JPH0465151B2 - - Google Patents
Info
- Publication number
- JPH0465151B2 JPH0465151B2 JP60287615A JP28761585A JPH0465151B2 JP H0465151 B2 JPH0465151 B2 JP H0465151B2 JP 60287615 A JP60287615 A JP 60287615A JP 28761585 A JP28761585 A JP 28761585A JP H0465151 B2 JPH0465151 B2 JP H0465151B2
- Authority
- JP
- Japan
- Prior art keywords
- phosphate
- weight
- hydroxylamine
- cold working
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 73
- 239000010452 phosphate Substances 0.000 claims abstract description 72
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 68
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000000314 lubricant Substances 0.000 claims abstract description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims description 44
- 239000002184 metal Substances 0.000 claims description 44
- 238000005482 strain hardening Methods 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 25
- -1 ferrous metals Chemical class 0.000 claims description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- 229930195729 fatty acid Natural products 0.000 claims description 14
- 150000004665 fatty acids Chemical class 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 8
- 239000000344 soap Substances 0.000 claims description 8
- 238000005461 lubrication Methods 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 238000000576 coating method Methods 0.000 abstract description 33
- 239000011248 coating agent Substances 0.000 abstract description 27
- 229910052725 zinc Inorganic materials 0.000 abstract description 17
- 239000011701 zinc Substances 0.000 abstract description 17
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract description 15
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 15
- 230000002378 acidificating effect Effects 0.000 abstract description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 229910001959 inorganic nitrate Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 150000002828 nitro derivatives Chemical class 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 description 68
- 239000000243 solution Substances 0.000 description 56
- 239000000126 substance Substances 0.000 description 29
- 238000006243 chemical reaction Methods 0.000 description 15
- 230000001050 lubricating effect Effects 0.000 description 14
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 12
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229910001463 metal phosphate Inorganic materials 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 229910001448 ferrous ion Inorganic materials 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 235000011007 phosphoric acid Nutrition 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 4
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 229910001447 ferric ion Inorganic materials 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 150000002443 hydroxylamines Chemical class 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 229940114930 potassium stearate Drugs 0.000 description 2
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000000641 cold extrusion Methods 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- HYYHQASRTSDPOD-UHFFFAOYSA-N hydroxylamine;phosphoric acid Chemical compound ON.OP(O)(O)=O HYYHQASRTSDPOD-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052827 phosphophyllite Inorganic materials 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000002424 x-ray crystallography Methods 0.000 description 1
- NPJHXSZKSBSLLK-UHFFFAOYSA-L zinc;2-hydroxyoctadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCC(O)C([O-])=O.CCCCCCCCCCCCCCCCC(O)C([O-])=O NPJHXSZKSBSLLK-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/13—Orthophosphates containing zinc cations containing also nitrate or nitrite anions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
- C23C22/182—Orthophosphates containing manganese cations containing also zinc cations
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Chemical Treatment Of Metals (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Forging (AREA)
- Mounting, Exchange, And Manufacturing Of Dies (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Glass Compositions (AREA)
- Non-Reversible Transmitting Devices (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Materials For Medical Uses (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68384184A | 1984-12-20 | 1984-12-20 | |
| US683841 | 1984-12-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61157684A JPS61157684A (ja) | 1986-07-17 |
| JPH0465151B2 true JPH0465151B2 (pt) | 1992-10-19 |
Family
ID=24745668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60287615A Granted JPS61157684A (ja) | 1984-12-20 | 1985-12-20 | 鉄系金属の冷間加工用潤滑処理方法 |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0186823B1 (pt) |
| JP (1) | JPS61157684A (pt) |
| AT (1) | ATE63575T1 (pt) |
| AU (1) | AU577424B2 (pt) |
| CA (1) | CA1257527A (pt) |
| DE (2) | DE3582873D1 (pt) |
| ES (1) | ES8703943A1 (pt) |
| GB (1) | GB2169620B (pt) |
| ZA (1) | ZA859171B (pt) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5234509A (en) * | 1984-12-20 | 1993-08-10 | Henkel Corporation | Cold deformation process employing improved lubrication coating |
| DE3636390A1 (de) * | 1986-10-25 | 1988-04-28 | Metallgesellschaft Ag | Verfahren zur erzeugung von phosphatueberzuegen auf metallen |
| DE3712339A1 (de) * | 1987-04-11 | 1988-10-20 | Metallgesellschaft Ag | Verfahren zur phosphatierung vor der elektrotauchlackierung |
| US5236565A (en) * | 1987-04-11 | 1993-08-17 | Metallgesellschaft Aktiengesellschaft | Process of phosphating before electroimmersion painting |
| US4865653A (en) * | 1987-10-30 | 1989-09-12 | Henkel Corporation | Zinc phosphate coating process |
| DE3800835A1 (de) * | 1988-01-14 | 1989-07-27 | Henkel Kgaa | Verfahren zur phosphatierung von metalloberflaechen |
| DE58905074D1 (de) * | 1988-02-03 | 1993-09-09 | Metallgesellschaft Ag | Verfahren zur erzeugung von phosphatueberzuegen auf metallen. |
| ZA903498B (en) * | 1989-05-19 | 1992-01-29 | Henkel Corp | Composition and process for zinc phosphating |
| DE4210513A1 (de) * | 1992-03-31 | 1993-10-07 | Henkel Kgaa | Nickel-freie Phosphatierverfahren |
| LT4252B (en) | 1996-12-18 | 1997-12-29 | Chemijos Inst | Method for the formation of the phosphatic coatings on the surface of steel |
| DE19716075A1 (de) * | 1997-04-17 | 1998-10-22 | Henkel Kgaa | Mit Hydroxylamin und Chlorat beschleunigtes Phosphatierverfahren |
| DE19808440C2 (de) | 1998-02-27 | 2000-08-24 | Metallgesellschaft Ag | Wässrige Lösung und Verfahren zur Phosphatierung metallischer Oberflächen sowie eine Verwendung der Lösung und des Verfahrens |
| JP2004068068A (ja) * | 2002-08-05 | 2004-03-04 | Nippon Parkerizing Co Ltd | 複合材、その製造方法 |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2298280A (en) * | 1939-02-02 | 1942-10-13 | Parker Rust Proof Co | Treatment of metal |
| US2702768A (en) * | 1948-07-23 | 1955-02-22 | Parker Rust Proof Co | Ferrous surface coating process using alkali metal phosphates and hydroxylamines |
| US2928762A (en) * | 1955-08-09 | 1960-03-15 | Neilson Chemical Company | Phosphate coating of metals |
| JPS50143736A (pt) * | 1974-04-22 | 1975-11-19 | ||
| JPS513695A (pt) * | 1974-06-28 | 1976-01-13 | Hitachi Ltd | |
| JPS51125653A (en) * | 1975-01-24 | 1976-11-02 | Nippon Steel Corp | Cold working rust preventive lubricating steel material |
| US4003761A (en) * | 1974-04-13 | 1977-01-18 | Gerhard Collardin Gmbh | Process for the production of sprayed phosphate coats on iron and steel |
| US4149909A (en) * | 1977-12-30 | 1979-04-17 | Amchem Products, Inc. | Iron phosphate accelerator |
| US4220486A (en) * | 1978-10-30 | 1980-09-02 | Nihon Parkerizing Co., Ltd. | Conversion coating solution for treating metallic surfaces |
| JPS57152473A (en) * | 1981-03-06 | 1982-09-20 | Metallgesellschaft Ag | Manufacture of phosphate film on metal surface |
| JPS58213880A (ja) * | 1982-06-04 | 1983-12-12 | Nippon Parkerizing Co Ltd | 鉄鋼材の冷間加工潤滑処理方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE432557A (pt) * | 1938-02-04 | |||
| DE1072055B (pt) * | 1952-08-28 | |||
| FR1172741A (fr) * | 1956-02-27 | 1959-02-13 | Parker Ste Continentale | Solution de phosphatation et procédé de revêtement à l'aide de cette solution |
| AT233914B (de) * | 1959-07-25 | 1964-06-10 | Stefan Dr Klinghoffer | Verfahren zur Verbesserung der Korrosionsbeständigkeit von Eisen, Stahl und Eisenlegierungen durch Aufbringen einer Phosphatschicht |
| US3839099A (en) * | 1972-07-27 | 1974-10-01 | Amchem Prod | Iron-phosphate coating for tin-plated ferrous metal surfaces |
| US3923554A (en) * | 1974-02-07 | 1975-12-02 | Detrex Chem Ind | Phosphate coating composition and method |
| JPS5811513B2 (ja) * | 1979-02-13 | 1983-03-03 | 日本ペイント株式会社 | 金属表面の保護方法 |
| DE3023479A1 (de) * | 1980-06-24 | 1982-01-14 | Metallgesellschaft Ag, 6000 Frankfurt | Phosphatierverfahren |
| DE3311738A1 (de) * | 1983-03-31 | 1984-10-04 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur phosphatierung von metalloberflaechen |
-
1985
- 1985-11-27 CA CA000496351A patent/CA1257527A/en not_active Expired
- 1985-11-29 AU AU50522/85A patent/AU577424B2/en not_active Ceased
- 1985-11-29 ZA ZA859171A patent/ZA859171B/xx unknown
- 1985-12-11 DE DE8585115775T patent/DE3582873D1/de not_active Expired - Fee Related
- 1985-12-11 EP EP85115775A patent/EP0186823B1/de not_active Expired - Lifetime
- 1985-12-11 AT AT85115775T patent/ATE63575T1/de active
- 1985-12-11 DE DE19853543733 patent/DE3543733A1/de not_active Withdrawn
- 1985-12-18 ES ES550112A patent/ES8703943A1/es not_active Expired
- 1985-12-20 GB GB08531408A patent/GB2169620B/en not_active Expired
- 1985-12-20 JP JP60287615A patent/JPS61157684A/ja active Granted
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2298280A (en) * | 1939-02-02 | 1942-10-13 | Parker Rust Proof Co | Treatment of metal |
| US2702768A (en) * | 1948-07-23 | 1955-02-22 | Parker Rust Proof Co | Ferrous surface coating process using alkali metal phosphates and hydroxylamines |
| US2928762A (en) * | 1955-08-09 | 1960-03-15 | Neilson Chemical Company | Phosphate coating of metals |
| US4003761A (en) * | 1974-04-13 | 1977-01-18 | Gerhard Collardin Gmbh | Process for the production of sprayed phosphate coats on iron and steel |
| JPS50143736A (pt) * | 1974-04-22 | 1975-11-19 | ||
| JPS513695A (pt) * | 1974-06-28 | 1976-01-13 | Hitachi Ltd | |
| JPS51125653A (en) * | 1975-01-24 | 1976-11-02 | Nippon Steel Corp | Cold working rust preventive lubricating steel material |
| US4149909A (en) * | 1977-12-30 | 1979-04-17 | Amchem Products, Inc. | Iron phosphate accelerator |
| US4220486A (en) * | 1978-10-30 | 1980-09-02 | Nihon Parkerizing Co., Ltd. | Conversion coating solution for treating metallic surfaces |
| JPS57152473A (en) * | 1981-03-06 | 1982-09-20 | Metallgesellschaft Ag | Manufacture of phosphate film on metal surface |
| JPS58213880A (ja) * | 1982-06-04 | 1983-12-12 | Nippon Parkerizing Co Ltd | 鉄鋼材の冷間加工潤滑処理方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU577424B2 (en) | 1988-09-22 |
| ZA859171B (en) | 1986-08-27 |
| DE3582873D1 (de) | 1991-06-20 |
| EP0186823A2 (de) | 1986-07-09 |
| GB2169620B (en) | 1988-05-11 |
| GB8531408D0 (en) | 1986-02-05 |
| EP0186823B1 (de) | 1991-05-15 |
| EP0186823A3 (en) | 1988-04-27 |
| ES550112A0 (es) | 1987-03-16 |
| ES8703943A1 (es) | 1987-03-16 |
| AU5052285A (en) | 1986-06-26 |
| DE3543733A1 (de) | 1986-07-03 |
| CA1257527A (en) | 1989-07-18 |
| ATE63575T1 (de) | 1991-06-15 |
| GB2169620A (en) | 1986-07-16 |
| JPS61157684A (ja) | 1986-07-17 |
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