JP7249420B2 - モノマー組成物の製造方法、原料組成物、モノマー組成物、硬化性組成物、及び成形体 - Google Patents

モノマー組成物の製造方法、原料組成物、モノマー組成物、硬化性組成物、及び成形体 Download PDF

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JP7249420B2
JP7249420B2 JP2021540732A JP2021540732A JP7249420B2 JP 7249420 B2 JP7249420 B2 JP 7249420B2 JP 2021540732 A JP2021540732 A JP 2021540732A JP 2021540732 A JP2021540732 A JP 2021540732A JP 7249420 B2 JP7249420 B2 JP 7249420B2
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meth
acrylate
compound
diisocyanate
iso
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JPWO2021033585A5 (https=
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直志 柿沼
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Mitsui Chemicals Inc
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Mitsui Chemicals Inc
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/60—Preparations for dentistry comprising organic or organo-metallic additives
    • A61K6/62—Photochemical radical initiators
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/15—Compositions characterised by their physical properties
    • A61K6/16—Refractive index
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • A61K6/889—Polycarboxylate cements; Glass ionomer cements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/106—Esters of polycondensation macromers
    • C08F222/1065—Esters of polycondensation macromers of alcohol terminated (poly)urethanes, e.g. urethane(meth)acrylates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
    • C08G18/8116—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group esters of acrylic or alkylacrylic acid having only one isocyanate or isothiocyanate group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Biophysics (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Dental Preparations (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2021540732A 2019-08-20 2020-08-07 モノマー組成物の製造方法、原料組成物、モノマー組成物、硬化性組成物、及び成形体 Active JP7249420B2 (ja)

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JP2019150510 2019-08-20
JP2019150510 2019-08-20
PCT/JP2020/030437 WO2021033585A1 (ja) 2019-08-20 2020-08-07 モノマー組成物の製造方法、原料組成物、モノマー組成物、硬化性組成物、及び成形体

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JPWO2021033585A1 JPWO2021033585A1 (https=) 2021-02-25
JPWO2021033585A5 JPWO2021033585A5 (https=) 2022-04-15
JP7249420B2 true JP7249420B2 (ja) 2023-03-30

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US (1) US12605306B2 (https=)
EP (1) EP3988592A4 (https=)
JP (1) JP7249420B2 (https=)
CN (1) CN114302900B (https=)
WO (1) WO2021033585A1 (https=)

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EP4286427A4 (en) * 2021-01-26 2025-04-09 Mitsui Chemicals, Inc. MONOMER COMPOSITION, CURABLE COMPOSITION, MOULDED BODIES AND METHOD FOR PRODUCING THE MONOMER COMPOSITION
JPWO2023182241A1 (https=) * 2022-03-24 2023-09-28
WO2025192235A1 (ja) * 2024-03-14 2025-09-18 三井化学株式会社 （メタ）アクリレート化合物、モノマー組成物、硬化性組成物、歯科材料、及び（メタ）アクリレート化合物の製造方法

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WO2007097116A1 (ja) 2006-02-21 2007-08-30 Mitsui Chemicals, Inc. ポリチオウレタン系光学材料用重合性組成物
JP2007326971A (ja) 2006-06-08 2007-12-20 Inoac Corp フレームラミネート用ポリウレタン発泡体
WO2010001550A1 (ja) 2008-06-30 2010-01-07 三井化学株式会社 ポリチオウレタン系光学材料用重合性組成物、該重合性組成物より得られるポリチオウレタン系光学材料及びポリチオウレタン系光学材料用重合触媒
JP2010185074A (ja) 2009-02-12 2010-08-26 Bayer Materialscience Ag 化学線硬化性基を有する特に反応性で低粘性のアロファネートの製造方法および特に耐引掻性の被覆物の製造のためのその使用
US20120082954A1 (en) 2010-09-30 2012-04-05 Voco Gmbh Composition Comprising a Monomer with a Polyalicyclic Structure Element for Filling and/or Sealing a Root Canal
JP2012102086A (ja) 2010-10-13 2012-05-31 Nippon Synthetic Chem Ind Co Ltd:The ウレタン化合物の製造方法およびそれにより得られるウレタン化合物
JP2013087287A (ja) 2011-10-14 2013-05-13 Bayer Intellectual Property Gmbh 放射線硬化性基を有する低粘性水乳化性アロファネートの製造方法
WO2013099766A1 (ja) 2011-12-26 2013-07-04 旭硝子株式会社 ウレタン（メタ）アクリレート組成物
JP2018203946A (ja) 2017-06-08 2018-12-27 Dic株式会社 ウレタン（メタ）アクリレート樹脂
JP2018203947A (ja) 2017-06-08 2018-12-27 Dic株式会社 ウレタン（メタ）アクリレート樹脂

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Patent Citations (10)

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Publication number Priority date Publication date Assignee Title
WO2007097116A1 (ja) 2006-02-21 2007-08-30 Mitsui Chemicals, Inc. ポリチオウレタン系光学材料用重合性組成物
JP2007326971A (ja) 2006-06-08 2007-12-20 Inoac Corp フレームラミネート用ポリウレタン発泡体
WO2010001550A1 (ja) 2008-06-30 2010-01-07 三井化学株式会社 ポリチオウレタン系光学材料用重合性組成物、該重合性組成物より得られるポリチオウレタン系光学材料及びポリチオウレタン系光学材料用重合触媒
JP2010185074A (ja) 2009-02-12 2010-08-26 Bayer Materialscience Ag 化学線硬化性基を有する特に反応性で低粘性のアロファネートの製造方法および特に耐引掻性の被覆物の製造のためのその使用
US20120082954A1 (en) 2010-09-30 2012-04-05 Voco Gmbh Composition Comprising a Monomer with a Polyalicyclic Structure Element for Filling and/or Sealing a Root Canal
JP2012102086A (ja) 2010-10-13 2012-05-31 Nippon Synthetic Chem Ind Co Ltd:The ウレタン化合物の製造方法およびそれにより得られるウレタン化合物
JP2013087287A (ja) 2011-10-14 2013-05-13 Bayer Intellectual Property Gmbh 放射線硬化性基を有する低粘性水乳化性アロファネートの製造方法
WO2013099766A1 (ja) 2011-12-26 2013-07-04 旭硝子株式会社 ウレタン（メタ）アクリレート組成物
JP2018203946A (ja) 2017-06-08 2018-12-27 Dic株式会社 ウレタン（メタ）アクリレート樹脂
JP2018203947A (ja) 2017-06-08 2018-12-27 Dic株式会社 ウレタン（メタ）アクリレート樹脂

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WO2021033585A1 (ja) 2021-02-25
EP3988592A4 (en) 2023-07-26
US20220249331A1 (en) 2022-08-11
US12605306B2 (en) 2026-04-21
JPWO2021033585A1 (https=) 2021-02-25
EP3988592A1 (en) 2022-04-27
CN114302900A (zh) 2022-04-08
CN114302900B (zh) 2024-07-30

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