JPH03502464A - 石炭熱分解の際に生じる廃水の処理方法 - Google Patents
石炭熱分解の際に生じる廃水の処理方法Info
- Publication number
- JPH03502464A JPH03502464A JP1501719A JP50171989A JPH03502464A JP H03502464 A JPH03502464 A JP H03502464A JP 1501719 A JP1501719 A JP 1501719A JP 50171989 A JP50171989 A JP 50171989A JP H03502464 A JPH03502464 A JP H03502464A
- Authority
- JP
- Japan
- Prior art keywords
- coke
- water
- gasification
- gas
- salt solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 45
- 239000002351 wastewater Substances 0.000 title claims description 25
- 239000003245 coal Substances 0.000 title claims description 16
- 238000000197 pyrolysis Methods 0.000 title claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 239000000571 coke Substances 0.000 claims description 40
- 239000007789 gas Substances 0.000 claims description 35
- 238000001816 cooling Methods 0.000 claims description 29
- 150000003839 salts Chemical class 0.000 claims description 24
- 239000012266 salt solution Substances 0.000 claims description 18
- 238000002309 gasification Methods 0.000 claims description 14
- 239000012466 permeate Substances 0.000 claims description 14
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000001223 reverse osmosis Methods 0.000 claims description 12
- 239000012528 membrane Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 3
- 239000012141 concentrate Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 239000012670 alkaline solution Substances 0.000 claims 2
- 230000002378 acidificating effect Effects 0.000 claims 1
- 239000012223 aqueous fraction Substances 0.000 claims 1
- 229910002090 carbon oxide Inorganic materials 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- -1 L42kg Chemical class 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001768 cations Chemical group 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 238000009295 crossflow filtration Methods 0.000 description 2
- 238000010612 desalination reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000002085 enols Chemical class 0.000 description 2
- 230000007717 exclusion Effects 0.000 description 2
- 239000000383 hazardous chemical Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 2
- 239000008235 industrial water Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical class CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 206010057040 Temperature intolerance Diseases 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229940081735 acetylcellulose Drugs 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001784 detoxification Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008543 heat sensitivity Effects 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- KSSNXJHPEFVKHY-UHFFFAOYSA-N phenol;hydrate Chemical compound O.OC1=CC=CC=C1 KSSNXJHPEFVKHY-UHFFFAOYSA-N 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
- B01D61/026—Reverse osmosis; Hyperfiltration comprising multiple reverse osmosis steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/04—Feed pretreatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B39/00—Cooling or quenching coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/169—Integration of gasification processes with another plant or parts within the plant with water treatments
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Combustion & Propulsion (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Physical Water Treatments (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3803905A DE3803905A1 (de) | 1988-02-09 | 1988-02-09 | Verfahren zur behandlung von bei der kohlepyrolyse anfallendem abwasser |
| DE3803905.2 | 1988-02-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03502464A true JPH03502464A (ja) | 1991-06-06 |
Family
ID=6346983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1501719A Pending JPH03502464A (ja) | 1988-02-09 | 1989-02-02 | 石炭熱分解の際に生じる廃水の処理方法 |
Country Status (5)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010202871A (ja) * | 2009-02-27 | 2010-09-16 | General Electric Co <Ge> | 石炭発電装置の複合サイクル効率を向上するための脱水システム及び方法 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4002624C1 (US07122547-20061017-C00273.png) * | 1990-01-30 | 1991-11-28 | Still Otto Gmbh, 4630 Bochum, De | |
| US5997745A (en) * | 1998-04-08 | 1999-12-07 | Zenon Environmental Inc. | Method for producing high purity water using triple pass reverse osmosis (TPRO) |
| FR2799751B1 (fr) * | 1999-10-19 | 2002-01-18 | Kaltenbach Thuring Sa | Procede de traitement d'un effluent contenant des dechets organiques |
| DE10114537A1 (de) * | 2001-03-21 | 2002-10-24 | Elipsa Gmbh | Array von Filtrationsmembranen mit systematisch variierenden Trenneigenschaften, Verfahren zur Herstellung und Verwendung |
| GC0001026A (en) * | 2002-06-18 | 2010-03-31 | Sasol Tech Pty Ltd | Method of purifying fischer-tropsch derived water |
| RU2328456C2 (ru) | 2002-06-18 | 2008-07-10 | Сэйзол Текнолоджи (Пти) Лтд | Способ очистки воды, полученной в процессе фишера-тропша |
| CN100363268C (zh) * | 2004-11-15 | 2008-01-23 | 华东理工大学 | 冷焦污水处理方法及装置 |
| CN101781039B (zh) * | 2010-03-05 | 2012-07-18 | 中冶焦耐(大连)工程技术有限公司 | 催化氧化法与膜分离技术相结合的焦化废水深度处理工艺 |
| DE102011014221A1 (de) * | 2011-03-17 | 2012-09-20 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zur Gewinnung von Schwermetallen aus Rußwasser |
| CN113582335B (zh) * | 2021-08-17 | 2023-08-08 | 哈尔滨工创环保科技有限公司 | 一种提高煤热解废水硝态氮去除率的原位装置及其方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE353290C (de) * | 1921-03-20 | 1922-05-12 | Schomburg & Soehne Akt Ges H | Verfahren zur Befestigung von Koerpern in den Hohlraeumen von Porzellangegenstaenden, insbesondere zur Herstellung zwei- oder mehrteiliger Isolatoren durch Aufschrumpfen |
| JPS6019099A (ja) * | 1983-07-12 | 1985-01-31 | Sumikin Coke Co Ltd | コ−クス乾式消火設備による余剰汚泥の処理方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3912578A (en) * | 1973-01-22 | 1975-10-14 | United States Steel Corp | Apparatus for and a method of purifying waste fluid |
| DD133787A1 (de) * | 1977-11-16 | 1979-01-24 | Volker Becker | Verfahren zur schadlosen vernichtung des in biologischen abwasserreinigungsanlagen entstehenden abwasserschlammes |
| US4170550A (en) * | 1978-03-30 | 1979-10-09 | Koppers Company, Inc. | Process for reducing aqueous effluents containing environmentally unacceptable compounds from a process for gasifying carbonaceous materials |
| DE3532390A1 (de) * | 1984-09-12 | 1986-06-19 | Carl Still Gmbh & Co Kg, 4350 Recklinghausen | Verfahren zur behandlung von bei der verkokung oder anderen kohleveredelungsprozessen anfallendem abwasser |
| DE3515484A1 (de) * | 1985-04-30 | 1986-10-30 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zum behandeln von kondensat aus dem produktgas der vergasung fester brennstoffe |
-
1988
- 1988-02-09 DE DE3803905A patent/DE3803905A1/de active Granted
-
1989
- 1989-02-02 JP JP1501719A patent/JPH03502464A/ja active Pending
- 1989-02-02 WO PCT/EP1989/000093 patent/WO1989007636A1/de unknown
- 1989-02-02 AU AU30350/89A patent/AU3035089A/en not_active Abandoned
- 1989-02-14 IN IN128/CAL/89A patent/IN171475B/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE353290C (de) * | 1921-03-20 | 1922-05-12 | Schomburg & Soehne Akt Ges H | Verfahren zur Befestigung von Koerpern in den Hohlraeumen von Porzellangegenstaenden, insbesondere zur Herstellung zwei- oder mehrteiliger Isolatoren durch Aufschrumpfen |
| JPS6019099A (ja) * | 1983-07-12 | 1985-01-31 | Sumikin Coke Co Ltd | コ−クス乾式消火設備による余剰汚泥の処理方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010202871A (ja) * | 2009-02-27 | 2010-09-16 | General Electric Co <Ge> | 石炭発電装置の複合サイクル効率を向上するための脱水システム及び方法 |
| US8968430B2 (en) | 2009-02-27 | 2015-03-03 | General Electric Company | Dewatering system and process for increasing the combined cycle efficiency of a coal powerplant |
Also Published As
| Publication number | Publication date |
|---|---|
| IN171475B (US07122547-20061017-C00273.png) | 1992-10-24 |
| WO1989007636A1 (en) | 1989-08-24 |
| DE3803905C2 (US07122547-20061017-C00273.png) | 1993-07-22 |
| AU3035089A (en) | 1989-09-06 |
| DE3803905A1 (de) | 1989-08-17 |
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