JP7150754B2 - ヒドロホルミル化反応方法 - Google Patents
ヒドロホルミル化反応方法 Download PDFInfo
- Publication number
- JP7150754B2 JP7150754B2 JP2019568094A JP2019568094A JP7150754B2 JP 7150754 B2 JP7150754 B2 JP 7150754B2 JP 2019568094 A JP2019568094 A JP 2019568094A JP 2019568094 A JP2019568094 A JP 2019568094A JP 7150754 B2 JP7150754 B2 JP 7150754B2
- Authority
- JP
- Japan
- Prior art keywords
- reactor
- flow
- fluid
- reaction
- cylindrical reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2336—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer
- B01F23/23362—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer the gas being introduced under the stirrer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/20—Jet mixers, i.e. mixers using high-speed fluid streams
- B01F25/21—Jet mixers, i.e. mixers using high-speed fluid streams with submerged injectors, e.g. nozzles, for injecting high-pressure jets into a large volume or into mixing chambers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/50—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
- B01F25/53—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle in which the mixture is discharged from and reintroduced into a receptacle through a recirculation tube, into which an additional component is introduced
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/19—Stirrers with two or more mixing elements mounted in sequence on the same axis
- B01F27/191—Stirrers with two or more mixing elements mounted in sequence on the same axis with similar elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/90—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1806—Stationary reactors having moving elements inside resulting in a turbulent flow of the reactants, such as in centrifugal-type reactors, or having a high Reynolds-number
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
- B01J4/002—Nozzle-type elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
- B01J4/004—Sparger-type elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00893—Feeding means for the reactants
- B01J2208/00902—Nozzle-type feeding elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00893—Feeding means for the reactants
- B01J2208/00911—Sparger-type feeding elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00779—Baffles attached to the stirring means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/19—Details relating to the geometry of the reactor
- B01J2219/194—Details relating to the geometry of the reactor round
- B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
- B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
- B01J2219/332—Details relating to the flow of the phases
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
Description
角度β1は、図4に示すように、分流器が挿入されて取り付けられた反応器ノズルの中心線に位置する基準水平面(H)上の分流器から出る液体ジェットの角度として定義され、
角度β2は、図4に示すように、分流器が挿入されて取り付けられた反応器ノズルの中心線に位置する基準水平面(H)下の分流器から出る液体ジェットの角度として定義される。
角度α1は、図4に示すように分流器が挿入されて取り付けられた反応器ノズルの中心線に位置する基準垂直面(V)の一面上の分流器から出る液体ジェットの角度として定義され、
角度α2は、図4に示すように、分流器が挿入されて取り付けられた反応器ノズルの中心線に位置する基準垂直面(V)の対向面上の分流器から出る液体ジェットの角度として定義される。
従来のCSTRヒドロホルミル化反応器の混合効率を確立するために、算出流体力学(CFD)モデリング研究が行われた。反応システムの概略図を図5~6に示す。図5~6は、反応器の概略図と特定のデバイスの位置を示す。様々な成分の寸法と位置を表1に示す。動作圧力は約16bargである。この圧力で、液体プロピレンの密度は約737kg/m3(約46lb/ft3)であり、合成ガスの密度は約21.5kg/m3(1.35lb/ft3)である。全ての例の合成ガスと液体プロピレンの供給流量も表1に示す。液体プロピレンの粘度は0.0003Pa.s、合成ガスの粘度は1.8e-5Pa.sとする。合成ガスと液体プロピレンの間の気液表面張力は、同様の有機物の典型的な値に合わせて、18ダイン/cm(0.018N/m)とする。合成ガスは、反応器の下接線に近接して配置されたリングスパージャーで導入される。スパージャーの直径は102cmで、直径がそれぞれ7.9mmの69個の穴があり、15mmの間隔で配置される。CFD反応器モデルには、反応器の底部近くにある単一の標準52インチの直径ガス分配タービンと、85rpm以下で動作する反応器の中央と上部近くにある直径60インチの2つのピッチドブレード液体混合撹拌器とが含まれる。
実施例2及び3
実施例4
実施例5
Claims (10)
- ヒドロホルミル化反応方法であって、
垂直型の円筒型反応器内において均一系触媒の存在下でオレフィン、水素、及び一酸化炭素を接触させて反応流体を提供することと、
前記円筒型反応器から前記反応流体の一部を除去することと、
前記除去された反応流体の少なくとも一部を前記円筒型反応器に戻すことと、を含み、
前記円筒型反応器の高さは一定の高さであり、少なくとも0.5kW/m3の総混合エネルギーが前記円筒型反応器内の前記流体に伝達され、前記戻される反応流体は、前記一定の高さの80%未満の高さに配置される少なくとも2つの戻り位置に導入され、前記少なくとも2つの戻り位置は、前記反応器内の、水素と一酸化炭素が導入される位置の上方に配置され、前記混合エネルギーの少なくとも15%が前記戻される反応流体によって提供される、方法。 - 少なくとも2つの戻り位置は、前記円筒型反応器の半径の10%以上50%以下の距離だけ前記円筒型反応器内に突き出て、前記戻される反応流体の流れを方向付ける1つ以上のノズルを含む、請求項1に記載の方法。
- 前記戻される反応流体の流れは、各戻り位置に配置された分流器によって方向付けられ、各分流器は、前記戻される反応流体の流れを水平又は垂直に方向付け請求項1又は2に記載の方法。
- 前記戻される反応流体の流れは、前記分流器によって方向付けられ、前記円筒型反応器の前記中心縦軸の周りの前記流体の旋回流の誘発を防止する、請求項2又は3に記載の方法。
- 前記戻される反応流体の流れは、前記円筒型反応器の中心縦軸に向かず、前記中心縦軸に垂直でない複数の方向に分割されて方向付けられる、請求項2~4のいずれか1項に記載の方法。
- 前記分流器の流れ面積と前記戻される反応流体の流量との組み合わせは、前記円筒型反応器の内側に運動量を与えるとともに前記円筒型反応器内のバルク流体の混合を引き起こす流体ジェットを形成し、前記戻される反応流体は、複数の方向に分割されて方向付けられる、請求項1又は2に記載の方法。
- 水素と一酸化炭素は、前記円筒型反応器に前記反応器の前記一定の高さの20%未満の高さで導入され、前記戻り位置は前記一定の高さの80%未満の高さに配置される、請求項1~6のいずれか1項に記載の方法。
- 水素と一酸化炭素は、合成ガスとして提供され、前記合成ガスは、前記円筒型反応器に直径の15mm未満のサイズ範囲の離散気泡を形成するように導入される、請求項1~7のいずれか1項に記載の方法。
- 前記円筒型反応器内に配置される撹拌器をさらに備え、前記撹拌器と前記戻される反応流体が、前記円筒型反応器内に前記混合エネルギーを提供する、請求項1~8のいずれか1項に記載の方法。
- 前記円筒型反応器内に配置される撹拌器をさらに備え、前記撹拌器は動作せず、前記戻される反応流体のみが前記円筒型反応器内に前記混合エネルギーを提供する、請求項1~9のいずれか1項に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IN201741022124 | 2017-06-23 | ||
IN201741022124 | 2017-06-23 | ||
PCT/US2018/038216 WO2018236823A1 (en) | 2017-06-23 | 2018-06-19 | HYDROFORMYLATION REACTION METHOD |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2020524665A JP2020524665A (ja) | 2020-08-20 |
JP7150754B2 true JP7150754B2 (ja) | 2022-10-11 |
Family
ID=62904575
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019568094A Active JP7150754B2 (ja) | 2017-06-23 | 2018-06-19 | ヒドロホルミル化反応方法 |
Country Status (12)
Country | Link |
---|---|
US (1) | US10843992B2 (ja) |
EP (1) | EP3642178A1 (ja) |
JP (1) | JP7150754B2 (ja) |
KR (1) | KR102636278B1 (ja) |
CN (1) | CN110709374B (ja) |
BR (1) | BR112019025844B1 (ja) |
CA (1) | CA3067995A1 (ja) |
MX (1) | MX2019014635A (ja) |
RU (1) | RU2763424C2 (ja) |
TW (1) | TWI788364B (ja) |
WO (1) | WO2018236823A1 (ja) |
ZA (1) | ZA202000286B (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20210041936A (ko) * | 2019-10-08 | 2021-04-16 | 한화솔루션 주식회사 | 알돌 축합 반응용 연속교반탱크 반응기 |
US11015156B1 (en) | 2020-05-22 | 2021-05-25 | Franzenburg | Protein concentration methods |
CA3202991A1 (en) * | 2020-12-22 | 2022-06-30 | Jason F. GILES | Hydroformylation reaction processes |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2804478A (en) | 1953-12-04 | 1957-08-27 | Montedison Spa | Continuous oxo process for gaseous olefines |
JP2001316321A (ja) | 2000-05-08 | 2001-11-13 | Mitsubishi Chemicals Corp | ヒドロホルミル化方法 |
JP2002522518A (ja) | 1998-08-14 | 2002-07-23 | ビーエーエスエフ アクチェンゲゼルシャフト | アルデヒドおよび/またはアルコールまたはアミンの製造法 |
JP6164331B2 (ja) | 2011-03-11 | 2017-07-19 | 宇部興産株式会社 | ポリイミド前駆体及びポリイミド |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3527809A (en) | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
US4148830A (en) | 1975-03-07 | 1979-04-10 | Union Carbide Corporation | Hydroformylation of olefins |
US4247486A (en) | 1977-03-11 | 1981-01-27 | Union Carbide Corporation | Cyclic hydroformylation process |
JPS55501178A (ja) | 1979-02-12 | 1980-12-25 | ||
US4283562A (en) | 1979-10-26 | 1981-08-11 | Union Carbide Corporation | Hydroformylation process using stable rhodium catalyst |
US4400548A (en) | 1981-08-17 | 1983-08-23 | Union Carbide Corporation | Hydroformylation process using bisphosphine monooxide ligands |
ATE16475T1 (de) | 1982-06-11 | 1985-11-15 | Davy Mckee London | Hydroformylierungsverfahren. |
DE3372361D1 (en) | 1982-06-11 | 1987-08-13 | Davy Mckee London | Hydroformylation process |
ATE26696T1 (de) | 1982-06-11 | 1987-05-15 | Davy Mckee London | Hydroformylierungsverfahren. |
DE3234701A1 (de) | 1982-09-18 | 1984-04-05 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
US4599206A (en) | 1984-02-17 | 1986-07-08 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
JPS64995Y2 (ja) * | 1984-10-02 | 1989-01-11 | ||
US4668651A (en) | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
US4683122A (en) | 1986-04-14 | 1987-07-28 | Herzog-Hart Corporation | Gas-liquid reactor and method for gas-liquid mixing |
US5312996A (en) | 1992-06-29 | 1994-05-17 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process for producing 1,6-hexanedials |
GB9312225D0 (en) | 1993-06-14 | 1993-07-28 | Exxon Chemical Patents Inc | Process and apparatus |
US5367106A (en) | 1993-09-20 | 1994-11-22 | Hoechst Celanese Corporation | Coupled secondary oxo reaction system |
US5756855A (en) | 1994-08-19 | 1998-05-26 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilization of phosphite ligands in hydroformylation process |
US5763671A (en) * | 1995-12-06 | 1998-06-09 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation processes |
US5731472A (en) | 1995-12-06 | 1998-03-24 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
US5952530A (en) | 1998-02-02 | 1999-09-14 | Union Carbide Chemicals & Plastics Technology Corporation | Separation processes |
US5932772A (en) | 1998-02-02 | 1999-08-03 | Union Carbide Chemicals & Plastics Technology Corporation | Separation processes |
US6090987A (en) | 1998-07-06 | 2000-07-18 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
DE10201676A1 (de) * | 2002-01-17 | 2003-07-31 | Basf Ag | Verfahren zur Hydroformylierung von Olefinen mit 2 bis 6 Kohlenstoffatomen |
US7446231B2 (en) | 2004-08-02 | 2008-11-04 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilization of a hydroformylation process |
CN101679173B (zh) * | 2007-05-29 | 2013-09-18 | Lg化学株式会社 | 烯烃的醛化方法及其装置 |
WO2010003073A1 (en) | 2008-07-03 | 2010-01-07 | Dow Technology Investments Llc | Process of controlling heavies in a recycle catalyst stream |
DE102008041652A1 (de) | 2008-08-28 | 2010-03-04 | Evonik Oxeno Gmbh | Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas |
KR101206214B1 (ko) | 2009-01-16 | 2012-12-03 | 주식회사 엘지화학 | 올레핀으로부터의 알코올을 제조하는 시스템 |
KR101342741B1 (ko) | 2010-03-09 | 2013-12-19 | 주식회사 엘지화학 | 반응효율이 뛰어난 올레핀의 하이드로포밀화 방법 |
WO2012008717A2 (en) | 2010-07-14 | 2012-01-19 | Lg Chem, Ltd. | Apparatus for coproducting iso type reaction products and alcohols from olefins, and method for coproducting them using the apparatus |
CN102030622B (zh) | 2010-12-09 | 2013-01-16 | 淄博诺奥化工有限公司 | 一种乙烯氢甲酰化合成丙醛的方法 |
CN102826970B (zh) | 2011-06-17 | 2015-08-19 | 中国石油化工股份有限公司 | 一种低碳烯烃氢甲酰化二段反应方法和装置 |
KR101611113B1 (ko) | 2011-12-20 | 2016-04-08 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 하이드로포밀화 방법 |
KR101448374B1 (ko) | 2013-02-26 | 2014-10-07 | 주식회사 엘지화학 | 반응 선택성이 우수한 올레핀의 하이드로포밀화 방법 |
CN104513143A (zh) | 2013-09-26 | 2015-04-15 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
JP2016540780A (ja) * | 2013-12-19 | 2016-12-28 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセス |
-
2018
- 2018-06-07 TW TW107119687A patent/TWI788364B/zh active
- 2018-06-19 RU RU2020100593A patent/RU2763424C2/ru active
- 2018-06-19 KR KR1020207000862A patent/KR102636278B1/ko active IP Right Grant
- 2018-06-19 WO PCT/US2018/038216 patent/WO2018236823A1/en active Application Filing
- 2018-06-19 JP JP2019568094A patent/JP7150754B2/ja active Active
- 2018-06-19 EP EP18740385.2A patent/EP3642178A1/en active Pending
- 2018-06-19 US US16/611,357 patent/US10843992B2/en active Active
- 2018-06-19 BR BR112019025844-2A patent/BR112019025844B1/pt active IP Right Grant
- 2018-06-19 CA CA3067995A patent/CA3067995A1/en active Pending
- 2018-06-19 MX MX2019014635A patent/MX2019014635A/es unknown
- 2018-06-19 CN CN201880038042.0A patent/CN110709374B/zh active Active
-
2020
- 2020-01-15 ZA ZA2020/00286A patent/ZA202000286B/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2804478A (en) | 1953-12-04 | 1957-08-27 | Montedison Spa | Continuous oxo process for gaseous olefines |
JP2002522518A (ja) | 1998-08-14 | 2002-07-23 | ビーエーエスエフ アクチェンゲゼルシャフト | アルデヒドおよび/またはアルコールまたはアミンの製造法 |
JP2001316321A (ja) | 2000-05-08 | 2001-11-13 | Mitsubishi Chemicals Corp | ヒドロホルミル化方法 |
JP6164331B2 (ja) | 2011-03-11 | 2017-07-19 | 宇部興産株式会社 | ポリイミド前駆体及びポリイミド |
Also Published As
Publication number | Publication date |
---|---|
CA3067995A1 (en) | 2018-12-27 |
BR112019025844B1 (pt) | 2023-03-14 |
US20200140361A1 (en) | 2020-05-07 |
EP3642178A1 (en) | 2020-04-29 |
CN110709374B (zh) | 2023-04-04 |
JP2020524665A (ja) | 2020-08-20 |
KR20200021072A (ko) | 2020-02-27 |
WO2018236823A1 (en) | 2018-12-27 |
CN110709374A (zh) | 2020-01-17 |
MX2019014635A (es) | 2020-02-03 |
RU2020100593A3 (ja) | 2021-11-08 |
KR102636278B1 (ko) | 2024-02-16 |
BR112019025844A2 (pt) | 2020-07-14 |
TWI788364B (zh) | 2023-01-01 |
ZA202000286B (en) | 2021-08-25 |
RU2763424C2 (ru) | 2021-12-29 |
TW201904924A (zh) | 2019-02-01 |
RU2020100593A (ru) | 2021-07-13 |
US10843992B2 (en) | 2020-11-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Schrimpf et al. | Intensified reactors for gas-liquid-liquid multiphase catalysis: From chemistry to engineering | |
KR100580423B1 (ko) | 알데히드 및(또는) 알콜 또는 아민의 제조 방법 | |
US6492564B1 (en) | Process for the catalytically carrying out multiphase reactions, in particular hydroformylations | |
JP7150754B2 (ja) | ヒドロホルミル化反応方法 | |
CA2733326C (en) | Parallelized jet loop reactors | |
US10315182B2 (en) | Cylindrical reactor and use thereof for continuous hydroformylation | |
JP2017521242A (ja) | 向上した均一触媒反応器システム | |
CN104030900A (zh) | 用于低碳烯烃氢甲酰化的方法 | |
US20230406802A1 (en) | Hydroformylation reaction processes | |
US7659431B2 (en) | Method of making dialkyl ketones | |
CN114177875A (zh) | 一种喷射环流反应器及其应用 | |
CN114177876A (zh) | 一种喷射环流反应器及其应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20191224 |
|
RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20200117 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20200323 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20210604 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20211111 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20211116 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20220215 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20220830 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20220928 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 7150754 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S802 | Written request for registration of partial abandonment of right |
Free format text: JAPANESE INTERMEDIATE CODE: R311802 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |