æ©å€ãçµæ¶åé床調ç¯æ·»å å€ïŒå éå€åã³
é 延å€ïŒãææãé¡æãªã©ãå«ãŸããã æ¬çºæã®æ£ç¢ºãªç¯å²ã¯ä»å±ã®ç¹èš±è«æ±ã®ç¯å²ã«
è¿°ã¹ããã次ã®ç¹å®ã®å®æœäŸã¯æ¬çºæã®ããç¹åŸŽ
ã説æãããããŠæŽã«è©³çŽ°ã«ã¯ãã®ãã®ã®è©äŸ¡æ¹
æ³ãææãããããããªãããæ¬å®æœäŸã¯èª¬æã®
ããã®ã¿ã«ç€ºããããããŠä»å±ããç¹èš±è«æ±ã®ç¯
å²ã«è¿°ã¹ããã以å€ã¯æ¬çºæãéå®ãããã®ã§ã¯
ãªããç¹èšãã¬éããã¹ãŠã®éšåã³ïŒ ã¯ééã«ã
ããã®ã§ããã çš èª æ¬æ现æžã®å®æœäŸåã³ä»ã®å Žæã§äœ¿çšããã次
ã®å称ã¯æ¬¡ã®æå³ãæããïŒ PBTïŒGafiteTM1400AïŒâ GAF Corp.ããè³Œå ¥ããžã¡ãã«ãã¬ãã¿ã¬ãŒ
ãåã³ïŒïŒïŒâãã¿ã³ãžãªãŒã«ã®åå¿çæç©ãå ¬
称0.8åºæç²åºŠïŒ25âãªã«ãã¯ã«ã«ããšããŒã«
äžïŒã PETïŒCleartufTM7207ïŒâ Goodyear Corp.ããè³Œå ¥ããã¬ãã¿ã«é žãŸã
ã¯ãžã¡ãã«ãã¬ãã¿ã¬ãŒãã®ãšãã¬ã³ã°ãªã³ãŒã«
ã®åå¿çæç©ãå ¬ç§°0.72åºæç²åºŠïŒ30âããªãã«
ãªãé ¢é žäžïŒã ãã€ãã³ïŒZytelTM101ïŒâ Du Pont補ã®ãã€ãã³66ã WhitexTMClayâ FreeportâKaolinãçŒãããç²åã å ¬ç§°å¹³åç²åŸ3ÎŒã ã±ã€ç°ç³ïŒNYADTMïŒâ ã±ã€é žã«ã«ã·ãŠã å ãŠãå€ïŒ15ïŒïŒçžŠæšªæ¯å ¬
称ïŒãNyco Corp.ããè³Œå ¥ã Epon 828â Shell Chemical Co.補ã®ãšããã·æš¹èããã¹
ããšããŒã«ïŒ¡åã³ãšãã¯ãããããªã³ã®åå¿çæ
ç©ãå ¬ç§°åœééé190ã UPTESâ 50ïŒ ã¡ã¿ããŒã«æº¶æ¶²ãšããŠã®ã¬ã³ããŒãŠã¬ã€ã
ãããã«ããªãšããã·ã·ã©ã³ GAPTESâ ã¬ã³ãâã¢ãããããã«ããªãšããã·ã·ã©ã³ DCSâ ç¡æ°Žããªã¡ãªãé žåã³ ïŒCH3OïŒ3SiïŒCH2ïŒ3NHïŒCH2ïŒ3SiïŒOCH3ïŒ3ã®å
å¿ã«ãã調補ããã ã·ã¢ããšãã«ããªã¡ããã·ã©ã³ CNEâ ã·ã¢ããšãã«ããªãšããã·ã·ã©ã³ æŒåºæ©æº¶èåŠçâ ç±å¯å¡æ§çž®åéåäœã®æº¶èç©ãããšããã³ã°ã
ããã¬ã©ã¹ãé±ç©å ãŠãå€ãŸãã¯åã ã®é åç©ã
æŒåºäžãããŸãæŒåºåã®é åããããããŸãã¯æ··
åãããããã«ããããã«å ç±ããæŒåºæ©ã䜿
çšã å®æœäŸïŒãïŒã®è€åç©ã¯Wernerâ Pleiderer ZSKâ30 åã¹ã¯ãªãŠãŒæŒåºæ©äžã§
åŠçããïŒ24ïŒïŒ ïŒïŒ€æ¯ïŒã å®æœäŸïŒã®è€åäœã¯Hartig2ã€ã³ãçŽåŸåã¹ã¯
ãªãŠãŒæŒåºæ©äžã§æº¶è§£åŠçããïŒ24ïŒïŒ ïŒïŒ€
æ¯ïŒã å°åºæ圢â ASTMè©Šéšçã¯Arburg2ãªã³ã¹ã22ãã³ãŠã
ããäžã§æ圢ããã æ圢ããããŸãŸâ Arburgè£ çœ®äžã§æ圢ããASTMè©Šéšçã¯è©Šéš
åã«å®€æž©ã§å°ãªããšã48æé平衡ãããã 72æé氎沞隰詊éšâ ASTMè©Šéšçã沞隰氎ã«72æé浞挬ãã220ã
ã§ïŒæé也ç¥ããè©Šéšåã«å®€æž©ã§å°ãªããšã24æ
é平衡ãããã åŒåŒµåŒ·ãâ ASTM â638ïŒ0.2ã€ã³ãïŒåè©Šéšé床ïŒã æ¹è¯ãããããã³ã°ãããªã ã¢ã€ãŸããè¡æå€â ãããã³ã°ãããªã2.5Ã0.5Ã0.125ã€ã³ãã®è©Š
éšçãè©Šéšçã®1/2ã®é·ããè¡æãåããããã«
é²åºããããã«ã¢ã€ãŸããè¡æè©Šéšæ©äžã«çœ®ãã
è¡æã¯ãã€ãŒãã»ãã³ãïŒã€ã³ãã§èšç®ãããã
ããã¯æ¹è¯ãããASTM â256è©Šéšã§ããã ãããã³ã°ãããã¢ã€ãŸããè¡æå€â ASTM â256ã PSiâŠâŠãã³ãïŒå¹³æ¹ã€ã³ã ïŒ âŠâŠç¹èšãã¬éãééïŒ ïœâŠâŠã°ã©ã wtâŠâŠé é éšâŠâŠç¹èšãã¬éãéééš ptsâŠâŠç¹èšãã¬éãéééš phwâŠâŠéééš ppmâŠâŠ100äžéééšåœãã®éééš ftâ1bsïŒinâŠâŠãã€ãŒãã»ãã³ãïŒã€ã³ã inâ1beïŒinâŠâŠã€ã³ãã»ãã³ãïŒã€ã³ã phrâŠâŠæš¹èïŒéåäœïŒ100éééšåœãã®éš HDTïŒ 264 psi ASTM â648 äºååŠçâ ç±ãã©ã¹ããã¯ã«å ããåã«æ·»å ç©ãïŒéšã®ã¡
ã¿ããŒã«ïŒæ°ŽïŒïŒïŒïŒå®¹éæ¯ïŒã«åžéããããšã«
ãã现ããåå²ãããå ãŠãå€ãåŠçãããããŸ
ãã¯è¢«èŠããããã«æ·»å ç©ãé©çšãããããŠ
PattersonâKellyåã·ãšã«é ååšãçšããŠå ãŠ
ãå€ã«é©çšããæ¹æ³ã105âã§ïŒæéã®ä¹Ÿç¥ãµã€
ã¯ã«ã å®å šæ·»å â 溶èåŠçåã«æ··åç©ãæ¹æããªãã液äœãŸãã¯
åºäœæ·»å å€ãå ãŠãå€ïŒæš¹èã®æ··åç©ãžåã«é
åã代衚çã«ã¯Hobartæ··ååšãHenschelæ··å
åšããªãã³é ååšãŸãã¯ãã©ã ã¿ã³ãã©ãŒãçšã
ãã åèäŸ ïŒ å®€æž©ã§ã®å®å®æ§ãæ±ããããã«äžé£ã®å®éšãé
å§ãããããŠå ãŠããããçž®åéåäœè€åç©ã«å¯Ÿ
ããæå¹ãªäžæåæ·»å å€ã補é ããããšãã§ã
ããã¬ã³ããŒã¢ãããããã«ããªãšããã·ã·ã©ã³
ãšé åãããšããã·æš¹èïŒEpon 828ïŒãããã
ãUPTESãCNMåã³DCSãšã®Epon 828ã®å¥ã
ã®æ··åç©ãšæ¯èŒããå Žåã«æ¯èŒçäžå®å®ã§ããã
ãšãåã€ããå®éšã¯ãããªç¿äžã§ãªãã·ã©ã³ãã·
ã©ã³ãšæ··åãã次ã«ã«ããŒããããããšãããªã€
ãŠãããäžå®æéã«ãããèçŒã§ã®èŠ³å¯ãèšé²ã
ãã硬ãæš¹èç¶ã®å¡ãçµç¹ã®åŸŽåã§ãã€ããäŸã
ã°ãEpon 828 åã³ã¬ã³ããŒã¢ãããããã«ã
ãªãšããã·ã·ã©ã³ãïŒïŒïŒã®ééæ¯ã§äžç·ã«ãã
å Žåã宀枩ïŒæéã§åãŒã©ãã³ç¶çæç©ãã24æ
éã§æè»ãªåºäœã®å¡ãããããŠ48æéã§åºäœæš¹è
ç¶çæç©ãçŸãããã第ïŒè¡šã¯èçŒã®èŠ³å¯ã«ãã
çµç¹ã®åºäœæš¹èç¶çæç©ã®çµæã瀺ããããã«ã
ãEpon 828ãšäžç·ã«ããå Žåã«UPTESãCNM
åã³æäœéã®DCSã®åã ã¯192æéã«åºäœæš¹èç¶
çæç©ãçæãããªãããšãç¥ãããšãã§ããã
ãããã®ç³»ã¯Epon 828ïŒã¬ã³ããŒã¢ããããã
ã«ããªãšããã·ã·ã©ã³ããå®å®ã§ããããšãçµè«
ãããã å®æœäŸïŒâïŒãæ¯èŒäŸïŒ 第ïŒè¡šã¯40ïŒ whitexTMç²åãå ãŠããã
PBTïŒPETïŒïŒïŒïŒæ¯ïŒã®è€åäœã®æ©æ¢°çç¹æ§ã
瀺ããEpon 828ïŒUPTESã®é åãç¹ã«äžå®ã®
Epon 828éã§ã®äœæ¿åºŠã®UPTESã¯æ§èœã«ãããŠ
Epon 828ïŒã¬ã³ããŒã¢ãããããã«ããªãšãã
ã·ã·ã©ã³ã«å¹æµããããšãç¥ãããšãã§ãããäž¡
æ¹ã®è€åäœã¯æ°Žæ²žéš°è©Šéšã®ååã³åŸã§å¯Ÿç §è€åäœ
ããåªããŠããã å®æœäŸ ïŒâïŒ ç¬¬ïŒè¡šã¯40ïŒ ç²åãå ãŠãããPBTïŒPET
ïŒïŒïŒïŒæ¯ïŒã«ãããïŒã€ã®æ¿åºŠã§ã®Epon 828ïŒ
CNMã®æ§èœã瀺ãããããã®è€åäœã®æ©æ¢°çç¹
æ§ã¯72æéã®æ°Žæ²žéš°è©Šéšã®ååã³åŸã§å¯Ÿç §è€åäœ
ããåªããŠããã å®æœäŸ ïŒâïŒ ç¬¬ïŒè¡šã¯40ïŒ ç²åå ãŠããããPBTïŒPET
ïŒïŒïŒïŒæ¯ïŒã«ãããïŒã€ã®å¥ã ã®æ¿åºŠã§ã®Epon
828ïŒDCSã®æ§èœã瀺ããEpon 828ã®äžå®éãšé
åããäœæ¿åºŠã®DCSã¯ç¬¬ïŒè¡šã«èšèŒã®Epon
828ïŒDCSæ¯ã®å®€æž©å®å®æ§ãèæ ®ããå Žåã«å¥œãŸ
ãããDCSãå«ãè€åäœã¯ã¬ã³ããŒã¢ãããã
ãã«ããªãšããã·ã·ã©ã³ãå«ãè€åäœã®æ§èœã«å°
éãïŒãã®ãã®ã¯å¯Ÿç §è€åäœããåªããŠããã å®æœäŸ ïŒâïŒ ããšããã³ã°ãããã¬ã©ã¹ïŒç²åå ãŠãããã
PETè€åäœã第ïŒè¡šã«ç€ºãã15ïŒ ããšããã³ã°
ãããã¬ã©ã¹ïŒ15ïŒ ç²åå ãŠããããPETè€å
äœã«ãããŠUPTESåã³CNEãšå¥ã ã«äžç·ã«ãã
Epon 828ã¯æ圢ãããŸãŸã®ç¹æ§ãããŒã¹ã®ãã
å¯Ÿç §è€åäœããããªãè¯å¥œã®æ§èœã瀺ãã å®æœäŸ 10â11 ïŒïŒïŒééæ¯ã®Pponâ828ïŒUPTESãæ··åãã
ãããŠ75âã«å ç±ãããã®éã«ã¡ã¿ããŒã«ãé€å»
ããããã«ç空ãçšããã宀枩ã§å®å®ãªéæã§ç¥
çè²ã®åäžãªçæç©ãçãããã¡ã¿ããŒã«ãé€å»
ããEponâ828ïŒUPTESã1/8ã«ããšããã³ã°ã
ããã¬ã©ã¹åã³PBTïŒPETïŒïŒïŒïŒæ¯ïŒã®æ··åç©
äžã«å®å šã«é åãããå¯Ÿç §è€åäœã¯EPONâ
828ïŒUPTESãå«ãŸã¬PBTïŒPETïŒïŒïŒïŒæ¯ïŒ
ãšæ··åããïŒïŒïŒã€ã³ãã®ããšããã³ã°ãããã¬
ã©ã¹ãããªã€ãŠãããåã ã®è€åäœã«ãããŠ30ïŒ
äžå®ã®ããšããã³ã°ãããã¬ã©ã¹éãçšãïŒ1.5
ïŒ åã³3.0ïŒ ïŒã¬ã©ã¹ãåºæºïŒã®ã¹ããªããã³ã°
ïŒstrippedïŒEPONâ828ïŒUPTESæ¿åºŠã®ãã®ã
è©Šéšããã 第ïŒè¡šã¯è©Šéšçã®æº¶èæŒåºåã³å°åºæ圢åŸã®è€
åäœç¹æ§ã瀺ããEPONâ828ïŒUPTESãå«ã
è€åäœã¯24æéã®æ°Žæ²žéš°è©ŠéšåŸã«å¯Ÿç §è€åäœãã
åªããŠããããããŠãå¯Ÿç §è€åäœãšæ¯èŒããå Ž
åãé·æå ç±èåïŒ180âã§300æéïŒåŸã®è¡æå€
ã®ä¿æã«åªããŠããã å®æœäŸ 12 æšæºçæ··åãã¬ãŒããåããHobartã¹ãã³ã¬
ã¹ã»ã¹ããŒã«è£œæ··ååšãçšããŠãEpon 828 500
ïœåã³UPTESïŒã¡ã¿ããŒã«äž50ïŒ åºäœïŒ500ïœã
æ··åããŠã«ã«å ããç¶ããŠäœéã§æ¹æãããå¥ã®
å®éšããããã®æ··åç©ã¯ äžåäžæ§ã§ããïŒUPTESåºäœãæéãšå ±ã«æ²
殿ãããããããªãããæ²æ®¿ãçããåã«ãã®æ··
åç©ãç³è±ã¬ã©ã¹è£œç¶ã«ç§»ããããããã³ã«ã¯æ
ããããã®ç¶ã®å 容ç©ã50âã«èšå®ãã氎济äžã«
眮ããããã®æ··åç©ã50âã«ïŒæéæãããç¶ã
ãŠç¶åã³å 容ç©ãå·åŽããã補é ïŒãæåŸã«æ²æ®¿
ã¯å šãçããªãã€ãããã®æ··åç©ã¯éæã§ããã
ãŠåäžã§ãã€ãïŒçæç©ïŒãåç §ïŒã å®æœäŸ 13 å®æœäŸïŒã«èšèŒã®å®éšã«ããçŽ25ïŒ ã®ã¡ã¿ããŒ
ã«ãå«ãéæã§åäžãæ··åç©UPTESãã補é ã
ããå®æœäŸïŒã«èšèŒã®éããç空ãçšããŠ50âã®
å ç±ãµã€ã¯ã«ïŒæéã«ç¶ããŠçŽã¡ã«ã¡ã¿ããŒã«ã®
é€å»ãè¡ã€ããéæã§ãåäžã§ãããç²çš ãªçæ
ç©ãçããã å®æœäŸ 14â15 第ïŒè¡šã¯éæã§äžã€åäžãªå®æœäŸïŒåã³Epon
828ïŒDCSé åäœã®æ··åç©ãå«ã40ïŒ whitexç²å
å ãŠãããããã€ãã³è€åäœã®ç¹æ§ã瀺ããå šäœ
ã«ãããã®è€åäœã¯ç¹ã«æ²žéš°æ°Žã«72æéæããåŸ
ã«å¯Ÿç §è€åäœããåªããŠããããŸããã®å®éšã§ã¯
æ·»å å€ã®å€ç§»æ§ïŒversatilityïŒãææãããã å¯Ÿç §è€åäœãšæ¯èŒããå Žåããšããã·æš¹è
ïŒEpon 828ïŒã¯40ïŒ ã±ã€ç°ç³ïŒNyco Corp.補ã®
NYADGçŽïŒãå ãŠãããPBTïŒPETè€åäœã®
æ圢ç¹æ§ãäºå®æ¹åããããšã確èªãããããã®
ããšã¯40ïŒ ãçŒç²åïŒFreeportâKaolin補ã®
Whitexç²åïŒãå ãŠãããPBTïŒPETã«ããã
ãšããã·æš¹èæ§èœãšå¯Ÿç §çã§ãã€ãããã®å Žåã
æ圢ãããŸãŸã®è€åäœã®è¡æå€ãæ¹åãããã®ã¿
ã§ããããããŠåæ¥çã«ã¯èš±å®¹ãããªãé倧ãªæ¿
ãè²èª¿ã®å€åãè€åäœã«çããã
ãè¡šã
ãè¡šã
泚ïŒæåããããªç¿äžã§æ··åããã«ããŒã
ãããããŠç¡¬ãæš¹èç¶å¡ã®çæã®
城åã芳å¯ããã
ãããããŠç¡¬ãæš¹èç¶å¡ã®çæã®
城åã芳å¯ããã
ãè¡šã
ãè¡šã
å€ããã€ãŒãã»ãã³ãïŒã€ã³ã
泚ïŒ(IB)ïŒå®å šé å
(PT)ïŒå ãŠãå€äžã§äºååŠç
ïŒ 300ãã§4æé也ç¥ããæš¹è
泚ïŒ(IB)ïŒå®å šé å
(PT)ïŒå ãŠãå€äžã§äºååŠç
ïŒ 300ãã§4æé也ç¥ããæš¹è
ãè¡šã
ãè¡šã
ãè¡æå€ããã€ãŒãã»ãã³
ãïŒã€ã³ã
ãïŒã€ã³ã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ å ãŠãå€ãšæ·»å å€ãããªãå ãŠãå€çµæç©å
ã³çž®åéåäœãããªãçž®åéåäœè€åç©ã§ãã€
ãŠã該添å å€ããåŒ åŒäžãR1ãR2ãR3åã³R4ã¯ããããç¬ç«ããŠ
ã¢ã«ãã«ãã¢ãªãŒã«ãã¢ã«ã±ãã«ããšããã·ãæ
æ©ã·ãªã«åã³æ°ŽçŽ ã®çŸ€ããéžã°ããåºã§ããã ã§è¡šãããããªãã·ã©ã³ååç©ïŒã95ééïŒ äžŠã³
ã«å°ãªããšãïŒã€ã®ã¢ã·ã«ã¢ããã·ã©ã³çµå åŒäžãã¯ã¢ã«ãã¬ã³åã¯ã¢ãªãŒã¬ã³åºã§ã
ãã ãå«ãã¢ã·ã«ã¢ããã·ã©ã³åã³å°ãªããšãïŒã€ã®
ã·ã¢ãã·ã©ã³çµå â¡CRSiâ¡ åŒäžãã¯ã¢ã«ãã¬ã³åã¯ã¢ãªãŒã¬ã³åºã§ã
ãã ãå«ãã·ã¢ãã·ã©ã³åã³ãããã®çµã¿åããã®çŸ€
ããéžã°ããææ©ã±ã€çŽ 95ãïŒééïŒ ãããªãæ
æ©ã±ã€çŽ ïŒãªãã·ã©ã³çµæç©ãã§ããããšãç¹åŸŽ
ãšãããçž®åéåäœè€åç©ã ïŒ å ãŠãå€ãç²åã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®çž®åéåäœè€åç©ã ïŒ å ãŠãå€ãé²æ¯ã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®çž®åéåäœè€åç©ã ïŒ å ãŠãå€ãã±ã€ç°ç³ã§ãããç¹èš±è«æ±ã®ç¯å²
第ïŒé èšèŒã®çž®åéåäœè€åç©ã ïŒ å ãŠãå€ãããšããã³ã°ãããã¬ã©ã¹ã§ã
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çž®åéåäœè€å
ç©ã ïŒ è©²å ãŠãå€ãšè©²æ·»å å€ã®å®å šæ··åã«ããããŸ
ãã¯åŒ·åæ··ååšã«ããã該å ãŠãå€ã該添å å€ã§
äºååŠçããŠè£œé ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒ
ã®çž®åéåäœè€åç©ã ïŒ å ãŠãå€çµæç©ãããã®ééãåºæºãšããŠ80
ã99.98ééïŒ ã®å ãŠãå€åã³20ã0.02ééïŒ ã®
æ·»å å€ãããªãããšãç¹åŸŽãšããç¹èš±è«æ±ã®ç¯å²
第ïŒé èšèŒã®çž®åéåäœè€åç©ã ïŒ ïŒã85ééïŒ ã®å ãŠãå€çµæç©åã³95ã15é
éïŒ ã®çž®åéåäœãããªãããšãç¹åŸŽãšããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çž®åéåäœè€åç©ã ïŒ çž®åéåäœãããªãšã¹ãã«ãããªã¢ãããã
ãªãšã¹ãã«ïŒããªã¢ããæ··åç©ããŸãã¯å°ããšã
äžçš®ã®ãã®ä»ã®ããªããŒãšããªãšã¹ãã«ãããªã¢
ããããŸãã¯ããªãšã¹ãã«ïŒããªã¢ããæ··åç©ã§
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çž®åéåäœè€å
ç©ã ïŒïŒ çž®åéåäœãããªããã¬ã³ãã¬ãã¿ã¬ãŒã
ã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çž®åéåäœ
è€åç©ã ïŒïŒ çž®åéåäœãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒã
ã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çž®åéåäœ
è€åç©ã ïŒïŒ çž®åéåäœãããªã¢ãããã€ãã³ææã§ã
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çž®åéåäœè€å
ç©ã ïŒïŒ ææ©ã±ã€çŽ ïŒãªãã·ã©ã³çµæç©ãã¢ã·ã«ã¢
ããã·ã©ã³ïŒãšããã·æš¹èçµæç©ã§ãããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®çž®åéåäœè€åç©ã ïŒïŒ ææ©ã±ã€çŽ ïŒãªãã·ã©ã³çµæç©ãã¢ã·ã«ã¢
ããã·ã©ã³ïŒãšããã·æš¹èçµæç©ã§ãããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®çž®åéåäœè€åç©ã ïŒïŒ ææ©ã±ã€çŽ ïŒãªãã·ã©ã³çµæç©ãã¢ã·ã«ã¢
ããã·ã©ã³ïŒãšããã·æš¹èçµæç©ã§ãããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®çž®åéåäœè€åç©ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/589,470 US4542174A (en) | 1984-03-14 | 1984-03-14 | Organosilicon/oxirane additives for filled condensation polymer composites |
| US589470 | 1990-09-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63241042A JPS63241042A (ja) | 1988-10-06 |
| JPH0471427B2 true JPH0471427B2 (ja) | 1992-11-13 |
Family
ID=24358154
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60048451A Granted JPS60208323A (ja) | 1984-03-14 | 1985-03-13 | ææ©ã±ã€çŽ ïŒãªãã·ã©ã³çµæç© |
| JP63040893A Granted JPS63241042A (ja) | 1984-03-14 | 1988-02-25 | çž®åéåäœè€åç© |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60048451A Granted JPS60208323A (ja) | 1984-03-14 | 1985-03-13 | ææ©ã±ã€çŽ ïŒãªãã·ã©ã³çµæç© |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4542174A (ja) |
| EP (1) | EP0154985A3 (ja) |
| JP (2) | JPS60208323A (ja) |
| KR (1) | KR850006701A (ja) |
| AU (1) | AU4108785A (ja) |
| CA (1) | CA1266343A (ja) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61126170A (ja) * | 1984-11-21 | 1986-06-13 | Toray Ind Inc | ããªã¢ããæš¹èçµæç© |
| DE3711225A1 (de) * | 1987-04-03 | 1988-10-13 | Wacker Chemie Gmbh | Verfahren zur verstaerkung des haftens von polymeren stoffen |
| JP2809638B2 (ja) * | 1988-04-13 | 1998-10-15 | æ ªåŒäŒç€Ÿããªãã¹ãã³ | åææš¹èçµæç© |
| JPH02149503U (ja) * | 1989-05-22 | 1990-12-20 | ||
| JP2574055B2 (ja) * | 1990-07-25 | 1997-01-22 | ããªãã©ã¹ããã¯ã¹æ ªåŒäŒç€Ÿ | ããªããã¬ã³ãã¬ãã¿ã¬ãŒã系暹èäžç©ºæ圢ååã³ãã®è£œé æ³ |
| JPH0613510U (ja) * | 1992-07-30 | 1994-02-22 | ç±åžå å®äº | éŽåºæ§é |
| US6515094B2 (en) | 2000-03-16 | 2003-02-04 | Crompton Corporation | Silicone amino-epoxy cross-linking system |
| US11299619B2 (en) * | 2011-07-01 | 2022-04-12 | The Boeing Company | Composite structure having an inorganic coating adhered thereto and method of making same |
| FR2997035B1 (fr) * | 2012-10-23 | 2016-07-01 | Arkema France | Procede de fabrication d'une piece composite thermoplastique, par injection-compression-moulage sous vide, dispositif de mise en Åuvre et piece ainsi obtenue |
| CN111138983B (zh) * | 2020-01-09 | 2022-09-13 | èå·åžæ°å¹¿ççµåè¡ä»œæéå ¬åž | äžç§ç¡ è¶å£°åŠè¶èåå ¶ç产æ¹æ³ |
| US11760900B2 (en) | 2021-10-27 | 2023-09-19 | Momentive Performance Materials Inc. | Condensation curable composition |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1237844A (en) * | 1968-12-30 | 1971-06-30 | Monsanto Co | Reinforced polymer compositions |
| US3833534A (en) * | 1969-12-24 | 1974-09-03 | Monsanto Co | Reinforced polyamide compositions and process of preparation thereof |
| US3855175A (en) * | 1970-09-01 | 1974-12-17 | Mitsubishi Petrochemical Co | Process for preparing novel glass fiber reinforced thermoplastic composition |
| JPS545420B2 (ja) * | 1973-12-26 | 1979-03-16 | ||
| US4203887A (en) * | 1978-01-19 | 1980-05-20 | General Electric Company | Modified polyester composition |
| JPS56850A (en) * | 1979-06-15 | 1981-01-07 | Dainippon Ink & Chem Inc | Glass bead-filled resin composition |
| JPS6036513B2 (ja) * | 1981-02-05 | 1985-08-21 | ãâã¬ã»ã·ãªã³âã³æ ªåŒäŒç€Ÿ | ç¹ç¶çšåŠçå€ |
| JPS5936143A (ja) * | 1982-08-20 | 1984-02-28 | Kuraray Co Ltd | åªããæ§èœãæããæš¹èçµæç© |
-
1984
- 1984-03-14 US US06/589,470 patent/US4542174A/en not_active Expired - Fee Related
-
1985
- 1985-03-01 CA CA000475575A patent/CA1266343A/en not_active Expired - Lifetime
- 1985-03-13 JP JP60048451A patent/JPS60208323A/ja active Granted
- 1985-03-13 EP EP85102856A patent/EP0154985A3/en not_active Withdrawn
- 1985-03-13 KR KR1019850001592A patent/KR850006701A/ko not_active Application Discontinuation
- 1985-04-12 AU AU41087/85A patent/AU4108785A/en not_active Abandoned
-
1988
- 1988-02-25 JP JP63040893A patent/JPS63241042A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63241042A (ja) | 1988-10-06 |
| KR850006701A (ko) | 1985-10-16 |
| AU4108785A (en) | 1985-10-03 |
| EP0154985A2 (en) | 1985-09-18 |
| EP0154985A3 (en) | 1986-05-14 |
| CA1266343A (en) | 1990-02-27 |
| US4542174A (en) | 1985-09-17 |
| JPS60208323A (ja) | 1985-10-19 |
| JPS6354307B2 (ja) | 1988-10-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4536531A (en) | Polyester resin composition | |
| US5965648A (en) | Poly(alkylene ether)s as plasticizers and flow aids in poly (1,4-cyclohexanedimethylene terephthalate) resins | |
| JPH0471427B2 (ja) | ||
| EP0020693B1 (en) | Copolyesters of polybutylene terephthalate | |
| US5122551A (en) | Glass filled copolyether-polyester compositions | |
| JPS5991149A (ja) | ããªã¢ããæåçµæç© | |
| JP3413523B2 (ja) | é«ããããç¹æ§ãæããããªãšã¹ãã«ïŒããªã«ãŒãããŒããã¬ã³ã | |
| JP2683442B2 (ja) | ããªã¢ãªãŒã¬ã³ãµã«ãã¡ã€ãæš¹èçµæç©åã³ãã®è£œé æ³ | |
| US6027818A (en) | Thermoplastic copolyester compositions modified with epoxide compounds | |
| GB1569345A (en) | Reinforced thermoplastic polyester composition having highvoltage breakdown resistance | |
| US5177132A (en) | Flame retardant resin composition | |
| US4271063A (en) | Thermoplastic molding compositions | |
| JP4154761B2 (ja) | ããªãšã¹ãã«æš¹èçµæç© | |
| US4889898A (en) | Thermoplastic polyester blends of improved impact resistance | |
| AU603741B2 (en) | Flame-retardant resin composition | |
| JPH07173394A (ja) | ç±å¯å¡æ§æš¹èçµæç© | |
| JPS61261346A (ja) | é£çæ§è³éŠæããªãšã¹ãã«æš¹èçµæç© | |
| JPS5853946A (ja) | æš¹èçµæç© | |
| JP2004531633A (ja) | èå æ°Žå解æ§ããªãšã¹ãã«ããã³ãããã補é ãããç©å | |
| JPS5938265B2 (ja) | ããªã¢ãªâã¬ã³ãšã¹ãã«çµæç© | |
| KR940001074B1 (ko) | íŽëŠ¬ìì€í 륎 ìì§ ì¡°ì±ë¬Œ | |
| EP0384138A2 (en) | Blends of polyesters and high flow polycarbonate | |
| JPH09249807A (ja) | ããªã¢ããçšæ»å€ããã³ãããå«æããããªã¢ããçµæç© | |
| CA2039795A1 (en) | Glass filled copolyether-polyester compositions | |
| JPH03128963A (ja) | ããªãšã¹ãã«æš¹èçµæç© |