JP7277146B2 - カドミウムフリー系量子ドット、その製造方法、これを含む組成物と複合体、及び表示素子 - Google Patents
カドミウムフリー系量子ドット、その製造方法、これを含む組成物と複合体、及び表示素子 Download PDFInfo
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- JP7277146B2 JP7277146B2 JP2019003319A JP2019003319A JP7277146B2 JP 7277146 B2 JP7277146 B2 JP 7277146B2 JP 2019003319 A JP2019003319 A JP 2019003319A JP 2019003319 A JP2019003319 A JP 2019003319A JP 7277146 B2 JP7277146 B2 JP 7277146B2
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
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- C—CHEMISTRY; METALLURGY
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- H01L33/50—Wavelength conversion elements
- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
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Description
前記半導体ナノ結晶コアは、亜鉛(Zn)を更に含み得る。
前記第1半導体ナノ結晶シェルは、硫黄(S)を含まなくてもよい
前記第1半導体ナノ結晶シェルは、前記半導体ナノ結晶コアの直上に配置され得る。
前記第1半導体ナノ結晶シェルは、厚さが3モノレイヤー以上10モノレイヤー以下であり得る。
前記第2半導体ナノ結晶シェルは、前記カドミウムフリー系量子ドットの最外郭層であり得る。
前記第2半導体ナノ結晶シェルは、前記第1半導体ナノ結晶シェルの直上に配置され得る。
前記カドミウムフリー系量子ドットのUV-Vis吸収スペクトルにおける第1吸収ピーク波長の強度(1st OD)に対する450nmの強度(450nm OD)の比は、1.5以上であり得る。
前記カドミウムフリー系量子ドット1グラム当たりの青色吸収率は、1以上であり得る。
前記カドミウムフリー系量子ドットは、量子効率が85%以上、88%以上、又は90%以上であり得る。
前記カドミウムフリー系量子ドットは、半値幅が45nm以下又は40nm以下であり得る
前記カドミウムフリー系量子ドットの前記第1吸収ピーク波長は、450nm超及び前記カドミウムフリー系量子ドットの光発光ピーク波長未満の範囲内に存在し得る。
前記第2混合物は、前記第1反応温度で50分以上維持して前記第1半導体ナノ結晶シェルの厚さを3モノレイヤー以上に形成し得る。
前記カルボン酸基含有バインダー高分子は、酸価が50mgKOH/g以上240mgKOH/g以下であり得る。
前記組成物は、末端に少なくとも2個のチオール基を有する多重チオール化合物、金属酸化物微粒子、又はこれらの組み合わせを更に含み得る。
前記金属酸化物微粒子は、TiO2、SiO2、BaTiO3、Ba2TiO4、ZnO、又はこれらの組み合わせを含み得る。
前記金属酸化物の含有量は、組成物の固形分を基準に15重量%以下であり得る。
前記量子ドットポリマー複合体は、(例えば、前記カドミウムフリー系量子ドットの含有量が複合体の総重量を基準に45%である場合)波長450nmの青色光吸収率が82%以上であり得る。
前記量子ドットポリマー複合体は、窒素雰囲気中で180℃30分間熱処理された場合、光転換効率(PCE)が20%以上であり得る。
前記発光要素は、前記量子ドットポリマー複合体のシート(sheet)を含み得る。
前記表示素子は、液晶パネルを更に含み、前記光源と前記液晶パネルとの間に前記量子ドットポリマー複合体のシートが介在し得る。
前記表示素子は、基板及び前記基板上に配置された光発光層を含む積層構造物を前記発光要素として含み、前記光発光層は、前記量子ドットポリマー複合体のパターンを含み、前記パターンは、予め定められた波長の光を放出する一つ以上の反復区画(section)を含み得る。
前記パターンは、第1光を放出する第1区画及び前記第1光と異なる中心波長を有する第2光を放出する第2区画を含み得る。
前記光源は、前記第1区画及び前記第2区画にそれぞれ対応する複数の発光単位を含み、前記発光単位は、互いに向き合う第1電極及び第2電極、並びに前記第1電極と前記第2電極との間に配置された電界発光層を含み得る。
前記表示装置は、下部基板、前記下部基板の下に配置された偏光板、及び前記積層構造物と前記下部基板との間に介在する液晶層を更に含み、前記積層構造物は、前記光発光層が前記液晶層に対面するように配置され得る。
前記表示装置は、前記液晶層と前記発光層との間に偏光板を更に含み得る。
前記光源は、LED及び選択により導光板を更に含み得る。
Lは、直接結合、C1乃至C10のアルキレン、炭素-炭素二重結合を含む置換基を有するC1乃至C10のアルキレン、C1乃至C10のオキシアルキレン、又は炭素-炭素二重結合を含む置換基を有するC1乃至C10のオキシアルキレンであり、
Aは、-NH-、-O-、又はC1乃至C10のアルキレンであり、
Z2は、C6乃至C40の芳香族有機基であり、
R1及びR2は、それぞれ独立に、水素原子、ハロゲン原子、又は置換若しくは非置換のC1乃至C20アルキル基であり、
m1及びm2は、それぞれ独立に、0~4の整数であり、*は、隣接原子に連結される部分である。
R3及びR4は、それぞれ独立に、水素原子、ハロゲン原子又は置換又は非置換のC1乃至C20アルキル基であり、
Z1は、上記化学式A-1~A-6で表される連結残基から選択される一つの残基であり、
Z2は、C6乃至C40芳香族有機基であって、例えば上記で記載した通りであり、
m1及びm2は、それぞれ独立に、0~4の整数であり、
*は、隣接する原子に連結される部分である。
R1は、水素;置換又は非置換のC1乃至C30の直鎖又は分枝鎖アルキル基;置換又は非置換のC6乃至C30のアリール基;置換又は非置換のC7乃至C30のアリールアルキル基;置換又は非置換のC3乃至C30のヘテロアリール基;置換又は非置換のC4乃至C30のヘテロアリールアルキル基;置換又は非置換のC3乃至C30のシクロアルキル基;置換又は非置換のC3乃至C30のヘテロシクロアルキル基;C1乃至C10のアルコキシ基;ヒドロキシ基;-NH2;置換又は非置換のC1乃至C30のアミン基(-NRR’、ここで、R及びR’は、互いに独立に、水素又はC1乃至C30の直鎖又は分枝鎖アルキル基であるが、但し、同時に水素ではない);イソシアネート基;ハロゲン;-ROR’(ここで、Rは、置換又は非置換のC1乃至C20のアルキレン基であり、R’は、水素又はC1乃至20の直鎖又は分枝鎖アルキル基である);アシルハライド(-RC(=O)X、ここで、Rは、置換又は非置換のアルキレン基であり、Xは、ハロゲンである);-C(=O)OR’(ここで、R’は、水素又はC1乃至C20の直鎖又は分枝鎖アルキル基である);-CN;-C(=O)NRR’、又は-C(=O)ONRR’(ここで、R及びR’は、互いに独立に、水素又はC1乃至C20の直鎖又は分枝鎖アルキル基である)より選択され、
L1は、炭素原子、置換又は非置換のC1乃至C30のアルキレン基、置換又は非置換のC3乃至C30のシクロアルキレン基、置換又は非置換のC6乃至C30のアリーレン基、又は置換又は非置換のC3乃至C30のヘテロアリーレン基であるが、置換されたC1乃至C30のアルキレン基に含まれるメチレン(-CH2-)は、スルホニル(-SO2-)、カルボニル(CO)、エーテル(-O-)、スルフィド(-S-)、スルホキシド(-SO-)、エステル(-C(=O)O-)、アミド(-C(=O)NR-)(ここで、Rは、水素又はC1乃至C10のアルキル基である)、又はこれらの組み合わせで置換され、
Y1は、単一結合;置換又は非置換のC1乃至C30のアルキレン基;置換又は非置換のC2乃至C30のアルケニレン基;少なくとも一つのメチレン(-CH2-)がスルホニル(-S(=O)2-)、カルボニル(-C(=O)-)、エーテル(-O-)、スルフィド(-S-)、スルホキシド(-S(=O)-)、エステル(-C(=O)O-)、アミド(-C(=O)NR-)(ここで、Rは、水素又はC1乃至C10の直鎖又は分枝鎖アルキル基である)、イミン(-NR-)(ここで、Rは、水素又はC1乃至C10の直鎖又は分枝鎖アルキル基である)、又はこれらの組み合わせで置換されたC1乃至C30のアルキレン基又はC2乃至C30のアルケニレン基であり、
mは、1以上の整数であり、
k1は、0又は1以上の整数であり、k2は、1以上の整数であり、
mとk2との合計は、3以上の整数であって、
Y1が単一結合でない場合、mは、Y1の原子価を越えず、k1とk2との合計は、L1の原子価を超えない。
多重チオール化合物は、下記化学式6-1で表される化合物を含む。
Ya乃至Ydは、それぞれ独立に、直接結合;置換又は非置換のC1乃至C30のアルキレン基;置換又は非置換のC2乃至C30のアルケニレン基;又は少なくとも一つのメチレン(-CH2-)がスルホニル(-S(=O)2-)、カルボニル(-C(=O)-)、エーテル(-O-)、スルフィド(-S-)、スルホキシド(-S(=O)-)、エステル(-C(=O)O-)、アミド(-C(=O)NR-)(ここで、Rは、水素又はC1乃至C10の直鎖又は分枝鎖アルキル基である)、イミン(-NR-)(ここで、Rは、水素又はC1乃至C10の直鎖又は分枝鎖アルキル基である)、又はこれらの組み合わせで置換されたC1乃至C30のアルキレン基又はC2乃至C30のアルケニレン基であり、
Ra乃至Rdは、それぞれ独立に、化学式6のR1又はSHであるが、但し、Ra乃至Rdのうちの少なくとも2つはSHである。
光転換率=A/(B-B’)
<比較例1>
120 導光板
200 液晶パネル
210 下部基板
211 配線板
220 液晶層
221 配向膜
230 カラーフィルター層
231 共通電極
240 上部基板
241 ブラックマトリックス
300 光学素子
Claims (32)
- インジウム(In)及びリン(P)を含む半導体ナノ結晶コア(core)、前記半導体ナノ結晶コア上に配置されて亜鉛及びセレニウムを含む第1半導体ナノ結晶シェル(first semiconductor nanocrystal shell)、並びに前記第1半導体ナノ結晶シェル上に配置されて亜鉛及び硫黄を含む第2半導体ナノ結晶シェル(second semiconductor nanocrystal shell)を有し、カドミウムを含まないカドミウムフリー系量子ドット(cadmium free quantum dot)であって、
前記カドミウムフリー系量子ドットが600nm~650nmの範囲で光発光ピーク波長を有する場合、前記カドミウムフリー系量子ドットの硫黄及びセレニウムの総モル含有量に対するインジウムのモル含有量の比[In/(Se+S)]は、0.06以上0.3以下であり、
前記カドミウムフリー系量子ドットが500nm~550nmの範囲で光発光ピーク波長を有する場合、前記カドミウムフリー系量子ドットの硫黄及びセレニウムの総モル含有量に対するインジウムのモル含有量の比は、0.027以上0.1以下であり、
UV-Vis吸収スペクトルで、第1吸収ピーク波長(first absorption peak wavelength)の強度(1st OD)に対する450nmの強度(450nm OD)の比が、1.5以上であり、
前記カドミウムフリー系量子ドットは、80%超の量子効率(Quantum Yield)を有することを特徴とするカドミウムフリー系量子ドット。 - インジウム(In)及びリン(P)を含む半導体ナノ結晶コア(core)、前記半導体ナノ結晶コア上に配置されて亜鉛及びセレニウムを含む第1半導体ナノ結晶シェル(first semiconductor nanocrystal shell)、並びに前記第1半導体ナノ結晶シェル上に配置されて亜鉛及び硫黄を含む第2半導体ナノ結晶シェル(second semiconductor nanocrystal shell)を有し、カドミウムを含まないカドミウムフリー系量子ドット(cadmium free quantum dot)であって、
前記カドミウムフリー系量子ドットが600nm~650nmの範囲で光発光ピーク波長を有する場合、前記カドミウムフリー系量子ドットの硫黄及びセレニウムの総モル含有量に対するインジウムのモル含有量の比[In/(Se+S)]は、0.06以上0.3以下であり、
前記カドミウムフリー系量子ドットが500nm~550nmの範囲で光発光ピーク波長を有する場合、前記カドミウムフリー系量子ドットの硫黄及びセレニウムの総モル含有量に対するインジウムのモル含有量の比は、0.027以上0.1以下であり、インジウムに対する硫黄のモル含有量比は7~12.1であり、
前記カドミウムフリー系量子ドットは、UV-Vis吸収スペクトルで、第1吸収ピーク波長(first absorption peak wavelength)の強度(1st OD)に対する450nmの強度(450nm OD)の比が1.2以上であり、
前記カドミウムフリー系量子ドットは、80%超の量子効率(Quantum Yield)を有することを特徴とするカドミウムフリー系量子ドット。 - 前記半導体ナノ結晶コアは、亜鉛を更に含むことを特徴とする請求項1または請求項2に記載のカドミウムフリー系量子ドット。
- 前記第1半導体ナノ結晶シェルは、硫黄(S)を含まないことを特徴とする請求項1に記載のカドミウムフリー系量子ドット。
- 前記第1半導体ナノ結晶シェルは、前記半導体ナノ結晶コアの直上に配置されることを特徴とする請求項1に記載のカドミウムフリー系量子ドット。
- 前記第1半導体ナノ結晶シェルは、厚さが3モノレイヤー以上10モノレイヤー以下であることを特徴とする請求項1に記載のカドミウムフリー系量子ドット。
- 前記第2半導体ナノ結晶シェルは、前記カドミウムフリー系量子ドットの最外郭層であることを特徴とする請求項1に記載のカドミウムフリー系量子ドット。
- 前記第2半導体ナノ結晶シェルは、前記第1半導体ナノ結晶シェルの直上に配置されることを特徴とする請求項1に記載のカドミウムフリー系量子ドット。
- 前記カドミウムフリー系量子ドットは、600nm~650nmの範囲で光発光ピーク波長を有し、
硫黄及びセレニウムの総モル含有量に対するインジウムのモル含有量の比[In/(Se+S)]は、0.064以上0.25以下であることを特徴とする請求項1または請求項2に記載のカドミウムフリー系量子ドット。 - インジウム(In)及びリン(P)を含む半導体ナノ結晶コア(core)、前記半導体ナノ結晶コア上に配置されて亜鉛及びセレニウムを含む第1半導体ナノ結晶シェル(first semiconductor nanocrystal shell)、並びに前記第1半導体ナノ結晶シェル上に配置されて亜鉛及び硫黄を含む第2半導体ナノ結晶シェル(second semiconductor nanocrystal shell)を有し、カドミウムを含まないカドミウムフリー系量子ドット(cadmium free quantum dot)であって、
前記カドミウムフリー系量子ドットが600nm~650nmの範囲で光発光ピーク波長を有する場合、前記カドミウムフリー系量子ドットの硫黄及びセレニウムの総モル含有量に対するインジウムのモル含有量の比[In/(Se+S)]は、0.06以上0.3以下であり、
前記カドミウムフリー系量子ドットが500nm~550nmの範囲で光発光ピーク波長を有する場合、前記カドミウムフリー系量子ドットの硫黄及びセレニウムの総モル含有量に対するインジウムのモル含有量の比[In/(Se+S)]は、0.027以上0.046以下であり、
前記カドミウムフリー系量子ドットは、80%超の量子効率(Quantum Yield)を有することを特徴とするカドミウムフリー系量子ドット。 - 前記カドミウムフリー系量子ドット1グラム当たりの青色吸収率は、1以上であることを特徴とする請求項1、請求項2、または請求項10に記載のカドミウムフリー系量子ドット。
- 前記カドミウムフリー系量子ドットは、量子効率が85%以上であることを特徴とする請求項1、請求項2、または請求項10に記載の量子ドット。
- 前記カドミウムフリー系量子ドットは、450nm超及び光発光ピーク波長未満の範囲内に第1吸収ピーク波長を有することを特徴とする請求項1、請求項2、請求項10、または請求項1、請求項2、または請求項10に記載のカドミウムフリー系量子ドット。
- 前記カドミウムフリー系量子ドットは、半値幅が44nm以下であることを特徴とする請求項1、請求項2、または請求項10に記載の量子ドット。
- 請求項1、請求項2、または請求項10に記載のカドミウムフリー系量子ドットの製造方法であって、
亜鉛を含む第1シェル前駆体、有機リガンド、及び有機溶媒を含む第1混合物を得る段階と、
前記第1混合物を選択により加熱する段階と、
選択により加熱された前記第1混合物に、インジウム及びリンを含む半導体ナノ結晶コア、並びにセレニウム含有前駆体を注入して第2混合物を得る段階と、
前記第2混合物を第1反応温度で加熱し、前記第1反応温度で40分以上維持して前記半導体ナノ結晶コア上に亜鉛及びセレニウムを含む第1半導体ナノ結晶シェルが形成された粒子を含む第3混合物を得る段階と、
前記第1反応温度で、前記第3混合物に硫黄含有前駆体を付加して亜鉛及び硫黄を含む第2半導体ナノ結晶シェルを前記第1半導体ナノ結晶シェル上に形成してカドミウムフリー系量子ドットを得る段階と、を有し、
前記第2混合物及び前記第3混合物の前記インジウムに対する前記セレニウム含有前駆体の総含有量及び前記硫黄含有前駆体の総含有量を調節し、
前記カドミウムフリー系量子ドットが600nm~650nmの範囲で光発光ピーク波長を有する場合、前記カドミウムフリー系量子ドットの硫黄及びセレニウムの総モル含有量に対する前記インジウムのモル含有量の比が0.06以上0.3以下になるようにし、
前記カドミウムフリー系量子ドットが500nm~550nmの範囲で光発光ピーク波長を有する場合、前記カドミウムフリー系量子ドットの硫黄及びセレニウムの総モル含有量に対するインジウムのモル含有量の比が0.027以上0.1以下になるようにすることを特徴とする製造方法。 - 前記製造方法は、前記第3混合物の温度を100℃以下に下げる段階を含まないことを特徴とする請求項15に記載の製造方法。
- 請求項1、請求項2、または請求項10に記載のカドミウムフリー系量子ドットと
カルボン酸基含有バインダー高分子と、
炭素-炭素二重結合を含む光重合性単量体と、
光開始剤と、を有することを特徴とする組成物。 - 前記カルボン酸基含有バインダー高分子は、
カルボン酸基及び炭素-炭素二重結合を含む第1モノマー、炭素-炭素二重結合及び疎水性残基を有してカルボン酸基を含まない第2モノマー、並びに選択により炭素-炭素二重結合を含み親水性残基を有してカルボン酸基を含まない第3モノマーを含むモノマー組み合わせの共重合体、
主鎖内に2個の芳香族環が他の環状残基の構成原子である第4級炭素原子と結合した骨格構造を有してカルボン酸基(-COOH)を含む多重芳香族環含有ポリマー、
又はこれらの組み合わせを含むことを特徴とする請求項17に記載の組成物。 - 前記カルボン酸基含有バインダー高分子は、酸価が50mgKOH/g以上240mgKOH/g以下であることを特徴とする請求項17に記載の組成物。
- 前記組成物は、末端に少なくとも1個のチオール基を有するチオール化合物、金属酸化物微粒子、又はこれらの組み合わせを更に含むことを特徴とする請求項17に記載の組成物。
- 前記金属酸化物微粒子は、TiO2、SiO2、BaTiO3、Ba2TiO4、ZnO、又はこれらの組み合わせを含み、
前記チオール化合物は、下記化学式6で表される化合物を含むことを特徴とする請求項20に記載の組成物。
R1は、水素;置換又は非置換のC1乃至C30の直鎖又は分枝鎖アルキル基;置換又は非置換のC6乃至C30のアリール基;置換又は非置換のC3乃至C30のヘテロアリール基;置換又は非置換のC3乃至C30のシクロアルキル基;置換又は非置換のC3乃至C30のヘテロシクロアルキル基;C1乃至C10のアルコキシ基;ヒドロキシ基;-NH2;置換又は非置換のC1乃至C30のアミン基(-NRR’、ここで、R及びR’は、互いに独立に、水素又はC1乃至C30の直鎖又は分枝鎖アルキル基であり、但し、同時に水素ではない);イソシアネート基;ハロゲン;-ROR’(ここで、Rは、置換又は非置換のC1乃至C20のアルキレン基であり、R’は、水素又はC1乃至C20の直鎖又は分枝鎖アルキル基である);アシルハライド(-RC(=O)X、ここで、Rは、置換又は非置換のアルキレン基であり、Xは、ハロゲンである);-C(=O)OR’(ここで、R’は、水素又はC1乃至C20の直鎖又は分枝鎖アルキル基である);-CN;-C(=O)ORR’又は-C(=O)ONRR’(ここで、R及びR’は、互いに独立に、水素又はC1乃至C20の直鎖又は分枝鎖アルキル基である)より選択され、
L1は、炭素原子、置換又は非置換のC1乃至C30のアルキレン基、一つ以上のメチレン(-CH2-)がスルホニル(-SO2-)、カルボニル(CO)、エーテル(-O-)、スルフィド(-S-)、スルホキシド(-SO-)、エステル(-C(=O)O-)、アミド(-C(=O)NR-)(ここで、Rは、水素又はC1乃至C10のアルキル基である)、又はこれらの組み合わせで代替された置換又は非置換のC1乃至C30のアルキレン基、置換又は非置換のC3乃至C30のシクロアルキレン基、置換又は非置換のC6乃至C30のアリーレン基、置換又は非置換のC3乃至C30のヘテロアリーレン基、又は置換又は非置換のC3乃至C30のヘテロシクロアルキレン残基であり、
Y1は、単一結合;置換又は非置換のC1乃至C30のアルキレン基;置換又は非置換のC2乃至C30のアルケニレン基;少なくとも一つのメチレン(-CH2-)がスルホニル(-S(=O)2-)、カルボニル(-C(=O)-)、エーテル(-O-)、スルフィド(-S-)、スルホキシド(-S(=O)-)、エステル(-C(=O)O-)、アミド(-C(=O)NR-)(ここで、Rは、水素又はC1乃至C10の直鎖又は分枝鎖アルキル基である)、イミン(-NR-)(ここで、Rは、水素又はC1乃至C10の直鎖又は分枝鎖アルキル基である)、又はこれらの組み合わせで置換されたC1乃至C30のアルキレン基又はC2乃至C30のアルケニレン基であり、
mは、1以上の整数であり、
k1は、0又は1以上の整数であり、k2は、1以上の整数であり、
mとk2との合計は、3以上の整数であって、
mは、Y1の原子価を越えず、k1とk2との合計は、L1の原子価を超えない。 - 前記組成物内の前記金属酸化物微粒子の含有量は、組成物の固形分を基準に15重量%以下であることを特徴とする請求項20に記載の組成物。
- ポリマーマトリックスと、
前記ポリマーマトリックス内に分散された請求項1、請求項2、または請求項10に記載のカドミウムフリー系量子ドットと、を有し、
前記ポリマーマトリックスは、バインダー高分子、少なくとも一つの炭素-炭素二重結合を含む光重合性単量体の重合生成物、及び選択により前記光重合性単量体と末端に少なくとも2個のチオール基を有する多重チオール化合物との間の重合生成物を含むことを特徴とする量子ドット-ポリマー複合体。 - 前記量子ドット-ポリマー複合体は、前記カドミウムフリー系量子ドットの含有量が前記量子ドット-ポリマー複合体の総重量を基準に45%である場合、波長450nmの青色光吸収率が82%以上であることを特徴とする請求項23に記載の量子ドット-ポリマー複合体。
- 前記量子ドット-ポリマー複合体は、窒素雰囲気中で180℃30分間熱処理された場合、光転換効率(CE)が20%以上であることを特徴とする請求項23に記載の量子ドット-ポリマー複合体。
- 光源と、
発光要素と、を備え、
前記発光要素は、請求項23に記載の量子ドット-ポリマー複合体を含み、
前記光源は、前記発光要素に入射光を提供することを特徴とする表示素子。 - 前記入射光は、440nm~460nmの範囲にある光発光ピーク波長を有することを特徴とする請求項26に記載の表示素子。
- 前記発光要素は、前記量子ドット-ポリマー複合体のシート(sheet)を含むことを特徴とする請求項26に記載の表示素子。
- 前記発光要素は、基板及び前記基板上に配置された発光層を含む積層構造物であり、
前記発光層は、前記量子ドット-ポリマー複合体のパターンを含み、
前記パターンは、予め定められた波長の光を放出する一つ以上の反復区画(section)を含むことを特徴とする請求項26に記載の表示素子。 - 前記パターンは、第1光を放出する第1区画及び前記第1光と異なる中心波長を有する第2光を放出する第2区画を含むことを特徴とする請求項29に記載の表示素子。
- 前記半導体ナノ結晶コアは、亜鉛を更に含むことを特徴とする請求項10に記載のカドミウムフリー系量子ドット。
- 前記カドミウムフリー系量子ドットは、600nm~650nmの範囲で光発光ピーク波長を有し、
硫黄及びセレニウムの総モル含有量に対するインジウムのモル含有量の比[In/(Se+S)]は、0.064以上0.25以下であることを特徴とする請求項10に記載のカドミウムフリー系量子ドット。
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US20220017818A1 (en) | 2022-01-20 |
US11505740B2 (en) | 2022-11-22 |
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US20230106180A1 (en) | 2023-04-06 |
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