JPH0426628B2 - - Google Patents
Info
- Publication number
- JPH0426628B2 JPH0426628B2 JP62281516A JP28151687A JPH0426628B2 JP H0426628 B2 JPH0426628 B2 JP H0426628B2 JP 62281516 A JP62281516 A JP 62281516A JP 28151687 A JP28151687 A JP 28151687A JP H0426628 B2 JPH0426628 B2 JP H0426628B2
- Authority
- JP
- Japan
- Prior art keywords
- vinyl
- vinyl chloride
- isocyanate
- compound
- poly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 40
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 28
- LVLANIHJQRZTPY-UHFFFAOYSA-N vinyl carbamate Chemical group NC(=O)OC=C LVLANIHJQRZTPY-UHFFFAOYSA-N 0.000 claims description 28
- -1 isocyanate compound Chemical class 0.000 claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 239000012948 isocyanate Substances 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 13
- 150000007524 organic acids Chemical class 0.000 claims description 10
- 229920006163 vinyl copolymer Polymers 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 12
- 239000002585 base Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 150000002430 hydrocarbons Chemical group 0.000 description 10
- 239000004800 polyvinyl chloride Substances 0.000 description 10
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 8
- 238000007127 saponification reaction Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 150000002513 isocyanates Chemical class 0.000 description 6
- QWDQYHPOSSHSAW-UHFFFAOYSA-N 1-isocyanatooctadecane Chemical compound CCCCCCCCCCCCCCCCCCN=C=O QWDQYHPOSSHSAW-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- XFEWMFDVBLLXFE-UHFFFAOYSA-N 1-isocyanatodecane Chemical compound CCCCCCCCCCN=C=O XFEWMFDVBLLXFE-UHFFFAOYSA-N 0.000 description 1
- ODDFKRTWSQGENK-UHFFFAOYSA-N 1-isocyanatodocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCN=C=O ODDFKRTWSQGENK-UHFFFAOYSA-N 0.000 description 1
- YIDSTEJLDQMWBR-UHFFFAOYSA-N 1-isocyanatododecane Chemical compound CCCCCCCCCCCCN=C=O YIDSTEJLDQMWBR-UHFFFAOYSA-N 0.000 description 1
- DENCZFRTPQHXBD-UHFFFAOYSA-N 1-isocyanatodotriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCN=C=O DENCZFRTPQHXBD-UHFFFAOYSA-N 0.000 description 1
- YTLOZRAQBILOFJ-UHFFFAOYSA-N 1-isocyanatohexacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCN=C=O YTLOZRAQBILOFJ-UHFFFAOYSA-N 0.000 description 1
- GFLXBRUGMACJLQ-UHFFFAOYSA-N 1-isocyanatohexadecane Chemical compound CCCCCCCCCCCCCCCCN=C=O GFLXBRUGMACJLQ-UHFFFAOYSA-N 0.000 description 1
- RWCDAKQLMGCVLI-UHFFFAOYSA-N 1-isocyanatoicosane Chemical compound CCCCCCCCCCCCCCCCCCCCN=C=O RWCDAKQLMGCVLI-UHFFFAOYSA-N 0.000 description 1
- AOMWQNAKLINEBU-UHFFFAOYSA-N 1-isocyanatononacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCN=C=O AOMWQNAKLINEBU-UHFFFAOYSA-N 0.000 description 1
- XDCBSPQSPOCKEV-UHFFFAOYSA-N 1-isocyanatononadecane Chemical compound CCCCCCCCCCCCCCCCCCCN=C=O XDCBSPQSPOCKEV-UHFFFAOYSA-N 0.000 description 1
- DLGUAUVHTOCKTB-UHFFFAOYSA-N 1-isocyanatononane Chemical compound CCCCCCCCCN=C=O DLGUAUVHTOCKTB-UHFFFAOYSA-N 0.000 description 1
- BCHGIKGGESSNON-UHFFFAOYSA-N 1-isocyanatooctacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCN=C=O BCHGIKGGESSNON-UHFFFAOYSA-N 0.000 description 1
- DYQFCTCUULUMTQ-UHFFFAOYSA-N 1-isocyanatooctane Chemical compound CCCCCCCCN=C=O DYQFCTCUULUMTQ-UHFFFAOYSA-N 0.000 description 1
- LQVNCYGVUCRMMT-UHFFFAOYSA-N 1-isocyanatopentacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCN=C=O LQVNCYGVUCRMMT-UHFFFAOYSA-N 0.000 description 1
- HULTVDSPXGVYBQ-UHFFFAOYSA-N 1-isocyanatopentadecane Chemical compound CCCCCCCCCCCCCCCN=C=O HULTVDSPXGVYBQ-UHFFFAOYSA-N 0.000 description 1
- CXALGFGVGGHZGI-UHFFFAOYSA-N 1-isocyanatotetracosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCN=C=O CXALGFGVGGHZGI-UHFFFAOYSA-N 0.000 description 1
- CSMJMAQKBKGDQX-UHFFFAOYSA-N 1-isocyanatotetradecane Chemical compound CCCCCCCCCCCCCCN=C=O CSMJMAQKBKGDQX-UHFFFAOYSA-N 0.000 description 1
- HYUGWGDRJJGQEQ-UHFFFAOYSA-N 1-isocyanatotricosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCN=C=O HYUGWGDRJJGQEQ-UHFFFAOYSA-N 0.000 description 1
- BAZBBHGFCBVAQU-UHFFFAOYSA-N 1-isocyanatotridecane Chemical compound CCCCCCCCCCCCCN=C=O BAZBBHGFCBVAQU-UHFFFAOYSA-N 0.000 description 1
- JXAYHHMVMJVFPQ-UHFFFAOYSA-N 1-isocyanatoundecane Chemical compound CCCCCCCCCCCN=C=O JXAYHHMVMJVFPQ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229940057867 methyl lactate Drugs 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesive Tapes (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62281516A JPH01123878A (ja) | 1987-11-07 | 1987-11-07 | 剥離剤及びその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62281516A JPH01123878A (ja) | 1987-11-07 | 1987-11-07 | 剥離剤及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01123878A JPH01123878A (ja) | 1989-05-16 |
| JPH0426628B2 true JPH0426628B2 (Direct) | 1992-05-07 |
Family
ID=17640269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62281516A Granted JPH01123878A (ja) | 1987-11-07 | 1987-11-07 | 剥離剤及びその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01123878A (Direct) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023053735A1 (ja) * | 2021-09-29 | 2023-04-06 | Ａｇｃ株式会社 | 重合体、重合体の製造方法、撥水撥油剤組成物及び物品 |
-
1987
- 1987-11-07 JP JP62281516A patent/JPH01123878A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01123878A (ja) | 1989-05-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0024908B1 (en) | Release agent and products comprising a coating thereof | |
| EP0099675B1 (en) | Polymerisable compounds, their preparation and adhesive surgical or medical dressing comprising these compounds | |
| JPH0210193B2 (Direct) | ||
| JPS595155B2 (ja) | 可撓性フィルム | |
| JP5471183B2 (ja) | 接着剤用組成物 | |
| JPH0426628B2 (Direct) | ||
| JPS6281475A (ja) | 剥離性処理剤及びその製造法 | |
| JPH0474362B2 (Direct) | ||
| JPH0386778A (ja) | 水性剥離剤およびその製造方法 | |
| JPS60169490A (ja) | アルケニルアシロキシシラン、その製造法および該化合物を含有する接着剤 | |
| EP0287306B1 (en) | Removable pressure-sensitive adhesive tape | |
| JPS6269898A (ja) | 紙コ−テイング用水溶性樹脂組成物 | |
| JPS62116680A (ja) | 粘着剤組成物 | |
| JPS6281476A (ja) | 剥離性処理剤及びその製造法 | |
| JPS6372778A (ja) | 剥離性処理層 | |
| US5147924A (en) | Selectively soluble, protective coating compositions derived from vinyl acetate/monoalkyl maleate copolymers | |
| JP3105695B2 (ja) | 剥離剤 | |
| KR840000442B1 (ko) | 박리제(剝離劑) | |
| JPH0428002B2 (Direct) | ||
| JP2762464B2 (ja) | ブロッキング防止剤被覆ポリエステルフィルム | |
| US4117241A (en) | Polymerizable materials | |
| JPS63225685A (ja) | 剥離性処理剤 | |
| JPS5959767A (ja) | エチレン性不飽和基を有する化合物から成るコポリマ−をベ−スとする感圧接着剤 | |
| JPH01146983A (ja) | 剥離剤 | |
| JPH0257111B2 (Direct) |