JPH0125485B2 - - Google Patents
Info
- Publication number
- JPH0125485B2 JPH0125485B2 JP59063066A JP6306684A JPH0125485B2 JP H0125485 B2 JPH0125485 B2 JP H0125485B2 JP 59063066 A JP59063066 A JP 59063066A JP 6306684 A JP6306684 A JP 6306684A JP H0125485 B2 JPH0125485 B2 JP H0125485B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- polymerization
- particles
- suspension
- particle size
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002245 particle Substances 0.000 claims description 65
- 238000006116 polymerization reaction Methods 0.000 claims description 28
- 229920001577 copolymer Polymers 0.000 claims description 24
- 239000000725 suspension Substances 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000003381 stabilizer Substances 0.000 claims description 10
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 7
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 claims description 4
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 4
- -1 acrylic ester Chemical class 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 claims description 3
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 2
- CIKJANOSDPPCAU-UHFFFAOYSA-N ditert-butyl cyclohexane-1,4-dicarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1CCC(C(=O)OOC(C)(C)C)CC1 CIKJANOSDPPCAU-UHFFFAOYSA-N 0.000 claims description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 12
- 235000019731 tricalcium phosphate Nutrition 0.000 description 12
- 239000001506 calcium phosphate Substances 0.000 description 11
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 11
- 229940078499 tricalcium phosphate Drugs 0.000 description 11
- 238000000034 method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000005856 abnormality Effects 0.000 description 4
- 230000001186 cumulative effect Effects 0.000 description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 150000001451 organic peroxides Chemical class 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229960001708 magnesium carbonate Drugs 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229940032158 sodium silicate Drugs 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229960001296 zinc oxide Drugs 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6306684A JPS60206811A (ja) | 1984-03-29 | 1984-03-29 | 共重合体粒子の製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6306684A JPS60206811A (ja) | 1984-03-29 | 1984-03-29 | 共重合体粒子の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60206811A JPS60206811A (ja) | 1985-10-18 |
JPH0125485B2 true JPH0125485B2 (fr) | 1989-05-18 |
Family
ID=13218593
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6306684A Granted JPS60206811A (ja) | 1984-03-29 | 1984-03-29 | 共重合体粒子の製造方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60206811A (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH072814B2 (ja) * | 1986-05-21 | 1995-01-18 | 化薬アクゾ株式会社 | α−メチルスチレン−アクリロニトリル共重合体の製造方法 |
GB9813199D0 (en) * | 1998-06-18 | 1998-08-19 | Zeneca Ltd | Process |
KR20020048583A (ko) * | 2000-12-18 | 2002-06-24 | 안복현 | 작업성이 우수한 스티렌계 공중합체의 제조방법 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4967987A (fr) * | 1972-10-31 | 1974-07-02 | ||
JPS5382892A (en) * | 1976-12-29 | 1978-07-21 | Denki Kagaku Kogyo Kk | Preparation of copolymer |
JPS55725A (en) * | 1978-06-19 | 1980-01-07 | Denki Kagaku Kogyo Kk | Copolymerization |
-
1984
- 1984-03-29 JP JP6306684A patent/JPS60206811A/ja active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4967987A (fr) * | 1972-10-31 | 1974-07-02 | ||
JPS5382892A (en) * | 1976-12-29 | 1978-07-21 | Denki Kagaku Kogyo Kk | Preparation of copolymer |
JPS55725A (en) * | 1978-06-19 | 1980-01-07 | Denki Kagaku Kogyo Kk | Copolymerization |
Also Published As
Publication number | Publication date |
---|---|
JPS60206811A (ja) | 1985-10-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
RU2283323C2 (ru) | Вспениваемые винилароматические полимеры и способ их получения | |
MX2011006635A (es) | Composiciones de polimeros aromaticos de vinilo expandibles con una capacidad de aislamiento termico mejorada, proceso para su produccion y articulos expandidos obtenidos de las mismas. | |
US4663357A (en) | Higher molecular weight thermoplastics having multimodal molecular weight distribution | |
JPH0125485B2 (fr) | ||
EP2439232A1 (fr) | Agent d'amélioration de l'aptitude au traitement pour moulage de mousse et composition de résine de chlorure de vinyle le contenant | |
US2692260A (en) | Catalytic polymerization process for vinyl aryl compositions | |
JPH0125483B2 (fr) | ||
JPS6213442A (ja) | カ−ボン含有発泡性スチレン系樹脂粒子の製法 | |
JPS60206846A (ja) | 発泡性熱可塑性共重合体粒子の製造法 | |
US5310810A (en) | Segmented copolymers | |
JPS60206809A (ja) | 共重合体の製造法 | |
JPS60206848A (ja) | 発泡性熱可塑性共重合体粒子製造の方法 | |
JP2019183091A (ja) | スチレン系樹脂 | |
JPS60203619A (ja) | 熱可塑性樹脂の製造方法 | |
JPS60206810A (ja) | 共重合体の製法 | |
KR100527298B1 (ko) | 응집현상이 감소된 아크릴계 수지의 제조방법 | |
JP2003040906A (ja) | メタクリル樹脂板の製造方法 | |
JP6626730B2 (ja) | 着色発泡性スチレン系樹脂粒子の製造方法 | |
KR100280217B1 (ko) | 발포성 스티렌계 중합체 수지비드의 제조방법 | |
JP2783476B2 (ja) | 重合体凝固物およびその組成物の製造方法 | |
JPS61278520A (ja) | フツ素含有エラストマ−粒子の改質方法 | |
JPS63182309A (ja) | 熱可塑性耐熱樹脂の製造方法 | |
JP3571178B2 (ja) | 熱可塑性重合体粒子および発泡性熱可塑性重合体粒子の製造方法 | |
JP4587499B2 (ja) | 発泡性スチレン系樹脂粒子及びその製造法 | |
JP4587499B6 (ja) | 発泡性スチレン系樹脂粒子及びその製造法 |