JPH0376736B2 - - Google Patents
Info
- Publication number
- JPH0376736B2 JPH0376736B2 JP59160860A JP16086084A JPH0376736B2 JP H0376736 B2 JPH0376736 B2 JP H0376736B2 JP 59160860 A JP59160860 A JP 59160860A JP 16086084 A JP16086084 A JP 16086084A JP H0376736 B2 JPH0376736 B2 JP H0376736B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- dye
- silver
- image
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 silver halide Chemical class 0.000 claims description 122
- 239000000126 substance Substances 0.000 claims description 62
- 239000000463 material Substances 0.000 claims description 38
- 229910052709 silver Inorganic materials 0.000 claims description 36
- 239000004332 silver Substances 0.000 claims description 36
- 150000001875 compounds Chemical class 0.000 claims description 26
- 125000001424 substituent group Chemical group 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 19
- 239000011230 binding agent Substances 0.000 claims description 16
- 125000000623 heterocyclic group Chemical group 0.000 claims description 16
- 239000003638 chemical reducing agent Substances 0.000 claims description 11
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 10
- 125000003545 alkoxy group Chemical group 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 125000004442 acylamino group Chemical group 0.000 claims description 8
- 125000004104 aryloxy group Chemical group 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 7
- 125000003277 amino group Chemical group 0.000 claims description 6
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 claims description 5
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 79
- 239000000975 dye Substances 0.000 description 46
- 238000000034 method Methods 0.000 description 37
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 24
- 239000002904 solvent Substances 0.000 description 20
- 238000011161 development Methods 0.000 description 16
- 238000012546 transfer Methods 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 239000006185 dispersion Substances 0.000 description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 11
- 108010010803 Gelatin Proteins 0.000 description 10
- 229920000159 gelatin Polymers 0.000 description 10
- 239000008273 gelatin Substances 0.000 description 10
- 235000019322 gelatine Nutrition 0.000 description 10
- 235000011852 gelatine desserts Nutrition 0.000 description 10
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical group CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000009835 boiling Methods 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Chemical group 0.000 description 6
- 239000002184 metal Chemical group 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 150000003378 silver Chemical class 0.000 description 6
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical group NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 206010070834 Sensitisation Diseases 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 230000008313 sensitization Effects 0.000 description 5
- 125000000565 sulfonamide group Chemical group 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 239000005457 ice water Substances 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 229940043375 1,5-pentanediol Drugs 0.000 description 3
- WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 3
- WVKWKEWFTVEVCF-UHFFFAOYSA-N 2h-benzotriazole-4-sulfonic acid Chemical class OS(=O)(=O)C1=CC=CC2=NNN=C12 WVKWKEWFTVEVCF-UHFFFAOYSA-N 0.000 description 3
- PLYFWZGSBMDRKW-UHFFFAOYSA-N 2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=CC=CC2=NNN=C12 PLYFWZGSBMDRKW-UHFFFAOYSA-N 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium on carbon Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 3
- 229910001864 baryta Inorganic materials 0.000 description 3
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 125000004093 cyano group Chemical group *C#N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 3
- 150000002832 nitroso derivatives Chemical class 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 150000007530 organic bases Chemical class 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
- LUBJCRLGQSPQNN-UHFFFAOYSA-N 1-Phenylurea Chemical compound NC(=O)NC1=CC=CC=C1 LUBJCRLGQSPQNN-UHFFFAOYSA-N 0.000 description 2
- NQMUGNMMFTYOHK-UHFFFAOYSA-N 1-methoxynaphthalene Chemical compound C1=CC=C2C(OC)=CC=CC2=C1 NQMUGNMMFTYOHK-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- AFBBKYQYNPNMAT-UHFFFAOYSA-N 1h-1,2,4-triazol-1-ium-3-thiolate Chemical compound SC=1N=CNN=1 AFBBKYQYNPNMAT-UHFFFAOYSA-N 0.000 description 2
- SGWZVZZVXOJRAQ-UHFFFAOYSA-N 2,6-Dimethyl-1,4-benzenediol Chemical compound CC1=CC(O)=CC(C)=C1O SGWZVZZVXOJRAQ-UHFFFAOYSA-N 0.000 description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 2
- JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 description 2
- LQZMLBORDGWNPD-UHFFFAOYSA-N N-iodosuccinimide Chemical compound IN1C(=O)CCC1=O LQZMLBORDGWNPD-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 2
- 125000004414 alkyl thio group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- 125000004391 aryl sulfonyl group Chemical group 0.000 description 2
- 125000005110 aryl thio group Chemical group 0.000 description 2
- 125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 2
- KHBQMWCZKVMBLN-IDEBNGHGSA-N benzenesulfonamide Chemical group NS(=O)(=O)[13C]1=[13CH][13CH]=[13CH][13CH]=[13CH]1 KHBQMWCZKVMBLN-IDEBNGHGSA-N 0.000 description 2
- XSCHRSMBECNVNS-UHFFFAOYSA-N benzopyrazine Natural products N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 2
- 125000001164 benzothiazolyl group Chemical group S1C(=NC2=C1C=CC=C2)* 0.000 description 2
- 150000001565 benzotriazoles Chemical class 0.000 description 2
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 2
- 125000001584 benzyloxycarbonyl group Chemical group C(=O)(OCC1=CC=CC=C1)* 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 description 2
- DNSISZSEWVHGLH-UHFFFAOYSA-N butanamide Chemical group CCCC(N)=O DNSISZSEWVHGLH-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 125000004181 carboxyalkyl group Chemical group 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 238000004440 column chromatography Methods 0.000 description 2
- PFURGBBHAOXLIO-UHFFFAOYSA-N cyclohexane-1,2-diol Chemical compound OC1CCCCC1O PFURGBBHAOXLIO-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001240 enamine group Chemical group 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229960005219 gentisic acid Drugs 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 150000007857 hydrazones Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 125000002883 imidazolyl group Chemical group 0.000 description 2
- OKJPEAGHQZHRQV-UHFFFAOYSA-N iodoform Chemical compound IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 2
- HNQIVZYLYMDVSB-UHFFFAOYSA-N methanesulfonimidic acid Chemical group CS(N)(=O)=O HNQIVZYLYMDVSB-UHFFFAOYSA-N 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- HRRDCWDFRIJIQZ-UHFFFAOYSA-N naphthalene-1,8-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=CC2=C1 HRRDCWDFRIJIQZ-UHFFFAOYSA-N 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 description 2
- IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 description 2
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 125000004076 pyridyl group Chemical group 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 2
- 125000004964 sulfoalkyl group Chemical group 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000001132 ultrasonic dispersion Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- GVTLFGJNTIRUEG-ZHACJKMWSA-N (e)-n-(3-methoxyphenyl)-3-phenylprop-2-enamide Chemical compound COC1=CC=CC(NC(=O)\C=C\C=2C=CC=CC=2)=C1 GVTLFGJNTIRUEG-ZHACJKMWSA-N 0.000 description 1
- TUMNHQRORINJKE-UHFFFAOYSA-N 1,1-diethylurea Chemical compound CCN(CC)C(N)=O TUMNHQRORINJKE-UHFFFAOYSA-N 0.000 description 1
- HGRZLIGHKHRTRE-UHFFFAOYSA-N 1,2,3,4-tetrabromobutane Chemical compound BrCC(Br)C(Br)CBr HGRZLIGHKHRTRE-UHFFFAOYSA-N 0.000 description 1
- OWQPOVKKUWUEKE-UHFFFAOYSA-N 1,2,3-benzotriazine Chemical compound N1=NN=CC2=CC=CC=C21 OWQPOVKKUWUEKE-UHFFFAOYSA-N 0.000 description 1
- UDATXMIGEVPXTR-UHFFFAOYSA-N 1,2,4-triazolidine-3,5-dione Chemical compound O=C1NNC(=O)N1 UDATXMIGEVPXTR-UHFFFAOYSA-N 0.000 description 1
- IZQGCATXOBZJQL-UHFFFAOYSA-N 1,3-benzothiazine-2,4-dione Chemical compound C1=CC=C2SC(=O)NC(=O)C2=C1 IZQGCATXOBZJQL-UHFFFAOYSA-N 0.000 description 1
- STOQYCJHYNCPTL-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione;silver Chemical compound [Ag].C1=CC=C2NC(=S)NC2=C1 STOQYCJHYNCPTL-UHFFFAOYSA-N 0.000 description 1
- GUMZPHOQHLZJOY-UHFFFAOYSA-N 1,3-oxazine-2,4-dione Chemical compound O=C1C=COC(=O)N1 GUMZPHOQHLZJOY-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical compound C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- UOJUPXODQRLOBQ-UHFFFAOYSA-N 1-(2-hydroxy-6-nitronaphthalen-1-yl)-6-nitronaphthalen-2-ol Chemical group [O-][N+](=O)C1=CC=C2C(C3=C4C=CC(=CC4=CC=C3O)[N+]([O-])=O)=C(O)C=CC2=C1 UOJUPXODQRLOBQ-UHFFFAOYSA-N 0.000 description 1
- ZPANWZBSGMDWON-UHFFFAOYSA-N 1-[(2-hydroxynaphthalen-1-yl)methyl]naphthalen-2-ol Chemical compound C1=CC=C2C(CC3=C4C=CC=CC4=CC=C3O)=C(O)C=CC2=C1 ZPANWZBSGMDWON-UHFFFAOYSA-N 0.000 description 1
- UNILWMWFPHPYOR-KXEYIPSPSA-M 1-[6-[2-[3-[3-[3-[2-[2-[3-[[2-[2-[[(2r)-1-[[2-[[(2r)-1-[3-[2-[2-[3-[[2-(2-amino-2-oxoethoxy)acetyl]amino]propoxy]ethoxy]ethoxy]propylamino]-3-hydroxy-1-oxopropan-2-yl]amino]-2-oxoethyl]amino]-3-[(2r)-2,3-di(hexadecanoyloxy)propyl]sulfanyl-1-oxopropan-2-yl Chemical compound O=C1C(SCCC(=O)NCCCOCCOCCOCCCNC(=O)COCC(=O)N[C@@H](CSC[C@@H](COC(=O)CCCCCCCCCCCCCCC)OC(=O)CCCCCCCCCCCCCCC)C(=O)NCC(=O)N[C@H](CO)C(=O)NCCCOCCOCCOCCCNC(=O)COCC(N)=O)CC(=O)N1CCNC(=O)CCCCCN\1C2=CC=C(S([O-])(=O)=O)C=C2CC/1=C/C=C/C=C/C1=[N+](CC)C2=CC=C(S([O-])(=O)=O)C=C2C1 UNILWMWFPHPYOR-KXEYIPSPSA-M 0.000 description 1
- WDRZVZVXHZNSFG-UHFFFAOYSA-N 1-ethenylpyridin-1-ium Chemical compound C=C[N+]1=CC=CC=C1 WDRZVZVXHZNSFG-UHFFFAOYSA-N 0.000 description 1
- IQIOOZJZTRAXTO-UHFFFAOYSA-M 1-ethyl-2H-1,3-thiazol-2-ylium bromide Chemical compound [Br-].CCS1=CC=N[CH+]1 IQIOOZJZTRAXTO-UHFFFAOYSA-M 0.000 description 1
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 description 1
- ULEQVBQWYCGDON-UHFFFAOYSA-N 1h-benzimidazole;silver Chemical compound [Ag].C1=CC=C2NC=NC2=C1 ULEQVBQWYCGDON-UHFFFAOYSA-N 0.000 description 1
- IWDUDCDZGOLTTJ-UHFFFAOYSA-N 1h-imidazole;silver Chemical compound [Ag].C1=CNC=N1 IWDUDCDZGOLTTJ-UHFFFAOYSA-N 0.000 description 1
- VLPZUANQXMDIPV-UHFFFAOYSA-N 1h-pyrazole;silver Chemical compound [Ag].C=1C=NNC=1 VLPZUANQXMDIPV-UHFFFAOYSA-N 0.000 description 1
- AVRPFRMDMNDIDH-UHFFFAOYSA-N 1h-quinazolin-2-one Chemical compound C1=CC=CC2=NC(O)=NC=C21 AVRPFRMDMNDIDH-UHFFFAOYSA-N 0.000 description 1
- MQCPOLNSJCWPGT-UHFFFAOYSA-N 2,2'-Bisphenol F Chemical class OC1=CC=CC=C1CC1=CC=CC=C1O MQCPOLNSJCWPGT-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- WNOVBLHBCHOXKD-UHFFFAOYSA-N 2,3-bis(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=C(O)C=CC(O)=C1C(C)(C)CC(C)(C)C WNOVBLHBCHOXKD-UHFFFAOYSA-N 0.000 description 1
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
- KGLPWQKSKUVKMJ-UHFFFAOYSA-N 2,3-dihydrophthalazine-1,4-dione Chemical compound C1=CC=C2C(=O)NNC(=O)C2=C1 KGLPWQKSKUVKMJ-UHFFFAOYSA-N 0.000 description 1
- CTOQUCNYLFHOAH-UHFFFAOYSA-N 2,3-dihydropyrrolo[2,3-d]triazole-5,6-dithione Chemical compound N1NN=C2C(=S)C(=S)N=C21 CTOQUCNYLFHOAH-UHFFFAOYSA-N 0.000 description 1
- GLDQAMYCGOIJDV-UHFFFAOYSA-N 2,3-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(O)=C1O GLDQAMYCGOIJDV-UHFFFAOYSA-N 0.000 description 1
- JFZFRIKFAXTVMP-UHFFFAOYSA-N 2,4-bis(3-tert-butyl-2-hydroxy-5-methylphenyl)-3-methylbicyclo[3.1.1]hepta-1,3,5-trien-6-ol Chemical compound C1C2=C(C1=C(C(=C2C1=C(C(=CC(=C1)C)C(C)(C)C)O)C)C1=C(C(=CC(=C1)C)C(C)(C)C)O)O JFZFRIKFAXTVMP-UHFFFAOYSA-N 0.000 description 1
- 125000004201 2,4-dichlorophenyl group Chemical group [H]C1=C([H])C(*)=C(Cl)C([H])=C1Cl 0.000 description 1
- LXWZXEJDKYWBOW-UHFFFAOYSA-N 2,4-ditert-butyl-6-[(3,5-ditert-butyl-2-hydroxyphenyl)methyl]phenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)C)C(C)(C)C)O)=C1O LXWZXEJDKYWBOW-UHFFFAOYSA-N 0.000 description 1
- QHPKIUDQDCWRKO-UHFFFAOYSA-N 2,6-ditert-butyl-4-[2-(3,5-ditert-butyl-4-hydroxyphenyl)propan-2-yl]phenol Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(C(C)(C)C=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 QHPKIUDQDCWRKO-UHFFFAOYSA-N 0.000 description 1
- PYMWDAQVSJGRIA-UHFFFAOYSA-N 2-(1-bromo-6-methylcyclohexa-2,4-dien-1-yl)acetamide Chemical compound CC1C=CC=CC1(Br)CC(N)=O PYMWDAQVSJGRIA-UHFFFAOYSA-N 0.000 description 1
- DYNQKTWPOTTWGS-UHFFFAOYSA-N 2-(1-bromo-6-methylcyclohexa-2,4-dien-1-yl)sulfonylacetamide Chemical compound CC1C=CC=CC1(Br)S(=O)(=O)CC(N)=O DYNQKTWPOTTWGS-UHFFFAOYSA-N 0.000 description 1
- DUUBQTCYVNKWFW-UHFFFAOYSA-N 2-(1-hydroxy-4-methoxynaphthalen-2-yl)-4-methoxynaphthalen-1-ol Chemical group C1=CC=CC2=C(O)C(C=3C=C(C4=CC=CC=C4C=3O)OC)=CC(OC)=C21 DUUBQTCYVNKWFW-UHFFFAOYSA-N 0.000 description 1
- AGUJUBACOOIWDV-UHFFFAOYSA-N 2-(1-hydroxynaphthalen-2-yl)naphthalen-1-ol Chemical group C1=CC=CC2=C(O)C(C3=C(C4=CC=CC=C4C=C3)O)=CC=C21 AGUJUBACOOIWDV-UHFFFAOYSA-N 0.000 description 1
- XXXFZKQPYACQLD-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl acetate Chemical compound CC(=O)OCCOCCO XXXFZKQPYACQLD-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- BBFDQRZRKYWUHY-UHFFFAOYSA-N 2-[(1-hydroxynaphthalen-2-yl)methyl]naphthalen-1-ol Chemical class C1=CC2=CC=CC=C2C(O)=C1CC1=CC=C(C=CC=C2)C2=C1O BBFDQRZRKYWUHY-UHFFFAOYSA-N 0.000 description 1
- SZAQZZKNQILGPU-UHFFFAOYSA-N 2-[1-(2-hydroxy-3,5-dimethylphenyl)-2-methylpropyl]-4,6-dimethylphenol Chemical compound C=1C(C)=CC(C)=C(O)C=1C(C(C)C)C1=CC(C)=CC(C)=C1O SZAQZZKNQILGPU-UHFFFAOYSA-N 0.000 description 1
- RPWDFMGIRPZGTI-UHFFFAOYSA-N 2-[1-(2-hydroxy-3,5-dimethylphenyl)-3,5,5-trimethylhexyl]-4,6-dimethylphenol Chemical compound C=1C(C)=CC(C)=C(O)C=1C(CC(C)CC(C)(C)C)C1=CC(C)=CC(C)=C1O RPWDFMGIRPZGTI-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- YAQLSKVCTLCIIE-UHFFFAOYSA-N 2-bromobutyric acid Chemical compound CCC(Br)C(O)=O YAQLSKVCTLCIIE-UHFFFAOYSA-N 0.000 description 1
- LDLCZOVUSADOIV-UHFFFAOYSA-N 2-bromoethanol Chemical compound OCCBr LDLCZOVUSADOIV-UHFFFAOYSA-N 0.000 description 1
- CQJNLNKTOGXYCH-UHFFFAOYSA-N 2-bromophthalazin-1-one Chemical compound C1=CC=C2C(=O)N(Br)N=CC2=C1 CQJNLNKTOGXYCH-UHFFFAOYSA-N 0.000 description 1
- SZTBMYHIYNGYIA-UHFFFAOYSA-M 2-chloroacrylate Chemical compound [O-]C(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-M 0.000 description 1
- KSBRTGXRNZVPAT-UHFFFAOYSA-N 2-chlorophthalazin-1-one Chemical compound C1=CC=C2C(=O)N(Cl)N=CC2=C1 KSBRTGXRNZVPAT-UHFFFAOYSA-N 0.000 description 1
- VKNASXZDGZNEDA-UHFFFAOYSA-N 2-cyanoethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC#N VKNASXZDGZNEDA-UHFFFAOYSA-N 0.000 description 1
- KTWCUGUUDHJVIH-UHFFFAOYSA-N 2-hydroxybenzo[de]isoquinoline-1,3-dione Chemical compound C1=CC(C(N(O)C2=O)=O)=C3C2=CC=CC3=C1 KTWCUGUUDHJVIH-UHFFFAOYSA-N 0.000 description 1
- YZOXPLQWARQVEJ-UHFFFAOYSA-N 2-methylsulfonyl-1,3-benzothiazole Chemical compound C1=CC=C2SC(S(=O)(=O)C)=NC2=C1 YZOXPLQWARQVEJ-UHFFFAOYSA-N 0.000 description 1
- RSEBUVRVKCANEP-UHFFFAOYSA-N 2-pyrroline Chemical compound C1CC=CN1 RSEBUVRVKCANEP-UHFFFAOYSA-N 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- UHSLAFBDUFODHO-UHFFFAOYSA-N 2-tert-butyl-4-[2-(3-tert-butyl-4-hydroxy-5-methylphenyl)propan-2-yl]-6-methylphenol Chemical compound CC(C)(C)C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 UHSLAFBDUFODHO-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- DNMNQAUVYXEIKX-UHFFFAOYSA-N 2H-benzotriazol-4-ol silver Chemical compound [Ag].Oc1cccc2[nH]nnc12 DNMNQAUVYXEIKX-UHFFFAOYSA-N 0.000 description 1
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 description 1
- KUAFZXXUYLLLAN-UHFFFAOYSA-N 2h-benzotriazol-5-amine;silver Chemical compound [Ag].C1=C(N)C=CC2=NNN=C21 KUAFZXXUYLLLAN-UHFFFAOYSA-N 0.000 description 1
- GUOVBFFLXKJFEE-UHFFFAOYSA-N 2h-benzotriazole-5-carboxylic acid Chemical compound C1=C(C(=O)O)C=CC2=NNN=C21 GUOVBFFLXKJFEE-UHFFFAOYSA-N 0.000 description 1
- VAVIJGPIFNIPSG-UHFFFAOYSA-N 2h-benzotriazole-5-carboxylic acid;silver Chemical compound [Ag].C1=C(C(=O)O)C=CC2=NNN=C21 VAVIJGPIFNIPSG-UHFFFAOYSA-N 0.000 description 1
- IBWXIFXUDGADCV-UHFFFAOYSA-N 2h-benzotriazole;silver Chemical compound [Ag].C1=CC=C2NN=NC2=C1 IBWXIFXUDGADCV-UHFFFAOYSA-N 0.000 description 1
- QGGXUUYCRXZROA-UHFFFAOYSA-N 3,4-bis(methoxycarbonyl)benzenesulfonic acid Chemical compound COC(=O)C1=CC=C(S(O)(=O)=O)C=C1C(=O)OC QGGXUUYCRXZROA-UHFFFAOYSA-N 0.000 description 1
- KAYAKFYASWYOEB-ISLYRVAYSA-N 3-[(e)-octadec-1-enyl]oxolane-2,5-dione Chemical compound CCCCCCCCCCCCCCCC\C=C\C1CC(=O)OC1=O KAYAKFYASWYOEB-ISLYRVAYSA-N 0.000 description 1
- WBWMBQOVLZOXLI-UHFFFAOYSA-N 3-benzylsulfanyl-1h-1,2,4-triazol-5-amine;silver Chemical compound [Ag].N1C(N)=NC(SCC=2C=CC=CC=2)=N1 WBWMBQOVLZOXLI-UHFFFAOYSA-N 0.000 description 1
- OGMRHLUHIHYVRU-UHFFFAOYSA-M 3-methyl-1,3-thiazol-3-ium;bromide Chemical compound [Br-].C[N+]=1C=CSC=1 OGMRHLUHIHYVRU-UHFFFAOYSA-M 0.000 description 1
- GPJUVPHNQFWGKA-UHFFFAOYSA-N 3h-1,3-benzothiazole-2-thione;silver Chemical compound [Ag].C1=CC=C2SC(=S)NC2=C1 GPJUVPHNQFWGKA-UHFFFAOYSA-N 0.000 description 1
- AMHVHKFKFDBCTE-UHFFFAOYSA-N 3h-1,3-benzoxazole-2-thione;silver Chemical compound [Ag].C1=CC=C2OC(S)=NC2=C1 AMHVHKFKFDBCTE-UHFFFAOYSA-N 0.000 description 1
- BOTGCZBEERTTDQ-UHFFFAOYSA-N 4-Methoxy-1-naphthol Chemical compound C1=CC=C2C(OC)=CC=C(O)C2=C1 BOTGCZBEERTTDQ-UHFFFAOYSA-N 0.000 description 1
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 1
- ABJQKDJOYSQVFX-UHFFFAOYSA-N 4-aminonaphthalen-1-ol Chemical compound C1=CC=C2C(N)=CC=C(O)C2=C1 ABJQKDJOYSQVFX-UHFFFAOYSA-N 0.000 description 1
- ZPOGLINFVDQHBZ-UHFFFAOYSA-N 4-dodecoxybenzenesulfonamide Chemical group CCCCCCCCCCCCOC1=CC=C(S(N)(=O)=O)C=C1 ZPOGLINFVDQHBZ-UHFFFAOYSA-N 0.000 description 1
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 1
- FXKQPQOOZSXQAG-UHFFFAOYSA-N 4-methyltriazine Chemical compound CC1=CC=NN=N1 FXKQPQOOZSXQAG-UHFFFAOYSA-N 0.000 description 1
- DAOLGZTXBRODCV-UHFFFAOYSA-N 4-phenyl-1h-1,2,4-triazole-5-thione;silver Chemical compound [Ag].SC1=NN=CN1C1=CC=CC=C1 DAOLGZTXBRODCV-UHFFFAOYSA-N 0.000 description 1
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 1
- WZUUZPAYWFIBDF-UHFFFAOYSA-N 5-amino-1,2-dihydro-1,2,4-triazole-3-thione Chemical class NC1=NNC(S)=N1 WZUUZPAYWFIBDF-UHFFFAOYSA-N 0.000 description 1
- AFQMMWNCTDMSBG-UHFFFAOYSA-N 5-chloro-2h-benzotriazole;silver Chemical compound [Ag].ClC1=CC=C2NN=NC2=C1 AFQMMWNCTDMSBG-UHFFFAOYSA-N 0.000 description 1
- FJBXHJCLTSWMLN-UHFFFAOYSA-N 5-methoxy-2h-benzotriazole;silver Chemical compound [Ag].C1=C(OC)C=CC2=NNN=C21 FJBXHJCLTSWMLN-UHFFFAOYSA-N 0.000 description 1
- BBGRQUUSRRKFSS-UHFFFAOYSA-N 5-nitro-2h-benzotriazole;silver Chemical compound [Ag].C1=C([N+](=O)[O-])C=CC2=NNN=C21 BBGRQUUSRRKFSS-UHFFFAOYSA-N 0.000 description 1
- OORIFUHRGQKYEV-UHFFFAOYSA-N 6-bromo-1-(6-bromo-2-hydroxynaphthalen-1-yl)naphthalen-2-ol Chemical group BrC1=CC=C2C(C3=C4C=CC(Br)=CC4=CC=C3O)=C(O)C=CC2=C1 OORIFUHRGQKYEV-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- CLSHYAPSFMMGDB-UHFFFAOYSA-N 6-nitro-1h-benzimidazole;silver Chemical compound [Ag].[O-][N+](=O)C1=CC=C2N=CNC2=C1 CLSHYAPSFMMGDB-UHFFFAOYSA-N 0.000 description 1
- PKDNVQWIKHXVGL-UHFFFAOYSA-N 9h-fluorene;n-propylpropan-1-amine Chemical compound CCCNCCC.C1=CC=C2CC3=CC=CC=C3C2=C1 PKDNVQWIKHXVGL-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 241001479434 Agfa Species 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- AXVCDCGTJGNMKM-UHFFFAOYSA-L C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Ag+2] Chemical compound C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Ag+2] AXVCDCGTJGNMKM-UHFFFAOYSA-L 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 206010073306 Exposure to radiation Diseases 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- MGJKQDOBUOMPEZ-UHFFFAOYSA-N N,N'-dimethylurea Chemical compound CNC(=O)NC MGJKQDOBUOMPEZ-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 229920002732 Polyanhydride Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- LLIUOUGGDURLHJ-UHFFFAOYSA-N [Ag].Cc1cc(O)n2ncnc2n1 Chemical compound [Ag].Cc1cc(O)n2ncnc2n1 LLIUOUGGDURLHJ-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
- NZHXEWZGTQSYJM-UHFFFAOYSA-N [bromo(diphenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(Br)C1=CC=CC=C1 NZHXEWZGTQSYJM-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- CWRYPZZKDGJXCA-UHFFFAOYSA-N acenaphthene Chemical compound C1=CC(CC2)=C3C2=CC=CC3=C1 CWRYPZZKDGJXCA-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 238000006359 acetalization reaction Methods 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical group 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000005138 alkoxysulfonyl group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000004422 alkyl sulphonamide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001409 amidines Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical class NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 description 1
- 150000003927 aminopyridines Chemical class 0.000 description 1
- 150000005010 aminoquinolines Chemical class 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229940051880 analgesics and antipyretics pyrazolones Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229940114079 arachidonic acid Drugs 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 description 1
- 125000005142 aryl oxy sulfonyl group Chemical group 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 150000007656 barbituric acids Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- CCGGDOVGIDSGQN-UHFFFAOYSA-N benzo[f][1,2]benzoxazine-1,2-dione Chemical compound C1=CC=CC2=C(C(C(=O)NO3)=O)C3=CC=C21 CCGGDOVGIDSGQN-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229950005228 bromoform Drugs 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001767 cationic compounds Chemical group 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001808 coupling effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- GWZCCUDJHOGOSO-UHFFFAOYSA-N diphenic acid Chemical compound OC(=O)C1=CC=CC=C1C1=CC=CC=C1C(O)=O GWZCCUDJHOGOSO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229930004069 diterpene Natural products 0.000 description 1
- 150000004141 diterpene derivatives Chemical class 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical group CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- NQGIJDNPUZEBRU-UHFFFAOYSA-N dodecanoyl chloride Chemical compound CCCCCCCCCCCC(Cl)=O NQGIJDNPUZEBRU-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
- ZCRZCMUDOWDGOB-UHFFFAOYSA-N ethanesulfonimidic acid Chemical group CCS(N)(=O)=O ZCRZCMUDOWDGOB-UHFFFAOYSA-N 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- VUFOSBDICLTFMS-UHFFFAOYSA-M ethyl-hexadecyl-dimethylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)CC VUFOSBDICLTFMS-UHFFFAOYSA-M 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 125000000816 ethylene group Polymers [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000004705 ethylthio group Chemical group C(C)S* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- PWSKHLMYTZNYKO-UHFFFAOYSA-N heptane-1,7-diamine Chemical compound NCCCCCCCN PWSKHLMYTZNYKO-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 125000001841 imino group Chemical class [H]N=* 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 229910001502 inorganic halide Inorganic materials 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XUPFNPFFFUXGMP-UHFFFAOYSA-N isoindole-1,3-dione;silver Chemical compound [Ag].C1=CC=C2C(=O)NC(=O)C2=C1 XUPFNPFFFUXGMP-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- AZEPWULHRMVZQR-UHFFFAOYSA-M lithium;dodecanoate Chemical compound [Li+].CCCCCCCCCCCC([O-])=O AZEPWULHRMVZQR-UHFFFAOYSA-M 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- CUONGYYJJVDODC-UHFFFAOYSA-N malononitrile Chemical class N#CCC#N CUONGYYJJVDODC-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000001819 mass spectrum Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- DDIZAANNODHTRB-UHFFFAOYSA-N methyl p-anisate Chemical compound COC(=O)C1=CC=C(OC)C=C1 DDIZAANNODHTRB-UHFFFAOYSA-N 0.000 description 1
- BBBWQGQLFSDGIQ-UHFFFAOYSA-N methyl(3-phenylpropyl)sulfanium bromide Chemical compound [Br-].C(C1=CC=CC=C1)CC[SH+]C BBBWQGQLFSDGIQ-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- OTVPURYEWXIAKH-UHFFFAOYSA-N n,n-dibromobenzenesulfonamide Chemical compound BrN(Br)S(=O)(=O)C1=CC=CC=C1 OTVPURYEWXIAKH-UHFFFAOYSA-N 0.000 description 1
- SQARMCGNIUBXAJ-UHFFFAOYSA-N n-(2-hydroxyphenyl)benzenesulfonamide Chemical compound OC1=CC=CC=C1NS(=O)(=O)C1=CC=CC=C1 SQARMCGNIUBXAJ-UHFFFAOYSA-N 0.000 description 1
- KFPBEVFQCXRYIR-UHFFFAOYSA-N n-(3,5-dichloro-4-hydroxyphenyl)benzenesulfonamide Chemical compound C1=C(Cl)C(O)=C(Cl)C=C1NS(=O)(=O)C1=CC=CC=C1 KFPBEVFQCXRYIR-UHFFFAOYSA-N 0.000 description 1
- WHZPMLXZOSFAKY-UHFFFAOYSA-N n-(4-hydroxyphenyl)benzenesulfonamide Chemical compound C1=CC(O)=CC=C1NS(=O)(=O)C1=CC=CC=C1 WHZPMLXZOSFAKY-UHFFFAOYSA-N 0.000 description 1
- UMBBGOALZMAJSF-UHFFFAOYSA-N n-benzylethenamine;hydrochloride Chemical compound [Cl-].C=C[NH2+]CC1=CC=CC=C1 UMBBGOALZMAJSF-UHFFFAOYSA-N 0.000 description 1
- DVNYDODOESWBJY-UHFFFAOYSA-N n-bromo-n-methylbenzenesulfonamide Chemical compound CN(Br)S(=O)(=O)C1=CC=CC=C1 DVNYDODOESWBJY-UHFFFAOYSA-N 0.000 description 1
- FWLGGSWAIHNLLW-UHFFFAOYSA-N n-bromo-n-phenylacetamide Chemical compound CC(=O)N(Br)C1=CC=CC=C1 FWLGGSWAIHNLLW-UHFFFAOYSA-N 0.000 description 1
- VBTQNRFWXBXZQR-UHFFFAOYSA-N n-bromoacetamide Chemical compound CC(=O)NBr VBTQNRFWXBXZQR-UHFFFAOYSA-N 0.000 description 1
- AQJKSMHXNZWIGG-UHFFFAOYSA-N n-methyltetradecane-1-sulfonamide Chemical group CCCCCCCCCCCCCCS(=O)(=O)NC AQJKSMHXNZWIGG-UHFFFAOYSA-N 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000005186 naphthyloxy group Chemical group C1(=CC=CC2=CC=CC=C12)O* 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- QWOKKHXWFDAJCZ-UHFFFAOYSA-N octane-1-sulfonamide Chemical group CCCCCCCCS(N)(=O)=O QWOKKHXWFDAJCZ-UHFFFAOYSA-N 0.000 description 1
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- BIAGWOZIXODKKS-UHFFFAOYSA-N oxadiazole-4-thiol;silver Chemical compound [Ag].SC1=CON=N1 BIAGWOZIXODKKS-UHFFFAOYSA-N 0.000 description 1
- 150000001475 oxazolidinediones Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- LFSXCDWNBUNEEM-UHFFFAOYSA-N phthalazine Chemical compound C1=NN=CC2=CC=CC=C21 LFSXCDWNBUNEEM-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 1
- 229920000779 poly(divinylbenzene) Polymers 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920000205 poly(isobutyl methacrylate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920002776 polycyclohexyl methacrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
- ZVJHJDDKYZXRJI-UHFFFAOYSA-N pyrroline Natural products C1CC=NC1 ZVJHJDDKYZXRJI-UHFFFAOYSA-N 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- GJAWHXHKYYXBSV-UHFFFAOYSA-N quinolinic acid Chemical compound OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
- 229940071536 silver acetate Drugs 0.000 description 1
- AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- SPIDTRPQUQLJAY-UHFFFAOYSA-N silver;1h-1,2,4-triazole Chemical compound [Ag].C=1N=CNN=1 SPIDTRPQUQLJAY-UHFFFAOYSA-N 0.000 description 1
- HMGKNQRMNITOOM-UHFFFAOYSA-M silver;2h-benzotriazole-4-sulfonate Chemical compound [Ag+].[O-]S(=O)(=O)C1=CC=CC2=NNN=C12 HMGKNQRMNITOOM-UHFFFAOYSA-M 0.000 description 1
- VMPMKNVWTFEJAO-UHFFFAOYSA-N silver;2h-tetrazole Chemical compound [Ag].C=1N=NNN=1 VMPMKNVWTFEJAO-UHFFFAOYSA-N 0.000 description 1
- CLDWGXZGFUNWKB-UHFFFAOYSA-M silver;benzoate Chemical compound [Ag+].[O-]C(=O)C1=CC=CC=C1 CLDWGXZGFUNWKB-UHFFFAOYSA-M 0.000 description 1
- LTYHQUJGIQUHMS-UHFFFAOYSA-M silver;hexadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCC([O-])=O LTYHQUJGIQUHMS-UHFFFAOYSA-M 0.000 description 1
- ORYURPRSXLUCSS-UHFFFAOYSA-M silver;octadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCC([O-])=O ORYURPRSXLUCSS-UHFFFAOYSA-M 0.000 description 1
- OHGHHPYRRURLHR-UHFFFAOYSA-M silver;tetradecanoate Chemical compound [Ag+].CCCCCCCCCCCCCC([O-])=O OHGHHPYRRURLHR-UHFFFAOYSA-M 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 229960002317 succinimide Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BUUPQKDIAURBJP-UHFFFAOYSA-N sulfinic acid Chemical compound OS=O BUUPQKDIAURBJP-UHFFFAOYSA-N 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 1
- RKSOPLXZQNSWAS-UHFFFAOYSA-N tert-butyl bromide Chemical compound CC(C)(C)Br RKSOPLXZQNSWAS-UHFFFAOYSA-N 0.000 description 1
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- LIXPXSXEKKHIRR-UHFFFAOYSA-M tetraethylphosphanium;bromide Chemical compound [Br-].CC[P+](CC)(CC)CC LIXPXSXEKKHIRR-UHFFFAOYSA-M 0.000 description 1
- DDFYFBUWEBINLX-UHFFFAOYSA-M tetramethylammonium bromide Chemical compound [Br-].C[N+](C)(C)C DDFYFBUWEBINLX-UHFFFAOYSA-M 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 150000001467 thiazolidinediones Chemical class 0.000 description 1
- CBDKQYKMCICBOF-UHFFFAOYSA-N thiazoline Chemical compound C1CN=CS1 CBDKQYKMCICBOF-UHFFFAOYSA-N 0.000 description 1
- ZEMGGZBWXRYJHK-UHFFFAOYSA-N thiouracil Chemical compound O=C1C=CNC(=S)N1 ZEMGGZBWXRYJHK-UHFFFAOYSA-N 0.000 description 1
- 229950000329 thiouracil Drugs 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical group CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- YFDSDPIBEUFTMI-UHFFFAOYSA-N tribromoethanol Chemical compound OCC(Br)(Br)Br YFDSDPIBEUFTMI-UHFFFAOYSA-N 0.000 description 1
- 229950004616 tribromoethanol Drugs 0.000 description 1
- 229940066528 trichloroacetate Drugs 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- GNMJFQWRASXXMS-UHFFFAOYSA-M trimethyl(phenyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)C1=CC=CC=C1 GNMJFQWRASXXMS-UHFFFAOYSA-M 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- ZOPCDOGRWDSSDQ-UHFFFAOYSA-N trinonyl phosphate Chemical compound CCCCCCCCCOP(=O)(OCCCCCCCCC)OCCCCCCCCC ZOPCDOGRWDSSDQ-UHFFFAOYSA-N 0.000 description 1
- JBWKIWSBJXDJDT-UHFFFAOYSA-N triphenylmethyl chloride Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(Cl)C1=CC=CC=C1 JBWKIWSBJXDJDT-UHFFFAOYSA-N 0.000 description 1
- INDZTCRIYSRWOH-UHFFFAOYSA-N undec-10-enyl carbamimidothioate;hydroiodide Chemical compound I.NC(=N)SCCCCCCCCCC=C INDZTCRIYSRWOH-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/40—Development by heat ; Photo-thermographic processes
- G03C8/4013—Development by heat ; Photo-thermographic processes using photothermographic silver salt systems, e.g. dry silver
- G03C8/4033—Transferable dyes or precursors
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
Description
ç£æ¥äžã®å©çšåé
æ¬çºæã¯æ°èŠãªç±çŸåã«ã©ãŒæå
ææã«é¢ãã
詳ããã¯ç±çŸåæå èŠçŽ äžã«ãããŠåœ¢æãããæ¡
æ£æ§è²çŽ ã®åæ§ååžãååå±€ã«ç±è»¢åããããšã«
ããç»åãåŸãç±çŸåã«ã©ãŒæå ææã«é¢ããã
ã®ã§ãããããã«è©³ããã¯ãè²çŽ äŸäžç©è³ªãé«çº
è²æ§ã§ãæ¡æ£æ§ã®ããããŒã³ã¿è²çŽ ãçæããç±
転åæã«é«æ¿åºŠã®è»¢åç»åãåŸããããããã«ã
ãªãå°ãªãç±çŸåã«ã©ãŒæå ææã«é¢ããã åŸæ¥æè¡ïŒœ åŸæ¥ããç¥ãããŠããæå æ§ããã²ã³åéãçš
ããã«ã©ãŒåçæ³ã¯ãæå æ§ãé調æ§ãªãã³ã«ç»
åä¿åæ§çã«ãããŠããã®ä»ã®ã«ã©ãŒåçæ³ã«å
ããã®ã§ãããæãåºãå®çšåãããŠããããã
ããªããããã®æ¹æ³ã«ãããŠã¯çŸåãæŒçœãå®
çãæ°ŽæŽãªã©ã®å·¥çšã«æ¹¿åŒåŠçæ³ãçšãããã
ã«ãåŠçã«æéãšæéããããããŸãåŠçè¬åã«
ãã人äœãžã®å ¬å®³ãæžå¿µããããããããã¯åŠç
宀ãäœæ¥è ã«å¯ŸããåŠçè¬åã«ããæ±æãå¿é ã
ããããããã«ã¯å»æ¶²åŠçã®æéãã³ã¹ããªã©å€
ãã®åé¡ç¹ãååšããŠããã åŸã€ãŠã也åŒåŠçãå¯èœãªã«ã©ãŒç»åã®åœ¢ææ¹
æ³ã®éçºãèŠæãããŠããã çŸåå·¥çšãç±åŠçã§è¡ãªãããšãç¹åŸŽãšããé»
çœç±çŸåæå ææã¯ä»¥åããç¥ãããŠãããäŸã
ã°ç¹å ¬æ43â4921å·ããã³å43â4924å·å ¬å ±ã«ã
ã®èšèŒããããææ©éå¡©ãããã²ã³åéããã³çŸ
åå€ãããªãæå ææãé瀺ãããŠãããããã«
ãã®é»çœç±çŸåæå ææãå¿çšããã«ã©ãŒç±çŸå
æå ææãæ°å€ãç¥ãããŠããã äŸãã°ãç±³åœç¹èš±ç¬¬3531286å·ãå第3761270
å·ãå第3764328å·ããªãµãŒãã»ãã€ã¹ã¯ããŒãž
ã€ãŒïŒä»¥äžRDãšããïŒNo.15108ãåNo.15127ãå
No.12044ããã³åNo.16479çã«ã¯ç±çŸåæå ææäž
ã«åççšã«ãã©ãŒãšçºè²çŸåäž»è¬ãå«æãããã
ã®ã«ã€ããŠãç±³åœç¹èš±ç¬¬3180731å·ãRDNo.13443
ããã³åNo.14347çã«ã¯ããã€ã³è²çŽ ãçšããã
ã®ã«ã€ããŠãç±³åœç¹èš±ç¬¬4235957å·ãRDNo.
14433ãåNo.14448ãåNo.15227ãåNo.15776ãåNo.
18137ããã³åNo.19419çã«ã¯ãéè²çŽ æŒçœæ³ãå¿
çšãããã®ã«ã€ããŠãç±³åœç¹èš±ç¬¬4124398å·ãå
第4124387å·ããã³å第4123273å·ã«ã¯ç±çŸåæå
ææã®ç±æŒçœæ¹æ³ã«ã€ããŠè¿°ã¹ãããŠããã ããããªãããã«ã©ãŒç±çŸåæå ææã«é¢ãã
ãããã®ææ¡ã¯ãåæã«åœ¢æãããé»çœéç»åã
æŒçœãŸãã¯å®çããããšãå°é£ã§ãã€ããããã
ãã¯å šãäžå¯èœã§ãã€ãããå¯èœã§ãã€ãŠã湿åŒ
åŠçãªã©ãå¿ èŠãšãããã®ã§ãããåŸã€ãŠããã
ãã®ææ¡ã¯ãé®®æãªã«ã©ãŒç»åãåŸãããšãå°é£
ã§ãã€ããããŸãç¹éãªåŸåŠçãå¿ èŠãšãããªã©
å€ãã®æ¬ ç¹ãæããŠããã äžè¿°ã®æ¬ ç¹ãæ¹è¯ããæ¹åŒãšããŠãç±çŸåã«ã
ãæ¡æ£æ§æãã¯æè¯æ§ã®è²çŽ ãæŸåºããããã®è²
çŽ ãååå±€ã«è»¢åãããããšã«ããéç»åãšè²çŽ
ãåé¢ããŠã«ã©ãŒç»åãåŸãåŠãç±çŸåã«ã©ãŒæ
å ææãç¹éæ57â179840å·ãå57â186744å·ã
ãã³å59â12431å·æ现æžçã«èšèŒãããŠããã
ããããªãããããã®æ¹åŒãç¹ã«ç¹éæ57â
179840å·ãå57â186744å·ã«èšèŒã®æ¹åŒã§ã¯ãè²
çŽ ã®æ¡æ£ãšåæã«è²çŽ äŸäžç©è³ªãååå±€ã«è»¢åã
ååå±€ãæ±æãããšããåé¡ç¹ãããã ãããã«çšããããè²çŽ äŸäžç©è³ªãæ¡æ£æ§è²çŽ
ãããã¯æè¯æ§è²çŽ ãæŸåºãããããªè²çŽ æŸåºæ§
ç©è³ªã§ããå Žåã«ã¯ãè²çŽ äŸäžç©è³ªèªäœãæè²å
åç©ã§ããããã«ãç¹ã«æ±æãã²ã©ãããŸãè²çŽ
æŸåºæã«åœ¢æãããè²çŽ ç»å以å€ã«äžå¿ èŠãªè²çŽ
ã転åããŠããã®ã§ããã®ããã®æ±æããããªã©
倧ããªåé¡ãããã ãã®ããšã¯ãè²çŽ äŸäžç©è³ªãè²çŽ æŸåºæ§ç©è³ªã§
ããå Žåã«ã¯ãè²çŽ 圢ææ§ç©è³ªã§ããå Žåãšæ¯èŒ
ããŠã該ååç©èªäœãæè²ã§ããããã«ååå±€ã
æ¿ããæ±æããŠããŸããšããæ¬ ç¹ãæããããšã
æå³ããã ããã«å¥ã®åé¡ç¹ãšããŠè²çŽ äŸäžç©è³ªãè²çŽ æŸ
åºæ§ç©è³ªã§ããå Žåã«ã¯ãè²çŽ 圢ææ§ç©è³ªã§ãã
å Žåãšæ¯èŒããŠã該ååç©ãæè²ã§ãããããã«
éåžžã«æžæããŠããŸããšããæ¬ ç¹ããæããã 以äžã®èŠ³ç¹ãããç±çŸåã«ã©ãŒæå ææã«çšã
ãããè²çŽ äŸäžç©è³ªãšããŠã¯ãè²çŽ æŸåºæ§ç©è³ªã
ãè²çŽ 圢ææ§ç©è³ªã奜ãŸãããšèšããã è²çŽ 圢ææ§ç©è³ªãšããŠã¯ãäŸãã°ç¹éæ58â
123533å·ãå58â149046å·å ¬å ±ããã³ç¹é¡æ58â
33364å·æ现æžã«èšèŒãããŠããååç©ããããã
ãããã®è²çŽ 圢ææ§ç©è³ªãçšããŠããæªã çºè²æ§
ãäœãã€ãããçæããè²çŽ ãååã«ç±è»¢åãã
ãªãã€ãããã«ããªãé«ãçã®åé¡ç¹ããã€ãã
ç¹ã«ãäžèšè²çŽ 圢ææ§ç©è³ªã®ãã¡ãããŒã³ã¿è²çŽ
ã圢æããååç©ã§ã¯ããã®çºè²æ§ãäžååã§ã
ããé«ãç»åæ¿åºŠãæããããŒã³ã¿ç»åãäžããª
ããšããæ¬ ç¹ããã€ãã çºæã®ç®ç æ¬çºæã¯ãäžèšã®åé¡ç¹ã«éã¿çºããããã®
ã§ãæ¬çºæã®ç®çã¯ãé«æ¿åºŠã§ãã€ã«ããªãå°ãª
ãããŒã³ã¿è²çŽ ã®è»¢åç»åãåŸãããšãã§ããç±
çŸåã«ã©ãŒæå ææãæäŸããããšã«ããã çºæã®æ§æ æ¬çºæã®äžèšç®çã¯ãæ¯æäœäžã«ãå°ãªããšã
æå æ§ããã²ã³åéãéå å€ãææ©éå¡©ãè²çŽ äŸ
äžç©è³ªããã³ãã€ã³ããŒãå«æããåçæ§æå±€ã
æããç±çŸåã«ã©ãŒæå ææã«ãããŠãåèšè²çŽ
äŸäžç©è³ªã®å°ãªããšãïŒã€ãäžèšäžè¬åŒïŒ»ïŒœã§
è¡šããããååç©ã§ããããšãç¹åŸŽãšããç±çŸå
ã«ã©ãŒæå ææã äžè¬åŒïŒ»ïŒœ åŒäžãR1ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ããª
ãåºãã¢ã·ã«ã¢ããåºãŸãã¯ãŠã¬ã€ãåºãè¡šã
ãããããR1ã§è¡šããããããããã®åºã¯ãã
ã®ççŽ ååæ°ã®ç·åãïŒã12åã§ãããäžã€ãã
ãã®åºã¯ããããã眮æåºãæããŠããããR2
ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·åºãã¢ãª
ãŒã«ãªãã·åºãã¢ããåºãŸãã¯ãããç°æ®åºãè¡š
ããããã®ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·
åºãã¢ãªãŒã«ãªãã·åºãã¢ããåºããããç°æ®åº
ã¯ã眮æåºãæããŠãããã Arã¯ã¢ãªãŒã«åºãŸãã¯ãããç°æ®åºãè¡šããã
ãã®ã¢ãªãŒã«åºããããç°æ®åºã¯ã眮æåºãæã
ãŠããããã¯âSO2âãŸãã¯âCOâãè¡šããã çºæã®å ·äœçæ§æ åèšäžè¬åŒïŒ»ïŒœã«ãããŠãR1ã¯ããããã
眮æåºãæããŠãããã¢ã«ãã«åºãã¢ãªãŒã«åºã
ã¢ããªãåºãã¢ã·ã«ã¢ããåºãŸãã¯ãŠã¬ã€ãåºã
è¡šããããR1ã§è¡šããããã¢ã«ãã«åºãšããŠã¯ã
çŽéã§ãåå²ç¶ã§ããããäŸãã°ãã¡ãã«åºããª
ã¯ãã«åºããŠã³ãã·ã«åºçãæãããããR1ã§
è¡šããããã¢ã·ã«ã¢ããåºãšããŠã¯ãäŸãã°ãã¢
ã»ãã¢ããåºããã³ãºã¢ããåºçãæããããã äžèšR1ã®ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ããªã
åºãã¢ã·ã«ã¢ããåºãŸãã¯ãŠã¬ã€ãåºã®çœ®æåºãš
ããŠã¯ãããã²ã³ååïŒäŸãã°å¡©çŽ ååçïŒãçŽ
éãããã¯åå²ç¶ã¢ã«ãã«åºïŒäŸãã°ã¡ãã«åºã
ãšãã«åºãïœâããã«åºçïŒãã¢ãªãŒã«åºïŒäŸã
ã°ããšãã«åºçïŒãã·ã¯ãã¢ã«ãã«åºïŒäŸãã°ã·
ã¯ãããã·ã«åºçïŒãã¢ã·ã«ã¢ããåºïŒäŸãã°ã¢
ã»ãã¢ããåºããã³ãºã¢ããåºçïŒãã¹ã«ãã³ã¢
ããåºïŒäŸãã°ã¹ã«ãã³ã¢ããåºãã¡ã¿ã³ã¹ã«ã
ã³ã¢ããåºããã³ãŒã³ã¹ã«ãã³ã¢ããåºçïŒãã¹
ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¹ã«ãã¢ã¢ã€ã«åºãâ
ãšãã«ã¹ã«ãã¢ã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã¹ã«
ãã¢ã¢ã€ã«åºçïŒãã¢ã«ã³ãã·ã«ã«ããã«åºïŒäŸ
ãã°ã¡ããã·ã«ã«ããã«åºçïŒãã¢ãªãŒã«ãªãã·
ã«ã«ããã«åºïŒäŸãã°ãã³ãžã«ãªãã·ã«ã«ããã«
åºçïŒãã¢ã·ã«åºïŒäŸãã°ã¢ã»ãã«åºããã³ãŸã€
ã«åºçïŒããããåºãã·ã¢ãåºçãæããããšã
ã§ããã R1ã§è¡šããããåºã®ççŽ ååæ°ã®ç·åã¯ã奜
ãŸããã¯ïŒã12ããã奜ãŸããã¯ïŒãïŒã§ããã åèšäžè¬åŒïŒ»ïŒœã«ãããŠãR2ã¯ããããã
眮æåºãæããŠãããã¢ã«ãã«åºãã¢ãªãŒã«åºã
ã¢ã«ã³ãã·åºãã¢ãªãŒã«ãªãã·åºãã¢ããåºãŸã
ã¯ãããç°æ®åºãè¡šããããR2ã§è¡šããããã¢
ã«ãã«åºã¯çŽéã§ãåå²ç¶ã§ããããäŸãã°ããš
ãã«åºããã·ã«åºããŠã³ãã·ã«åºãããã·ã«åºã
ããªãã·ã«åºããããµãã·ã«åºããšã€ã³ã·ã«åºç
ãæãããããR2ã§è¡šããããã¢ãªãŒã«åºãšã
ãŠã¯ãäŸãã°ãããšãã«åºããããã«åºçãæã
ããããR2ã§è¡šããããã¢ã«ãã³ã·åºãšããŠã¯ã
äŸãã°ããªã¯ãã«ãªãã·åºãããã·ã«ãªãã·åºã
çãæãããããR2ã§è¡šããããã¢ãªãŒã«ãªã
ã·åºãšããŠã¯ãäŸãã°ãããšãã«ãªãã·åºãïŒïŒ
ïŒâãžâïœâãã³ãã«ããšãã«ãªãã·åºãããã
ã«ãªãã·åºçæãããããR2ã§è¡šãããããã
ãç°æ®åºãšããŠã¯ã奜ãŸããã¯ïŒãããã¯ïŒå¡ç°
ã§ãäŸãã°ãããªãžã«åºãã€ãããŸãªã«åºããã³
ãŸãã¢ãŸãªã«åºçãæããããã äžèšR2ã®ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ã
ã·åºãã¢ãªãŒã«ãªãã·åºãã¢ããåºããããç°æ®
åºã®çœ®æåºãšããŠã¯ãããã²ã³ååïŒäŸãã°ãã
ãçŽ ååãå¡©çŽ ååãèçŽ ååçïŒãçŽéããã
ã¯åå²ç¶ã¢ã«ãã«åºïŒäŸãã°ãšãã«åºãïœâãã
ã«åºããªã¯ãã«åºããŠã³ãã·ã«åºãããã·ã«åºã
ãããµãã·ã«åºçïŒãã¢ãªãŒã«åºïŒäŸãã°ããšã
ã«åºçïŒãã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·åºãã
ãããã·åºãïŒâãšãã«ããã·ã«ãªãã·åºããã
ã·ã«ãªãã·åºçïŒãã¢ãªãŒã«ãªãã·åºïŒäŸãã°ã
ããšãã«ãªãã·åºãïŒïŒïŒâãžâïœâãã³ãã«ã
ãšãã«ãªãã·åºçïŒãã¢ã·ã«ã¢ããåºïŒ»äŸãã°ã¢
ã»ãã¢ããåºããã³ãã¢ããåºããã¿ã³ã¢ãã
åºãããã«ã³ã¢ããåºãαâïŒïŒïŒïŒâãžâïœâ
ã¢ã·ã«ããšããã·ïŒã¢ã»ãã¢ããåºãαâïŒïŒïŒ
ïŒâãžâïœâã¢ã·ã«ããšããã·ïŒãã¿ã³ã¢ãã
åºãâã¡ãã«âãããµããã«ã³ã¢ããåºçã
ã¹ã«ãã³ã¢ããåºïŒäŸãã°ãšã¿ã³ã¹ã«ãã³ã¢ãã
åºããã³ãŒã³ã¹ã«ãã³ã¢ããåºããªã¯ã¿ã³ã¹ã«ã
ã³ã¢ããåºãïœâããã·ã«ãªãã·ãã³ãŒã³ã¹ã«ã
ã³ã¢ããåºãâã¡ãã«âããã©ãã«ã³ã¹ã«ãã³
ã¢ããåºçïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ãã¹ã«
ãã¢ã¢ã€ã«åºãâãšãã«ã¹ã«ãã¢ã¢ã€ã«åºã
ïŒïŒ®âãžããã·ã«ã¹ã«ãã¢ã¢ã€ã«åºãâãã
ã©ãã·ã«ã¹ã«ãã¢ã¢ã€ã«åºãâã¡ãã«ââã
ãã©ãã·ã«ã¹ã«ãã¢ã¢ã€ã«åºçïŒãã«ã«ãã¢ã€ã«
åºïŒäŸãã°ãâã¡ãã«ã«ã«ãã¢ã€ã«åºãâãª
ã¯ãã«ã«ã«ãã¢ã€ã«åºãâãããµãã·ã«ã«ã«ã
ã¢ã€ã«åºãâã¡ãã«ââããã©ãã·ã«ã«ã«ã
ã¢ã€ã«åºçïŒãã¢ã«ã³ãã·ã«ã«ããã«åºïŒäŸãã°ã
ã¡ããã·ã«ã«ããã«åºãããã©ãã·ã«ãªãã·ã«ã«
ããã«åºããã³ãžã«ãªãã·ã«ã«ããã«åºçïŒãã¢
ã«ã³ãã·ã¹ã«ããã«åºïŒäŸãã°ãã¡ããã·ã¹ã«ã
ãã«åºããªã¯ãã«ãªãã·ã¹ã«ããã«åºãããã·ã«
ãªãã·ã¹ã«ããã«åºçïŒãã¢ãªãŒã«ãªãã·ã¹ã«ã
ãã«åºïŒäŸãã°ãããšããã·ã¹ã«ããã«åºãïœâ
ããã·ã«ãªãã·ããšããã·ã¹ã«ããã«åºçïŒãã¢
ã«ãã«ã¹ã«ããã«åºïŒäŸãã°ãã¡ã¿ã³ã¹ã«ããã«
åºããšã¿ã³ã¹ã«ããã«åºçïŒãã¢ãªãŒã«ã¹ã«ãã
ã«åºïŒäŸãã°ããã³ãŒã³ã¹ã«ããã«åºãïœâãã«
ãšã³ã¹ã«ããã«åºçïŒãã¢ã«ãã«ããªåºïŒäŸãã°ã
ã¡ãã«ããªåºãããã·ã«ããªåºããã³ãžã«ããªåº
çïŒãã¢ãªãŒã«ããªåºïŒäŸãã°ãããšãã«ããªåºã
ïœâïœâããã«ããšãã«ããªåºçïŒããŠã¬ã€ãåº
ïŒäŸãã°ãâã¡ãã«ãŠã¬ã€ãåºãâããšãã«
ãŠã¬ã€ãåºãïŒïŒ®âãžããã·ã«ãŠã¬ã€ãåºçïŒã
ã¢ã·ã«åºïŒäŸãã°ãã¢ã»ãã«åºããã³ãŸã€ã«åº
çïŒããããåºãã·ã¢ãåºãã«ã«ããã·åºãã¹ã«
ãåºãããããã·åºçãæããããšãã§ãããã
ãã®çœ®æåºãïŒã€ä»¥äžãããšãã¯åãã§ãç°ãªã€
ãŠããŠãããããããã®çœ®æåºã®äžã§ãè²çŽ äŸäž
ç©è³ªã®èæ¡æ£æ§ãããé«ããåºãšããŠã芪氎æ§
åºãç¹ã«ã«ã«ããã·åºãã¹ã«ãåºããã³ãããã®
åºã眮æãã眮æåºã奜ãŸããã äžèšR2ã«ãããŠã眮æåºãæããŠãããã¢ã«
ãã«åºãã¢ã«ã³ãã·åºãã¢ããåºã§è¡šããããåº
ã®å ŽåãççŽ ååæ°ãšããŠã¯ïŒã36ã奜ãŸããã
眮æåºãæããŠãããã¢ãªãŒã«åºãã¢ãªãŒã«ãªã
ã·åºããããç°æ®åºã§è¡šããããåºã®å ŽåãççŽ
ååæ°ãšããŠïŒã38ã奜ãŸããã åèšäžè¬åŒïŒ»ïŒœã«ãããŠãArã¯ã¢ãªãŒã«åº
ãŸãã¯ãããç°æ®åºãè¡šããããArã§è¡šããã
ãã¢ãªãŒã«åºãšããŠã¯ãäŸãã°çœ®æåºãæããŠã
ããããšãã«åºãæããããArã§è¡šããããã
ããç°æ®åºãšããŠã¯ã奜ãŸããã¯ïŒãïŒå¡ç°ã§ã
äŸãã°ãããªãžã«åºãã€ãããŸãªã«åºããã³ãŸã
ã¢ãŸãªã«åºçãæããããããã®ã¢ãªãŒã«åºãã
ããç°æ®åºã®çœ®æåºãšããŠã¯ãã¢ã«ãã«åºïŒäŸã
ã°ãã¡ãã«åºããšãã«åºãããªã¯ããã¡ãã«åºã
ããªãã«ãªãã¡ãã«åºçïŒãã¢ã«ã³ãã·åºïŒäŸã
ã°ãã¡ããã·åºããšããã·åºçïŒãã¢ãªãŒã«ãªã
ã·åºïŒäŸãã°ãããšãã«ãªãã·åºçïŒãã¢ã«ã³ã
ã·ã«ã«ããã«åºïŒäŸãã°ãã¡ããã·ã«ã«ããã«åº
çïŒãã¢ã·ã«ã¢ããåºïŒäŸãã°ãã¢ã»ãã¢ããåº
çïŒãã«ã«ãã¢ã€ã«åºïŒäŸãã°ãã«ã«ãã¢ã€ã«åºã
ã¡ãã«ã«ã«ãã¢ã€ã«åºãããšãã«ã«ã«ãã¢ã€ã«åº
çïŒãã¢ã«ãã«ã¹ã«ããã«åºïŒäŸãã°ãã¡ã¿ã³ã¹
ã«ããã«åºçïŒãã¢ãªãŒã«ã¹ã«ããã«åºïŒäŸãã°ã
ãã³ãŒã³ã¹ã«ããã«åºçïŒãã¹ã«ãã³ã¢ããåº
ïŒäŸãã°ãã¡ã¿ã³ã¹ã«ãã³ã¢ããåºãïœâãã«ãš
ã³ã¹ã«ãã³ã¢ããåºçïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒäŸ
ãã°ãã¹ã«ãã¢ã¢ã€ã«åºãã¡ãã«ã¹ã«ãã¢ã¢ã€ã«
åºãããšãã«ã¹ã«ãã¢ã¢ã€ã«åºããžã¡ãã«ã¹ã«ã
ã¢ã¢ã€ã«åºçïŒãã¢ã«ãã«ããªåºïŒäŸãã°ããšã
ã«ããªåºçïŒãã¢ãªãŒã«ããªåºïŒäŸãã°ãããšã
ã«ããªåºçïŒãã·ã¢ãåºããããåºãããã²ã³å
åïŒäŸãã°ãããçŽ ååãå¡©çŽ ååãèçŽ åå
çïŒãæãããããããã®çœ®æåºãïŒå以äžãã
ãšãã¯ãåãã§ãç°ãªã€ãŠããŠãããã äžè¬åŒïŒ»ïŒœã«ãããŠãã¯âSO2âãŸãã¯â
COâã§è¡šãããããã奜ãŸããã¯âCOâã§ã
ãã åèšäžè¬åŒïŒ»ïŒœã§è¡šããããæ¬çºæã®ããŒã³
ã¿è²çŽ äŸäžç©è³ªã¯ãç±çŸåãããåã«ãããŠã¯è
æ¡æ£åãããååç©ã§ãããç±çŸåã«éããŠã¯æ¡
æ£æ§ã®ããŒã³ã¿è²çŽ ã圢æãåŸãååç©ã§ããã æ¬çºæã«ãããŠãäžèšç±çŸåã«éããŠçæãã
ãæ¡æ£æ§è²çŽ ã®âæ¡æ£æ§âãšã¯ãåèšè²çŽ äŸäžç©
質ããçæãããè²çŽ ãã該è²çŽ äŸäžç©è³ªãå«æ
ããå±€ããç©éé¢ä¿ã«ããé£æ¥å±€ïŒååå±€ïŒã«ç§»
åãåŸãæ§è³ªãæå³ãããã®ç§»åã®æ æ§ã«ã€ããŠ
ã¯ãäŸãã°çæãããè²çŽ èªäœã溶èããæ¡æ£ç§»
åãè¡ãªããããã®ããŸãä»ã®äŸãšããŠã¯ãçæ
ãããè²çŽ ãè²çŽ ã®æº¶å€ã«æº¶è§£ããããŸãã¯ç±æº¶
å€ã«ãã€ãŠå ç±æº¶å€ãããŠç§»åãè¡ãªãããå Žå
çãå«ãŸãããããã«çæãããè²çŽ èªäœãæè¯
æ§ã§ãã€ãŠãçæãããè²çŽ ãæè¯ãæ°åããŠé£
æ¥å±€ãžç§»åããæ æ§ãå«ãŸããã ããã§ãäžèšâæè¯æ§âãšã¯äžè¬ã«çšããããŠ
ãã液äœç¶æ ãçµãããšãªããåºäœããæ°äœã«å€
åããæ§è³ªã ãã§ãªããåºäœã溶èããŠæ¶²äœã«ãª
ãããã®æ¶²äœããæŽã«æ°äœã«å€åããæ§è³ªããå«
ããã®ã§ããã æ¬çºæã«çšããããåèšäžè¬åŒïŒ»ïŒœã§è¡šãã
ããããŒã³ã¿è²çŽ äŸäžç©è³ªã¯ãããŒã³ã¿ã«ãã©ãŒ
æ¯æ žã§ãããã©ãŸã©ã³èªå°äœã®ïŒäœïŒä»¥äžã掻æ§
ç¹ãšããïŒã§ç°å å€ïŒçºè²çŸåäž»è¬ïŒã®é žåäœãš
åå¿ããããŒã³ã¿è²çŽ ã圢æããããããã®éã
ãŒã³ã¿ã«ãã©ãŒæ¯æ žã®ååéãå°ããïŒå¥œãŸãã
ã¯400以äžïŒå Žåã«ã¯ããŒã³ã¿è²çŽ ã®æ¡æ£æ§ã«ã
ããŠæå©ã«ãªãã 以äžãæ¬çºæã«çšããããåèšäžè¬åŒïŒ»ïŒœã§
è¡šããããããŒã³ã¿è²çŽ äŸäžç©è³ªã®ä»£è¡šçå ·äœäŸ
ãèšèŒããããæ¬çºæã¯ãããã«éå®ããããã®
ã§ã¯ãªãã äžè¬åŒãã
詳ããã¯ç±çŸåæå èŠçŽ äžã«ãããŠåœ¢æãããæ¡
æ£æ§è²çŽ ã®åæ§ååžãååå±€ã«ç±è»¢åããããšã«
ããç»åãåŸãç±çŸåã«ã©ãŒæå ææã«é¢ããã
ã®ã§ãããããã«è©³ããã¯ãè²çŽ äŸäžç©è³ªãé«çº
è²æ§ã§ãæ¡æ£æ§ã®ããããŒã³ã¿è²çŽ ãçæããç±
転åæã«é«æ¿åºŠã®è»¢åç»åãåŸããããããã«ã
ãªãå°ãªãç±çŸåã«ã©ãŒæå ææã«é¢ããã åŸæ¥æè¡ïŒœ åŸæ¥ããç¥ãããŠããæå æ§ããã²ã³åéãçš
ããã«ã©ãŒåçæ³ã¯ãæå æ§ãé調æ§ãªãã³ã«ç»
åä¿åæ§çã«ãããŠããã®ä»ã®ã«ã©ãŒåçæ³ã«å
ããã®ã§ãããæãåºãå®çšåãããŠããããã
ããªããããã®æ¹æ³ã«ãããŠã¯çŸåãæŒçœãå®
çãæ°ŽæŽãªã©ã®å·¥çšã«æ¹¿åŒåŠçæ³ãçšãããã
ã«ãåŠçã«æéãšæéããããããŸãåŠçè¬åã«
ãã人äœãžã®å ¬å®³ãæžå¿µããããããããã¯åŠç
宀ãäœæ¥è ã«å¯ŸããåŠçè¬åã«ããæ±æãå¿é ã
ããããããã«ã¯å»æ¶²åŠçã®æéãã³ã¹ããªã©å€
ãã®åé¡ç¹ãååšããŠããã åŸã€ãŠã也åŒåŠçãå¯èœãªã«ã©ãŒç»åã®åœ¢ææ¹
æ³ã®éçºãèŠæãããŠããã çŸåå·¥çšãç±åŠçã§è¡ãªãããšãç¹åŸŽãšããé»
çœç±çŸåæå ææã¯ä»¥åããç¥ãããŠãããäŸã
ã°ç¹å ¬æ43â4921å·ããã³å43â4924å·å ¬å ±ã«ã
ã®èšèŒããããææ©éå¡©ãããã²ã³åéããã³çŸ
åå€ãããªãæå ææãé瀺ãããŠãããããã«
ãã®é»çœç±çŸåæå ææãå¿çšããã«ã©ãŒç±çŸå
æå ææãæ°å€ãç¥ãããŠããã äŸãã°ãç±³åœç¹èš±ç¬¬3531286å·ãå第3761270
å·ãå第3764328å·ããªãµãŒãã»ãã€ã¹ã¯ããŒãž
ã€ãŒïŒä»¥äžRDãšããïŒNo.15108ãåNo.15127ãå
No.12044ããã³åNo.16479çã«ã¯ç±çŸåæå ææäž
ã«åççšã«ãã©ãŒãšçºè²çŸåäž»è¬ãå«æãããã
ã®ã«ã€ããŠãç±³åœç¹èš±ç¬¬3180731å·ãRDNo.13443
ããã³åNo.14347çã«ã¯ããã€ã³è²çŽ ãçšããã
ã®ã«ã€ããŠãç±³åœç¹èš±ç¬¬4235957å·ãRDNo.
14433ãåNo.14448ãåNo.15227ãåNo.15776ãåNo.
18137ããã³åNo.19419çã«ã¯ãéè²çŽ æŒçœæ³ãå¿
çšãããã®ã«ã€ããŠãç±³åœç¹èš±ç¬¬4124398å·ãå
第4124387å·ããã³å第4123273å·ã«ã¯ç±çŸåæå
ææã®ç±æŒçœæ¹æ³ã«ã€ããŠè¿°ã¹ãããŠããã ããããªãããã«ã©ãŒç±çŸåæå ææã«é¢ãã
ãããã®ææ¡ã¯ãåæã«åœ¢æãããé»çœéç»åã
æŒçœãŸãã¯å®çããããšãå°é£ã§ãã€ããããã
ãã¯å šãäžå¯èœã§ãã€ãããå¯èœã§ãã€ãŠã湿åŒ
åŠçãªã©ãå¿ èŠãšãããã®ã§ãããåŸã€ãŠããã
ãã®ææ¡ã¯ãé®®æãªã«ã©ãŒç»åãåŸãããšãå°é£
ã§ãã€ããããŸãç¹éãªåŸåŠçãå¿ èŠãšãããªã©
å€ãã®æ¬ ç¹ãæããŠããã äžè¿°ã®æ¬ ç¹ãæ¹è¯ããæ¹åŒãšããŠãç±çŸåã«ã
ãæ¡æ£æ§æãã¯æè¯æ§ã®è²çŽ ãæŸåºããããã®è²
çŽ ãååå±€ã«è»¢åãããããšã«ããéç»åãšè²çŽ
ãåé¢ããŠã«ã©ãŒç»åãåŸãåŠãç±çŸåã«ã©ãŒæ
å ææãç¹éæ57â179840å·ãå57â186744å·ã
ãã³å59â12431å·æ现æžçã«èšèŒãããŠããã
ããããªãããããã®æ¹åŒãç¹ã«ç¹éæ57â
179840å·ãå57â186744å·ã«èšèŒã®æ¹åŒã§ã¯ãè²
çŽ ã®æ¡æ£ãšåæã«è²çŽ äŸäžç©è³ªãååå±€ã«è»¢åã
ååå±€ãæ±æãããšããåé¡ç¹ãããã ãããã«çšããããè²çŽ äŸäžç©è³ªãæ¡æ£æ§è²çŽ
ãããã¯æè¯æ§è²çŽ ãæŸåºãããããªè²çŽ æŸåºæ§
ç©è³ªã§ããå Žåã«ã¯ãè²çŽ äŸäžç©è³ªèªäœãæè²å
åç©ã§ããããã«ãç¹ã«æ±æãã²ã©ãããŸãè²çŽ
æŸåºæã«åœ¢æãããè²çŽ ç»å以å€ã«äžå¿ èŠãªè²çŽ
ã転åããŠããã®ã§ããã®ããã®æ±æããããªã©
倧ããªåé¡ãããã ãã®ããšã¯ãè²çŽ äŸäžç©è³ªãè²çŽ æŸåºæ§ç©è³ªã§
ããå Žåã«ã¯ãè²çŽ 圢ææ§ç©è³ªã§ããå Žåãšæ¯èŒ
ããŠã該ååç©èªäœãæè²ã§ããããã«ååå±€ã
æ¿ããæ±æããŠããŸããšããæ¬ ç¹ãæããããšã
æå³ããã ããã«å¥ã®åé¡ç¹ãšããŠè²çŽ äŸäžç©è³ªãè²çŽ æŸ
åºæ§ç©è³ªã§ããå Žåã«ã¯ãè²çŽ 圢ææ§ç©è³ªã§ãã
å Žåãšæ¯èŒããŠã該ååç©ãæè²ã§ãããããã«
éåžžã«æžæããŠããŸããšããæ¬ ç¹ããæããã 以äžã®èŠ³ç¹ãããç±çŸåã«ã©ãŒæå ææã«çšã
ãããè²çŽ äŸäžç©è³ªãšããŠã¯ãè²çŽ æŸåºæ§ç©è³ªã
ãè²çŽ 圢ææ§ç©è³ªã奜ãŸãããšèšããã è²çŽ 圢ææ§ç©è³ªãšããŠã¯ãäŸãã°ç¹éæ58â
123533å·ãå58â149046å·å ¬å ±ããã³ç¹é¡æ58â
33364å·æ现æžã«èšèŒãããŠããååç©ããããã
ãããã®è²çŽ 圢ææ§ç©è³ªãçšããŠããæªã çºè²æ§
ãäœãã€ãããçæããè²çŽ ãååã«ç±è»¢åãã
ãªãã€ãããã«ããªãé«ãçã®åé¡ç¹ããã€ãã
ç¹ã«ãäžèšè²çŽ 圢ææ§ç©è³ªã®ãã¡ãããŒã³ã¿è²çŽ
ã圢æããååç©ã§ã¯ããã®çºè²æ§ãäžååã§ã
ããé«ãç»åæ¿åºŠãæããããŒã³ã¿ç»åãäžããª
ããšããæ¬ ç¹ããã€ãã çºæã®ç®ç æ¬çºæã¯ãäžèšã®åé¡ç¹ã«éã¿çºããããã®
ã§ãæ¬çºæã®ç®çã¯ãé«æ¿åºŠã§ãã€ã«ããªãå°ãª
ãããŒã³ã¿è²çŽ ã®è»¢åç»åãåŸãããšãã§ããç±
çŸåã«ã©ãŒæå ææãæäŸããããšã«ããã çºæã®æ§æ æ¬çºæã®äžèšç®çã¯ãæ¯æäœäžã«ãå°ãªããšã
æå æ§ããã²ã³åéãéå å€ãææ©éå¡©ãè²çŽ äŸ
äžç©è³ªããã³ãã€ã³ããŒãå«æããåçæ§æå±€ã
æããç±çŸåã«ã©ãŒæå ææã«ãããŠãåèšè²çŽ
äŸäžç©è³ªã®å°ãªããšãïŒã€ãäžèšäžè¬åŒïŒ»ïŒœã§
è¡šããããååç©ã§ããããšãç¹åŸŽãšããç±çŸå
ã«ã©ãŒæå ææã äžè¬åŒïŒ»ïŒœ åŒäžãR1ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ããª
ãåºãã¢ã·ã«ã¢ããåºãŸãã¯ãŠã¬ã€ãåºãè¡šã
ãããããR1ã§è¡šããããããããã®åºã¯ãã
ã®ççŽ ååæ°ã®ç·åãïŒã12åã§ãããäžã€ãã
ãã®åºã¯ããããã眮æåºãæããŠããããR2
ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·åºãã¢ãª
ãŒã«ãªãã·åºãã¢ããåºãŸãã¯ãããç°æ®åºãè¡š
ããããã®ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·
åºãã¢ãªãŒã«ãªãã·åºãã¢ããåºããããç°æ®åº
ã¯ã眮æåºãæããŠãããã Arã¯ã¢ãªãŒã«åºãŸãã¯ãããç°æ®åºãè¡šããã
ãã®ã¢ãªãŒã«åºããããç°æ®åºã¯ã眮æåºãæã
ãŠããããã¯âSO2âãŸãã¯âCOâãè¡šããã çºæã®å ·äœçæ§æ åèšäžè¬åŒïŒ»ïŒœã«ãããŠãR1ã¯ããããã
眮æåºãæããŠãããã¢ã«ãã«åºãã¢ãªãŒã«åºã
ã¢ããªãåºãã¢ã·ã«ã¢ããåºãŸãã¯ãŠã¬ã€ãåºã
è¡šããããR1ã§è¡šããããã¢ã«ãã«åºãšããŠã¯ã
çŽéã§ãåå²ç¶ã§ããããäŸãã°ãã¡ãã«åºããª
ã¯ãã«åºããŠã³ãã·ã«åºçãæãããããR1ã§
è¡šããããã¢ã·ã«ã¢ããåºãšããŠã¯ãäŸãã°ãã¢
ã»ãã¢ããåºããã³ãºã¢ããåºçãæããããã äžèšR1ã®ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ããªã
åºãã¢ã·ã«ã¢ããåºãŸãã¯ãŠã¬ã€ãåºã®çœ®æåºãš
ããŠã¯ãããã²ã³ååïŒäŸãã°å¡©çŽ ååçïŒãçŽ
éãããã¯åå²ç¶ã¢ã«ãã«åºïŒäŸãã°ã¡ãã«åºã
ãšãã«åºãïœâããã«åºçïŒãã¢ãªãŒã«åºïŒäŸã
ã°ããšãã«åºçïŒãã·ã¯ãã¢ã«ãã«åºïŒäŸãã°ã·
ã¯ãããã·ã«åºçïŒãã¢ã·ã«ã¢ããåºïŒäŸãã°ã¢
ã»ãã¢ããåºããã³ãºã¢ããåºçïŒãã¹ã«ãã³ã¢
ããåºïŒäŸãã°ã¹ã«ãã³ã¢ããåºãã¡ã¿ã³ã¹ã«ã
ã³ã¢ããåºããã³ãŒã³ã¹ã«ãã³ã¢ããåºçïŒãã¹
ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¹ã«ãã¢ã¢ã€ã«åºãâ
ãšãã«ã¹ã«ãã¢ã¢ã€ã«åºãïŒïŒ®âãžã¡ãã«ã¹ã«
ãã¢ã¢ã€ã«åºçïŒãã¢ã«ã³ãã·ã«ã«ããã«åºïŒäŸ
ãã°ã¡ããã·ã«ã«ããã«åºçïŒãã¢ãªãŒã«ãªãã·
ã«ã«ããã«åºïŒäŸãã°ãã³ãžã«ãªãã·ã«ã«ããã«
åºçïŒãã¢ã·ã«åºïŒäŸãã°ã¢ã»ãã«åºããã³ãŸã€
ã«åºçïŒããããåºãã·ã¢ãåºçãæããããšã
ã§ããã R1ã§è¡šããããåºã®ççŽ ååæ°ã®ç·åã¯ã奜
ãŸããã¯ïŒã12ããã奜ãŸããã¯ïŒãïŒã§ããã åèšäžè¬åŒïŒ»ïŒœã«ãããŠãR2ã¯ããããã
眮æåºãæããŠãããã¢ã«ãã«åºãã¢ãªãŒã«åºã
ã¢ã«ã³ãã·åºãã¢ãªãŒã«ãªãã·åºãã¢ããåºãŸã
ã¯ãããç°æ®åºãè¡šããããR2ã§è¡šããããã¢
ã«ãã«åºã¯çŽéã§ãåå²ç¶ã§ããããäŸãã°ããš
ãã«åºããã·ã«åºããŠã³ãã·ã«åºãããã·ã«åºã
ããªãã·ã«åºããããµãã·ã«åºããšã€ã³ã·ã«åºç
ãæãããããR2ã§è¡šããããã¢ãªãŒã«åºãšã
ãŠã¯ãäŸãã°ãããšãã«åºããããã«åºçãæã
ããããR2ã§è¡šããããã¢ã«ãã³ã·åºãšããŠã¯ã
äŸãã°ããªã¯ãã«ãªãã·åºãããã·ã«ãªãã·åºã
çãæãããããR2ã§è¡šããããã¢ãªãŒã«ãªã
ã·åºãšããŠã¯ãäŸãã°ãããšãã«ãªãã·åºãïŒïŒ
ïŒâãžâïœâãã³ãã«ããšãã«ãªãã·åºãããã
ã«ãªãã·åºçæãããããR2ã§è¡šãããããã
ãç°æ®åºãšããŠã¯ã奜ãŸããã¯ïŒãããã¯ïŒå¡ç°
ã§ãäŸãã°ãããªãžã«åºãã€ãããŸãªã«åºããã³
ãŸãã¢ãŸãªã«åºçãæããããã äžèšR2ã®ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ã
ã·åºãã¢ãªãŒã«ãªãã·åºãã¢ããåºããããç°æ®
åºã®çœ®æåºãšããŠã¯ãããã²ã³ååïŒäŸãã°ãã
ãçŽ ååãå¡©çŽ ååãèçŽ ååçïŒãçŽéããã
ã¯åå²ç¶ã¢ã«ãã«åºïŒäŸãã°ãšãã«åºãïœâãã
ã«åºããªã¯ãã«åºããŠã³ãã·ã«åºãããã·ã«åºã
ãããµãã·ã«åºçïŒãã¢ãªãŒã«åºïŒäŸãã°ããšã
ã«åºçïŒãã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·åºãã
ãããã·åºãïŒâãšãã«ããã·ã«ãªãã·åºããã
ã·ã«ãªãã·åºçïŒãã¢ãªãŒã«ãªãã·åºïŒäŸãã°ã
ããšãã«ãªãã·åºãïŒïŒïŒâãžâïœâãã³ãã«ã
ãšãã«ãªãã·åºçïŒãã¢ã·ã«ã¢ããåºïŒ»äŸãã°ã¢
ã»ãã¢ããåºããã³ãã¢ããåºããã¿ã³ã¢ãã
åºãããã«ã³ã¢ããåºãαâïŒïŒïŒïŒâãžâïœâ
ã¢ã·ã«ããšããã·ïŒã¢ã»ãã¢ããåºãαâïŒïŒïŒ
ïŒâãžâïœâã¢ã·ã«ããšããã·ïŒãã¿ã³ã¢ãã
åºãâã¡ãã«âãããµããã«ã³ã¢ããåºçã
ã¹ã«ãã³ã¢ããåºïŒäŸãã°ãšã¿ã³ã¹ã«ãã³ã¢ãã
åºããã³ãŒã³ã¹ã«ãã³ã¢ããåºããªã¯ã¿ã³ã¹ã«ã
ã³ã¢ããåºãïœâããã·ã«ãªãã·ãã³ãŒã³ã¹ã«ã
ã³ã¢ããåºãâã¡ãã«âããã©ãã«ã³ã¹ã«ãã³
ã¢ããåºçïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ãã¹ã«
ãã¢ã¢ã€ã«åºãâãšãã«ã¹ã«ãã¢ã¢ã€ã«åºã
ïŒïŒ®âãžããã·ã«ã¹ã«ãã¢ã¢ã€ã«åºãâãã
ã©ãã·ã«ã¹ã«ãã¢ã¢ã€ã«åºãâã¡ãã«ââã
ãã©ãã·ã«ã¹ã«ãã¢ã¢ã€ã«åºçïŒãã«ã«ãã¢ã€ã«
åºïŒäŸãã°ãâã¡ãã«ã«ã«ãã¢ã€ã«åºãâãª
ã¯ãã«ã«ã«ãã¢ã€ã«åºãâãããµãã·ã«ã«ã«ã
ã¢ã€ã«åºãâã¡ãã«ââããã©ãã·ã«ã«ã«ã
ã¢ã€ã«åºçïŒãã¢ã«ã³ãã·ã«ã«ããã«åºïŒäŸãã°ã
ã¡ããã·ã«ã«ããã«åºãããã©ãã·ã«ãªãã·ã«ã«
ããã«åºããã³ãžã«ãªãã·ã«ã«ããã«åºçïŒãã¢
ã«ã³ãã·ã¹ã«ããã«åºïŒäŸãã°ãã¡ããã·ã¹ã«ã
ãã«åºããªã¯ãã«ãªãã·ã¹ã«ããã«åºãããã·ã«
ãªãã·ã¹ã«ããã«åºçïŒãã¢ãªãŒã«ãªãã·ã¹ã«ã
ãã«åºïŒäŸãã°ãããšããã·ã¹ã«ããã«åºãïœâ
ããã·ã«ãªãã·ããšããã·ã¹ã«ããã«åºçïŒãã¢
ã«ãã«ã¹ã«ããã«åºïŒäŸãã°ãã¡ã¿ã³ã¹ã«ããã«
åºããšã¿ã³ã¹ã«ããã«åºçïŒãã¢ãªãŒã«ã¹ã«ãã
ã«åºïŒäŸãã°ããã³ãŒã³ã¹ã«ããã«åºãïœâãã«
ãšã³ã¹ã«ããã«åºçïŒãã¢ã«ãã«ããªåºïŒäŸãã°ã
ã¡ãã«ããªåºãããã·ã«ããªåºããã³ãžã«ããªåº
çïŒãã¢ãªãŒã«ããªåºïŒäŸãã°ãããšãã«ããªåºã
ïœâïœâããã«ããšãã«ããªåºçïŒããŠã¬ã€ãåº
ïŒäŸãã°ãâã¡ãã«ãŠã¬ã€ãåºãâããšãã«
ãŠã¬ã€ãåºãïŒïŒ®âãžããã·ã«ãŠã¬ã€ãåºçïŒã
ã¢ã·ã«åºïŒäŸãã°ãã¢ã»ãã«åºããã³ãŸã€ã«åº
çïŒããããåºãã·ã¢ãåºãã«ã«ããã·åºãã¹ã«
ãåºãããããã·åºçãæããããšãã§ãããã
ãã®çœ®æåºãïŒã€ä»¥äžãããšãã¯åãã§ãç°ãªã€
ãŠããŠãããããããã®çœ®æåºã®äžã§ãè²çŽ äŸäž
ç©è³ªã®èæ¡æ£æ§ãããé«ããåºãšããŠã芪氎æ§
åºãç¹ã«ã«ã«ããã·åºãã¹ã«ãåºããã³ãããã®
åºã眮æãã眮æåºã奜ãŸããã äžèšR2ã«ãããŠã眮æåºãæããŠãããã¢ã«
ãã«åºãã¢ã«ã³ãã·åºãã¢ããåºã§è¡šããããåº
ã®å ŽåãççŽ ååæ°ãšããŠã¯ïŒã36ã奜ãŸããã
眮æåºãæããŠãããã¢ãªãŒã«åºãã¢ãªãŒã«ãªã
ã·åºããããç°æ®åºã§è¡šããããåºã®å ŽåãççŽ
ååæ°ãšããŠïŒã38ã奜ãŸããã åèšäžè¬åŒïŒ»ïŒœã«ãããŠãArã¯ã¢ãªãŒã«åº
ãŸãã¯ãããç°æ®åºãè¡šããããArã§è¡šããã
ãã¢ãªãŒã«åºãšããŠã¯ãäŸãã°çœ®æåºãæããŠã
ããããšãã«åºãæããããArã§è¡šããããã
ããç°æ®åºãšããŠã¯ã奜ãŸããã¯ïŒãïŒå¡ç°ã§ã
äŸãã°ãããªãžã«åºãã€ãããŸãªã«åºããã³ãŸã
ã¢ãŸãªã«åºçãæããããããã®ã¢ãªãŒã«åºãã
ããç°æ®åºã®çœ®æåºãšããŠã¯ãã¢ã«ãã«åºïŒäŸã
ã°ãã¡ãã«åºããšãã«åºãããªã¯ããã¡ãã«åºã
ããªãã«ãªãã¡ãã«åºçïŒãã¢ã«ã³ãã·åºïŒäŸã
ã°ãã¡ããã·åºããšããã·åºçïŒãã¢ãªãŒã«ãªã
ã·åºïŒäŸãã°ãããšãã«ãªãã·åºçïŒãã¢ã«ã³ã
ã·ã«ã«ããã«åºïŒäŸãã°ãã¡ããã·ã«ã«ããã«åº
çïŒãã¢ã·ã«ã¢ããåºïŒäŸãã°ãã¢ã»ãã¢ããåº
çïŒãã«ã«ãã¢ã€ã«åºïŒäŸãã°ãã«ã«ãã¢ã€ã«åºã
ã¡ãã«ã«ã«ãã¢ã€ã«åºãããšãã«ã«ã«ãã¢ã€ã«åº
çïŒãã¢ã«ãã«ã¹ã«ããã«åºïŒäŸãã°ãã¡ã¿ã³ã¹
ã«ããã«åºçïŒãã¢ãªãŒã«ã¹ã«ããã«åºïŒäŸãã°ã
ãã³ãŒã³ã¹ã«ããã«åºçïŒãã¹ã«ãã³ã¢ããåº
ïŒäŸãã°ãã¡ã¿ã³ã¹ã«ãã³ã¢ããåºãïœâãã«ãš
ã³ã¹ã«ãã³ã¢ããåºçïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒäŸ
ãã°ãã¹ã«ãã¢ã¢ã€ã«åºãã¡ãã«ã¹ã«ãã¢ã¢ã€ã«
åºãããšãã«ã¹ã«ãã¢ã¢ã€ã«åºããžã¡ãã«ã¹ã«ã
ã¢ã¢ã€ã«åºçïŒãã¢ã«ãã«ããªåºïŒäŸãã°ããšã
ã«ããªåºçïŒãã¢ãªãŒã«ããªåºïŒäŸãã°ãããšã
ã«ããªåºçïŒãã·ã¢ãåºããããåºãããã²ã³å
åïŒäŸãã°ãããçŽ ååãå¡©çŽ ååãèçŽ åå
çïŒãæãããããããã®çœ®æåºãïŒå以äžãã
ãšãã¯ãåãã§ãç°ãªã€ãŠããŠãããã äžè¬åŒïŒ»ïŒœã«ãããŠãã¯âSO2âãŸãã¯â
COâã§è¡šãããããã奜ãŸããã¯âCOâã§ã
ãã åèšäžè¬åŒïŒ»ïŒœã§è¡šããããæ¬çºæã®ããŒã³
ã¿è²çŽ äŸäžç©è³ªã¯ãç±çŸåãããåã«ãããŠã¯è
æ¡æ£åãããååç©ã§ãããç±çŸåã«éããŠã¯æ¡
æ£æ§ã®ããŒã³ã¿è²çŽ ã圢æãåŸãååç©ã§ããã æ¬çºæã«ãããŠãäžèšç±çŸåã«éããŠçæãã
ãæ¡æ£æ§è²çŽ ã®âæ¡æ£æ§âãšã¯ãåèšè²çŽ äŸäžç©
質ããçæãããè²çŽ ãã該è²çŽ äŸäžç©è³ªãå«æ
ããå±€ããç©éé¢ä¿ã«ããé£æ¥å±€ïŒååå±€ïŒã«ç§»
åãåŸãæ§è³ªãæå³ãããã®ç§»åã®æ æ§ã«ã€ããŠ
ã¯ãäŸãã°çæãããè²çŽ èªäœã溶èããæ¡æ£ç§»
åãè¡ãªããããã®ããŸãä»ã®äŸãšããŠã¯ãçæ
ãããè²çŽ ãè²çŽ ã®æº¶å€ã«æº¶è§£ããããŸãã¯ç±æº¶
å€ã«ãã€ãŠå ç±æº¶å€ãããŠç§»åãè¡ãªãããå Žå
çãå«ãŸãããããã«çæãããè²çŽ èªäœãæè¯
æ§ã§ãã€ãŠãçæãããè²çŽ ãæè¯ãæ°åããŠé£
æ¥å±€ãžç§»åããæ æ§ãå«ãŸããã ããã§ãäžèšâæè¯æ§âãšã¯äžè¬ã«çšããããŠ
ãã液äœç¶æ ãçµãããšãªããåºäœããæ°äœã«å€
åããæ§è³ªã ãã§ãªããåºäœã溶èããŠæ¶²äœã«ãª
ãããã®æ¶²äœããæŽã«æ°äœã«å€åããæ§è³ªããå«
ããã®ã§ããã æ¬çºæã«çšããããåèšäžè¬åŒïŒ»ïŒœã§è¡šãã
ããããŒã³ã¿è²çŽ äŸäžç©è³ªã¯ãããŒã³ã¿ã«ãã©ãŒ
æ¯æ žã§ãããã©ãŸã©ã³èªå°äœã®ïŒäœïŒä»¥äžã掻æ§
ç¹ãšããïŒã§ç°å å€ïŒçºè²çŸåäž»è¬ïŒã®é žåäœãš
åå¿ããããŒã³ã¿è²çŽ ã圢æããããããã®éã
ãŒã³ã¿ã«ãã©ãŒæ¯æ žã®ååéãå°ããïŒå¥œãŸãã
ã¯400以äžïŒå Žåã«ã¯ããŒã³ã¿è²çŽ ã®æ¡æ£æ§ã«ã
ããŠæå©ã«ãªãã 以äžãæ¬çºæã«çšããããåèšäžè¬åŒïŒ»ïŒœã§
è¡šããããããŒã³ã¿è²çŽ äŸäžç©è³ªã®ä»£è¡šçå ·äœäŸ
ãèšèŒããããæ¬çºæã¯ãããã«éå®ããããã®
ã§ã¯ãªãã äžè¬åŒãã
ãåŒã
ãè¡šã
ãè¡šã
ãè¡šã

CïŒHïŒïŒ
19 âNHCONHCHïŒ
â
COâ

CïŒHïŒïŒ
19 âNHCONHCHïŒ
â
COâ
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
次ã«æ¬çºæã®åèšäžè¬åŒïŒ»ïŒœã§è¡šããããã
ãŒã³ã¿è²çŽ äŸäžç©è³ªã®å ·äœçåæäŸã瀺ãã äžéäœã®åæ ïŒâããšãã«âïŒâã€ãœãã¿ã³âïŒâããããœ
âïŒâãã©ãŸãã³ã®åæ ïŒâããšãã«âïŒâã€ãœãã¿ã³ã¢ããâïŒâã
ã©ãŸãã³24.5ïœãé ¢é ž250mlã«æº¶è§£ãã宀枩æ¹æ
äžã«äºç¡é žãœãŒã10ïœãå ãããïŒæéæ¹æåŸã
åå¿æ··åç©ãæ°·æ°Žã«ãããæåºããåºäœãéãã
èµ€æ©è²ã®åºäœ21.9ïœãmp199ã201âãåŸãã äŸç€ºååç©ïŒã®åæ äžèšããããœäœ2.74ïœãïœâãªã¯ã¿ãã»ãã«ã³
ãã¯é žç¡æ°Žç©3.51ïœãé ¢é ž50mlã«æº¶è§£ãã宀枩æ¹
æäžã«äºéæ«3.27ïœãå ãããïŒæéæ¹æåŸãäž
溶ç©ãå£éããå£æ¶²ãæ°·æ°Žã«ãããæåºããæ²¹ç¶
ç©ãé ¢é žãšãã«ã«ãŠæœåºãããé ¢é žãšãã«å±€ã¯æ°Ž
æŽã飜åNaHCO3氎溶液ã§æŽæµã也ç¥åŸãæžå§
çå»ãããæ®çç©ãã«ã©ã ã¯ãããã«ãã粟補
ããã¢ã¡ç¶ç©4.27ïœãåŸãã äŸç€ºååç©ïŒã®åæ åèšããããœäœ2.74ïœãé ¢é ž30mlã«æžæ¿ãã宀
æž©æ¹æäžãäºéæ«3.27ïœãå ããã30åéæ¹æã
ãåŸãäžæº¶ç©ãå£éããå°éã®é ¢é žã§æŽã€ããæŽ
液ãšå£æ¶²ãåãããããã«é ¢é žãœãŒã0.8ïœãã©
ãŠãã€ã«ã¯ãã©ã€ã2.19ïœãå ã宀枩äžïŒæéæ¹
æãããåå¿æ¶²ãæ°·æ°Žã«ãããé ¢é žãšãã«ã§æœ
åºãé ¢é žãšãã«æº¶æ¶²ã¯ãæ°ŽæŽã也ç¥åŸãæžå§çå»
ãããæ®çç©ã®ã«ã©ã ã¯ãããã«ããç®çç©ãå
é¢ç²Ÿè£œããã¢ã¡ç¶ç©3.0ïœãåŸãã äŸç€ºååç©13ã®åæ åèšããããœäœ2.74ïœãæ¿å¡©é žïŒmlããšã¿ããŒ
ã«50mlã«æžæ¿ããïŒïŒ PdâC300mgãå ããæ°ŽçŽ
æ¥è§Šç°å ãè¡ã€ããçè«éã®æ°ŽçŽ ãåžåããåŸã
觊åªãå£éããå£æ¶²ãæžå§çå»ãããæ®çç©ã«ïœ
âããã·ã«ãªãã·ããšãã«ã¹ã«ããã«ã¯ãã©ã€ã
3.61ïœãå ãã宀枩ã§ïŒæéæ¹æãããåå¿æ¶²ã
æ°·æ°Žã«ãããæŽã«æ¿å¡©é žã§é žæ§ãšããæåºããæ²¹
ç¶ç©ãé ¢é žãšãã«ã§æœåºãããåèšãšåæ§ã®åŠç
ãè¡ãªãç¡è²åºäœ3.53ïœãmp144ã145âãåŸãã äžèšåæäŸã«ãããŠãäžéäœããã³ç®çç©ã¯
IRãNMRããã³FDâãã¹ã¹ãã¯ãã«ã«ããã
ã®æ§é ã確èªããã ä»ã®äŸç€ºååç©ãäžè¿°ã®åæäŸãšåæ§ãªæ¹æ³ã«
ããåæã§ããã æ¬çºæã«çšããããããŒã³ã¿è²çŽ äŸäžç©è³ªã¯ã
åç¬ã§çšããŠãããããïŒçš®ä»¥äžã䜵çšããŠãã
ãã æ¬çºæã«çšããããããŒã³ã¿è²çŽ äŸäžç©è³ªã¯ã
ç±çŸåæå çµæãå¡åžæ¡ä»¶ãåŠçæ¹æ³çã«ããç°
ãªãããæŠãæ¯æäœïŒm2åœã0.005ïœã10ïœã®ç¯
å²ã§çšãããã奜ãŸããã¯0.1ïœã5.0ïœã§ããã æ¬çºæã«çšããããåè¿°ã®ããŒã³ã¿ã®è²çŽ äŸäž
ç©è³ªãç±çŸåã«ã©ãŒæå ææã«å«æããããã«
ã¯ãäŸãã°ãã«ãã©ãŒã®åæ£æ³ã«é¢ããç±³åœç¹èš±
第2322027å·ã«èšèŒãããŠããããã«é«æ²žç¹æº¶åª
ã«æº¶è§£ããŠå«æãããããšãã§ãããããã«äžèš
ã®åŠå®ãåæ£æ¹æ³ã«ãããŠäžèšé«æ²žç¹æº¶åªã«å¿ èŠ
ã«å¿ããŠäœæ²žç¹æº¶åªã䜵çšããŠè²çŽ äŸäžç©è³ªã溶
解ããŠç±çŸåæå å±€ã«å«æãããããšãã§ããã äžèšã®é«æ²žç¹æº¶åªãšããŠã¯ãäŸãã°ãžâïœâã
ãã«ãã¿ã¬ãŒããããªã¯ã¬ãžã«ãã¹ããšãŒãããž
âãªã¯ãã«ãã¿ã¬ãŒããïœâããã«ããšããŒã«ç
ãããããŸãäœæ²žç¹æº¶åªãšããŠã¯ãäŸãã°é ¢é žã¡
ãã«ãããããªã³é žããã«ãã·ã¯ããããµããŒ
ã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¢ã»ããŒããªã©ã
ç¥ãããŠããããããã®æº¶åªã¯åç¬ã§çšããŠãã
æ··åããŠçšããŠãããããã®ããã«æº¶åªã«æº¶è§£ã
ããè²çŽ äŸäžç©è³ªã¯ãã¢ã«ãã«ãã³ãŒã³ã¹ã«ãã³
é žããã³ã¢ã«ãã«ããã¿ã¬ã³ã¹ã«ãã³é žã®åŠãã¢
ããªã³ç³»çé¢æŽ»æ§å€ããã³ïŒãŸãã¯ãœã«ãã¿ã³ã¢
ãã©ãŠãªã³é žãšã¹ãã«ã®åŠããããªã³ç³»çé¢æŽ»æ§
å€ãå«ããŒã©ãã³çã®èŠªæ°Žæ§ãã€ã³ããŒãå«æã
ã氎溶液ãšæ··åããã³ãã€ããã«ãŸãã¯è¶ é³æ³¢å
æ£è£ 眮çã§ä¹³ååæ£ããç±çŸåæå å±€ã«æ·»å ãã
ããããšãã§ããã äžèšé«æ²žç¹æº¶åªã¯ãè²çŽ äŸäžç©è³ªãå®å šã«æº¶è§£
ããããéã§çšãããããã奜ãŸããã¯è²çŽ äŸäž
ç©è³ªïŒéšïŒéééšïŒã«å¯ŸããŠ0.05ã100éšïŒéé
éšïŒã®ç¯å²ã§çšããããšãã§ããã äžèšä»¥å€ã®å¥œãŸããåæ£æ¹æ³ãšããŠã¯ãã€ãã·
ã€ãŒåæ£ãããã該ãã€ãã·ã€ãŒåæ£ãšã¯ãåäž
ååäžã«èŠªæ°Žæ§æåãšçæ°Žæ§æåãšãæããè²çŽ
äŸäžç©è³ªãã¢ã«ã«ãªæ°Žæº¶æ¶²ã«æº¶è§£ãåæ£ããããš
ãããããã®æº¶è§£ãåæ£ã«ããããæ°Žãšçžæº¶æ§ã
æããææ©æº¶åªãæ·»å ããããå ç±ãæ¹æïŒãã¢
ãžãã€ã¶ãŒãè¶ é³æ³¢åæ£ãªã©ïŒãããããããã¯
çé¢æŽ»æ§å€ã®å©ããããããªã©ããŠããããã¢ã«
ã«ãªæ°Žæº¶æ¶²ã®ã¢ã«ã«ãªãšããŠã¯ãç¡æ©å¡©åºãæ°Žãš
çžæº¶æ§ã®ããææ©å¡©åºãçšããããšãã§ããè²çŽ
äŸäžç©è³ªã溶解ãåæ£ããåŸãå¿ èŠã«å¿ããŠPHã
調æŽããããšãã§ããããã®å Žåã®PH調æŽå€ã«ã¯
æ°Žãšçžæº¶æ§ã®ããææ©åã¯ç¡æ©é žãçšããããšã
ã§ãããåæ£å©å€ãšããŠã®çé¢æŽ»æ§å€ã¯ãã¢ããª
ã³ç³»ããããªã³ç³»æŽ»æ§å€çã§è¯ãããã¢ããªã³ç³»
掻æ§å€ã奜ãŸããã ãªãäžèšãã€ãã·ã€ãŒåæ£ã¯ãã¢ã°ãã¢ãŒåæ£
ãšåŒã°ããããšããããè±åœç¹èš±ç¬¬455556å·ãå
第465823å·ãå第298979å·çã«èšèŒãããŠããæ
è¡å ç©ãåèã«ããããšãã§ããã æ¬çºæã«çšããããããŒã³ã¿è²çŽ äŸäžç©è³ªã¯ã
ç±çŸåæå å±€ã«åŸè¿°ã®ãã€ã³ããŒãçšããŠããã®
ãã€ã³ããŒäžã«äžè¿°ã®ããã«ãã€ãã·ã€ãŒåæ£å
ã¯ãªã€ã«ãããã¯ãåæ£ããããããšãã§ããã
ã®å ŽåãåŸæ¥ã®ããã«ããŒã«ãã«ãŸãã¯ãµã³ãã
ã«çã䜿çšããŠç£šç ããå¿ èŠããªãã®ã§çæéã®
äœæ¥ã§åŸ®çŽ°ãã€å®å®ã«ç±çŸåæå å±€äžã«åæ£ãã
ããããšãã§ããè²çŽ ç»åã®è»¢åæ¿åºŠãæ¹è¯ãã
ããšãã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯åèšã®è²çŽ
äŸäžç©è³ªãšåæ§ã«æå æ§ããã²ã³åéãå«æã
ãã æ¬çºæã«çšããããæå æ§ããã²ã³åéãšããŠ
ã¯ãå¡©åéãèåéãæ²åéãå¡©èåéãå¡©æ²å
éãæ²èåéãå¡©æ²èåéçããããããã該æ
å æ§ããã²ã³åéã¯ãåçæè¡åéã§å ¬ç¥ã®ã·ã³
ã°ã«ãžãšããæ³ãããã«ãžãšããæ³çã®ä»»æã®æ¹
æ³ã§èª¿è£œããããšãã§ããããæ¬çºæã«æŒããŠ
ã¯ãéåžžã®ããã²ã³åéãŒã©ãã³ä¹³å€ã®èª¿æŽæ¹æ³
ã«åŸã€ãŠèª¿è£œããæå æ§ããã²ã³åéä¹³å€ã奜ãŸ
ããçµæãäžããã 該æå æ§ããã²ã³åéä¹³å€ã¯ãåçæè¡åéã§
å ¬ç¥ã®ä»»æã®æ¹æ³ã§ååŠçã«å¢æããŠãè¯ããã
ããå¢ææ³ãšããŠã¯ãéå¢æãã€ãªãŠå¢æãéâ
ã€ãªãŠå¢æãéå å¢æçåçš®ã®æ¹æ³ããããã
ãã äžèšæå æ§ä¹³å€äžã®ããã²ã³åéã¯ãç²ç²åã§
ãã€ãŠã埮ç²åã§ãã€ãŠãè¯ããã奜ãŸããç²å
ãµã€ãºã¯ããã®åŸãçŽ0.001ÎŒmãçŽ1.5ÎŒmã§ããã
ããã«å¥œãŸããã¯çŽ0.01ÎŒmãçŽ0.5ÎŒmã§ããã äžèšã®ããã«èª¿è£œãããæå æ§ããã²ã³åéä¹³
å€ãæ¬çºæã®æå ææã®æ§æå±€ã§ããç±çŸåæ§æ
å å±€ã«æã奜ãŸããé©çšããããšãã§ããã æ¬çºæã«ãããŠãä»ã®æå æ§ããã²ã³åéã®èª¿
補æ³ãšããŠãæå æ§é塩圢ææåãåŸè¿°ããææ©
éå¡©ãšå ±åãããææ©éå¡©ã®äžéšã«æå æ§ããã²
ã³åéã圢æãããããšãã§ããããã®èª¿è£œæ³ã«
çšããããæå æ§é塩圢ææåãšããŠã¯ãç¡æ©ã
ãã²ã³åç©ãäŸãã°ãMXnã§è¡šããããããã²
ã³åç©ïŒããã§ãïŒã¯ïŒšååãNH4åºãŸãã¯é
å±ååãè¡šãããã¯ClãBrãŸãã¯ïŒ©ãè¡šããã
ïœã¯ïŒãååãNH4åºã®æã¯ïŒãïŒãéå±å
åã®æã¯ãã®åå䟡ã瀺ããéå±ååãšããŠã¯ã
ãªããŠã ããããªãŠã ãã«ãªãŠã ãã«ããžãŠã ã
ã»ã·ãŠã ãé ãéãããªãªãŠã ããã°ãã·ãŠã ã
ã«ã«ã·ãŠã ãã¹ããã³ããŠã ãããªãŠã ãäºéã
ã«ãããŠã ãæ°Žéãã¢ã«ãããŠã ãã€ã³ãžãŠã ã
ã©ã³ã¿ã³ãã«ãããŠã ãã¿ãªãŠã ãã²ã«ãããŠ
ã ãé«ãéãã¢ã³ãã¢ã³ããã¹ãã¹ãã¯ãã ãã¢
ãªããã³ãã¿ã³ã°ã¹ãã³ããã³ã¬ã³ãã¬ããŠã ã
éãã³ãã«ããããã±ã«ãããžãŠã ããã©ãžãŠ
ã ããªã¹ããŠã ãã€ãªãžãŠã ãçœéãã»ãªãŠã ç
ãããããããïŒãå«ããã²ã³éå±é¯äœïŒäŸãã°ã
K2PtCl6ïŒK2PtBr6ïŒHAuCl4ïŒïŒNH4ïŒ2IrCl6ïŒ
ïŒNNH4ïŒ3IrCl6ïŒïŒNH4ïŒ2RuCl6ïŒïŒNH4ïŒ3RuCl6ïŒ
ïŒNH4ïŒ3RhCl6ïŒïŒNH4ïŒ3RhBr6çïŒããªããŠã ã
ã©ã€ãïŒäŸãã°ãããã©ã¡ãã«ã¢ã³ã¢ããŠã ãã
ãã€ããããªã¡ãã«ããšãã«ã¢ã³ã¢ããŠã ããã
ã€ããã»ãã«ãšãã«ãžã¡ãã«ã¢ã³ã¢ããŠã ããã
ã€ããïŒâã¡ãã«ãã¢ãŸãªãŠã ãããã€ããããª
ã¡ãã«ãã³ãžã«ã¢ã³ã¢ããŠã ãããã€ãã®ãããª
ïŒçŽã¢ã³ã¢ããŠã ãã©ã€ããããã©ãšãã«ããªã¹
ããªããŠã ãããã€ãã®ãããªïŒçŽããªã¹ããªã
ãŠã ãã©ã€ãããã³ãžã«ãšãã«ã¡ãã«ã¹ã«ãããŠ
ã ãããã€ããïŒâãšãã«ãã¢ãŸãªãŠã ãããã€
ãã®ãããªïŒçŽã¹ã«ãããŠã ãã©ã€ãçïŒããã
ã²ã³åçåæ°ŽçŽ ïŒäŸãã°ããšãŒããã«ã ãããã¢
ãã«ã ãåèåççŽ ãïŒâããã¢âïŒâã¡ãã«ã
ããã³çïŒãâããã²ã³ååç©ïŒïŒ®âã¯ããã³
ãã¯é žã€ãããâããã¢ã³ãã¯é žã€ãããâ
ããã¢ãã¿ã«é žã€ãããâããã¢ã¢ã»ãã¢ã
ããâãšãŒãã³ãã¯é žã€ãããâããã¢ãã¿
ã©ãžãã³ãâã¯ãããã¿ã©ãžãã³ãâããã¢
ã¢ã»ãã¢ããªããïŒïŒ®âãžããã¢ãã³ãŒã³ã¹ã«
ãã³ã¢ãããâããã¢ââã¡ãã«ãã³ãŒã³ã¹
ã«ãã³ã¢ãããïŒïŒïŒâãžããã¢âïŒïŒïŒâãžã¡
ãã«ããã³ãã€ã³çïŒããã®ä»ã®å«ããã²ã³åå
ç©ïŒäŸãã°å¡©åããªããšãã«ã¡ãã«ãèåããªã
ãšãã«ã¡ãã«ãïŒâããã¢é ªé žãïŒâããã¢ãšã¿
ããŒã«çïŒãªã©ããããããšãã§ããã ãããæå æ§ããã²ã³åéããã³æå æ§é塩圢
ææåã¯ãçš®ã ã®æ¹æ³ã«ãããŠçµåããŠäœ¿çšã§
ãã䜿çšéã¯ãè²çŽ äŸäžç©è³ªïŒã¢ã«ã«å¯ŸããŠã
0.002ã¢ã«ã20ã¢ã«ã§ããã奜ãŸããã¯ã0.02ã¢
ã«ã10ã¢ã«ã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã¯ãæ¬çºæã®ã
ãŒã³ã¿è²çŽ äŸäžç©è³ªãå«æããå±€ãå°ãªããšãïŒ
å±€æããŠããã°ããããéè²å ãç·è²å ãèµ€è²å
ã«æå æ§ãæããåå±€ãå³ã¡ç±çŸåéæå æ§å±€ã
ç±çŸåç·æå æ§å±€ãç±çŸåèµ€æå æ§å±€ãšããŠå€å±€
æ§æãšããããšãã§ããããŸããåè²æå å±€ãïŒ
局以äžïŒäŸãã°ãé«æ床局ãšäœæ床局ïŒã«åå²ã
ãŠèšããããšãã§ããã äžèšã®å Žåãåã çšããããéæå æ§ããã²ã³
åéä¹³å€ãç·æå æ§ããã²ã³åéä¹³å€ãèµ€æå æ§
ããã²ã³åéä¹³å€ã¯ãåèšããã²ã³åéä¹³å€ã«å
çš®ã®åå å¢æè²çŽ ãå ããããšã«ãã€ãŠåŸãããš
ãã§ããã æ¬çºæã«çšãããã代衚çãªåå å¢æè²çŽ ãšã
ãŠã¯ãäŸãã°ã·ã¢ãã³ãã¡ãã·ã¢ãã³ãã³ã³ãã¬
ãã¯ã¹ïŒïŒæ žåã¯ïŒæ žã®ïŒã·ã¢ãã³ãããããŒã©
âã·ã¢ãã³ãã¹ããªã«ãããã·ã¢ãã³ããªããœã
ãŒã«çãããããããã·ã¢ãã³é¡ã®è²çŽ ã®ãã¡ã§
ãã¢ãŸãªã³ããªããµãŸãªã³ããããªã³ãããªãž
ã³ããªããµãŸãŒã«ããã¢ãŸãŒã«ãã»ã¬ããŸãŒã«ã
ã€ãããŸãŒã«ã®æ§ãªå¡©åºæ§æ žãæãããã®ããã
ã奜ãŸããããã®æ§ãªæ žã«ã¯ã¢ã«ãã«åºãã¢ã«ã
ã¬ã³åºãããããã·ã¢ã«ãã«åºãã¹ã«ãã¢ã«ãã«
åºãã«ã«ããã·ã¢ã«ãã«åºãã¢ããã¢ã«ãã«åºãŸ
ãã¯çž®åççŽ ç°åŒãŸãã¯è€çŽ ç°è²ç°ãäœãäºã®åº
æ¥ããšããã³åºãæããŠããŠãããããŸã察称圢
ã§ãé察称圢ã§ãããããŸãã¡ãã³éãããªã¡ã
ã³éã«ã¢ã«ãã«åºãããšãã«åºããšããã³åºãã
ããç°çœ®æåºãæããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ã¯äžèšå¡©åºæ§æ žã®ä»ã«ãäŸã
ã°ããªããã³ãã€ã³æ žãããŒããã³æ žããªããµãŸ
ãªãžã³ãžãªã³æ žããã¢ãŸãªãžã³ãžãªã³æ žããã«ã
ããŒã«é žæ žããã¢ãŸãªã³ããªã³æ žãããããããª
ã«æ žããã©ãŸãã³æ žã®æ§ãªé žæ§æ žãæããŠããŠã
ããããããã®é žæ§æ žã¯æŽã«ã¢ã«ãã«åºãã¢ã«ã
ã¬ã³åºãããšãã«åºãã«ã«ããã·ã¢ã«ãã«åºãã¹
ã«ãã¢ã«ãã«åºãããããã·ã¢ã«ãã«åºãã¢ã«ã³
ãã·ã¢ã«ãã«åºãã¢ã«ãã«ã¢ãã³åºåã¯ãããç°
åŒæ žã§çœ®æãããŠããŠããããåå¿ èŠãªãã°ãã
ãã®è²çŽ ãçµåãããŠäœ¿çšããŠããããæŽã«ã¢ã¹
ã³ã«ãã³é žèªå°äœãã¢ã¶ã€ã³ãã³ã«ãããŠã å¡©ã
ææ©ã¹ã«ãã³é žçãäŸãã°ç±³åœç¹èš±ç¬¬2933390å·ã
å第2937089å·ã®æ现æžçã«èšèŒãããŠããæ§ãª
å¯èŠå ãåžåããªãè¶ å¢ææ§æ·»å å€ã䜵çšããã
ãšãã§ããã ãããè²çŽ ã®æ·»å éã¯ããã²ã³åéãŸãã¯ãã
ã²ã³åé圢ææåïŒã¢ã«åœãïŒÃ10-4ã¢ã«ãïŒã¢
ã«ã§ãããæŽã«å¥œãŸããã¯ãïŒÃ10-4ã¢ã«ãïŒÃ
10-1ã¢ã«ã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«çšããããæ
æ©éå¡©ãšããŠã¯ãç¹å ¬æ43â4921å·ãå44â
26582å·ãå45â18416å·ãå45â12700å·ãå45
â22185å·ãç¹éæ49â52626å·ãå52â31728å·ã
å52â137321å·ãå52â141222å·ãå53â36224
å·ããã³å53â37610å·çã®åå ¬å ±ãªãã³ã«ç±³åœ
ç¹èš±ç¬¬3330633å·ãå第3794496å·ãå第4105451
å·ãå第4123274å·ãå第4168980å·çã®åæ现æž
äžã«èšèŒãããŠãããããªèèªæã«ã«ãã³é žã®é
å¡©ãäŸãã°ã©ãŠãªã³é žãããªã¹ãã³é žéããã«ã
ãã³é žéãã¹ãã¢ãªã³é žéãã¢ã©ããã³é žéãã
ãã³é žéãαâïŒïŒâããšãã«ããã©ãŸãŒã«ããªïŒ
é ¢é žéãªã©ãè³éŠæã«ã«ãã³é žéãäŸãã°å®æ¯éŠ
é žéããã¿ã«é žéãªã©ãç¹å ¬æ44â26582å·ãå
45â12700å·ãå45â18416å·ãå45â22185å·ã
ç¹éæ52â31728å·ããã³å52â137321å·ã®åå ¬
å ±ã䞊ã³ã«ç¹é¡æ57â1065å·ãå57â1066å·çã®
åæ现æžã«èšèŒãããŠãããããªã€ããåºã®é
å¡©ãäŸãã°ãã³ãŸããªã¢ãŸãŒã«éãïŒâãããã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã¯ãããã³ãŸããªã¢ãŸ
ãŒã«éãïŒâã¡ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒ
âã¹ã«ããã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¢ãããã³ãŸããªã¢
ãŸãŒã«éãïŒâã«ã«ããã·ãã³ãŸããªã¢ãŸãŒã«
éãã€ãããŸãŒã«éããã³ãºã€ãããŸãŒã«éãïŒ
âããããã³ãºã€ãããŸãŒã«éããã©ãŸãŒã«éã
ãŠã©ãŸãŒã«éãïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«éã
1Hâããã©ãŸãŒã«éãïŒâã¢ããâïŒâãã³ãž
ã«ããªâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«éããµãã«ãª
ã³éããã¿ã©ãžãã³éããã¿ã«ã€ããéãªã©ãã
ã®ä»ïŒâã¡ã«ã«ãããã³ãŸãªããµãŸãŒã«éãã¡ã«
ã«ãããªããµãžã¢ãŸãŒã«éãïŒâã¡ã«ã«ãããã³
ãŸãã¢ãŸãŒã«éãïŒâã¡ã«ã«ãããã³ãºã€ãããŸ
ãŒã«éãïŒâã¡ã«ã«ããâïŒâããšãã«âïŒïŒ
ïŒïŒïŒâããªã¢ãŸãŒã«éãïŒâããããã·âïŒâ
ã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ãã³é
ããã³ïŒâã¡ãã«âïŒâããããã·âïŒïŒïŒïŒ
ïŒïŒïŒïŒïŒâãã³ã¿ã¶ã€ã³ãã³éãªã©ãæããã
ãã以äžã®ææ©éå¡©ã®ãã¡ã§ãã€ããåºã®éå¡©ã
奜ãŸãããç¹ã«ãã³ãŸããªã¢ãŸãŒã«èªå°äœã®é
å¡©ããã奜ãŸããã¯ã¹ã«ããã³ãŸããªã¢ãŸãŒã«èª
å°äœã®éå¡©ã奜ãŸããã æ¬çºæã«çšããããææ©éå¡©ã¯ãåé¢ãããã®
ãé©åœãªæ段ã«ãããã€ã³ããŒäžã«åæ£ããŠäœ¿çš
ã«äŸããŠããããããŸãé©åœãªãã€ã³ããŒäžã§é
å¡©ã調補ããåé¢ããã«ãã®ãŸãŸäœ¿çšã«äŸããŠã
ããã 該ææ©éå¡©ã®äœ¿çšéã¯ãæ¯æäœïŒm2åœã0.05ïœ
ã10.0ïœã§ããã奜ãŸããã¯0.2ïœã2.0ïœã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«çšããããé
å å€ã¯ãç±çŸåã«ã©ãŒæå ææã®åéã§éåžžçšã
ããããã®ãçšããããšãã§ããäŸãã°ç±³åœç¹èš±
第3531286å·ãå第3761270å·ãå第3764328å·å
æ现æžããŸãRDNo.12146ãåNo.15108ãåNo.
15127ããã³ç¹éæ56â27132å·å ¬å ±çã«èšèŒã®ïœ
âããšãã¬ã³ãžã¢ãã³ç³»ããã³ïœâã¢ããããšã
ãŒã«ç³»çŸåäž»è¬ãããªã¹ããªãã¢ããããšããŒã«
ç³»ããã³ã¹ã«ãã³ã¢ããããšããŒã«ç³»çŸåäž»è¬ã
ãŸãããã©ãŸã³ç³»çºè²çŸåäž»è¬ãæããããããŸ
ããç±³åœç¹èš±ç¬¬3342599å·ãå第3719492å·ãç¹é
æ53â135628å·ãå54â79035å·çã«èšèŒãããŠ
ããçºè²çŸåäž»è¬ãã¬ã«ãŒãµãŒçãæå©ã«çšãã
ããšãã§ããã ç¹ã«å¥œãŸããéå å€ãšããŠãç¹éæ56â146133
å·ã«èšèŒãããŠããäžèšäžè¬åŒïŒ»ïŒœã§è¡šããã
ãéå å€ãæããããã äžè¬åŒïŒ»ïŒœ åŒäžãR3ããã³R4ã¯æ°ŽçŽ ååããŸãã¯çœ®æåº
ãæããŠãããççŽ ååæ°ïŒã30ïŒå¥œãŸããã¯ïŒ
ãïŒïŒã®ã¢ã«ãã«åºãè¡šãããR3ãšR4ãšã¯éç°
ããŠè€çŽ ç°ã圢æããŠããããR5ïŒR6ïŒR7ãã
ã³R8ã¯æ°ŽçŽ ååãããã²ã³ååãããããã·åºã
ã¢ããåºãã¢ã«ã³ãã·åºãã¢ã·ã«ã¢ããåºãã¹ã«
ãã³ã¢ããåºãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºãŸãã¯
眮æåºãæããŠãããççŽ ååæ°ïŒã30ïŒå¥œãŸã
ãã¯ïŒãïŒïŒã®ã¢ã«ãã«åºãè¡šãããR5ãšR3ã
ãã³R7ãšR4ã¯ããããéç°ããŠè€çŽ ç°ã圢æã
ãŠããããïŒã¯ã¢ã«ã«ãªéå±ååãã¢ã³ã¢ããŠã
åºãå«çªçŽ ææ©å¡©åºãŸãã¯ç¬¬ïŒçŽçªçŽ ååãå«ã
ååç©ãè¡šããã äžèšäžè¬åŒïŒ»ïŒœã«ãããå«çªçŽ ææ©å¡©åºãšã¯
ç¡æ©é žãšå¡©ãçæãåŸãå¡©åºæ§ã瀺ãçªçŽ ååã
å«ãææ©ååç©ã§ãããç¹ã«éèŠãªææ©å¡©åºãšã
ãŠã¯ã¢ãã³ååç©ãæããããããããŠéç¶ã®ã¢
ãã³ååç©ãšããŠã¯ç¬¬ïŒçŽã¢ãã³ã第ïŒçŽã¢ã
ã³ã第ïŒçŽã¢ãã³ãªã©ãããŸãç°ç¶ã®ã¢ãã³åå
ç©ãšããŠã¯å žåçãªãããç°åŒææ©å¡©åºã®äŸãšã
ãŠèåãªããªãžã³ããããªã³ããããªãžã³ãã€ã
ããŸãŒã«çãæããããããã®ä»ããããã·ã«ã¢
ãã³ãããã©ãžã³ãã¢ããžã³ãªã©ã®ååç©ãéç¶
ã®ã¢ãã³ãšããŠæçšã§ããããŸãå«çªçŽ ææ©å¡©åº
ã®å¡©ãšããŠã¯äžèšã®ãããªææ©å¡©åºã®ç¡æ©é žå¡©
ïŒäŸãã°å¡©é žå¡©ãç¡«é žå¡©ãç¡é žå¡©çïŒã奜ãŸãã
çšãããããäžæ¹ãäžèšäžè¬åŒã«ããã第ïŒçŽçª
çŽ ãå«ãååç©ãšããŠã¯ãïŒäŸ¡ã®å ±æçµåãæã
ãçªçŽ ååç©ã®å¡©ãŸãã¯æ°Žé žåç©çãæããã
ãã 次ã«ãåèšäžè¬åŒããã§ç€ºãããéå å€ã®å¥œ
ãŸããå ·äœäŸã以äžã«ç€ºãã äžèšäžè¬åŒïŒ»ïŒœã§è¡šããããéå å€ã¯ãå ¬ç¥
ã®æ¹æ³ãäŸãã°HoubenâWeylïŒMethodender
Organischen ChemieïŒBandXIïŒ2645â703é ã«
èšèŒãããŠããæ¹æ³ã«åŸã€ãŠåæã§ããããã®ä»
以äžã«è¿°ã¹ããããªéå å€ãçšããããšãã§ã
ãã å³ã¡ãããšããŒã«é¡ïŒäŸãã°ïœâããšãã«ããš
ããŒã«ãïœâã¡ããã·ããšããŒã«ãïŒïŒïŒâãžâ
tertâããã«âïœâã¯ã¬ãŸãŒã«ãâã¡ãã«âïœ
âã¢ããããšããŒã«çïŒãã¹ã«ãã³ã¢ããããšã
ãŒã«é¡ïŒ»äŸãã°ïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããããš
ããŒã«ãïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããããšããŒ
ã«ãïŒïŒïŒâãžã¯ããâïŒâãã³ãŒã³ã¹ã«ãã³ã¢
ããããšããŒã«ãïŒïŒïŒâãžããã¢âïŒâïŒïœâ
ãã«ãšã³ã¹ã«ãã³ã¢ããïŒããšããŒã«çããŸã
ã¯ããªããããã·ãã³ãŒã³é¡ïŒäŸãã°ãã€ããã
ãã³ãtertâããã«ãã€ããããã³ãïŒïŒïŒâãž
ã¡ãã«ãã€ããããã³ãã¯ãããã€ããããã³ã
ã«ã«ããã·ãã€ããããã³ãã«ãã³ãŒã«ãïŒâã«
ã«ããã·ã«ãã³ãŒã«çïŒãããããŒã«é¡ïŒäŸãã°
αâããããŒã«ãβâããããŒã«ãïŒâã¢ããã
ãããŒã«ãïŒâã¡ããã·ããããŒã«çïŒãããã
ãã·ããããã«é¡ããã³ã¡ãã¬ã³ãã¹ããããŒã«
é¡ïŒ»äŸãã°ïŒïŒ1â²âãžããããã·âïŒïŒ2â²âãã
ããã«ãïŒïŒ6â²âãžããã¢âïŒïŒ2â²âãžãããã
ã·âïŒïŒ1â²âããããã«ãïŒïŒ6â²âãžãããâ
ïŒïŒ2â²âãžããããã·âïŒïŒ1â²âããããã«ã
ïŒïŒ4â²âãžã¡ããã·âïŒïŒ1â²âãžããããã·â
ïŒïŒ2â²âããããã«ããã¹ïŒïŒâããããã·âïŒ
âãããã«ïŒã¡ã¿ã³çãã¡ãã¬ã³ãã¹ããšããŒ
ã«é¡ïŒ»äŸãã°ïŒïŒïŒâãã¹ïŒïŒâããããã·â
ïŒïŒïŒâãžã¡ãã«ããšãã«ïŒâïŒïŒïŒïŒïŒâããª
ã¡ãã«ãããµã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·
âïŒâtertâããã«âïŒâã¡ãã«ããšãã«ïŒã¡ã¿
ã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒâãž
âtertâããã«ããšãã«ïŒã¡ã¿ã³ãïŒïŒïŒâã¡ã
ã¬ã³ãã¹ïŒïŒâããããã·âïŒâtertâããã«â
ïŒâã¡ãã«ããšãã«ïŒâïŒâã¡ãã«ããšããŒã«ã
αâããšãã«âαïŒÎ±âãã¹ïŒïŒâããããã·â
ïŒïŒïŒâãžâtertâããã«ããšãã«ïŒã¡ã¿ã³ãα
âããšãã«âαïŒÎ±âãã¹ïŒïŒâããããã·âïŒ
âtertâããã«âïŒâã¡ãã«ããšãã«ïŒã¡ã¿ã³ã
ïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒâãžã¡ã
ã«ããšãã«ïŒâïŒâã¡ãã«ãããã³ãïŒïŒïŒïŒïŒïŒ
ïŒâããã©ãã¹ïŒïŒâããããã·âïŒïŒïŒâãžã¡
ãã«ããšãã«ïŒâïŒïŒïŒâãšãã«ãã³ã¿ã³ãïŒïŒ
ïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒâãžã¡ãã«ã
ãšãã«ïŒãããã³ãïŒïŒïŒâãã¹ïŒïŒâãããã
ã·âïŒâã¡ãã«âïŒâtertâããã«ããšãã«ïŒã
ããã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒ
âãžâtertâããã«ããšãã«ïŒãããã³çãã¢
ã¹ã³ã«ãã³é žé¡ãïŒâãã©ãŸãªãã³é¡ããã©ãŸã
ã³é¡ãããã©ãŸã³é¡ããã³ãã©ããšãã¬ã³ãžã¢ã
ã³é¡ãæããããã ãããéå å€ã¯åç¬ãæãã¯ïŒçš®ä»¥äžçµåããŠ
çšããããšãã§ãããç°å å€ã®äœ¿çšéã¯ã䜿çšã
ããæå æ§ããã²ã³åéã®çš®é¡ãææ©é žéå¡©ã®çš®
é¡ããã³ãã®ä»ã®æ·»å å€ã®çš®é¡ãªã©ã«äŸåãã
ããéåžžã¯è²çŽ äŸäžç©è³ªïŒã¢ã«ã«å¯ŸããŠ0.05ã10
ã¢ã«ã®ç¯å²ã§ããã奜ãŸããã¯0.1ãïŒã¢ã«ã§ã
ãã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãäžèšåæ
å以å€ã«å¿ èŠã«å¿ãå皮添å å€ãæ·»å ããããšã
ã§ãããäŸãã°çŸåä¿é²å€ãšããŠã¯ãç±³åœç¹èš±ç¬¬
3220840å·ãå第3531285å·ãå第4012260å·ãå
第4060420å·ãå第4088496å·ãå第4207392å·å
æ现æžãRDNo.15733ãåNo.15734ãåNo.15776ã
ç¹éæ56â130745å·ãå56â132332å·çã«èšèŒã
ããå°¿çŽ ãã°ã¢ããžãŠã ããªã¯ããã¢ã»ããŒãç
ã®ã¢ã«ã«ãªæŸåºå€ãç¹å ¬æ45â12700å·èšèŒã®æ
æ©é žãç±³åœç¹èš±ç¬¬3667959å·èšèŒã®ãâCOâïŒâ
SO2âïŒâSOâåºãæããéæ°Žæ§æ¥µæ§æº¶åªåå
ç©ãç±³åœç¹èš±ç¬¬3438776å·èšèŒã®ã¡ã«ãããªãŒã
ãŒãç±³åœç¹èš±ç¬¬3666477å·ãç¹éæ51â19525å·ã«
èšèŒã®ããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«é¡çãããããŸ
ãè²èª¿å€ãšããŠã¯ãäŸãã°ç¹éæ46â4928å·ãå
46â6077å·ãå49â5019å·ãå49â5020å·ãå49
â91215å·ãå49â107727å·ãå50â2524å·ãå
50â97132å·ãå50â67641å·ãå50â114217å·ã
å52â33722å·ãå52â99813å·ãå53â1020å·ã
å53â55115å·ãå53â76020å·ãå53â125014
å·ãå54â156523å·ãå54â156524å·ãå54â
156525å·ãå54â156526å·ãå55â4060å·ãå55
â4061å·ãå55â32015å·çã®å ¬å ±ãªãã³ã«è¥¿ç¬
ç¹èš±ç¬¬5140406å·ãå第2147063å·ãå2220618å·ã
ç±³åœç¹èš±ç¬¬3080254å·ãå第3847612å·ãå第
3782941å·ãå第3994732å·ãå第4123282å·ãå
第4201582å·çã®åæ现æžã«èšèŒãããŠããåå
ç©ã§ãããã¿ã©ãžãã³ããã¿ã«ã€ããããã©ãŸã
ã³ããããŸãªãã³ãâããããã·ããã¿ã«ã€ã
ãããã³ããªããµãžã³ãããããªããµãžã³ãžãª
ã³ãïŒïŒïŒâãžãããâãã¿ã©ãžã³ãžãªã³ãïŒïŒ
ïŒâãžãããâïŒïŒïŒâãªããµãžã³âïŒïŒïŒâãž
ãªã³ããªãã·ããªãžã³ãã¢ããããªãžã³ãããã
ãã·ãããªã³ãã¢ãããããªã³ãã€ãœã«ã«ãã¹ã
ãªã«ãã¹ã«ãã³ã¢ããã2HâïŒïŒïŒâãã³ãŸã
ã¢ãžã³âïŒïŒïŒâïŒ3HïŒãžãªã³ããã³ãŸããªã¢ãž
ã³ãã¡ã«ã«ããããªã¢ãŸãŒã«ããžã¡ã«ã«ãããã
ã©ã¶ãã³ã¿ã¬ã³ããã¿ã«é žãããã¿ã«é žããã¿ã«
ã¢ãã³é žçãããããããã®ïŒã€ãŸãã¯ããã以
äžãšã€ãããŸãŒã«ååç©ãšã®æ··åç©ããŸããã¿ã«
é žãããã¿ã«é žçã®é žãŸãã¯é žç¡æ°Žç©ã®å°ãªããš
ãïŒã€ããã³ãã¿ã©ãžã³ååç©ã®æ··åç©ãããã«
ã¯ããã¿ã©ãžã³ãšãã¬ã€ã³é žãã€ã¿ã³ã³é žããã
ãªã³é žãã²ã³ããžã³é žçã®çµåãçãæããããš
ãã§ããããŸããç¹éæ58â189628å·ãå58â
193460å·å ¬å ±ã«èšèŒããããïŒâã¢ããâïŒâã¡
ã«ã«ããâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«é¡ãïŒâã¢
ã·ã«ã¢ããâïŒâã¡ã«ã«ããâïŒïŒïŒïŒïŒâããª
ã¢ãŸãŒã«é¡ãæå¹ã§ããã ãŸãããã«ãã«ããªé²æ¢å€ãšããŠã¯ãäŸãã°ã
ç¹å ¬æ47â11113å·ãç¹éæ49â90118å·ãå49â
10724å·ãå49â97613å·ãå50â101019å·ãå49
â130720å·ãå50â123331å·ãå51â47419å·ã
å51â57435å·ãå51â78227å·ãå51â104338
å·ãå53â19825å·ãå53â20923å·ãå51â
50725å·ãå51â3223å·ãå51â42529å·ãå51â
81124å·ãå54â51821å·ãå55â93149å·çã®å ¬
å ±ããªãã³ã«è±åœç¹èš±ç¬¬1455271å·ãç±³åœç¹èš±ç¬¬
3885968å·ãå第3700457å·ãå第4137079å·ãå
第4138265å·ã西ç¬ç¹èš±ç¬¬2617907å·çã®åæ现æž
ã«èšèŒãããŠããååç©ã§ãã第ïŒæ°Žéå¡©ãæã
ã¯é žåå€ïŒäŸãã°ãâããã²ãã¢ã»ãã¢ããã
âããã²ãã³ãã¯é žã€ãããéå¡©çŽ é žããã³ã
ã®å¡©é¡ãç¡æ©éé žåç©ãéç¡«é žå¡©çïŒæãã¯ãé ž
ããã³ãã®å¡©ïŒäŸãã°ãã¹ã«ãã€ã³é žãã©ãŠãªã³
é žãªããŠã ãããžã³ããžãã«ãã³é žãããªã¹ã«ã
ã³é žçïŒãæãã¯ã€ãªãŠå«æååç©ïŒäŸãã°ãã¡
ã«ã«ããååç©æŸåºæ§ååç©ãããªãŠã©ã·ã«ããž
ã¹ã«ãã€ããã€ãªãŠåäœãã¡ã«ã«ããâïŒïŒïŒïŒ
ïŒâããªã¢ãŸãŒã«ããã¢ãŸãªã³ããªã³ãããªã¹ã«
ãã€ãååç©çïŒããã®ä»ããªããµãŸãªã³ãïŒïŒ
ïŒïŒïŒâããªã¢ãŸãŒã«ããã¿ã«ã€ããçã®ååç©
ãæããããã ãŸãå®å®å€ãšããŠç¹ã«åŠçåŸã®ããªã³ãã¢ãŠã
é²æ¢å€ãåæã«çšããŠããããäŸãã°ç¹éæ48â
45228å·ãå50â119624å·ãå50â120328å·ãå
53â46020å·å ¬å ±çã«èšèŒã®ããã²ã³åçåæ°ŽçŽ
é¡ãå ·äœçã«ã¯ããã©ããã¢ãã¿ã³ãããªããã¢
ãšã¿ããŒã«ãïŒâããã¢âïŒâããªã«ã¢ã»ãã¢ã
ããïŒâããã¢âïŒâããªã«ã¹ã«ããã«ã¢ã»ãã¢
ãããïŒâããªããã¢ã¡ãã«ã¹ã«ããã«ãã³ãŸã
ã¢ãŸãŒã«ãïŒïŒïŒâãã¹ïŒããªããã¢ã¡ãã«ïŒâ
ïŒâã¡ãã«ããªã¢ãžã³ãªã©ããããããã ç¹ã«æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯åçš®ã®
ç±æº¶å€ãæ·»å ãããããšã奜ãŸãããæ¬çºæã®ç±
溶å€ãšã¯ç±çŸåããã³ïŒãŸãã¯ç±è»¢åãä¿é²ãã
ç©è³ªã§ããã°ããã奜ãŸããã¯åžžæž©äžã§ã¯åºäœã
ååºäœåã¯æ¶²äœã§ãã€ãŠå ç±ããããšã«ãã€ãŠã
ã€ã³ããŒäžã§æº¶è§£åã¯æº¶èããç©è³ªã§ãã€ãŠã奜
ãŸããã¯å°¿çŽ èªå°äœïŒäŸãã°ããžã¡ãã«ãŠã¬ã¢ã
ãžãšãã«ãŠã¬ã¢ãããšãã«ãŠã¬ã¢çïŒãã¢ããèª
å°äœïŒäŸãã°ãã¢ã»ãã¢ããããã³ãºã¢ããçïŒã
å€äŸ¡ã¢ã«ã³ãŒã«é¡ïŒäŸãã°ãïŒïŒïŒâãã³ã¿ã³ãž
ãªãŒã«ãïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«ãïŒïŒïŒâã·
ã¯ããããµã³ãžãªãŒã«ããã³ã¿ãšãªã¹ãªããŒã«ã
ããªã¡ãããŒã«ãšã¿ã³çïŒãåã¯ããªãšãã¬ã³ã°
ãªã³ãŒã«é¡ãæããããã詳ããå ·äœäŸãšããŠ
ã¯ãç¹é¡æ58â104249ã«èšèŒãããŠãããããã
ã®ç±æº¶å€ã¯åç¬ã§ãäºçš®ä»¥äžäœµçšããŠçšããŠãè¯
ãã ãŸãã«ããªé²æ¢å€ãšããŠã¯ãç¹é¡æ59â56506
å·ã«èšèŒã®ãã€ããããã³èªå°äœïŒäŸãã°ããžâ
ïœâãªã¯ãã«ãã€ããããã³ãããã«ãã«ãã€ã
ãããã³çïŒãç¹é¡æ59â66380å·ã«èšèŒã®ãã€
ããããã³èªå°äœãšãã³ãŸããªã¢ãŸãŒã«èªå°äœ
ïŒäŸãã°ãïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«ãïŒâ
ã«ã«ããã·ãã³ãŸããªã¢ãŸãŒã«çïŒãšã®äœµçšã奜
ãŸããçšããããšãã§ããã ãŸãç¹å ¬æ46â5393å·ãç¹éæ50â54329å·ã
å50â77034å·åå ¬å ±èšèŒã®ããã«å«ã€ãªãŠåå
ç©ãçšããŠåŸåŠçãè¡ãªã€ãŠãããã ããã«ã¯ãç±³åœç¹èš±ç¬¬3301678å·ãå第3506444
å·ãå第3824103å·ãå第3844788å·åæ现æžã«èš
èŒã®ã€ãœããŠãããŠã ç³»ã¹ã¿ãã©ã€ã¶ãŒãã¬ã«ãŒ
ãµãŒããŸãç±³åœç¹èš±ç¬¬3669670å·ãå第4012260
å·ãå第4060420å·æ现æžçã«èšèŒãããã¢ã¯ã
ããŒã¿ãŒã¹ã¿ãã©ã€ã¶ãŒãã¬ã«ãŒãµãŒçãå«æã
ãŠãããã ãŸããã·ãšç³ãNH4FeïŒSO4ïŒ2ã»12H2Oçã®æ°Ž
æŸåºå€ãçšããŠããããããã«ãŸããç¹éæ56â
132332å·ã®ããã«æ°ŽãäŸçµŠãç±çŸåãè¡ãªã€ãŠã
ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãããã«äž
èšæå以å€ã«å¿ èŠã«å¿ããŠãåå å¢æææããã¬
ãŒã·ãšã³é²æ¢ææãèå å¢çœå€ã硬èå€ã垯é»é²
æ¢å€ãå¯å¡å€ã延å±å€çåçš®ã®æ·»å å€ãå¡åžå©å€
çãæ·»å ãããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãã€ã³ããŒ
ãšããŠã¯èŠªæ°Žæ§ã®ãã€ã³ããŒãç¹ã«å¥œãŸãããã
çæ°Žæ§ãã€ã³ããŒãäžéšäœµçšããŠããããæ¬çºæ
ã«å¥œãŸããçšãããã芪氎æ§ãã€ã³ããŒãšã¯ãæ°Ž
ãããã¯ãæ°Žãšææ©æº¶åªã®æ··å液ã«å¯æº¶ã§ããã
ã®ããããäŸãã°ãŒã©ãã³ããŒã©ãã³èªå°äœã®åŠ
ãèçœè³ªãã»ã«ããŒã¹èªå°äœãããã¹ãã©ã³ã®åŠ
ãããªãµãã«ã©ã€ããã¢ã©ãã¢ãŽã çã®åŠã倩ç¶
ç©è³ªããã³æå¹ãªããªããŒãšããŠãããªããã«ã¢
ã»ã¿ãŒã«ïŒå¥œãŸããã¯ã¢ã»ã¿ãŒã«å床ã20ïŒ ä»¥
äžãäŸãã°ããªããã«ããã©ãŒã«ïŒãããªã¢ã¯ãª
ã«ã¢ãããããªããã«ãããªãã³ããšãã«ã»ã«ã
ãŒã¹ãããªããã«ã¢ã«ã³ãŒã«ïŒã±ã³åçã75ïŒ ä»¥
äžã®ãã®ã奜ãŸããïŒçã奜ãŸãããããããã®
ã¿ã«éå®ããããã®ã§ã¯ãªãããŸãå¿ èŠãªãã°ïŒ
皮以äžæ··å䜿çšããŠãããããã€ã³ããŒã®éã¯å
æå å±€ãããæ¯æäœïŒm2ã«å¯ŸããŠã0.1ïœã20ïœã
奜ãŸããã¯0.5ãïŒïœã§ããã æ¬çºæã®äžèšåæåãå«ãå±€ããã³ãã®ä»ã®å±€
ã¯åºç¯å²ã®åçš®æ¯æäœäžã«å¡åžãããæ¬çºæã®ã
ãŒã³ã¿è²çŽ äŸäžç©è³ªãå«ãç±çŸåæå æ§å±€ã®åã¿
ã¯ã也ç¥åŸ1ÎŒmã1000ÎŒmã奜ãŸããã¯2ÎŒmã
20ÎŒmã§ãããæ¬çºæã«äœ¿çšãããæ¯æäœãšããŠ
ã¯ãã»ã«ããŒã¹ãã€ãã¬ãŒããã€ã«ã ãã»ã«ããŒ
ã¹ãšã¹ãã«ãã€ã«ã ãããªããã«ã¢ã»ã¿ãŒã«ãã€
ã«ã ãããªãšãã¬ã³ãã€ã«ã ãããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããã€ã«ã ãããªã«ãŒãããŒããã€ã«ã
çã®ãã©ã¹ããã¯ãã€ã«ã ããã³ã¬ã©ã¹ãçŽãã¢
ã«ãããŠã çã®éå±çããããããããŸããã©ã€
ã¿çŽãã¬ãžã³ã³ãŒãã€ãçŽãèæ°Žæ§çŽãçšããã
ãšãã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã¯ãåºæ¬çã«ã¯
åäžå±€äžã«(1)æå æ§ããã²ã³åéã(2)éå å€ã(3)
æ¬çºæã®ããŒã³ã¿è²çŽ äŸäžç©è³ªã(4)ãã€ã³ããŒã
ãã³(5)ææ©éå¡©ãå«æãããããããããã¯å¿ ã
ããåäžã®åçæ§æå±€äžã«å«æãããå¿ èŠã¯ãª
ããäŸãã°ãç·æå æ§å±€ãïŒå±€ã«åããåèš(1)ã
(2)ã(3)ã(4)ã(5)ã®æåãäžæ¹åŽã®ç·æå æ§å±€ã«å«
æããããã®ç·æå æ§å±€ã«é£æ¥ããä»æ¹åŽã®å±€ã«
æ¬çºæã®ããŒã³ã¿è²çŽ äŸäžç©è³ªïŒãå«æãããã
çãçžäºã«åå¿å¯èœãªç¶æ ã§ããã°ïŒä»¥äžã®åç
æ§æå±€ã«åããŠå«æããããŠãããã ãŸããåèšããåŠãç·è²æå æ§å±€ãäŸãã°ãé«
æ床局ãšäœæ床局çã®ïŒå±€ä»¥äžã«åå²ããŠèšããŠ
ããããããã«ä»ã®æè²æ§ãç°ã«ããïŒåã¯ïŒä»¥
äžã®æå æ§å±€ãæããŠãããããäžå¡ãå±€ãäžå¡
ãå±€ããããã³ã°å±€ãäžéå±€ãæãã¯ãã€ã«ã¿ãŒ
å±€çåçš®ã®åçæ§æå±€ãæããŠããŠãããã æ¬çºæã®ããŒã³ã¿è²çŽ äŸäžç©è³ªã¯äžèšã®ããã«
ç·æå æ§å±€ã«å«æããããããšãã§ãããããã
ã«éå®ããããä»ã®éæå æ§å±€ãèµ€æå æ§å±€ã«å«
æããããŠãããã æ¬çºæã®ç±çŸåæå å±€ãšåæ§ãä¿è·å±€ãäžé
å±€ãäžå¡å±€ãããã¯å±€ããã®ä»ã®åçæ§æå±€ã«ã€
ããŠãããããã®å¡åžæ¶²ã調補ãã浞挬æ³ããšã¢
ãŒãã€ãæ³ãã«ãŒãã³å¡åžæ³ãŸãã¯ç±³åœç¹èš±ç¬¬
3681294å·ã«èšèŒã®ããããŒå¡åžæ³çã®åçš®ã®å¡
åžæ³ã«ããæå ææãäœæããããšãã§ããã æŽã«å¿ èŠãªãã°ãç±³åœç¹èš±ç¬¬2761791å·ããã³
è±åœç¹èš±ç¬¬837095å·ã«èšèŒãããŠããæ¹æ³ã«ãã€
ãŠïŒå±€ãŸãã¯ãã以äžãåæã«å¡åžããããšãã§
ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã¯ããã®ãŸãŸå
æ§é²å ããåŸãéåžž80âã200âã奜ãŸããã¯120
âã170âã®æž©åºŠç¯å²ã§ãïŒç§éã180ç§éã奜ãŸ
ããã¯1.5ç§éã120ç§éå ç±ãããã ãã§çºè²çŸ
åãããããŸããå¿ èŠã«å¿ããŠæ°Žäžééæ§ææã
å¯çããããŠçŸåããŠããããæãã¯é²å åã«70
âã180âã®æž©åºŠç¯å²ã§äºåå ç±ãæœããŠãããã æ¬çºæã«ããç±çŸåã«ã©ãŒæå ææã«ã¯ãçš®ã
ã®é²å æ段ãçšããããšãã§ãããæœåã¯å¯èŠå
ãå«ã茻å°ç·ã®ç»åé²å ã«ãã€ãŠåŸããããäžè¬
ã«ã¯éåžžã®ã«ã©ãŒããªã³ãã«äœ¿çšãããå æºãäŸ
ãã°ã¿ã³ã°ã¹ãã³ã©ã³ããæ°Žéç¯ããã»ãã³ã©ã³
ããã¬ãŒã¶ãŒå ç·ãCRTå ç·çãå æºãšããŠçš
ããããšãã§ããã å ç±æ段ã¯ãéåžžã®ç±çŸåæå ææã«é©çšãåŸ
ãæ¹æ³ããã¹ãŠå©çšã§ããäŸãã°å ç±ããããã
ãã¯ãªãããã¬ãŒãã«æ¥è§Šãããããç±ããŒã©ãŒ
ãç±ãã©ã ã«æ¥è§Šãããããé«æž©ã®é°å²æ°äžãé
éããããããããã¯é«åšæ³¢å ç±ãçšããããã
ãã«ã¯ãæ¬çºæã®æå ææäžãããã¯ç±è»¢åçšå
åå±€ïŒèŠçŽ ïŒäžã«å°é»æ§å±€ãèšããéé»ã匷ç£ç
ã«ãã€ãŠçãããžãŠãŒã«ç±ãå©çšããããšãã§ã
ããå ç±ãã¿ãŒã³ã¯ç¹ã«å¶éãããããšã¯ãªãã
ãããããäºç±ïŒãã¬ããŒãïŒããåŸãå床å ç±
ããæ¹æ³ãã¯ãããé«æž©ã§çæéããããã¯äœæž©
ã§é·æéãé£ç¶çã«äžæãäžéãããã¯ç¹°ããã
ããããã«ã¯äžé£ç¶å ç±ãå¯èœã§ã¯ãããã簡䟿
ãªãã¿ãŒã³ã奜ãŸããããŸãé²å ãšå ç±ãåæã«
é²è¡ããæ¹åŒã§ãã€ãŠãããã ãã®æ§ã«ããŠåŸãããç»åã¯ãä»»æã®æ¹æ³ã§å
åèŠçŽ äžã«è²ç»åãšããŠåŸãããšãã§ãããäŸã
ã°RDNo.15108å·ãåNo.15127å·ã«èšèŒãããŠãã
æ¹æ³ãäŸãã°ã¡ã¿ããŒã«ã®ãããªæº¶å€æãã¯ç±æº¶
å€ãšããŠã®ã¢ã»ãã¢ãããïŒïŒ10âãã«ã³ãžãªãŒ
ã«ãã³ãã¯é žã€ãããïŒïŒïŒâãããµã³ãžã«ã«ã
ã³é žãïŒïŒïŒâãšãã¬ã³ããã¿ã¬ã³ãã¢ãã¹é žã¡
ãã«ããã³ãŸããšãã³ãã¹ãã¢ãªã³é žã¡ãã«ãã¡
ããã·ããã¿ã¬ã³ããããšãã«çãå«ã転åçŽã®
åŠãååèŠçŽ ãšå¯çãããå¿ èŠã«å¿ããŠå ç±åŸã
å¥é¢ããããšã«ãã€ãŠè»¢åçŽã®åŠãååèŠçŽ äžã«
è²ç»åãåŸãããšãã§ããã æ¬çºæã®æå ææïŒä»¥äžãæ¬çºæã®æå èŠçŽ ãš
ãããïŒã¯ãåæ§é²å ããåŸãç±çŸåããããšã«
ãã€ãŠãç±è»¢åæ§ããŒã³ã¿è²çŽ ã®åæ§ååžãæ¬çº
æã®ããŒã³ã¿è²çŽ äŸäžç©è³ªãã圢æããã該åæ§
ååžã®å°ãªããšãäžéšããæ¬çºæã®æå ææãšç©
éé¢ä¿ã«ããååå±€ã«ç±è»¢åããã«ã©ãŒç±æ¡æ£è»¢
åæ¹æ³ã«é©çšãããå Žåãååå±€ã«åœ¢æãããã
ãŒã³ã¿ç»åæ¿åºŠãæ¹è¯ãããé«ãæ¿åºŠã®ç»åãäž
ãããã€ããŒã³ã¿ã«ããªã®çºçãæå¶ã§ããã ååå±€ã¯ãç±çŸåã«ãã圢æïŒä¹è³æŸåºïŒãã
ãè²çŽ ãå容ããæ©èœãæããã°ãããè²çŽ æ¡æ£
転ååæå ææã«çšããããåªæå€ãç¹éæ57â
207250å·çã«èšèŒãããã¬ã©ã¹è»¢ç§»æž©åºŠã40â以
äž250â以äžã®èç±æ§ææ©é«ååç©è³ªã§åœ¢æãã
ãããšã奜ãŸããã åèšåªæå€ã®å ·äœçãªäŸãšããŠã¯ãå«çªçŽ äº
çŽãäžçŽã¢ãã³é¡ãå«çªçŽ è€çŽ ç°ååç©ãããã
ã®åçŽã«ããªã³æ§ååç©ãç±³åœç¹èš±ç¬¬2548564å·ã
å2484430å·ãå3148061å·ãå3756814å·ã«é瀺
ãããŠããããã«ããªãžã³ããªããŒããã³ããã«
ããªãžããŠã ã«ããªã³ããªããŒãç±³åœç¹èš±ç¬¬
2675316å·ã«é瀺ãããŠãããžã¢ã«ãã«ã¢ããåº
ãå«ãããªããŒãç±³åœç¹èš±ç¬¬2882156å·ã«é瀺ã
ããŠããã¢ããã°ã¢ããžã³èªå°äœãç±³åœç¹èš±ç¬¬
3625694å·ãå3859096å·ãè±åœç¹èš±ç¬¬1277453å·ã
å2011012å·ã«é瀺ãããŠãããŒã©ãã³ãªã©ãšæ¶
æ©å¯èœãªåªæå€ãç±³åœç¹èš±ç¬¬3958995å·ãå
2721852å·ãå2798063å·ã«é瀺ãããŠããæ°Žæ§ãŸ
ã«ååªæå€ãç¹éæ50â61228å·ã«é瀺ãããŠã
ãæ°Žäžæº¶æ§åªæå€ãç±³åœç¹èš±ç¬¬3788855å·ã西ç¬
ç¹èš±åºé¡ïŒOLSïŒç¬¬2843320å·ãç¹éæ53â
30328å·ãå52â155528å·ãå53â125å·ãå53â
1024å·ãå54â74430å·ãå54â124726å·ãå55
â22766å·ãç±³åœç¹èš±ç¬¬3642482å·ãå3488706å·ã
å3557066å·ãå3271147å·ãå3271148å·ãç¹å ¬
æ55â29418å·ãå56â36414å·ãå57â12139å·ã
RDNo.12045ïŒ1974幎ïŒã«é瀺ãããŠããåçš®åªæ
å€ããããããšãã§ããã ç¹ã«æçšãªåªæå€ã¯ã¢ã³ã¢ããŠã å¡©ãå«ãããª
ããŒã§ãç±³åœç¹èš±ç¬¬3709690å·ã«èšèŒãããŠããã
äŸãã°ã¢ã³ã¢ããŠã å¡©ãå«ãããªããŒãšããŠã¯ã
ããªã¹ãã¬ã³âã³âïŒïŒ®ïŒïŒ®âããªâïœâãã
ã·ã«ââããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãã§ãã¹ãã¬ã³ãšããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãã®æ¯çã¯ïŒïŒïŒãïŒïŒïŒã奜ãŸããã¯
ïŒïŒïŒã§ããã å žåçãªè²çŽ æ¡æ£è»¢åçšã®ååå±€ã¯ãã¢ã³ã¢ã
ãŠã å¡©ãå«ãããªããŒããŒã©ãã³ãšæ··åããŠæ¯æ
äœäžã«å¡åžããããšã«ããåŸããããè²çŽ ã®ç±çŸ
åæå å±€ããååå±€ãžã®è»¢åã«ã¯ã転å溶åªãçš
ããããšãã§ããããã®è»¢å溶åªã«ã¯ãã¡ã¿ããŒ
ã«ãé ¢é žãšãã«ããžã€ãœããã«ã±ãã³çã®äœæ²žç¹
溶åªããã³ããªâïœâã¯ã¬ãžã«ããªã¹ããšãŒãã
ããªâïœâããã«ãã¹ããšãŒãããžâïœâããã«
ãã¿ã¬ãŒãçã®é«æ²žç¹æº¶åªãçšããé«æ²žç¹æº¶åªã®
å Žåã«ã¯ãé©åœãªä¹³åå€ãçšããŠãŒã©ãã³äžã«ä¹³
åãååå±€ã«æ·»å ããããšãã§ããã åèšèç±æ§ææ©é«ååç©è³ªã®äŸãšããŠã¯ãåå
é2000ã85000ã®ããªã¹ãã¬ã³ãççŽ æ°ïŒä»¥äžã®
眮æåºããã€ããªã¹ãã¬ã³èªå°äœãããªããã«ã·
ã¯ããããµã³ãããªãžããã«ãã³ãŒã³ãããªãã
ã«ãããªãã³ãããªããã«ã«ã«ããŸã«ãããªã¢ãª
ã«ãã³ãŒã³ãããªããã«ã¢ã«ã³ãŒã«ãããªããã«
ãã«ããŒã«ããã³ããªããã«ããã©ãŒã«ãªã©ã®ã
ãªã¢ã»ã¿ãŒã«é¡ãããªå¡©åããã«ãå¡©çŽ åããªãš
ãã¬ã³ãããªäžå¡©åããåãšãã¬ã³ãããªã¢ã¯ãª
ããããªã«ãããªâïŒïŒ®âãžã¡ãã«ã¢ãªã«ã¢ã
ããïœâã·ã¢ãããšãã«åºããã³ã¿ã¯ããããšã
ã«åºããã³ïŒïŒïŒâãžã¯ããããšãã«åºããã€ã
ãªã¢ã¯ãªã¬ãŒããããªã¢ã¯ãªã«ã¯ããã¢ã¯ãªã¬ãŒ
ããããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããããªãšãã«ã¡ã¿
ã¯ãªã¬ãŒããããªãããã«ã¡ã¿ã¯ãªã¬ãŒããããª
ã€ãœãããã«ã¡ã¿ã¯ãªã¬ãŒããããªã€ãœããã«ã¡
ã¿ã¯ãªã¬ãŒããããªâtertâããã«ã¡ã¿ã¯ãªã¬ãŒ
ããããªã·ã¯ãããã·ã«ã¡ã¿ã¯ãªã¬ãŒããããªãš
ãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããããªâïŒâ
ã·ã¢ãâãšãã«ã¡ã¿ã¯ãªã¬ãŒããããªãšãã¬ã³ã
ã¬ãã¿ã¬ãŒããªã©ã®ããªãšã¹ãã«é¡ãããªã¹ã«ã
ã³ããã¹ããšããŒã«ïŒ¡ããªã«ãŒãããŒãçã®ããª
ã«ãŒãããŒãé¡ãããªã¢ã³ããã©ã€ããããªã¢ã
ãé¡äžŠã³ã«ã»ãã«ãŒã¹ã¢ã»ããŒãé¡ãããããã
ãããŸããPolymer Handbook 2nd ed.ïŒJ.
BrandrupïŒE.H.Immergutç·šïŒJohn WileyïŒ
Sonsåºçãã«èšèŒãããŠããã¬ã©ã¹è»¢ç§»æž©åºŠ40
â以äžã®åæããªããŒãæçšã§ããããããã®é«
ååç©è³ªã¯ãåç¬ã§çšããããŠãããŸãïŒä»¥äžã
çµã¿åããŠå ±éåäœãšããŠçšããŠãããã ç¹ã«æçšãªããªããŒãšããŠã¯ãããªã¢ã»ããŒ
ãããžã¢ã»ããŒããªã©ã®ã»ã«ããŒã¹ã¢ã»ããŒãã
ããã¿ã¡ãã¬ã³ãžã¢ãã³ãšã®ãã¬ãã¿ã«é žããã«
ãªã¬ã³ãžãããã«ã¢ãã³ãšã¢ãžãã³é žããããµã¡
ãã¬ã³ãžã¢ãã³ãšãžããšã³é žããããµã¡ãã¬ã³ãž
ã¢ãã³ãšã€ãœãã¿ã«é žãªã©ã®çµã¿åãã«ããããª
ã¢ããããžãšãã¬ã³ã°ãªã³ãŒã«ãšãžããšãã«ã«ã«
ãã³é žããã¹âïœâã«ã«ããã·ããšããã·ãã¿ã³
ãšãšãã¬ã³ã°ãªã³ãŒã«ãªã©ã®çµã¿åãã«ããããª
ãšã¹ãã«ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããªã«
ãŒãããŒãããããããããããã®ããªããŒã¯æ¹
質ããããã®ã§ãã€ãŠããããããšãã°ãã·ã¯ã
ãããµã³ãžã¡ã¿ããŒã«ãã€ãœãã¿ã«é žãã¡ããã·
ããªãšãã¬ã³âã°ãªã³ãŒã«ãïŒïŒïŒâãžã«ã«ãã¡
ããã·âïŒâãã³ãŒã³ã¹ã«ãã³é žãªã©ãæ¹è³ªå€ãš
ããŠçšããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããæå¹ã§
ããã äžèšã®ããªããŒã¯é©åœãªæº¶å€ã«æº¶ãããŠæ¯æäœ
äžã«å¡åžããŠååå±€ãšãããããããã¯äžèšããª
ããŒããæããã€ã«ã ç¶ååå±€ãæ¯æäœã«ã©ãã
ãŒãããŠçšãããããããŸãã¯æ¯æäœäžã«å¡åžã
ãããšãªããäžèšããªããŒããæãéšæïŒäŸãã°
ãã€ã«ã ïŒåç¬ã§ååå±€ãæ§æããããšïŒåå
å±€ã»æ¯æäœå ŒçšåïŒãã§ããã ããã«ååå±€ãšããŠã¯éææ¯æäœäžã®ååå±€ã®
äžã«ãŒã©ãã³åæ£ããäºé žåãã¿ã³çãå«ãäžé
æåå±€ïŒåå°æ§å±€ïŒãèšããŠæ§æããããšãã§ã
ãããã®äžéæåå±€ã¯ã転åè²ç»åãååå±€ã®é
ææ¯æäœåŽããèŠãããšã«ããåå°åã®è²åãåŸ
ãããã å®æœäŸïŒœ 以äžã«æ¬çºæã®å®æœäŸã瀺ãããæ¬çºæã®å®æœ
æ æ§ã¯ãããã«éããããã®ã§ã¯ãªãã æ¯èŒäŸ ïŒ äŸç€ºè²çŽ äŸäžç©è³ª(8)520mgãé ¢é žãšãã«ïŒmlå
ã³ãžãªã¯ãã«ãã¿ã¬ãŒãïŒmlãæ··åããå ç±æº¶è§£
ããããã®æº¶æ¶²ãçé¢æŽ»æ§å€ãå«ã2.5ïŒ ãŒã©ã
ã³æº¶æ¶²ïŒmlãšæ··åããæ°Žãå ããŠ12mlãšããŠãã¢
ãžãã€ã¶ãŒã§ïŒåéä¹³ååæ£ããã äžèšã®åæ£æ¶²ïŒmlã450mgã®ããªããã«ãããª
ãã³ïŒååé30000ïŒåã³ïŒïŒïŒãã³ã¿ã³ãžãªãŒ
ã«ïŒ500mgïŒãå«ãæ°Ž3.5mlãšæ··åããåèšçŸåå€
ïŒïŒ²âïŒïŒ200mgãå ããããã®åæ£æ¶²ã«å¹³åç²åŸ
0.1ÎŒmã®æ²èåéãæç®ããŠãïŒÃ10-3ã¢ã«æ·»å
ããæ°Žãå ããŠ15mlã«ä»äžããåŸãããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒãããŒã¹äžã«æ¹¿æœ€èåã60ÎŒmãšãª
ãããã«ã¯ã€ã€ãŒããŒã«ãŠå¡åžããã åŸãããæå ææã也ç¥åŸã16000CMSã®çœè²
é²å ãã¹ããããŠãšããžãéããŠäžããã次ã
ã§ãé²å æžã¿è©Šæã®å¡åžé¢ãšãã©ã€ã¿çŽäžã«ããª
å¡©åããã«ïŒååå±€ïŒãå¡èšããååçŽã®ååé¢
ãéãåãããŠã150âã§ïŒåééå±æ§ããŒãã
ããã¯ãçšããŠç±çŸåããããªãã次ãã§ãåå
çŽãå¥ããããšãããååçŽäžã«ããŒã³ã¿ã®è»¢å
ç»åãåŸãããããã®è»¢åç»åã®æé«åå°æ¿åºŠ
ïŒDmaxïŒã¯0.73ãã«ããªïŒDminïŒã¯0.14ã§ãã€
ãã å®æœäŸ ïŒ ãïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«éå¡©ã®èª¿è£œã 24ïœã®ïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«åã³ïŒïœ
ã®æ°Žé žåãããªãŠã ããšã¿ããŒã«âæ°ŽïŒïŒïŒïŒïŒ
æ··å液300mlã«å ã溶解ããããã®æº¶æ¶²ã«ïŒèŠå®
ã®ç¡é žé溶液20mlã«æ»Žäžããããã®éãïŒèŠå®ã®
æ°Žé žåãããªãŠã 溶液ãåæã«æ»ŽäžããPHãïŒã
ïŒã«ç¶æããããã®æº¶æ¶²ãïŒæé宀枩ã§æ¹æãã
åŸãæ°Žã§400mlã«ä»äžããŠïŒâã¹ã«ããã³ãŸããª
ã¢ãŸãŒã«é溶液ã調補ããã äŸç€ºè²çŽ äŸäžç©è³ª(8)520mgãé ¢é žãšãã«ïŒmlå
ã³ãžãªã¯ãã«ãã¿ã¬ãŒãïŒmlãæ··åããå ç±æº¶è§£
ããããã®æº¶æ¶²ãšçé¢æŽ»æ§å€ãå«ã2.5ïŒ ãŒã©ã
ã³æº¶æ¶²ïŒmlãšæ··åããæ°Žãå ããŠ12mlãšãããã¢
ãžãã€ã¶ãŒã§ïŒåéä¹³ååæ£ããã äžèšã®ïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«é溶液ïŒ
mlãè²çŽ äŸäžç©è³ªã®äžèšåæ£æ¶²ïŒmlãæ··åããã
ãã«ããªããã«ãããªãã³ïŒååé30000ïŒ450
mgãïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«360mgãããªãšã
ã¬ã³ã°ãªã³ãŒã«ïŒååé300ïŒ120mgãæ°ŽïŒmlåã³
åèšçŸåå€ïŒïŒ²âïŒïŒ200mgãå ããåŸãïŒïŒ ã¯
ãšã³é žã§PHã5.5ãšããããã®åæ£æ¶²ã«å¹³åç²åŸ
0.05ÎŒmã®æ²èåéãéã«æç®ããŠïŒÃ10-4ã¢ã«
æ·»å ããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãæ¯æäœäžã«
湿最èå65ÎŒmãšãªãæ§ã«ã¯ã€ã€ãŒããŒã«ãŠå¡åž
ããã äžèšå¡åžç©ã也ç¥ããŠåŸãããè©Šæã«å¯ŸããŠã¹
ããããŠãšããžãéããŠã30000CMSïŒã«ã³ã
ã©ã»ã¡ãŒã¿ãŒã»ç§ïŒã®é²å ãäžããã 次ãã§äžèšé²å æžã¿è©Šæã®å¡åžé¢ã«ããã©ã€ã¿
çŽäžã«å¡©åããã«ãå¡åžããååçŽãéããŠãè¡š
é¢æž©åºŠã140âã®éå±è£œããŒããããã¯ã§60ç§é
å§çå ç±ãã次ãã§ååçŽãå¥ããååçŽã«è»¢å
ããè²çŽ åæ¿åºŠïŒåå°æ¿åºŠïŒã枬å®ããããã®çµ
æãåŸèšç¬¬ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ ãã€ã³ããŒã®ããªããã«ãããªãã³ãããªãã
ã«ã¢ã«ã³ãŒã«ïŒéå床400ïŒã«ä»£ãã以å€ã¯å®æœ
äŸïŒãšåãåŠæ³ã§äœæããè©Šæãçšæããå®æœäŸ
ïŒãšåãé²å ãçŸåãè¡ãªã€ãããã®çµæãåã
ã第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒãïŒ éå å€ãè¡šâïŒã«ç€ºãååç©ã«ä»£ãã以å€ã¯å®
æœäŸïŒãšåãåŠæ³ã§äœæããè©Šæãçšæããå®æœ
äŸïŒãšåãé²å ãçŸåãè¡ãªã€ãããã®çµæãå
ãã第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒãïŒ è²çŽ äŸäžç©è³ªãšããŠäŸç€ºè²çŽ äŸäžç©è³ª(8)ã®ä»£ã
ãã«è¡šâïŒã«ç€ºãè²çŽ äŸäžç©è³ªãçšãã以å€ã¯å®
æœäŸïŒãšåãåŠæ³ã§äœæããè©Šæãçšæããå®æœ
äŸïŒãšåãé²å ãçŸåãè¡ãªã€ãããã®çµæãå
ãã第ïŒè¡šã«ç€ºãã æ¯èŒäŸ ïŒïŒïŒããã³ïŒ è²çŽ äŸäžç©è³ªãšããŠäžèšè²çŽ äŸäžç©è³ªïŒ¡ïŒïŒ¢ã
ãã³ïŒ£ãçšãã以å€ã¯å®æœäŸïŒãšåãåŠæ³ã§äœæ
ããïŒçš®ã®è©Šæãçšæããå®æœäŸïŒãšåãé²å ã
çŸåãè¡ãªã€ãããã®çµæãåãã第ïŒè¡šã«ç€º
ãã
ãŒã³ã¿è²çŽ äŸäžç©è³ªã®å ·äœçåæäŸã瀺ãã äžéäœã®åæ ïŒâããšãã«âïŒâã€ãœãã¿ã³âïŒâããããœ
âïŒâãã©ãŸãã³ã®åæ ïŒâããšãã«âïŒâã€ãœãã¿ã³ã¢ããâïŒâã
ã©ãŸãã³24.5ïœãé ¢é ž250mlã«æº¶è§£ãã宀枩æ¹æ
äžã«äºç¡é žãœãŒã10ïœãå ãããïŒæéæ¹æåŸã
åå¿æ··åç©ãæ°·æ°Žã«ãããæåºããåºäœãéãã
èµ€æ©è²ã®åºäœ21.9ïœãmp199ã201âãåŸãã äŸç€ºååç©ïŒã®åæ äžèšããããœäœ2.74ïœãïœâãªã¯ã¿ãã»ãã«ã³
ãã¯é žç¡æ°Žç©3.51ïœãé ¢é ž50mlã«æº¶è§£ãã宀枩æ¹
æäžã«äºéæ«3.27ïœãå ãããïŒæéæ¹æåŸãäž
溶ç©ãå£éããå£æ¶²ãæ°·æ°Žã«ãããæåºããæ²¹ç¶
ç©ãé ¢é žãšãã«ã«ãŠæœåºãããé ¢é žãšãã«å±€ã¯æ°Ž
æŽã飜åNaHCO3氎溶液ã§æŽæµã也ç¥åŸãæžå§
çå»ãããæ®çç©ãã«ã©ã ã¯ãããã«ãã粟補
ããã¢ã¡ç¶ç©4.27ïœãåŸãã äŸç€ºååç©ïŒã®åæ åèšããããœäœ2.74ïœãé ¢é ž30mlã«æžæ¿ãã宀
æž©æ¹æäžãäºéæ«3.27ïœãå ããã30åéæ¹æã
ãåŸãäžæº¶ç©ãå£éããå°éã®é ¢é žã§æŽã€ããæŽ
液ãšå£æ¶²ãåãããããã«é ¢é žãœãŒã0.8ïœãã©
ãŠãã€ã«ã¯ãã©ã€ã2.19ïœãå ã宀枩äžïŒæéæ¹
æãããåå¿æ¶²ãæ°·æ°Žã«ãããé ¢é žãšãã«ã§æœ
åºãé ¢é žãšãã«æº¶æ¶²ã¯ãæ°ŽæŽã也ç¥åŸãæžå§çå»
ãããæ®çç©ã®ã«ã©ã ã¯ãããã«ããç®çç©ãå
é¢ç²Ÿè£œããã¢ã¡ç¶ç©3.0ïœãåŸãã äŸç€ºååç©13ã®åæ åèšããããœäœ2.74ïœãæ¿å¡©é žïŒmlããšã¿ããŒ
ã«50mlã«æžæ¿ããïŒïŒ PdâC300mgãå ããæ°ŽçŽ
æ¥è§Šç°å ãè¡ã€ããçè«éã®æ°ŽçŽ ãåžåããåŸã
觊åªãå£éããå£æ¶²ãæžå§çå»ãããæ®çç©ã«ïœ
âããã·ã«ãªãã·ããšãã«ã¹ã«ããã«ã¯ãã©ã€ã
3.61ïœãå ãã宀枩ã§ïŒæéæ¹æãããåå¿æ¶²ã
æ°·æ°Žã«ãããæŽã«æ¿å¡©é žã§é žæ§ãšããæåºããæ²¹
ç¶ç©ãé ¢é žãšãã«ã§æœåºãããåèšãšåæ§ã®åŠç
ãè¡ãªãç¡è²åºäœ3.53ïœãmp144ã145âãåŸãã äžèšåæäŸã«ãããŠãäžéäœããã³ç®çç©ã¯
IRãNMRããã³FDâãã¹ã¹ãã¯ãã«ã«ããã
ã®æ§é ã確èªããã ä»ã®äŸç€ºååç©ãäžè¿°ã®åæäŸãšåæ§ãªæ¹æ³ã«
ããåæã§ããã æ¬çºæã«çšããããããŒã³ã¿è²çŽ äŸäžç©è³ªã¯ã
åç¬ã§çšããŠãããããïŒçš®ä»¥äžã䜵çšããŠãã
ãã æ¬çºæã«çšããããããŒã³ã¿è²çŽ äŸäžç©è³ªã¯ã
ç±çŸåæå çµæãå¡åžæ¡ä»¶ãåŠçæ¹æ³çã«ããç°
ãªãããæŠãæ¯æäœïŒm2åœã0.005ïœã10ïœã®ç¯
å²ã§çšãããã奜ãŸããã¯0.1ïœã5.0ïœã§ããã æ¬çºæã«çšããããåè¿°ã®ããŒã³ã¿ã®è²çŽ äŸäž
ç©è³ªãç±çŸåã«ã©ãŒæå ææã«å«æããããã«
ã¯ãäŸãã°ãã«ãã©ãŒã®åæ£æ³ã«é¢ããç±³åœç¹èš±
第2322027å·ã«èšèŒãããŠããããã«é«æ²žç¹æº¶åª
ã«æº¶è§£ããŠå«æãããããšãã§ãããããã«äžèš
ã®åŠå®ãåæ£æ¹æ³ã«ãããŠäžèšé«æ²žç¹æº¶åªã«å¿ èŠ
ã«å¿ããŠäœæ²žç¹æº¶åªã䜵çšããŠè²çŽ äŸäžç©è³ªã溶
解ããŠç±çŸåæå å±€ã«å«æãããããšãã§ããã äžèšã®é«æ²žç¹æº¶åªãšããŠã¯ãäŸãã°ãžâïœâã
ãã«ãã¿ã¬ãŒããããªã¯ã¬ãžã«ãã¹ããšãŒãããž
âãªã¯ãã«ãã¿ã¬ãŒããïœâããã«ããšããŒã«ç
ãããããŸãäœæ²žç¹æº¶åªãšããŠã¯ãäŸãã°é ¢é žã¡
ãã«ãããããªã³é žããã«ãã·ã¯ããããµããŒ
ã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¢ã»ããŒããªã©ã
ç¥ãããŠããããããã®æº¶åªã¯åç¬ã§çšããŠãã
æ··åããŠçšããŠãããããã®ããã«æº¶åªã«æº¶è§£ã
ããè²çŽ äŸäžç©è³ªã¯ãã¢ã«ãã«ãã³ãŒã³ã¹ã«ãã³
é žããã³ã¢ã«ãã«ããã¿ã¬ã³ã¹ã«ãã³é žã®åŠãã¢
ããªã³ç³»çé¢æŽ»æ§å€ããã³ïŒãŸãã¯ãœã«ãã¿ã³ã¢
ãã©ãŠãªã³é žãšã¹ãã«ã®åŠããããªã³ç³»çé¢æŽ»æ§
å€ãå«ããŒã©ãã³çã®èŠªæ°Žæ§ãã€ã³ããŒãå«æã
ã氎溶液ãšæ··åããã³ãã€ããã«ãŸãã¯è¶ é³æ³¢å
æ£è£ 眮çã§ä¹³ååæ£ããç±çŸåæå å±€ã«æ·»å ãã
ããããšãã§ããã äžèšé«æ²žç¹æº¶åªã¯ãè²çŽ äŸäžç©è³ªãå®å šã«æº¶è§£
ããããéã§çšãããããã奜ãŸããã¯è²çŽ äŸäž
ç©è³ªïŒéšïŒéééšïŒã«å¯ŸããŠ0.05ã100éšïŒéé
éšïŒã®ç¯å²ã§çšããããšãã§ããã äžèšä»¥å€ã®å¥œãŸããåæ£æ¹æ³ãšããŠã¯ãã€ãã·
ã€ãŒåæ£ãããã該ãã€ãã·ã€ãŒåæ£ãšã¯ãåäž
ååäžã«èŠªæ°Žæ§æåãšçæ°Žæ§æåãšãæããè²çŽ
äŸäžç©è³ªãã¢ã«ã«ãªæ°Žæº¶æ¶²ã«æº¶è§£ãåæ£ããããš
ãããããã®æº¶è§£ãåæ£ã«ããããæ°Žãšçžæº¶æ§ã
æããææ©æº¶åªãæ·»å ããããå ç±ãæ¹æïŒãã¢
ãžãã€ã¶ãŒãè¶ é³æ³¢åæ£ãªã©ïŒãããããããã¯
çé¢æŽ»æ§å€ã®å©ããããããªã©ããŠããããã¢ã«
ã«ãªæ°Žæº¶æ¶²ã®ã¢ã«ã«ãªãšããŠã¯ãç¡æ©å¡©åºãæ°Žãš
çžæº¶æ§ã®ããææ©å¡©åºãçšããããšãã§ããè²çŽ
äŸäžç©è³ªã溶解ãåæ£ããåŸãå¿ èŠã«å¿ããŠPHã
調æŽããããšãã§ããããã®å Žåã®PH調æŽå€ã«ã¯
æ°Žãšçžæº¶æ§ã®ããææ©åã¯ç¡æ©é žãçšããããšã
ã§ãããåæ£å©å€ãšããŠã®çé¢æŽ»æ§å€ã¯ãã¢ããª
ã³ç³»ããããªã³ç³»æŽ»æ§å€çã§è¯ãããã¢ããªã³ç³»
掻æ§å€ã奜ãŸããã ãªãäžèšãã€ãã·ã€ãŒåæ£ã¯ãã¢ã°ãã¢ãŒåæ£
ãšåŒã°ããããšããããè±åœç¹èš±ç¬¬455556å·ãå
第465823å·ãå第298979å·çã«èšèŒãããŠããæ
è¡å ç©ãåèã«ããããšãã§ããã æ¬çºæã«çšããããããŒã³ã¿è²çŽ äŸäžç©è³ªã¯ã
ç±çŸåæå å±€ã«åŸè¿°ã®ãã€ã³ããŒãçšããŠããã®
ãã€ã³ããŒäžã«äžè¿°ã®ããã«ãã€ãã·ã€ãŒåæ£å
ã¯ãªã€ã«ãããã¯ãåæ£ããããããšãã§ããã
ã®å ŽåãåŸæ¥ã®ããã«ããŒã«ãã«ãŸãã¯ãµã³ãã
ã«çã䜿çšããŠç£šç ããå¿ èŠããªãã®ã§çæéã®
äœæ¥ã§åŸ®çŽ°ãã€å®å®ã«ç±çŸåæå å±€äžã«åæ£ãã
ããããšãã§ããè²çŽ ç»åã®è»¢åæ¿åºŠãæ¹è¯ãã
ããšãã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯åèšã®è²çŽ
äŸäžç©è³ªãšåæ§ã«æå æ§ããã²ã³åéãå«æã
ãã æ¬çºæã«çšããããæå æ§ããã²ã³åéãšããŠ
ã¯ãå¡©åéãèåéãæ²åéãå¡©èåéãå¡©æ²å
éãæ²èåéãå¡©æ²èåéçããããããã該æ
å æ§ããã²ã³åéã¯ãåçæè¡åéã§å ¬ç¥ã®ã·ã³
ã°ã«ãžãšããæ³ãããã«ãžãšããæ³çã®ä»»æã®æ¹
æ³ã§èª¿è£œããããšãã§ããããæ¬çºæã«æŒããŠ
ã¯ãéåžžã®ããã²ã³åéãŒã©ãã³ä¹³å€ã®èª¿æŽæ¹æ³
ã«åŸã€ãŠèª¿è£œããæå æ§ããã²ã³åéä¹³å€ã奜ãŸ
ããçµæãäžããã 該æå æ§ããã²ã³åéä¹³å€ã¯ãåçæè¡åéã§
å ¬ç¥ã®ä»»æã®æ¹æ³ã§ååŠçã«å¢æããŠãè¯ããã
ããå¢ææ³ãšããŠã¯ãéå¢æãã€ãªãŠå¢æãéâ
ã€ãªãŠå¢æãéå å¢æçåçš®ã®æ¹æ³ããããã
ãã äžèšæå æ§ä¹³å€äžã®ããã²ã³åéã¯ãç²ç²åã§
ãã€ãŠã埮ç²åã§ãã€ãŠãè¯ããã奜ãŸããç²å
ãµã€ãºã¯ããã®åŸãçŽ0.001ÎŒmãçŽ1.5ÎŒmã§ããã
ããã«å¥œãŸããã¯çŽ0.01ÎŒmãçŽ0.5ÎŒmã§ããã äžèšã®ããã«èª¿è£œãããæå æ§ããã²ã³åéä¹³
å€ãæ¬çºæã®æå ææã®æ§æå±€ã§ããç±çŸåæ§æ
å å±€ã«æã奜ãŸããé©çšããããšãã§ããã æ¬çºæã«ãããŠãä»ã®æå æ§ããã²ã³åéã®èª¿
補æ³ãšããŠãæå æ§é塩圢ææåãåŸè¿°ããææ©
éå¡©ãšå ±åãããææ©éå¡©ã®äžéšã«æå æ§ããã²
ã³åéã圢æãããããšãã§ããããã®èª¿è£œæ³ã«
çšããããæå æ§é塩圢ææåãšããŠã¯ãç¡æ©ã
ãã²ã³åç©ãäŸãã°ãMXnã§è¡šããããããã²
ã³åç©ïŒããã§ãïŒã¯ïŒšååãNH4åºãŸãã¯é
å±ååãè¡šãããã¯ClãBrãŸãã¯ïŒ©ãè¡šããã
ïœã¯ïŒãååãNH4åºã®æã¯ïŒãïŒãéå±å
åã®æã¯ãã®åå䟡ã瀺ããéå±ååãšããŠã¯ã
ãªããŠã ããããªãŠã ãã«ãªãŠã ãã«ããžãŠã ã
ã»ã·ãŠã ãé ãéãããªãªãŠã ããã°ãã·ãŠã ã
ã«ã«ã·ãŠã ãã¹ããã³ããŠã ãããªãŠã ãäºéã
ã«ãããŠã ãæ°Žéãã¢ã«ãããŠã ãã€ã³ãžãŠã ã
ã©ã³ã¿ã³ãã«ãããŠã ãã¿ãªãŠã ãã²ã«ãããŠ
ã ãé«ãéãã¢ã³ãã¢ã³ããã¹ãã¹ãã¯ãã ãã¢
ãªããã³ãã¿ã³ã°ã¹ãã³ããã³ã¬ã³ãã¬ããŠã ã
éãã³ãã«ããããã±ã«ãããžãŠã ããã©ãžãŠ
ã ããªã¹ããŠã ãã€ãªãžãŠã ãçœéãã»ãªãŠã ç
ãããããããïŒãå«ããã²ã³éå±é¯äœïŒäŸãã°ã
K2PtCl6ïŒK2PtBr6ïŒHAuCl4ïŒïŒNH4ïŒ2IrCl6ïŒ
ïŒNNH4ïŒ3IrCl6ïŒïŒNH4ïŒ2RuCl6ïŒïŒNH4ïŒ3RuCl6ïŒ
ïŒNH4ïŒ3RhCl6ïŒïŒNH4ïŒ3RhBr6çïŒããªããŠã ã
ã©ã€ãïŒäŸãã°ãããã©ã¡ãã«ã¢ã³ã¢ããŠã ãã
ãã€ããããªã¡ãã«ããšãã«ã¢ã³ã¢ããŠã ããã
ã€ããã»ãã«ãšãã«ãžã¡ãã«ã¢ã³ã¢ããŠã ããã
ã€ããïŒâã¡ãã«ãã¢ãŸãªãŠã ãããã€ããããª
ã¡ãã«ãã³ãžã«ã¢ã³ã¢ããŠã ãããã€ãã®ãããª
ïŒçŽã¢ã³ã¢ããŠã ãã©ã€ããããã©ãšãã«ããªã¹
ããªããŠã ãããã€ãã®ãããªïŒçŽããªã¹ããªã
ãŠã ãã©ã€ãããã³ãžã«ãšãã«ã¡ãã«ã¹ã«ãããŠ
ã ãããã€ããïŒâãšãã«ãã¢ãŸãªãŠã ãããã€
ãã®ãããªïŒçŽã¹ã«ãããŠã ãã©ã€ãçïŒããã
ã²ã³åçåæ°ŽçŽ ïŒäŸãã°ããšãŒããã«ã ãããã¢
ãã«ã ãåèåççŽ ãïŒâããã¢âïŒâã¡ãã«ã
ããã³çïŒãâããã²ã³ååç©ïŒïŒ®âã¯ããã³
ãã¯é žã€ãããâããã¢ã³ãã¯é žã€ãããâ
ããã¢ãã¿ã«é žã€ãããâããã¢ã¢ã»ãã¢ã
ããâãšãŒãã³ãã¯é žã€ãããâããã¢ãã¿
ã©ãžãã³ãâã¯ãããã¿ã©ãžãã³ãâããã¢
ã¢ã»ãã¢ããªããïŒïŒ®âãžããã¢ãã³ãŒã³ã¹ã«
ãã³ã¢ãããâããã¢ââã¡ãã«ãã³ãŒã³ã¹
ã«ãã³ã¢ãããïŒïŒïŒâãžããã¢âïŒïŒïŒâãžã¡
ãã«ããã³ãã€ã³çïŒããã®ä»ã®å«ããã²ã³åå
ç©ïŒäŸãã°å¡©åããªããšãã«ã¡ãã«ãèåããªã
ãšãã«ã¡ãã«ãïŒâããã¢é ªé žãïŒâããã¢ãšã¿
ããŒã«çïŒãªã©ããããããšãã§ããã ãããæå æ§ããã²ã³åéããã³æå æ§é塩圢
ææåã¯ãçš®ã ã®æ¹æ³ã«ãããŠçµåããŠäœ¿çšã§
ãã䜿çšéã¯ãè²çŽ äŸäžç©è³ªïŒã¢ã«ã«å¯ŸããŠã
0.002ã¢ã«ã20ã¢ã«ã§ããã奜ãŸããã¯ã0.02ã¢
ã«ã10ã¢ã«ã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã¯ãæ¬çºæã®ã
ãŒã³ã¿è²çŽ äŸäžç©è³ªãå«æããå±€ãå°ãªããšãïŒ
å±€æããŠããã°ããããéè²å ãç·è²å ãèµ€è²å
ã«æå æ§ãæããåå±€ãå³ã¡ç±çŸåéæå æ§å±€ã
ç±çŸåç·æå æ§å±€ãç±çŸåèµ€æå æ§å±€ãšããŠå€å±€
æ§æãšããããšãã§ããããŸããåè²æå å±€ãïŒ
局以äžïŒäŸãã°ãé«æ床局ãšäœæ床局ïŒã«åå²ã
ãŠèšããããšãã§ããã äžèšã®å Žåãåã çšããããéæå æ§ããã²ã³
åéä¹³å€ãç·æå æ§ããã²ã³åéä¹³å€ãèµ€æå æ§
ããã²ã³åéä¹³å€ã¯ãåèšããã²ã³åéä¹³å€ã«å
çš®ã®åå å¢æè²çŽ ãå ããããšã«ãã€ãŠåŸãããš
ãã§ããã æ¬çºæã«çšãããã代衚çãªåå å¢æè²çŽ ãšã
ãŠã¯ãäŸãã°ã·ã¢ãã³ãã¡ãã·ã¢ãã³ãã³ã³ãã¬
ãã¯ã¹ïŒïŒæ žåã¯ïŒæ žã®ïŒã·ã¢ãã³ãããããŒã©
âã·ã¢ãã³ãã¹ããªã«ãããã·ã¢ãã³ããªããœã
ãŒã«çãããããããã·ã¢ãã³é¡ã®è²çŽ ã®ãã¡ã§
ãã¢ãŸãªã³ããªããµãŸãªã³ããããªã³ãããªãž
ã³ããªããµãŸãŒã«ããã¢ãŸãŒã«ãã»ã¬ããŸãŒã«ã
ã€ãããŸãŒã«ã®æ§ãªå¡©åºæ§æ žãæãããã®ããã
ã奜ãŸããããã®æ§ãªæ žã«ã¯ã¢ã«ãã«åºãã¢ã«ã
ã¬ã³åºãããããã·ã¢ã«ãã«åºãã¹ã«ãã¢ã«ãã«
åºãã«ã«ããã·ã¢ã«ãã«åºãã¢ããã¢ã«ãã«åºãŸ
ãã¯çž®åççŽ ç°åŒãŸãã¯è€çŽ ç°è²ç°ãäœãäºã®åº
æ¥ããšããã³åºãæããŠããŠãããããŸã察称圢
ã§ãé察称圢ã§ãããããŸãã¡ãã³éãããªã¡ã
ã³éã«ã¢ã«ãã«åºãããšãã«åºããšããã³åºãã
ããç°çœ®æåºãæããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ã¯äžèšå¡©åºæ§æ žã®ä»ã«ãäŸã
ã°ããªããã³ãã€ã³æ žãããŒããã³æ žããªããµãŸ
ãªãžã³ãžãªã³æ žããã¢ãŸãªãžã³ãžãªã³æ žããã«ã
ããŒã«é žæ žããã¢ãŸãªã³ããªã³æ žãããããããª
ã«æ žããã©ãŸãã³æ žã®æ§ãªé žæ§æ žãæããŠããŠã
ããããããã®é žæ§æ žã¯æŽã«ã¢ã«ãã«åºãã¢ã«ã
ã¬ã³åºãããšãã«åºãã«ã«ããã·ã¢ã«ãã«åºãã¹
ã«ãã¢ã«ãã«åºãããããã·ã¢ã«ãã«åºãã¢ã«ã³
ãã·ã¢ã«ãã«åºãã¢ã«ãã«ã¢ãã³åºåã¯ãããç°
åŒæ žã§çœ®æãããŠããŠããããåå¿ èŠãªãã°ãã
ãã®è²çŽ ãçµåãããŠäœ¿çšããŠããããæŽã«ã¢ã¹
ã³ã«ãã³é žèªå°äœãã¢ã¶ã€ã³ãã³ã«ãããŠã å¡©ã
ææ©ã¹ã«ãã³é žçãäŸãã°ç±³åœç¹èš±ç¬¬2933390å·ã
å第2937089å·ã®æ现æžçã«èšèŒãããŠããæ§ãª
å¯èŠå ãåžåããªãè¶ å¢ææ§æ·»å å€ã䜵çšããã
ãšãã§ããã ãããè²çŽ ã®æ·»å éã¯ããã²ã³åéãŸãã¯ãã
ã²ã³åé圢ææåïŒã¢ã«åœãïŒÃ10-4ã¢ã«ãïŒã¢
ã«ã§ãããæŽã«å¥œãŸããã¯ãïŒÃ10-4ã¢ã«ãïŒÃ
10-1ã¢ã«ã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«çšããããæ
æ©éå¡©ãšããŠã¯ãç¹å ¬æ43â4921å·ãå44â
26582å·ãå45â18416å·ãå45â12700å·ãå45
â22185å·ãç¹éæ49â52626å·ãå52â31728å·ã
å52â137321å·ãå52â141222å·ãå53â36224
å·ããã³å53â37610å·çã®åå ¬å ±ãªãã³ã«ç±³åœ
ç¹èš±ç¬¬3330633å·ãå第3794496å·ãå第4105451
å·ãå第4123274å·ãå第4168980å·çã®åæ现æž
äžã«èšèŒãããŠãããããªèèªæã«ã«ãã³é žã®é
å¡©ãäŸãã°ã©ãŠãªã³é žãããªã¹ãã³é žéããã«ã
ãã³é žéãã¹ãã¢ãªã³é žéãã¢ã©ããã³é žéãã
ãã³é žéãαâïŒïŒâããšãã«ããã©ãŸãŒã«ããªïŒ
é ¢é žéãªã©ãè³éŠæã«ã«ãã³é žéãäŸãã°å®æ¯éŠ
é žéããã¿ã«é žéãªã©ãç¹å ¬æ44â26582å·ãå
45â12700å·ãå45â18416å·ãå45â22185å·ã
ç¹éæ52â31728å·ããã³å52â137321å·ã®åå ¬
å ±ã䞊ã³ã«ç¹é¡æ57â1065å·ãå57â1066å·çã®
åæ现æžã«èšèŒãããŠãããããªã€ããåºã®é
å¡©ãäŸãã°ãã³ãŸããªã¢ãŸãŒã«éãïŒâãããã
ã³ãŸããªã¢ãŸãŒã«éãïŒâã¯ãããã³ãŸããªã¢ãŸ
ãŒã«éãïŒâã¡ããã·ãã³ãŸããªã¢ãŸãŒã«éãïŒ
âã¹ã«ããã³ãŸããªã¢ãŸãŒã«éãïŒâããããã·
ãã³ãŸããªã¢ãŸãŒã«éãïŒâã¢ãããã³ãŸããªã¢
ãŸãŒã«éãïŒâã«ã«ããã·ãã³ãŸããªã¢ãŸãŒã«
éãã€ãããŸãŒã«éããã³ãºã€ãããŸãŒã«éãïŒ
âããããã³ãºã€ãããŸãŒã«éããã©ãŸãŒã«éã
ãŠã©ãŸãŒã«éãïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«éã
1Hâããã©ãŸãŒã«éãïŒâã¢ããâïŒâãã³ãž
ã«ããªâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«éããµãã«ãª
ã³éããã¿ã©ãžãã³éããã¿ã«ã€ããéãªã©ãã
ã®ä»ïŒâã¡ã«ã«ãããã³ãŸãªããµãŸãŒã«éãã¡ã«
ã«ãããªããµãžã¢ãŸãŒã«éãïŒâã¡ã«ã«ãããã³
ãŸãã¢ãŸãŒã«éãïŒâã¡ã«ã«ãããã³ãºã€ãããŸ
ãŒã«éãïŒâã¡ã«ã«ããâïŒâããšãã«âïŒïŒ
ïŒïŒïŒâããªã¢ãŸãŒã«éãïŒâããããã·âïŒâ
ã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ãã³é
ããã³ïŒâã¡ãã«âïŒâããããã·âïŒïŒïŒïŒ
ïŒïŒïŒïŒïŒâãã³ã¿ã¶ã€ã³ãã³éãªã©ãæããã
ãã以äžã®ææ©éå¡©ã®ãã¡ã§ãã€ããåºã®éå¡©ã
奜ãŸãããç¹ã«ãã³ãŸããªã¢ãŸãŒã«èªå°äœã®é
å¡©ããã奜ãŸããã¯ã¹ã«ããã³ãŸããªã¢ãŸãŒã«èª
å°äœã®éå¡©ã奜ãŸããã æ¬çºæã«çšããããææ©éå¡©ã¯ãåé¢ãããã®
ãé©åœãªæ段ã«ãããã€ã³ããŒäžã«åæ£ããŠäœ¿çš
ã«äŸããŠããããããŸãé©åœãªãã€ã³ããŒäžã§é
å¡©ã調補ããåé¢ããã«ãã®ãŸãŸäœ¿çšã«äŸããŠã
ããã 該ææ©éå¡©ã®äœ¿çšéã¯ãæ¯æäœïŒm2åœã0.05ïœ
ã10.0ïœã§ããã奜ãŸããã¯0.2ïœã2.0ïœã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«çšããããé
å å€ã¯ãç±çŸåã«ã©ãŒæå ææã®åéã§éåžžçšã
ããããã®ãçšããããšãã§ããäŸãã°ç±³åœç¹èš±
第3531286å·ãå第3761270å·ãå第3764328å·å
æ现æžããŸãRDNo.12146ãåNo.15108ãåNo.
15127ããã³ç¹éæ56â27132å·å ¬å ±çã«èšèŒã®ïœ
âããšãã¬ã³ãžã¢ãã³ç³»ããã³ïœâã¢ããããšã
ãŒã«ç³»çŸåäž»è¬ãããªã¹ããªãã¢ããããšããŒã«
ç³»ããã³ã¹ã«ãã³ã¢ããããšããŒã«ç³»çŸåäž»è¬ã
ãŸãããã©ãŸã³ç³»çºè²çŸåäž»è¬ãæããããããŸ
ããç±³åœç¹èš±ç¬¬3342599å·ãå第3719492å·ãç¹é
æ53â135628å·ãå54â79035å·çã«èšèŒãããŠ
ããçºè²çŸåäž»è¬ãã¬ã«ãŒãµãŒçãæå©ã«çšãã
ããšãã§ããã ç¹ã«å¥œãŸããéå å€ãšããŠãç¹éæ56â146133
å·ã«èšèŒãããŠããäžèšäžè¬åŒïŒ»ïŒœã§è¡šããã
ãéå å€ãæããããã äžè¬åŒïŒ»ïŒœ åŒäžãR3ããã³R4ã¯æ°ŽçŽ ååããŸãã¯çœ®æåº
ãæããŠãããççŽ ååæ°ïŒã30ïŒå¥œãŸããã¯ïŒ
ãïŒïŒã®ã¢ã«ãã«åºãè¡šãããR3ãšR4ãšã¯éç°
ããŠè€çŽ ç°ã圢æããŠããããR5ïŒR6ïŒR7ãã
ã³R8ã¯æ°ŽçŽ ååãããã²ã³ååãããããã·åºã
ã¢ããåºãã¢ã«ã³ãã·åºãã¢ã·ã«ã¢ããåºãã¹ã«
ãã³ã¢ããåºãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºãŸãã¯
眮æåºãæããŠãããççŽ ååæ°ïŒã30ïŒå¥œãŸã
ãã¯ïŒãïŒïŒã®ã¢ã«ãã«åºãè¡šãããR5ãšR3ã
ãã³R7ãšR4ã¯ããããéç°ããŠè€çŽ ç°ã圢æã
ãŠããããïŒã¯ã¢ã«ã«ãªéå±ååãã¢ã³ã¢ããŠã
åºãå«çªçŽ ææ©å¡©åºãŸãã¯ç¬¬ïŒçŽçªçŽ ååãå«ã
ååç©ãè¡šããã äžèšäžè¬åŒïŒ»ïŒœã«ãããå«çªçŽ ææ©å¡©åºãšã¯
ç¡æ©é žãšå¡©ãçæãåŸãå¡©åºæ§ã瀺ãçªçŽ ååã
å«ãææ©ååç©ã§ãããç¹ã«éèŠãªææ©å¡©åºãšã
ãŠã¯ã¢ãã³ååç©ãæããããããããŠéç¶ã®ã¢
ãã³ååç©ãšããŠã¯ç¬¬ïŒçŽã¢ãã³ã第ïŒçŽã¢ã
ã³ã第ïŒçŽã¢ãã³ãªã©ãããŸãç°ç¶ã®ã¢ãã³åå
ç©ãšããŠã¯å žåçãªãããç°åŒææ©å¡©åºã®äŸãšã
ãŠèåãªããªãžã³ããããªã³ããããªãžã³ãã€ã
ããŸãŒã«çãæããããããã®ä»ããããã·ã«ã¢
ãã³ãããã©ãžã³ãã¢ããžã³ãªã©ã®ååç©ãéç¶
ã®ã¢ãã³ãšããŠæçšã§ããããŸãå«çªçŽ ææ©å¡©åº
ã®å¡©ãšããŠã¯äžèšã®ãããªææ©å¡©åºã®ç¡æ©é žå¡©
ïŒäŸãã°å¡©é žå¡©ãç¡«é žå¡©ãç¡é žå¡©çïŒã奜ãŸãã
çšãããããäžæ¹ãäžèšäžè¬åŒã«ããã第ïŒçŽçª
çŽ ãå«ãååç©ãšããŠã¯ãïŒäŸ¡ã®å ±æçµåãæã
ãçªçŽ ååç©ã®å¡©ãŸãã¯æ°Žé žåç©çãæããã
ãã 次ã«ãåèšäžè¬åŒããã§ç€ºãããéå å€ã®å¥œ
ãŸããå ·äœäŸã以äžã«ç€ºãã äžèšäžè¬åŒïŒ»ïŒœã§è¡šããããéå å€ã¯ãå ¬ç¥
ã®æ¹æ³ãäŸãã°HoubenâWeylïŒMethodender
Organischen ChemieïŒBandXIïŒ2645â703é ã«
èšèŒãããŠããæ¹æ³ã«åŸã€ãŠåæã§ããããã®ä»
以äžã«è¿°ã¹ããããªéå å€ãçšããããšãã§ã
ãã å³ã¡ãããšããŒã«é¡ïŒäŸãã°ïœâããšãã«ããš
ããŒã«ãïœâã¡ããã·ããšããŒã«ãïŒïŒïŒâãžâ
tertâããã«âïœâã¯ã¬ãŸãŒã«ãâã¡ãã«âïœ
âã¢ããããšããŒã«çïŒãã¹ã«ãã³ã¢ããããšã
ãŒã«é¡ïŒ»äŸãã°ïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããããš
ããŒã«ãïŒâãã³ãŒã³ã¹ã«ãã³ã¢ããããšããŒ
ã«ãïŒïŒïŒâãžã¯ããâïŒâãã³ãŒã³ã¹ã«ãã³ã¢
ããããšããŒã«ãïŒïŒïŒâãžããã¢âïŒâïŒïœâ
ãã«ãšã³ã¹ã«ãã³ã¢ããïŒããšããŒã«çããŸã
ã¯ããªããããã·ãã³ãŒã³é¡ïŒäŸãã°ãã€ããã
ãã³ãtertâããã«ãã€ããããã³ãïŒïŒïŒâãž
ã¡ãã«ãã€ããããã³ãã¯ãããã€ããããã³ã
ã«ã«ããã·ãã€ããããã³ãã«ãã³ãŒã«ãïŒâã«
ã«ããã·ã«ãã³ãŒã«çïŒãããããŒã«é¡ïŒäŸãã°
αâããããŒã«ãβâããããŒã«ãïŒâã¢ããã
ãããŒã«ãïŒâã¡ããã·ããããŒã«çïŒãããã
ãã·ããããã«é¡ããã³ã¡ãã¬ã³ãã¹ããããŒã«
é¡ïŒ»äŸãã°ïŒïŒ1â²âãžããããã·âïŒïŒ2â²âãã
ããã«ãïŒïŒ6â²âãžããã¢âïŒïŒ2â²âãžãããã
ã·âïŒïŒ1â²âããããã«ãïŒïŒ6â²âãžãããâ
ïŒïŒ2â²âãžããããã·âïŒïŒ1â²âããããã«ã
ïŒïŒ4â²âãžã¡ããã·âïŒïŒ1â²âãžããããã·â
ïŒïŒ2â²âããããã«ããã¹ïŒïŒâããããã·âïŒ
âãããã«ïŒã¡ã¿ã³çãã¡ãã¬ã³ãã¹ããšããŒ
ã«é¡ïŒ»äŸãã°ïŒïŒïŒâãã¹ïŒïŒâããããã·â
ïŒïŒïŒâãžã¡ãã«ããšãã«ïŒâïŒïŒïŒïŒïŒâããª
ã¡ãã«ãããµã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·
âïŒâtertâããã«âïŒâã¡ãã«ããšãã«ïŒã¡ã¿
ã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒâãž
âtertâããã«ããšãã«ïŒã¡ã¿ã³ãïŒïŒïŒâã¡ã
ã¬ã³ãã¹ïŒïŒâããããã·âïŒâtertâããã«â
ïŒâã¡ãã«ããšãã«ïŒâïŒâã¡ãã«ããšããŒã«ã
αâããšãã«âαïŒÎ±âãã¹ïŒïŒâããããã·â
ïŒïŒïŒâãžâtertâããã«ããšãã«ïŒã¡ã¿ã³ãα
âããšãã«âαïŒÎ±âãã¹ïŒïŒâããããã·âïŒ
âtertâããã«âïŒâã¡ãã«ããšãã«ïŒã¡ã¿ã³ã
ïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒâãžã¡ã
ã«ããšãã«ïŒâïŒâã¡ãã«ãããã³ãïŒïŒïŒïŒïŒïŒ
ïŒâããã©ãã¹ïŒïŒâããããã·âïŒïŒïŒâãžã¡
ãã«ããšãã«ïŒâïŒïŒïŒâãšãã«ãã³ã¿ã³ãïŒïŒ
ïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒâãžã¡ãã«ã
ãšãã«ïŒãããã³ãïŒïŒïŒâãã¹ïŒïŒâãããã
ã·âïŒâã¡ãã«âïŒâtertâããã«ããšãã«ïŒã
ããã³ãïŒïŒïŒâãã¹ïŒïŒâããããã·âïŒïŒïŒ
âãžâtertâããã«ããšãã«ïŒãããã³çãã¢
ã¹ã³ã«ãã³é žé¡ãïŒâãã©ãŸãªãã³é¡ããã©ãŸã
ã³é¡ãããã©ãŸã³é¡ããã³ãã©ããšãã¬ã³ãžã¢ã
ã³é¡ãæããããã ãããéå å€ã¯åç¬ãæãã¯ïŒçš®ä»¥äžçµåããŠ
çšããããšãã§ãããç°å å€ã®äœ¿çšéã¯ã䜿çšã
ããæå æ§ããã²ã³åéã®çš®é¡ãææ©é žéå¡©ã®çš®
é¡ããã³ãã®ä»ã®æ·»å å€ã®çš®é¡ãªã©ã«äŸåãã
ããéåžžã¯è²çŽ äŸäžç©è³ªïŒã¢ã«ã«å¯ŸããŠ0.05ã10
ã¢ã«ã®ç¯å²ã§ããã奜ãŸããã¯0.1ãïŒã¢ã«ã§ã
ãã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãäžèšåæ
å以å€ã«å¿ èŠã«å¿ãå皮添å å€ãæ·»å ããããšã
ã§ãããäŸãã°çŸåä¿é²å€ãšããŠã¯ãç±³åœç¹èš±ç¬¬
3220840å·ãå第3531285å·ãå第4012260å·ãå
第4060420å·ãå第4088496å·ãå第4207392å·å
æ现æžãRDNo.15733ãåNo.15734ãåNo.15776ã
ç¹éæ56â130745å·ãå56â132332å·çã«èšèŒã
ããå°¿çŽ ãã°ã¢ããžãŠã ããªã¯ããã¢ã»ããŒãç
ã®ã¢ã«ã«ãªæŸåºå€ãç¹å ¬æ45â12700å·èšèŒã®æ
æ©é žãç±³åœç¹èš±ç¬¬3667959å·èšèŒã®ãâCOâïŒâ
SO2âïŒâSOâåºãæããéæ°Žæ§æ¥µæ§æº¶åªåå
ç©ãç±³åœç¹èš±ç¬¬3438776å·èšèŒã®ã¡ã«ãããªãŒã
ãŒãç±³åœç¹èš±ç¬¬3666477å·ãç¹éæ51â19525å·ã«
èšèŒã®ããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«é¡çãããããŸ
ãè²èª¿å€ãšããŠã¯ãäŸãã°ç¹éæ46â4928å·ãå
46â6077å·ãå49â5019å·ãå49â5020å·ãå49
â91215å·ãå49â107727å·ãå50â2524å·ãå
50â97132å·ãå50â67641å·ãå50â114217å·ã
å52â33722å·ãå52â99813å·ãå53â1020å·ã
å53â55115å·ãå53â76020å·ãå53â125014
å·ãå54â156523å·ãå54â156524å·ãå54â
156525å·ãå54â156526å·ãå55â4060å·ãå55
â4061å·ãå55â32015å·çã®å ¬å ±ãªãã³ã«è¥¿ç¬
ç¹èš±ç¬¬5140406å·ãå第2147063å·ãå2220618å·ã
ç±³åœç¹èš±ç¬¬3080254å·ãå第3847612å·ãå第
3782941å·ãå第3994732å·ãå第4123282å·ãå
第4201582å·çã®åæ现æžã«èšèŒãããŠããåå
ç©ã§ãããã¿ã©ãžãã³ããã¿ã«ã€ããããã©ãŸã
ã³ããããŸãªãã³ãâããããã·ããã¿ã«ã€ã
ãããã³ããªããµãžã³ãããããªããµãžã³ãžãª
ã³ãïŒïŒïŒâãžãããâãã¿ã©ãžã³ãžãªã³ãïŒïŒ
ïŒâãžãããâïŒïŒïŒâãªããµãžã³âïŒïŒïŒâãž
ãªã³ããªãã·ããªãžã³ãã¢ããããªãžã³ãããã
ãã·ãããªã³ãã¢ãããããªã³ãã€ãœã«ã«ãã¹ã
ãªã«ãã¹ã«ãã³ã¢ããã2HâïŒïŒïŒâãã³ãŸã
ã¢ãžã³âïŒïŒïŒâïŒ3HïŒãžãªã³ããã³ãŸããªã¢ãž
ã³ãã¡ã«ã«ããããªã¢ãŸãŒã«ããžã¡ã«ã«ãããã
ã©ã¶ãã³ã¿ã¬ã³ããã¿ã«é žãããã¿ã«é žããã¿ã«
ã¢ãã³é žçãããããããã®ïŒã€ãŸãã¯ããã以
äžãšã€ãããŸãŒã«ååç©ãšã®æ··åç©ããŸããã¿ã«
é žãããã¿ã«é žçã®é žãŸãã¯é žç¡æ°Žç©ã®å°ãªããš
ãïŒã€ããã³ãã¿ã©ãžã³ååç©ã®æ··åç©ãããã«
ã¯ããã¿ã©ãžã³ãšãã¬ã€ã³é žãã€ã¿ã³ã³é žããã
ãªã³é žãã²ã³ããžã³é žçã®çµåãçãæããããš
ãã§ããããŸããç¹éæ58â189628å·ãå58â
193460å·å ¬å ±ã«èšèŒããããïŒâã¢ããâïŒâã¡
ã«ã«ããâïŒïŒïŒïŒïŒâããªã¢ãŸãŒã«é¡ãïŒâã¢
ã·ã«ã¢ããâïŒâã¡ã«ã«ããâïŒïŒïŒïŒïŒâããª
ã¢ãŸãŒã«é¡ãæå¹ã§ããã ãŸãããã«ãã«ããªé²æ¢å€ãšããŠã¯ãäŸãã°ã
ç¹å ¬æ47â11113å·ãç¹éæ49â90118å·ãå49â
10724å·ãå49â97613å·ãå50â101019å·ãå49
â130720å·ãå50â123331å·ãå51â47419å·ã
å51â57435å·ãå51â78227å·ãå51â104338
å·ãå53â19825å·ãå53â20923å·ãå51â
50725å·ãå51â3223å·ãå51â42529å·ãå51â
81124å·ãå54â51821å·ãå55â93149å·çã®å ¬
å ±ããªãã³ã«è±åœç¹èš±ç¬¬1455271å·ãç±³åœç¹èš±ç¬¬
3885968å·ãå第3700457å·ãå第4137079å·ãå
第4138265å·ã西ç¬ç¹èš±ç¬¬2617907å·çã®åæ现æž
ã«èšèŒãããŠããååç©ã§ãã第ïŒæ°Žéå¡©ãæã
ã¯é žåå€ïŒäŸãã°ãâããã²ãã¢ã»ãã¢ããã
âããã²ãã³ãã¯é žã€ãããéå¡©çŽ é žããã³ã
ã®å¡©é¡ãç¡æ©éé žåç©ãéç¡«é žå¡©çïŒæãã¯ãé ž
ããã³ãã®å¡©ïŒäŸãã°ãã¹ã«ãã€ã³é žãã©ãŠãªã³
é žãªããŠã ãããžã³ããžãã«ãã³é žãããªã¹ã«ã
ã³é žçïŒãæãã¯ã€ãªãŠå«æååç©ïŒäŸãã°ãã¡
ã«ã«ããååç©æŸåºæ§ååç©ãããªãŠã©ã·ã«ããž
ã¹ã«ãã€ããã€ãªãŠåäœãã¡ã«ã«ããâïŒïŒïŒïŒ
ïŒâããªã¢ãŸãŒã«ããã¢ãŸãªã³ããªã³ãããªã¹ã«
ãã€ãååç©çïŒããã®ä»ããªããµãŸãªã³ãïŒïŒ
ïŒïŒïŒâããªã¢ãŸãŒã«ããã¿ã«ã€ããçã®ååç©
ãæããããã ãŸãå®å®å€ãšããŠç¹ã«åŠçåŸã®ããªã³ãã¢ãŠã
é²æ¢å€ãåæã«çšããŠããããäŸãã°ç¹éæ48â
45228å·ãå50â119624å·ãå50â120328å·ãå
53â46020å·å ¬å ±çã«èšèŒã®ããã²ã³åçåæ°ŽçŽ
é¡ãå ·äœçã«ã¯ããã©ããã¢ãã¿ã³ãããªããã¢
ãšã¿ããŒã«ãïŒâããã¢âïŒâããªã«ã¢ã»ãã¢ã
ããïŒâããã¢âïŒâããªã«ã¹ã«ããã«ã¢ã»ãã¢
ãããïŒâããªããã¢ã¡ãã«ã¹ã«ããã«ãã³ãŸã
ã¢ãŸãŒã«ãïŒïŒïŒâãã¹ïŒããªããã¢ã¡ãã«ïŒâ
ïŒâã¡ãã«ããªã¢ãžã³ãªã©ããããããã ç¹ã«æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯åçš®ã®
ç±æº¶å€ãæ·»å ãããããšã奜ãŸãããæ¬çºæã®ç±
溶å€ãšã¯ç±çŸåããã³ïŒãŸãã¯ç±è»¢åãä¿é²ãã
ç©è³ªã§ããã°ããã奜ãŸããã¯åžžæž©äžã§ã¯åºäœã
ååºäœåã¯æ¶²äœã§ãã€ãŠå ç±ããããšã«ãã€ãŠã
ã€ã³ããŒäžã§æº¶è§£åã¯æº¶èããç©è³ªã§ãã€ãŠã奜
ãŸããã¯å°¿çŽ èªå°äœïŒäŸãã°ããžã¡ãã«ãŠã¬ã¢ã
ãžãšãã«ãŠã¬ã¢ãããšãã«ãŠã¬ã¢çïŒãã¢ããèª
å°äœïŒäŸãã°ãã¢ã»ãã¢ããããã³ãºã¢ããçïŒã
å€äŸ¡ã¢ã«ã³ãŒã«é¡ïŒäŸãã°ãïŒïŒïŒâãã³ã¿ã³ãž
ãªãŒã«ãïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«ãïŒïŒïŒâã·
ã¯ããããµã³ãžãªãŒã«ããã³ã¿ãšãªã¹ãªããŒã«ã
ããªã¡ãããŒã«ãšã¿ã³çïŒãåã¯ããªãšãã¬ã³ã°
ãªã³ãŒã«é¡ãæããããã詳ããå ·äœäŸãšããŠ
ã¯ãç¹é¡æ58â104249ã«èšèŒãããŠãããããã
ã®ç±æº¶å€ã¯åç¬ã§ãäºçš®ä»¥äžäœµçšããŠçšããŠãè¯
ãã ãŸãã«ããªé²æ¢å€ãšããŠã¯ãç¹é¡æ59â56506
å·ã«èšèŒã®ãã€ããããã³èªå°äœïŒäŸãã°ããžâ
ïœâãªã¯ãã«ãã€ããããã³ãããã«ãã«ãã€ã
ãããã³çïŒãç¹é¡æ59â66380å·ã«èšèŒã®ãã€
ããããã³èªå°äœãšãã³ãŸããªã¢ãŸãŒã«èªå°äœ
ïŒäŸãã°ãïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«ãïŒâ
ã«ã«ããã·ãã³ãŸããªã¢ãŸãŒã«çïŒãšã®äœµçšã奜
ãŸããçšããããšãã§ããã ãŸãç¹å ¬æ46â5393å·ãç¹éæ50â54329å·ã
å50â77034å·åå ¬å ±èšèŒã®ããã«å«ã€ãªãŠåå
ç©ãçšããŠåŸåŠçãè¡ãªã€ãŠãããã ããã«ã¯ãç±³åœç¹èš±ç¬¬3301678å·ãå第3506444
å·ãå第3824103å·ãå第3844788å·åæ现æžã«èš
èŒã®ã€ãœããŠãããŠã ç³»ã¹ã¿ãã©ã€ã¶ãŒãã¬ã«ãŒ
ãµãŒããŸãç±³åœç¹èš±ç¬¬3669670å·ãå第4012260
å·ãå第4060420å·æ现æžçã«èšèŒãããã¢ã¯ã
ããŒã¿ãŒã¹ã¿ãã©ã€ã¶ãŒãã¬ã«ãŒãµãŒçãå«æã
ãŠãããã ãŸããã·ãšç³ãNH4FeïŒSO4ïŒ2ã»12H2Oçã®æ°Ž
æŸåºå€ãçšããŠããããããã«ãŸããç¹éæ56â
132332å·ã®ããã«æ°ŽãäŸçµŠãç±çŸåãè¡ãªã€ãŠã
ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãããã«äž
èšæå以å€ã«å¿ èŠã«å¿ããŠãåå å¢æææããã¬
ãŒã·ãšã³é²æ¢ææãèå å¢çœå€ã硬èå€ã垯é»é²
æ¢å€ãå¯å¡å€ã延å±å€çåçš®ã®æ·»å å€ãå¡åžå©å€
çãæ·»å ãããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã«ã¯ãã€ã³ããŒ
ãšããŠã¯èŠªæ°Žæ§ã®ãã€ã³ããŒãç¹ã«å¥œãŸãããã
çæ°Žæ§ãã€ã³ããŒãäžéšäœµçšããŠããããæ¬çºæ
ã«å¥œãŸããçšãããã芪氎æ§ãã€ã³ããŒãšã¯ãæ°Ž
ãããã¯ãæ°Žãšææ©æº¶åªã®æ··å液ã«å¯æº¶ã§ããã
ã®ããããäŸãã°ãŒã©ãã³ããŒã©ãã³èªå°äœã®åŠ
ãèçœè³ªãã»ã«ããŒã¹èªå°äœãããã¹ãã©ã³ã®åŠ
ãããªãµãã«ã©ã€ããã¢ã©ãã¢ãŽã çã®åŠã倩ç¶
ç©è³ªããã³æå¹ãªããªããŒãšããŠãããªããã«ã¢
ã»ã¿ãŒã«ïŒå¥œãŸããã¯ã¢ã»ã¿ãŒã«å床ã20ïŒ ä»¥
äžãäŸãã°ããªããã«ããã©ãŒã«ïŒãããªã¢ã¯ãª
ã«ã¢ãããããªããã«ãããªãã³ããšãã«ã»ã«ã
ãŒã¹ãããªããã«ã¢ã«ã³ãŒã«ïŒã±ã³åçã75ïŒ ä»¥
äžã®ãã®ã奜ãŸããïŒçã奜ãŸãããããããã®
ã¿ã«éå®ããããã®ã§ã¯ãªãããŸãå¿ èŠãªãã°ïŒ
皮以äžæ··å䜿çšããŠãããããã€ã³ããŒã®éã¯å
æå å±€ãããæ¯æäœïŒm2ã«å¯ŸããŠã0.1ïœã20ïœã
奜ãŸããã¯0.5ãïŒïœã§ããã æ¬çºæã®äžèšåæåãå«ãå±€ããã³ãã®ä»ã®å±€
ã¯åºç¯å²ã®åçš®æ¯æäœäžã«å¡åžãããæ¬çºæã®ã
ãŒã³ã¿è²çŽ äŸäžç©è³ªãå«ãç±çŸåæå æ§å±€ã®åã¿
ã¯ã也ç¥åŸ1ÎŒmã1000ÎŒmã奜ãŸããã¯2ÎŒmã
20ÎŒmã§ãããæ¬çºæã«äœ¿çšãããæ¯æäœãšããŠ
ã¯ãã»ã«ããŒã¹ãã€ãã¬ãŒããã€ã«ã ãã»ã«ããŒ
ã¹ãšã¹ãã«ãã€ã«ã ãããªããã«ã¢ã»ã¿ãŒã«ãã€
ã«ã ãããªãšãã¬ã³ãã€ã«ã ãããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããã€ã«ã ãããªã«ãŒãããŒããã€ã«ã
çã®ãã©ã¹ããã¯ãã€ã«ã ããã³ã¬ã©ã¹ãçŽãã¢
ã«ãããŠã çã®éå±çããããããããŸããã©ã€
ã¿çŽãã¬ãžã³ã³ãŒãã€ãçŽãèæ°Žæ§çŽãçšããã
ãšãã§ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã¯ãåºæ¬çã«ã¯
åäžå±€äžã«(1)æå æ§ããã²ã³åéã(2)éå å€ã(3)
æ¬çºæã®ããŒã³ã¿è²çŽ äŸäžç©è³ªã(4)ãã€ã³ããŒã
ãã³(5)ææ©éå¡©ãå«æãããããããããã¯å¿ ã
ããåäžã®åçæ§æå±€äžã«å«æãããå¿ èŠã¯ãª
ããäŸãã°ãç·æå æ§å±€ãïŒå±€ã«åããåèš(1)ã
(2)ã(3)ã(4)ã(5)ã®æåãäžæ¹åŽã®ç·æå æ§å±€ã«å«
æããããã®ç·æå æ§å±€ã«é£æ¥ããä»æ¹åŽã®å±€ã«
æ¬çºæã®ããŒã³ã¿è²çŽ äŸäžç©è³ªïŒãå«æãããã
çãçžäºã«åå¿å¯èœãªç¶æ ã§ããã°ïŒä»¥äžã®åç
æ§æå±€ã«åããŠå«æããããŠãããã ãŸããåèšããåŠãç·è²æå æ§å±€ãäŸãã°ãé«
æ床局ãšäœæ床局çã®ïŒå±€ä»¥äžã«åå²ããŠèšããŠ
ããããããã«ä»ã®æè²æ§ãç°ã«ããïŒåã¯ïŒä»¥
äžã®æå æ§å±€ãæããŠãããããäžå¡ãå±€ãäžå¡
ãå±€ããããã³ã°å±€ãäžéå±€ãæãã¯ãã€ã«ã¿ãŒ
å±€çåçš®ã®åçæ§æå±€ãæããŠããŠãããã æ¬çºæã®ããŒã³ã¿è²çŽ äŸäžç©è³ªã¯äžèšã®ããã«
ç·æå æ§å±€ã«å«æããããããšãã§ãããããã
ã«éå®ããããä»ã®éæå æ§å±€ãèµ€æå æ§å±€ã«å«
æããããŠãããã æ¬çºæã®ç±çŸåæå å±€ãšåæ§ãä¿è·å±€ãäžé
å±€ãäžå¡å±€ãããã¯å±€ããã®ä»ã®åçæ§æå±€ã«ã€
ããŠãããããã®å¡åžæ¶²ã調補ãã浞挬æ³ããšã¢
ãŒãã€ãæ³ãã«ãŒãã³å¡åžæ³ãŸãã¯ç±³åœç¹èš±ç¬¬
3681294å·ã«èšèŒã®ããããŒå¡åžæ³çã®åçš®ã®å¡
åžæ³ã«ããæå ææãäœæããããšãã§ããã æŽã«å¿ èŠãªãã°ãç±³åœç¹èš±ç¬¬2761791å·ããã³
è±åœç¹èš±ç¬¬837095å·ã«èšèŒãããŠããæ¹æ³ã«ãã€
ãŠïŒå±€ãŸãã¯ãã以äžãåæã«å¡åžããããšãã§
ããã æ¬çºæã®ç±çŸåã«ã©ãŒæå ææã¯ããã®ãŸãŸå
æ§é²å ããåŸãéåžž80âã200âã奜ãŸããã¯120
âã170âã®æž©åºŠç¯å²ã§ãïŒç§éã180ç§éã奜ãŸ
ããã¯1.5ç§éã120ç§éå ç±ãããã ãã§çºè²çŸ
åãããããŸããå¿ èŠã«å¿ããŠæ°Žäžééæ§ææã
å¯çããããŠçŸåããŠããããæãã¯é²å åã«70
âã180âã®æž©åºŠç¯å²ã§äºåå ç±ãæœããŠãããã æ¬çºæã«ããç±çŸåã«ã©ãŒæå ææã«ã¯ãçš®ã
ã®é²å æ段ãçšããããšãã§ãããæœåã¯å¯èŠå
ãå«ã茻å°ç·ã®ç»åé²å ã«ãã€ãŠåŸããããäžè¬
ã«ã¯éåžžã®ã«ã©ãŒããªã³ãã«äœ¿çšãããå æºãäŸ
ãã°ã¿ã³ã°ã¹ãã³ã©ã³ããæ°Žéç¯ããã»ãã³ã©ã³
ããã¬ãŒã¶ãŒå ç·ãCRTå ç·çãå æºãšããŠçš
ããããšãã§ããã å ç±æ段ã¯ãéåžžã®ç±çŸåæå ææã«é©çšãåŸ
ãæ¹æ³ããã¹ãŠå©çšã§ããäŸãã°å ç±ããããã
ãã¯ãªãããã¬ãŒãã«æ¥è§Šãããããç±ããŒã©ãŒ
ãç±ãã©ã ã«æ¥è§Šãããããé«æž©ã®é°å²æ°äžãé
éããããããããã¯é«åšæ³¢å ç±ãçšããããã
ãã«ã¯ãæ¬çºæã®æå ææäžãããã¯ç±è»¢åçšå
åå±€ïŒèŠçŽ ïŒäžã«å°é»æ§å±€ãèšããéé»ã匷ç£ç
ã«ãã€ãŠçãããžãŠãŒã«ç±ãå©çšããããšãã§ã
ããå ç±ãã¿ãŒã³ã¯ç¹ã«å¶éãããããšã¯ãªãã
ãããããäºç±ïŒãã¬ããŒãïŒããåŸãå床å ç±
ããæ¹æ³ãã¯ãããé«æž©ã§çæéããããã¯äœæž©
ã§é·æéãé£ç¶çã«äžæãäžéãããã¯ç¹°ããã
ããããã«ã¯äžé£ç¶å ç±ãå¯èœã§ã¯ãããã簡䟿
ãªãã¿ãŒã³ã奜ãŸããããŸãé²å ãšå ç±ãåæã«
é²è¡ããæ¹åŒã§ãã€ãŠãããã ãã®æ§ã«ããŠåŸãããç»åã¯ãä»»æã®æ¹æ³ã§å
åèŠçŽ äžã«è²ç»åãšããŠåŸãããšãã§ãããäŸã
ã°RDNo.15108å·ãåNo.15127å·ã«èšèŒãããŠãã
æ¹æ³ãäŸãã°ã¡ã¿ããŒã«ã®ãããªæº¶å€æãã¯ç±æº¶
å€ãšããŠã®ã¢ã»ãã¢ãããïŒïŒ10âãã«ã³ãžãªãŒ
ã«ãã³ãã¯é žã€ãããïŒïŒïŒâãããµã³ãžã«ã«ã
ã³é žãïŒïŒïŒâãšãã¬ã³ããã¿ã¬ã³ãã¢ãã¹é žã¡
ãã«ããã³ãŸããšãã³ãã¹ãã¢ãªã³é žã¡ãã«ãã¡
ããã·ããã¿ã¬ã³ããããšãã«çãå«ã転åçŽã®
åŠãååèŠçŽ ãšå¯çãããå¿ èŠã«å¿ããŠå ç±åŸã
å¥é¢ããããšã«ãã€ãŠè»¢åçŽã®åŠãååèŠçŽ äžã«
è²ç»åãåŸãããšãã§ããã æ¬çºæã®æå ææïŒä»¥äžãæ¬çºæã®æå èŠçŽ ãš
ãããïŒã¯ãåæ§é²å ããåŸãç±çŸåããããšã«
ãã€ãŠãç±è»¢åæ§ããŒã³ã¿è²çŽ ã®åæ§ååžãæ¬çº
æã®ããŒã³ã¿è²çŽ äŸäžç©è³ªãã圢æããã該åæ§
ååžã®å°ãªããšãäžéšããæ¬çºæã®æå ææãšç©
éé¢ä¿ã«ããååå±€ã«ç±è»¢åããã«ã©ãŒç±æ¡æ£è»¢
åæ¹æ³ã«é©çšãããå Žåãååå±€ã«åœ¢æãããã
ãŒã³ã¿ç»åæ¿åºŠãæ¹è¯ãããé«ãæ¿åºŠã®ç»åãäž
ãããã€ããŒã³ã¿ã«ããªã®çºçãæå¶ã§ããã ååå±€ã¯ãç±çŸåã«ãã圢æïŒä¹è³æŸåºïŒãã
ãè²çŽ ãå容ããæ©èœãæããã°ãããè²çŽ æ¡æ£
転ååæå ææã«çšããããåªæå€ãç¹éæ57â
207250å·çã«èšèŒãããã¬ã©ã¹è»¢ç§»æž©åºŠã40â以
äž250â以äžã®èç±æ§ææ©é«ååç©è³ªã§åœ¢æãã
ãããšã奜ãŸããã åèšåªæå€ã®å ·äœçãªäŸãšããŠã¯ãå«çªçŽ äº
çŽãäžçŽã¢ãã³é¡ãå«çªçŽ è€çŽ ç°ååç©ãããã
ã®åçŽã«ããªã³æ§ååç©ãç±³åœç¹èš±ç¬¬2548564å·ã
å2484430å·ãå3148061å·ãå3756814å·ã«é瀺
ãããŠããããã«ããªãžã³ããªããŒããã³ããã«
ããªãžããŠã ã«ããªã³ããªããŒãç±³åœç¹èš±ç¬¬
2675316å·ã«é瀺ãããŠãããžã¢ã«ãã«ã¢ããåº
ãå«ãããªããŒãç±³åœç¹èš±ç¬¬2882156å·ã«é瀺ã
ããŠããã¢ããã°ã¢ããžã³èªå°äœãç±³åœç¹èš±ç¬¬
3625694å·ãå3859096å·ãè±åœç¹èš±ç¬¬1277453å·ã
å2011012å·ã«é瀺ãããŠãããŒã©ãã³ãªã©ãšæ¶
æ©å¯èœãªåªæå€ãç±³åœç¹èš±ç¬¬3958995å·ãå
2721852å·ãå2798063å·ã«é瀺ãããŠããæ°Žæ§ãŸ
ã«ååªæå€ãç¹éæ50â61228å·ã«é瀺ãããŠã
ãæ°Žäžæº¶æ§åªæå€ãç±³åœç¹èš±ç¬¬3788855å·ã西ç¬
ç¹èš±åºé¡ïŒOLSïŒç¬¬2843320å·ãç¹éæ53â
30328å·ãå52â155528å·ãå53â125å·ãå53â
1024å·ãå54â74430å·ãå54â124726å·ãå55
â22766å·ãç±³åœç¹èš±ç¬¬3642482å·ãå3488706å·ã
å3557066å·ãå3271147å·ãå3271148å·ãç¹å ¬
æ55â29418å·ãå56â36414å·ãå57â12139å·ã
RDNo.12045ïŒ1974幎ïŒã«é瀺ãããŠããåçš®åªæ
å€ããããããšãã§ããã ç¹ã«æçšãªåªæå€ã¯ã¢ã³ã¢ããŠã å¡©ãå«ãããª
ããŒã§ãç±³åœç¹èš±ç¬¬3709690å·ã«èšèŒãããŠããã
äŸãã°ã¢ã³ã¢ããŠã å¡©ãå«ãããªããŒãšããŠã¯ã
ããªã¹ãã¬ã³âã³âïŒïŒ®ïŒïŒ®âããªâïœâãã
ã·ã«ââããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãã§ãã¹ãã¬ã³ãšããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãã®æ¯çã¯ïŒïŒïŒãïŒïŒïŒã奜ãŸããã¯
ïŒïŒïŒã§ããã å žåçãªè²çŽ æ¡æ£è»¢åçšã®ååå±€ã¯ãã¢ã³ã¢ã
ãŠã å¡©ãå«ãããªããŒããŒã©ãã³ãšæ··åããŠæ¯æ
äœäžã«å¡åžããããšã«ããåŸããããè²çŽ ã®ç±çŸ
åæå å±€ããååå±€ãžã®è»¢åã«ã¯ã転å溶åªãçš
ããããšãã§ããããã®è»¢å溶åªã«ã¯ãã¡ã¿ããŒ
ã«ãé ¢é žãšãã«ããžã€ãœããã«ã±ãã³çã®äœæ²žç¹
溶åªããã³ããªâïœâã¯ã¬ãžã«ããªã¹ããšãŒãã
ããªâïœâããã«ãã¹ããšãŒãããžâïœâããã«
ãã¿ã¬ãŒãçã®é«æ²žç¹æº¶åªãçšããé«æ²žç¹æº¶åªã®
å Žåã«ã¯ãé©åœãªä¹³åå€ãçšããŠãŒã©ãã³äžã«ä¹³
åãååå±€ã«æ·»å ããããšãã§ããã åèšèç±æ§ææ©é«ååç©è³ªã®äŸãšããŠã¯ãåå
é2000ã85000ã®ããªã¹ãã¬ã³ãççŽ æ°ïŒä»¥äžã®
眮æåºããã€ããªã¹ãã¬ã³èªå°äœãããªããã«ã·
ã¯ããããµã³ãããªãžããã«ãã³ãŒã³ãããªãã
ã«ãããªãã³ãããªããã«ã«ã«ããŸã«ãããªã¢ãª
ã«ãã³ãŒã³ãããªããã«ã¢ã«ã³ãŒã«ãããªããã«
ãã«ããŒã«ããã³ããªããã«ããã©ãŒã«ãªã©ã®ã
ãªã¢ã»ã¿ãŒã«é¡ãããªå¡©åããã«ãå¡©çŽ åããªãš
ãã¬ã³ãããªäžå¡©åããåãšãã¬ã³ãããªã¢ã¯ãª
ããããªã«ãããªâïŒïŒ®âãžã¡ãã«ã¢ãªã«ã¢ã
ããïœâã·ã¢ãããšãã«åºããã³ã¿ã¯ããããšã
ã«åºããã³ïŒïŒïŒâãžã¯ããããšãã«åºããã€ã
ãªã¢ã¯ãªã¬ãŒããããªã¢ã¯ãªã«ã¯ããã¢ã¯ãªã¬ãŒ
ããããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããããªãšãã«ã¡ã¿
ã¯ãªã¬ãŒããããªãããã«ã¡ã¿ã¯ãªã¬ãŒããããª
ã€ãœãããã«ã¡ã¿ã¯ãªã¬ãŒããããªã€ãœããã«ã¡
ã¿ã¯ãªã¬ãŒããããªâtertâããã«ã¡ã¿ã¯ãªã¬ãŒ
ããããªã·ã¯ãããã·ã«ã¡ã¿ã¯ãªã¬ãŒããããªãš
ãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããããªâïŒâ
ã·ã¢ãâãšãã«ã¡ã¿ã¯ãªã¬ãŒããããªãšãã¬ã³ã
ã¬ãã¿ã¬ãŒããªã©ã®ããªãšã¹ãã«é¡ãããªã¹ã«ã
ã³ããã¹ããšããŒã«ïŒ¡ããªã«ãŒãããŒãçã®ããª
ã«ãŒãããŒãé¡ãããªã¢ã³ããã©ã€ããããªã¢ã
ãé¡äžŠã³ã«ã»ãã«ãŒã¹ã¢ã»ããŒãé¡ãããããã
ãããŸããPolymer Handbook 2nd ed.ïŒJ.
BrandrupïŒE.H.Immergutç·šïŒJohn WileyïŒ
Sonsåºçãã«èšèŒãããŠããã¬ã©ã¹è»¢ç§»æž©åºŠ40
â以äžã®åæããªããŒãæçšã§ããããããã®é«
ååç©è³ªã¯ãåç¬ã§çšããããŠãããŸãïŒä»¥äžã
çµã¿åããŠå ±éåäœãšããŠçšããŠãããã ç¹ã«æçšãªããªããŒãšããŠã¯ãããªã¢ã»ããŒ
ãããžã¢ã»ããŒããªã©ã®ã»ã«ããŒã¹ã¢ã»ããŒãã
ããã¿ã¡ãã¬ã³ãžã¢ãã³ãšã®ãã¬ãã¿ã«é žããã«
ãªã¬ã³ãžãããã«ã¢ãã³ãšã¢ãžãã³é žããããµã¡
ãã¬ã³ãžã¢ãã³ãšãžããšã³é žããããµã¡ãã¬ã³ãž
ã¢ãã³ãšã€ãœãã¿ã«é žãªã©ã®çµã¿åãã«ããããª
ã¢ããããžãšãã¬ã³ã°ãªã³ãŒã«ãšãžããšãã«ã«ã«
ãã³é žããã¹âïœâã«ã«ããã·ããšããã·ãã¿ã³
ãšãšãã¬ã³ã°ãªã³ãŒã«ãªã©ã®çµã¿åãã«ããããª
ãšã¹ãã«ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããããªã«
ãŒãããŒãããããããããããã®ããªããŒã¯æ¹
質ããããã®ã§ãã€ãŠããããããšãã°ãã·ã¯ã
ãããµã³ãžã¡ã¿ããŒã«ãã€ãœãã¿ã«é žãã¡ããã·
ããªãšãã¬ã³âã°ãªã³ãŒã«ãïŒïŒïŒâãžã«ã«ãã¡
ããã·âïŒâãã³ãŒã³ã¹ã«ãã³é žãªã©ãæ¹è³ªå€ãš
ããŠçšããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããæå¹ã§
ããã äžèšã®ããªããŒã¯é©åœãªæº¶å€ã«æº¶ãããŠæ¯æäœ
äžã«å¡åžããŠååå±€ãšãããããããã¯äžèšããª
ããŒããæããã€ã«ã ç¶ååå±€ãæ¯æäœã«ã©ãã
ãŒãããŠçšãããããããŸãã¯æ¯æäœäžã«å¡åžã
ãããšãªããäžèšããªããŒããæãéšæïŒäŸãã°
ãã€ã«ã ïŒåç¬ã§ååå±€ãæ§æããããšïŒåå
å±€ã»æ¯æäœå ŒçšåïŒãã§ããã ããã«ååå±€ãšããŠã¯éææ¯æäœäžã®ååå±€ã®
äžã«ãŒã©ãã³åæ£ããäºé žåãã¿ã³çãå«ãäžé
æåå±€ïŒåå°æ§å±€ïŒãèšããŠæ§æããããšãã§ã
ãããã®äžéæåå±€ã¯ã転åè²ç»åãååå±€ã®é
ææ¯æäœåŽããèŠãããšã«ããåå°åã®è²åãåŸ
ãããã å®æœäŸïŒœ 以äžã«æ¬çºæã®å®æœäŸã瀺ãããæ¬çºæã®å®æœ
æ æ§ã¯ãããã«éããããã®ã§ã¯ãªãã æ¯èŒäŸ ïŒ äŸç€ºè²çŽ äŸäžç©è³ª(8)520mgãé ¢é žãšãã«ïŒmlå
ã³ãžãªã¯ãã«ãã¿ã¬ãŒãïŒmlãæ··åããå ç±æº¶è§£
ããããã®æº¶æ¶²ãçé¢æŽ»æ§å€ãå«ã2.5ïŒ ãŒã©ã
ã³æº¶æ¶²ïŒmlãšæ··åããæ°Žãå ããŠ12mlãšããŠãã¢
ãžãã€ã¶ãŒã§ïŒåéä¹³ååæ£ããã äžèšã®åæ£æ¶²ïŒmlã450mgã®ããªããã«ãããª
ãã³ïŒååé30000ïŒåã³ïŒïŒïŒãã³ã¿ã³ãžãªãŒ
ã«ïŒ500mgïŒãå«ãæ°Ž3.5mlãšæ··åããåèšçŸåå€
ïŒïŒ²âïŒïŒ200mgãå ããããã®åæ£æ¶²ã«å¹³åç²åŸ
0.1ÎŒmã®æ²èåéãæç®ããŠãïŒÃ10-3ã¢ã«æ·»å
ããæ°Žãå ããŠ15mlã«ä»äžããåŸãããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒãããŒã¹äžã«æ¹¿æœ€èåã60ÎŒmãšãª
ãããã«ã¯ã€ã€ãŒããŒã«ãŠå¡åžããã åŸãããæå ææã也ç¥åŸã16000CMSã®çœè²
é²å ãã¹ããããŠãšããžãéããŠäžããã次ã
ã§ãé²å æžã¿è©Šæã®å¡åžé¢ãšãã©ã€ã¿çŽäžã«ããª
å¡©åããã«ïŒååå±€ïŒãå¡èšããååçŽã®ååé¢
ãéãåãããŠã150âã§ïŒåééå±æ§ããŒãã
ããã¯ãçšããŠç±çŸåããããªãã次ãã§ãåå
çŽãå¥ããããšãããååçŽäžã«ããŒã³ã¿ã®è»¢å
ç»åãåŸãããããã®è»¢åç»åã®æé«åå°æ¿åºŠ
ïŒDmaxïŒã¯0.73ãã«ããªïŒDminïŒã¯0.14ã§ãã€
ãã å®æœäŸ ïŒ ãïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«éå¡©ã®èª¿è£œã 24ïœã®ïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«åã³ïŒïœ
ã®æ°Žé žåãããªãŠã ããšã¿ããŒã«âæ°ŽïŒïŒïŒïŒïŒ
æ··å液300mlã«å ã溶解ããããã®æº¶æ¶²ã«ïŒèŠå®
ã®ç¡é žé溶液20mlã«æ»Žäžããããã®éãïŒèŠå®ã®
æ°Žé žåãããªãŠã 溶液ãåæã«æ»ŽäžããPHãïŒã
ïŒã«ç¶æããããã®æº¶æ¶²ãïŒæé宀枩ã§æ¹æãã
åŸãæ°Žã§400mlã«ä»äžããŠïŒâã¹ã«ããã³ãŸããª
ã¢ãŸãŒã«é溶液ã調補ããã äŸç€ºè²çŽ äŸäžç©è³ª(8)520mgãé ¢é žãšãã«ïŒmlå
ã³ãžãªã¯ãã«ãã¿ã¬ãŒãïŒmlãæ··åããå ç±æº¶è§£
ããããã®æº¶æ¶²ãšçé¢æŽ»æ§å€ãå«ã2.5ïŒ ãŒã©ã
ã³æº¶æ¶²ïŒmlãšæ··åããæ°Žãå ããŠ12mlãšãããã¢
ãžãã€ã¶ãŒã§ïŒåéä¹³ååæ£ããã äžèšã®ïŒâã¹ã«ããã³ãŸããªã¢ãŸãŒã«é溶液ïŒ
mlãè²çŽ äŸäžç©è³ªã®äžèšåæ£æ¶²ïŒmlãæ··åããã
ãã«ããªããã«ãããªãã³ïŒååé30000ïŒ450
mgãïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«360mgãããªãšã
ã¬ã³ã°ãªã³ãŒã«ïŒååé300ïŒ120mgãæ°ŽïŒmlåã³
åèšçŸåå€ïŒïŒ²âïŒïŒ200mgãå ããåŸãïŒïŒ ã¯
ãšã³é žã§PHã5.5ãšããããã®åæ£æ¶²ã«å¹³åç²åŸ
0.05ÎŒmã®æ²èåéãéã«æç®ããŠïŒÃ10-4ã¢ã«
æ·»å ããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãæ¯æäœäžã«
湿最èå65ÎŒmãšãªãæ§ã«ã¯ã€ã€ãŒããŒã«ãŠå¡åž
ããã äžèšå¡åžç©ã也ç¥ããŠåŸãããè©Šæã«å¯ŸããŠã¹
ããããŠãšããžãéããŠã30000CMSïŒã«ã³ã
ã©ã»ã¡ãŒã¿ãŒã»ç§ïŒã®é²å ãäžããã 次ãã§äžèšé²å æžã¿è©Šæã®å¡åžé¢ã«ããã©ã€ã¿
çŽäžã«å¡©åããã«ãå¡åžããååçŽãéããŠãè¡š
é¢æž©åºŠã140âã®éå±è£œããŒããããã¯ã§60ç§é
å§çå ç±ãã次ãã§ååçŽãå¥ããååçŽã«è»¢å
ããè²çŽ åæ¿åºŠïŒåå°æ¿åºŠïŒã枬å®ããããã®çµ
æãåŸèšç¬¬ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ ãã€ã³ããŒã®ããªããã«ãããªãã³ãããªãã
ã«ã¢ã«ã³ãŒã«ïŒéå床400ïŒã«ä»£ãã以å€ã¯å®æœ
äŸïŒãšåãåŠæ³ã§äœæããè©Šæãçšæããå®æœäŸ
ïŒãšåãé²å ãçŸåãè¡ãªã€ãããã®çµæãåã
ã第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒãïŒ éå å€ãè¡šâïŒã«ç€ºãååç©ã«ä»£ãã以å€ã¯å®
æœäŸïŒãšåãåŠæ³ã§äœæããè©Šæãçšæããå®æœ
äŸïŒãšåãé²å ãçŸåãè¡ãªã€ãããã®çµæãå
ãã第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒãïŒ è²çŽ äŸäžç©è³ªãšããŠäŸç€ºè²çŽ äŸäžç©è³ª(8)ã®ä»£ã
ãã«è¡šâïŒã«ç€ºãè²çŽ äŸäžç©è³ªãçšãã以å€ã¯å®
æœäŸïŒãšåãåŠæ³ã§äœæããè©Šæãçšæããå®æœ
äŸïŒãšåãé²å ãçŸåãè¡ãªã€ãããã®çµæãå
ãã第ïŒè¡šã«ç€ºãã æ¯èŒäŸ ïŒïŒïŒããã³ïŒ è²çŽ äŸäžç©è³ªãšããŠäžèšè²çŽ äŸäžç©è³ªïŒ¡ïŒïŒ¢ã
ãã³ïŒ£ãçšãã以å€ã¯å®æœäŸïŒãšåãåŠæ³ã§äœæ
ããïŒçš®ã®è©Šæãçšæããå®æœäŸïŒãšåãé²å ã
çŸåãè¡ãªã€ãããã®çµæãåãã第ïŒè¡šã«ç€º
ãã
ãè¡šã
ãè¡šã
äžèšç¬¬ïŒè¡šã®çµæããã掻æ§ç¹ãæ¬çºæã®NH
ââR2ã§çœ®æããããšã«ããã転åç»åã®æ
é«æ¿åºŠãé«ãããããã«ããªãäœæžããããšãã§
ãããæ¯èŒäŸïŒã§ã¯ææ©éå¡©ããªãããã転åç»
åã®æ¿åºŠãååã§ãªãã€ããæ¯èŒäŸïŒã§ã¯è»¢åç»
åã®ã«ããªãé«ããæ¯èŒäŸïŒã§ã¯è»¢åç»åã®æé«
æ¿åºŠãäœããã«ãããªã³ã°æ§ãæªãè²çŽ ã®çæé
ãå°ãªããšæããããæ¯èŒäŸïŒã§ã¯æ¬çºæãšåã
眮æåºã§æŽ»æ§ç¹ã眮æãããŠããè²çŽ çæã¯åå
ãªãããŠããããçæããè²çŽ ã®ååéã倧ã®ã
ã転åãæªããªã€ãŠããã以äžã®ããã«æ¬çºæã®
è²çŽ äŸäžç©è³ªãããããŠããããšããããã
ââR2ã§çœ®æããããšã«ããã転åç»åã®æ
é«æ¿åºŠãé«ãããããã«ããªãäœæžããããšãã§
ãããæ¯èŒäŸïŒã§ã¯ææ©éå¡©ããªãããã転åç»
åã®æ¿åºŠãååã§ãªãã€ããæ¯èŒäŸïŒã§ã¯è»¢åç»
åã®ã«ããªãé«ããæ¯èŒäŸïŒã§ã¯è»¢åç»åã®æé«
æ¿åºŠãäœããã«ãããªã³ã°æ§ãæªãè²çŽ ã®çæé
ãå°ãªããšæããããæ¯èŒäŸïŒã§ã¯æ¬çºæãšåã
眮æåºã§æŽ»æ§ç¹ã眮æãããŠããè²çŽ çæã¯åå
ãªãããŠããããçæããè²çŽ ã®ååéã倧ã®ã
ã転åãæªããªã€ãŠããã以äžã®ããã«æ¬çºæã®
è²çŽ äŸäžç©è³ªãããããŠããããšããããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¯æäœäžã«ãå°ãªããšãæå æ§ããã²ã³å
éãéå å€ãææ©éå¡©ãè²çŽ äŸäžç©è³ªããã³ãã€
ã³ããŒãå«æããåçæ§æå±€ãæããç±çŸåã«ã©
ãŒæå ææã«ãããŠãåèšè²çŽ äŸäžç©è³ã®å°ãªã
ãšãïŒã€ãäžèšäžè¬åŒïŒ»ïŒœã§è¡šããããååç©
ã§ããããšãç¹åŸŽãšããç±çŸåã«ã©ãŒæå ææã äžè¬åŒïŒ»ïŒœ åŒäžãR1ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ããª
ãåºãã¢ã·ã«ã¢ããåºãŸãã¯ãŠã¬ã€ãåºãè¡šã
ãããããR1ã§è¡šããããããããã®åºã¯ãã
ã®ççŽ ååæ°ã®ç·åãïŒã12åã§ãããäžã€ãã
ãã®åºã¯ããããã眮æåºãæããŠããããR2
ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·åºãã¢ãª
ãŒã«ãªãã·åºãã¢ããåºãŸãã¯ãããç°æ®åºãè¡š
ããããã®ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã³ãã·
åºãã¢ãªãŒã«ãªãã·åºãã¢ããåºããããç°æ®åº
ã¯ã眮æåºãæããŠãããã Arã¯ã¢ãªãŒã«åºãŸãã¯ãããç°æ®åºãè¡šããã
ãã®ã¢ãªãŒã«åºããããç°æ®åºã¯ã眮æåºãæã
ãŠããããã¯âSO2âãŸãã¯âCOâãè¡šããã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16086084A JPS6139042A (ja) | 1984-07-31 | 1984-07-31 | ç±çŸåã«ã©âæå ææ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16086084A JPS6139042A (ja) | 1984-07-31 | 1984-07-31 | ç±çŸåã«ã©âæå ææ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6139042A JPS6139042A (ja) | 1986-02-25 |
| JPH0376736B2 true JPH0376736B2 (ja) | 1991-12-06 |
Family
ID=15723939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16086084A Granted JPS6139042A (ja) | 1984-07-31 | 1984-07-31 | ç±çŸåã«ã©âæå ææ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6139042A (ja) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58123533A (ja) * | 1982-01-18 | 1983-07-22 | Fuji Photo Film Co Ltd | ç±çŸåã«ã©âæå ææ |
-
1984
- 1984-07-31 JP JP16086084A patent/JPS6139042A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58123533A (ja) * | 1982-01-18 | 1983-07-22 | Fuji Photo Film Co Ltd | ç±çŸåã«ã©âæå ææ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6139042A (ja) | 1986-02-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0146053B2 (ja) | ||
| JPH0257298B2 (ja) | ||
| JPH0554667B2 (ja) | ||
| JPH027052B2 (ja) | ||
| US5071740A (en) | Heat developable color photosensitive material | |
| JPH0587819B2 (ja) | ||
| JPH0376736B2 (ja) | ||
| JPH0245179B2 (ja) | ||
| JPH0477892B2 (ja) | ||
| JPH0413702B2 (ja) | ||
| JPH0812412B2 (ja) | ç±çŸååŠçå®å®æ§åã³é·æä¿åå®å®æ§ã®åªããç±çŸåæå ææ | |
| JPS62103634A (ja) | ç±çŸåæå ææ | |
| JPS6275435A (ja) | ç±çŸåæå ææ | |
| JPH0527849B2 (ja) | ||
| JPH0685075B2 (ja) | ç±çŸåæå ææ | |
| JPH0533778B2 (ja) | ||
| JPH029336B2 (ja) | ||
| JPH0814693B2 (ja) | é«æ床ã§ç±ã«ããªããã³çžååäžè»ç¹æ§ã«åªããç±çŸåæå ææ | |
| JPH0513300B2 (ja) | ||
| JPS6250753A (ja) | ç±çŸåæå ææ | |
| JPH057698B2 (ja) | ||
| JPH023169B2 (ja) | ||
| JPS62139550A (ja) | ç±çŸåã«ã©âæå ææ | |
| JPH0346812B2 (ja) | ||
| JPH057697B2 (ja) |