JPH0149643B2 - - Google Patents
Info
- Publication number
- JPH0149643B2 JPH0149643B2 JP59267789A JP26778984A JPH0149643B2 JP H0149643 B2 JPH0149643 B2 JP H0149643B2 JP 59267789 A JP59267789 A JP 59267789A JP 26778984 A JP26778984 A JP 26778984A JP H0149643 B2 JPH0149643 B2 JP H0149643B2
- Authority
- JP
- Japan
- Prior art keywords
- gas
- adsorption
- pressure
- carbon monoxide
- adsorption tower
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007789 gas Substances 0.000 claims description 92
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 87
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 87
- 238000001179 sorption measurement Methods 0.000 claims description 81
- 238000000034 method Methods 0.000 claims description 58
- 239000003463 adsorbent Substances 0.000 claims description 31
- -1 copper halide Chemical class 0.000 claims description 31
- 239000010949 copper Substances 0.000 claims description 18
- 229910052802 copper Inorganic materials 0.000 claims description 18
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- 239000012535 impurity Substances 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 238000011027 product recovery Methods 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 150000003464 sulfur compounds Chemical class 0.000 claims description 2
- 239000007787 solid Substances 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 239000010457 zeolite Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 229910052680 mordenite Inorganic materials 0.000 description 3
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 208000018459 dissociative disease Diseases 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920005990 polystyrene resin Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910021594 Copper(II) fluoride Inorganic materials 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ODWXUNBKCRECNW-UHFFFAOYSA-M bromocopper(1+) Chemical compound Br[Cu+] ODWXUNBKCRECNW-UHFFFAOYSA-M 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- GWFAVIIMQDUCRA-UHFFFAOYSA-L copper(ii) fluoride Chemical compound [F-].[F-].[Cu+2] GWFAVIIMQDUCRA-UHFFFAOYSA-L 0.000 description 1
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
- Industrial Gases (AREA)
- Treating Waste Gases (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59267789A JPS61146705A (ja) | 1984-12-18 | 1984-12-18 | 一酸化炭素を含む混合ガスから高純度一酸化炭素を分離回収する方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59267789A JPS61146705A (ja) | 1984-12-18 | 1984-12-18 | 一酸化炭素を含む混合ガスから高純度一酸化炭素を分離回収する方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61146705A JPS61146705A (ja) | 1986-07-04 |
| JPH0149643B2 true JPH0149643B2 (de) | 1989-10-25 |
Family
ID=17449610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59267789A Granted JPS61146705A (ja) | 1984-12-18 | 1984-12-18 | 一酸化炭素を含む混合ガスから高純度一酸化炭素を分離回収する方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61146705A (de) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61205613A (ja) * | 1985-03-07 | 1986-09-11 | Chiyoda Chem Eng & Constr Co Ltd | 高純度ｃｏの分離製造方法 |
| US6770390B2 (en) * | 2000-11-13 | 2004-08-03 | Air Products And Chemicals, Inc. | Carbon monoxide/water removal from fuel cell feed gas |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55334A (en) * | 1978-06-16 | 1980-01-05 | Agency Of Ind Science & Technol | Benzoic acid derivative having metastable state |
| JPS5849436A (ja) * | 1981-08-31 | 1983-03-23 | Hidefumi Hirai | 一酸化炭素を分離する方法 |
| JPS5949818A (ja) * | 1982-09-13 | 1984-03-22 | Osaka Oxgen Ind Ltd | 吸着法を使用して一酸化炭素を含む混合ガス中の一酸化炭素を濃縮する方法 |
-
1984
- 1984-12-18 JP JP59267789A patent/JPS61146705A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55334A (en) * | 1978-06-16 | 1980-01-05 | Agency Of Ind Science & Technol | Benzoic acid derivative having metastable state |
| JPS5849436A (ja) * | 1981-08-31 | 1983-03-23 | Hidefumi Hirai | 一酸化炭素を分離する方法 |
| JPS5949818A (ja) * | 1982-09-13 | 1984-03-22 | Osaka Oxgen Ind Ltd | 吸着法を使用して一酸化炭素を含む混合ガス中の一酸化炭素を濃縮する方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61146705A (ja) | 1986-07-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5531809A (en) | Pretreatment layer for CO-VSA | |
| KR100966064B1 (ko) | 합성가스 정제 방법 | |
| AU662267B2 (en) | Hydrogen and carbon monoxide production by hydrocarbon steam reforming and pressure swing adsorption purification | |
| KR940006239B1 (ko) | 일산화탄소 생성을 위한 통합적 방법 | |
| KR100896455B1 (ko) | 압력변동흡착장치 및 이를 이용한 수소 정제 방법 | |
| TWI521056B (zh) | Methane recovery method and methane recovery unit | |
| US4025321A (en) | Purification of natural gas streams containing oxygen | |
| JPS6265918A (ja) | Ｃｏ分離回収用吸着剤、その製造法およびそれを用いて高純度ｃｏを分離回収する方法 | |
| JPH10114508A (ja) | 不活性ガス流れを精製する方法 | |
| JPS6137968B2 (de) | ||
| JPH0688768B2 (ja) | ゼオライトによるｃｏ▲下２▼の選択的吸着法 | |
| JPH01155945A (ja) | Ｃｏ分離回収用吸着剤の製造法 | |
| US5518527A (en) | Method for recovering ethylene from vent gas from ethylene oxide plant vent gas | |
| US3029575A (en) | Chlorine separation process | |
| JPH0624962B2 (ja) | 単結晶製造炉の排ガスより高純度アルゴンを回収する方法 | |
| JPH0149643B2 (de) | ||
| JPS6265919A (ja) | Ｃｏ分離回収用吸着剤、その製造法およびそれを用いてｃｏを分離回収する方法 | |
| JPS621766B2 (de) | ||
| CN115947949B (zh) | 一种多孔金属有机骨架材料及其合成方法，吸附剂及提纯乙烯的方法 | |
| JPS61242908A (ja) | Ｃｏ分離回収用吸着剤、その製造法およびそれを用いて高純度ｃｏを分離回収する方法 | |
| JPS61242638A (ja) | Ｃｏ分離回収用吸着剤、その製造法およびそれを用いて高純度ｃｏを分離回収する方法 | |
| JPS6265920A (ja) | 一酸化炭素を含む混合ガスから一酸化炭素を分離回収する方法 | |
| JPH0112529B2 (de) | ||
| KR101824771B1 (ko) | 표면개질된 활성탄을 이용한 이산화탄소 흡착분리 방법 | |
| JP2004300035A (ja) | メタンガスの分離方法および装置 |