JP7446719B2 - 有機化合物およびそれを有するエレクトロクロミック素子、光学フィルタ、レンズユニット、撮像素子及び窓 - Google Patents
有機化合物およびそれを有するエレクトロクロミック素子、光学フィルタ、レンズユニット、撮像素子及び窓 Download PDFInfo
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- JP7446719B2 JP7446719B2 JP2019084741A JP2019084741A JP7446719B2 JP 7446719 B2 JP7446719 B2 JP 7446719B2 JP 2019084741 A JP2019084741 A JP 2019084741A JP 2019084741 A JP2019084741 A JP 2019084741A JP 7446719 B2 JP7446719 B2 JP 7446719B2
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- 150000002894 organic compounds Chemical class 0.000 title claims description 63
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- 125000001424 substituent group Chemical group 0.000 claims description 55
- 125000000217 alkyl group Chemical group 0.000 claims description 43
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- 238000002834 transmittance Methods 0.000 claims description 18
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 17
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 15
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- 239000000758 substrate Substances 0.000 claims description 14
- 125000003545 alkoxy group Chemical group 0.000 claims description 13
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 12
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- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 6
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- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine hydrate Chemical compound O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 4
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- 239000003480 eluent Substances 0.000 description 3
- DQYBDCGIPTYXML-UHFFFAOYSA-N ethoxyethane;hydrate Chemical compound O.CCOCC DQYBDCGIPTYXML-UHFFFAOYSA-N 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 230000031700 light absorption Effects 0.000 description 3
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- NCYVXEGFNDZQCU-UHFFFAOYSA-N nikethamide Chemical class CCN(CC)C(=O)C1=CC=CN=C1 NCYVXEGFNDZQCU-UHFFFAOYSA-N 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
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- 235000011009 potassium phosphates Nutrition 0.000 description 3
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- 125000006850 spacer group Chemical group 0.000 description 3
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- VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 description 2
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- FJTMEJPKRKLJNO-UHFFFAOYSA-N 5,10-di(propan-2-yl)phenazine Chemical compound C1=CC=C2N(C(C)C)C3=CC=CC=C3N(C(C)C)C2=C1 FJTMEJPKRKLJNO-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical class [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
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- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- OKJPEAGHQZHRQV-UHFFFAOYSA-N Triiodomethane Natural products IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 2
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
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- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 2
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 2
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Images
Classifications
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- G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
- G02F1/1516—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising organic material
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
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- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
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- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
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- E06B3/6715—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light specially adapted for increased thermal insulation or for controlled passage of light
- E06B3/6722—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light specially adapted for increased thermal insulation or for controlled passage of light with adjustable passage of light
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- E—FIXED CONSTRUCTIONS
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- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
- E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
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- G—PHYSICS
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- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
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- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
- E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
- E06B2009/2464—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds featuring transparency control by applying voltage, e.g. LCD, electrochromic panels
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- G—PHYSICS
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- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2203/00—Function characteristic
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2203/00—Function characteristic
- G02F2203/02—Function characteristic reflective
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2203/00—Function characteristic
- G02F2203/05—Function characteristic wavelength dependent
- G02F2203/055—Function characteristic wavelength dependent wavelength filtering
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Description
<例示化合物A-19の合成>
1H NMR(CD3CN,500MHz),σ(ppm):9.12(s,1H),9.04(d,2H),8.92(d,1H),8.56(m,3H),8.45(d,1H),8.39(s,1H),8.23(m,1H),7.82(m,4H),7.73(m,4H),1.79(s,6H),1.44(s,9H),1.43(s,9H).
<例示化合物A-20の合成>
例示化合物A-19(0.035g、0.05mmol)を水に溶解させ、ビス(トリフルオロメタンスルホニル)イミドリチウム(0.29g、1mmol)を溶解した水溶液を滴下し、室温で3時間撹拌した後、ろ過し、得られた結晶を、エタノールで再結晶を行い、例示化合物A-20を0.051g(収率:92%)得た。NMR測定によりこの化合物の構造を確認した。
1H NMR(CD3CN,500MHz),σ(ppm):9.12(s,1H),9.04(d,2H),8.92(d,1H),8.56(m,3H),8.45(d,1H),8.39(s,1H),8.23(m,1H),7.82(m,4H),7.73(m,4H),1.79(s,6H),1.44(s,9H),1.43(s,9H).
<例示化合物A-17の合成>
1H NMR(DMSO-d6,500MHz) σ(ppm):9.65(s,1H),9.40(d,2H),9.28(d,1H),8.96(d,1H),8.90(d,2H),8.77(s,1H),8.70(d,1H),8.51(d,1H),7.75-7.55(m,8H),2.23(s,6H),1.77(s,6H).
<例示化合物A-18の合成>
例示化合物A-17(0.031g、0.05mmol)を水に溶解させ、ビス(トリフルオロメタンスルホニル)イミドリチウム(0.29g、1mmol)を溶解した水溶液を滴下し、室温で3時間撹拌した後、ろ過し、得られた結晶を、エタノールで再結晶を行い、例示化合物A-18を0.047g(収率:92%)得た。NMR測定によりこの化合物の構造を確認した。
1H NMR(CD3CN,500MHz),σ(ppm):8.97(s,1H),8.88(d,2H),8.76(d,1H),8.59(m,3H),8.48(d,1H),8.38(s,1H),8.23(m,1H),7.75-7.55(m,8H),2.24(s,6H),1.77(s,6H).
<例示化合物B-3の合成>
1H-NMR(DMSO-d6),δ(ppm):9.47(s,1H),9.49(d,1H),9.28(d,2H),9.17(d,1H),9.05(d,1H),8.77(d,2H),8.66(d,1H),4.66(t,4H),1.95(m,4H),1.73(s,6H),1.35(m,4H),0.93(t,6H).
<例示化合物B-4の合成>
1H-NMR(CD3CN),δ(ppm):9.27(d,1H),8.99(s,1H),8.82(d,2H),8.76(d,1H),8.61(d,1H),8.51(d,1H),8.43(d,2H),4.58(t,4H),2.06(m,4H),1.73(s,6H),1.43(m,4H),1.01(t,6H).
<例示化合物B-34の合成>
1H-NMR(CD3CN),δ(ppm):9.35(s,1H),9.26(s,2H),9.01-8.95(m,3H),8.76(d,1H),8.52(d,2H),4.84(s,3H),4.71(t,2H),4.66(t,2H),2.01(m,4H),1.82(s,6H),1.48(m,4H),1.04(t,6H).
<例示化合物B-6の合成>
1H-NMR(DMSO-d6),δ(ppm):9.77(s,1H),9.54(d,1H),9.39(d,2H),9.26(d,1H),9.13(d,1H),8.88(d,2H),8.76(d,1H),6.08(s,2H),6.01(s,2H),1.73(s,6H).
<例示化合物B-7の合成>
1H-NMR(CD3CN),δ(ppm):9.30(d,1H),9.08(s,1H),8.92(d,2H),8.87(d,1H),8.65(d,1H),8.59(d,1H),8.52(d,2H),5.65(s,2H),5.64(s,2H),1.73(s,6H).
<例示化合物B-20の合成>
1H-NMR(CD3CN),δ(ppm):9.39(d,1H),9.23(s,1H),9.07(d,2H),8.99(d,1H),8.72(d,1H),8.65(d,1H),8.60(d,2H),7.83-7.70(m,8H),1.80(s,6H),1.43(s,9H),1.42(s,9H).
<エレクトロクロミック素子の作製及び特性評価>
電解質として過塩素酸テトラブチルアンモニウムを0.1Mの濃度で炭酸プロピレンに溶解させ、次いで実施例2の例示化合物A-20を40.0mMの濃度で溶解させ、EC媒体を得た。
<エレクトロクロミック素子の作製及び特性評価>
実施例10において、例示化合物A-20の代わりに例示化合物A-18を使用した以外は、実施例10と同様の方法により素子を作製した。本実施例の素子に電圧を2.0V印加すると、例示化合物A-18の還元種に由来する吸収(λmax=520nm)を示し、素子は着色した。さらに-0.5V印加すると消色し、可逆的な着色及び消色した。この素子は着色状態と、消色状態と、を可逆的に変化できる。図6は、実施例11で作製した素子の紫外可視吸収スペクトルである。
<エレクトロクロミック特性の評価>
例示化合物B-20について、酸化還元電位の測定、および透過率スペクトル測定を行った。
<エレクトロクロミック特性の評価>
例示化合物B-20の代わりに例示化合物B-7を用いた以外は、実施例12と同様の方法で測定を行った。結果を表4にまとめた。
<エレクトロクロミック特性の評価>
例示化合物B-20の代わりに例示化合物B-34を用いた以外は、実施例12と同様の方法で測定を行った。結果を表4にまとめた。
<エレクトロクロミック特性の評価>
例示化合物B-20の代わりに例示化合物B-4を用いた以外は、実施例12と同様の方法で測定を行った。結果を表4にまとめた。
<エレクトロクロミック素子の作製および特性評価>
カソード性EC材料として例示化合物B-20、アノード性EC材料として下記構造のW-1(5、10-ジイソプロピル-5、10-ジヒドロフェナジン)をそれぞれ100mMの濃度で炭酸プロピレンに溶解させ、さらに増粘剤としてポリメチルメタクリレート(PMMA)を5wt%添加し、EC溶液を調製した。
7 制御器
8 駆動電源
9 抵抗切替器
10 透明基板
11 透明電極
12 EC層
13 シール材
20 駆動装置
100 撮像装置
101 光学フィルタ
102 レンズユニット
103 撮像ユニット
104 第1のレンズ群
105 第2のレンズ群
106 第3のレンズ群
107 第4のレンズ群
108 絞り
109 ガラスブロック
110 受光素子
111 調光窓
112 フレーム
113 透明板
Claims (28)
- 下記一般式[1]で表されることを特徴とする有機化合物。
一般式[1]において、Z1およびZ2は置換基を有してもよいアルキル基、置換基を有してもよいアリール基および置換基を有してもよいアラルキル基からそれぞれ独立に選ばれる。
R11乃至R17は、水素原子または置換基からそれぞれ独立に選ばれる。前記置換基は、置換基を有してもよいアルキル基、置換基を有してもよいアルコキシ基、置換基を有してもよいアリール基、または置換基を有してもよい複素環基またはハロゲン原子のいずれかである。R16とR17は、互いに結合して環を形成してもよい。
R21およびR22は、水素原子または置換基からそれぞれ独立に選ばれる。前記置換基は、置換基を有してもよい炭素原子数1以上8以下のアルキル基である。
Y1乃至Y3は、C-H、C-CH 3 、N原子、または(N+-L)(X-)からそれぞれ独立に選ばれる。Lは置換基を有してもよいアルキル基、置換基を有してもよいアリール基、置換基を有してもよいアラルキル基のいずれかである。X-は一価のアニオンである。 - 前記Y1乃至Y3がいずれも、C-Hであることを特徴とする請求項1に記載の有機化合物。
- 前記Y1が、N原子または(N+-L)(X-)であり、Y2およびY3がC-Hであることを特徴とする請求項1に記載の有機化合物。
- 前記Y1乃至Y3のいずれか1つがN原子または(N+-L)(X-)であり、他の2つがC-Hであることを特徴とする請求項1に記載の有機化合物。
- 前記Y1乃至Y3のいずれか1つがC-Hであり、他の2つがN原子または(N+-L)(X-)であることを特徴とする請求項1に記載の有機化合物。
- Z1およびZ2が、前記アリール基であることを特徴とする請求項1乃至5のいずれか一項に記載の有機化合物。
- Z1およびZ2が、前記アリール基のうちのフェニル基であり、前記フェニル基は、アルキル基を置換基として有することを特徴とする請求項6に記載の有機化合物。
- 前記フェニル基が置換基として有するアルキル基は、前記一般式[1]の基本骨格に対して、パラ位に置換していることを特徴とする請求項7に記載の有機化合物。
- 前記フェニル基が置換基として有するアルキル基は、前記一般式[1]の基本骨格に対して、オルト位に置換していることを特徴とする請求項7に記載の有機化合物。
- 前記フェニル基が置換基として有するアルキル基は、炭素原子数1乃至8のアルキル基であることを特徴とする請求項8または9に記載の有機化合物。
- 前記R11乃至R17が水素原子または炭素原子数1以上8以下のアルキル基からそれぞれ独立に選ばれることを特徴とする請求項1乃至10のいずれか一項に記載の有機化合物。
- 前記R11乃至R17が水素原子であることを特徴とする請求項1乃至11のいずれか一項に記載の有機化合物。
- 前記R21およびR22がメチル基であることを特徴とする請求項1乃至12のいずれか一項に記載の有機化合物。
- 前記X-が、PF6 -、ClO4 -、BF4 -、AsF6 -、SbF6 -、CF3SO3 -、(CF3SO2)2N-、Br-、Cl-、またはI-であることを特徴とする請求項1乃至13のいずれか一項に記載の有機化合物。
- 前記X-が、PF6 -、BF4 -、または(CF3SO2)2N-であることを特徴とする請求項1乃至13のいずれか一項に記載の有機化合物。
- 前記有機化合物が、対イオンとして前記X-を有することを特徴とする請求項1乃至15のいずれか一項に記載の有機化合物。
- 一対の電極と、前記一対の電極の間に配置されているエレクトロクロミック層を有するエレクトロクロミック素子であって、
前記エレクトロクロミック層は、請求項1乃至16のいずれか一項に記載の有機化合物を含有することを特徴とするエレクトロクロミック素子。 - 前記エレクトロクロミック層は前記有機化合物とは別種の第2のエレクトロクロミック化合物をさらに有する請求項17に記載のエレクトロクロミック素子。
- 前記第2のエレクトロクロミック化合物は、酸化状態における可視光の透過率が還元状態における可視光の透過率よりも低い、アノード性EC化合物である請求項18に記載のエレクトロクロミック素子。
- 前記エレクトロクロミック層は、4種類以上のエレクトロクロミック化合物を有することを特徴とする請求項17乃至19のいずれか一項に記載のエレクトロクロミック素子。
- 前記4種類以上のエレクトロクロミック化合物には、ビオロゲン系化合物、フェナジン系化合物が含まれることを特徴とする請求項20に記載のエレクトロクロミック素子。
- 前記エレクトロクロミック層は、溶液層であることを特徴とする請求項17乃至21のいずれか一項に記載のエレクトロクロミック素子。
- 前記エレクトロクロミック層は、増粘剤をさらに有することを特徴とする請求項22に記載のエレクトロクロミック素子。
- 前記増粘剤の重量比が、前記エレクトロクロミック層の重量を100wt%とした場合に、20wt%以下であることを特徴とする請求項23に記載のエレクトロクロミック素子。
- 請求項17乃至24のいずれか一項に記載のエレクトロクロミック素子と、前記エレクトロクロミック素子に接続されている能動素子とを有することを特徴とする光学フィルタ。
- 請求項17乃至24のいずれか一項に記載のエレクトロクロミック素子と、前記エレクトロクロミック素子を通過した光を受光する受光素子とを有することを特徴とする撮像装置。
- 一対の透明基板と、前記一対の透明基板の間に配置されている請求項17乃至24のいずれか一項に記載のエレクトロクロミック素子と、前記エレクトロクロミック素子に接続されている能動素子と、を有することを特徴とする窓。
- 請求項17乃至24のいずれか一項に記載のエレクトロクロミック素子と、光反射面に前記エレクトロクロミック素子を有する光反射部材と、を備えることを特徴とするエレクトロクロミックミラー。
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WO2017154681A1 (ja) | 2016-03-10 | 2017-09-14 | キヤノン株式会社 | 有機化合物、エレクトロクロミック素子、エレクトロクロミック装置、光学フィルタ、撮像装置、レンズユニット及び窓材 |
JP2017197477A (ja) | 2016-04-27 | 2017-11-02 | キヤノン株式会社 | 有機化合物、及びそれを有するエレクトロクロミック素子、光学フィルタ、レンズユニット、撮像装置、窓材 |
JP2018024624A (ja) | 2016-08-12 | 2018-02-15 | キヤノン株式会社 | 有機化合物及びそれを有するエレクトロクロミック素子、光学フィルム、レンズユニット、撮像装置 |
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