JP7376689B2 - ガス分離方法 - Google Patents

ガス分離方法 Download PDF

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Publication number
JP7376689B2
JP7376689B2 JP2022508134A JP2022508134A JP7376689B2 JP 7376689 B2 JP7376689 B2 JP 7376689B2 JP 2022508134 A JP2022508134 A JP 2022508134A JP 2022508134 A JP2022508134 A JP 2022508134A JP 7376689 B2 JP7376689 B2 JP 7376689B2
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gas
zeolite membrane
mixed gas
zeolite
highly permeable
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Japanese (ja)
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JPWO2021186959A1 (enExample
JPWO2021186959A5 (enExample
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克哉 清水
真紀子 市川
健二 谷島
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NGK Insulators Ltd
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NGK Insulators Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/108—Inorganic support material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1213—Laminated layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1218—Layers having the same chemical composition, but different properties, e.g. pore size, molecular weight or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/0215—Silicon carbide; Silicon nitride; Silicon oxycarbide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B01D2256/245—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708—Volatile organic compounds V.O.C.'s
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
JP2022508134A 2020-03-18 2021-02-10 ガス分離方法 Active JP7376689B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2020047803 2020-03-18
JP2020047803 2020-03-18
PCT/JP2021/004990 WO2021186959A1 (ja) 2020-03-18 2021-02-10 ガス分離方法およびゼオライト膜

Publications (3)

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JPWO2021186959A1 JPWO2021186959A1 (enExample) 2021-09-23
JPWO2021186959A5 JPWO2021186959A5 (enExample) 2022-11-18
JP7376689B2 true JP7376689B2 (ja) 2023-11-08

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US (1) US12458949B2 (enExample)
JP (1) JP7376689B2 (enExample)
WO (1) WO2021186959A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112752606A (zh) * 2018-09-28 2021-05-04 日本碍子株式会社 支撑体、沸石膜复合体、沸石膜复合体的制造方法以及分离方法
CN113860462B (zh) * 2021-10-26 2023-09-22 广东省科研五金制品有限公司 一种利用含氰废液制备气体的方法
CN118679006A (zh) * 2022-02-28 2024-09-20 日本碍子株式会社 陶瓷基材、陶瓷支撑体以及分离膜复合体

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004105942A (ja) 2002-07-22 2004-04-08 Ngk Insulators Ltd Ｄｄｒ型ゼオライト膜、ガス分離方法及びガス分離装置
JP2016155098A (ja) 2015-02-25 2016-09-01 三菱化学株式会社 分離膜モジュール
JP2019181456A (ja) 2018-03-30 2019-10-24 日本碍子株式会社 ゼオライト膜複合体、ゼオライト膜複合体の製造方法、および、分離方法
JP2020157275A (ja) 2019-03-28 2020-10-01 学校法人早稲田大学 エチレンの分離方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003024577A1 (en) * 2001-09-17 2003-03-27 Ngk Insulators, Ltd. Method for preparing ddr type zeolite film, ddr type zeolite film, and composite ddr type zeolite film, and method for preparation thereof
US8540800B2 (en) * 2011-03-21 2013-09-24 Uop Llc Microporous UZM-5 inorganic zeolite membranes for gas, vapor, and liquid separations
JP2012236123A (ja) 2011-05-10 2012-12-06 Hitachi Zosen Corp ゼオライト膜による排ガス中の二酸化炭素分離回収システム
JP2012236134A (ja) 2011-05-11 2012-12-06 Hitachi Zosen Corp 二酸化炭素分離システム
CN108031300B (zh) 2012-02-24 2022-02-08 三菱化学株式会社 沸石膜复合体
WO2013125661A1 (ja) * 2012-02-24 2013-08-29 三菱化学株式会社 多孔質支持体―ゼオライト膜複合体
JP2014000535A (ja) * 2012-06-19 2014-01-09 Jx Nippon Oil & Energy Corp 二酸化炭素の分離方法及び二酸化炭素の分離膜
MY183277A (en) 2014-07-10 2021-02-18 Hitachi Zosen Corp Zeolite membrane, production method therefor, and separation method using same
WO2016052058A1 (ja) 2014-09-29 2016-04-07 日本碍子株式会社 分離方法及び分離装置
WO2017142056A1 (ja) * 2016-02-19 2017-08-24 日立造船株式会社 ゼオライト分離膜およびその製造方法
CN106745026B (zh) * 2016-12-16 2019-01-11 南京工业大学 一种无缺陷ddr分子筛膜的制备方法
DE112019001707T5 (de) * 2018-03-30 2020-12-24 Ngk Insulators, Ltd. Keramischer Träger, Zeolith-Membrankomplex, Verfahren zur Herstellung eines Zeolith-Membrankomplexes und Trennverfahren
DE112021003114T5 (de) * 2020-07-21 2023-03-23 Ngk Insulators, Ltd. Trennmembrankomplex und Trennverfahren

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004105942A (ja) 2002-07-22 2004-04-08 Ngk Insulators Ltd Ｄｄｒ型ゼオライト膜、ガス分離方法及びガス分離装置
JP2016155098A (ja) 2015-02-25 2016-09-01 三菱化学株式会社 分離膜モジュール
JP2019181456A (ja) 2018-03-30 2019-10-24 日本碍子株式会社 ゼオライト膜複合体、ゼオライト膜複合体の製造方法、および、分離方法
JP2020157275A (ja) 2019-03-28 2020-10-01 学校法人早稲田大学 エチレンの分離方法

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US12458949B2 (en) 2025-11-04
WO2021186959A1 (ja) 2021-09-23
JPWO2021186959A1 (enExample) 2021-09-23
US20230018523A1 (en) 2023-01-19
BR112022018502A2 (pt) 2022-10-25

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