JP7040861B2 - 音響活性物品 - Google Patents
音響活性物品 Download PDFInfo
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- JP7040861B2 JP7040861B2 JP2018534526A JP2018534526A JP7040861B2 JP 7040861 B2 JP7040861 B2 JP 7040861B2 JP 2018534526 A JP2018534526 A JP 2018534526A JP 2018534526 A JP2018534526 A JP 2018534526A JP 7040861 B2 JP7040861 B2 JP 7040861B2
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- Prior art keywords
- metal oxide
- carbon
- acoustic device
- porous inorganic
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- Prior art date
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 75
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 62
- 229910052799 carbon Inorganic materials 0.000 claims description 57
- 229910044991 metal oxide Inorganic materials 0.000 claims description 54
- 150000004706 metal oxides Chemical class 0.000 claims description 54
- 239000011324 bead Substances 0.000 claims description 45
- 239000000178 monomer Substances 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 40
- 239000000843 powder Substances 0.000 claims description 38
- 239000000377 silicon dioxide Substances 0.000 claims description 37
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- 238000000034 method Methods 0.000 claims description 25
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- 150000003254 radicals Chemical class 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
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- 239000002491 polymer binding agent Substances 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- 229910001868 water Inorganic materials 0.000 claims description 12
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 38
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- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 4
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 3
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- MTPIZGPBYCHTGQ-UHFFFAOYSA-N 2-[2,2-bis(2-prop-2-enoyloxyethoxymethyl)butoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCC(CC)(COCCOC(=O)C=C)COCCOC(=O)C=C MTPIZGPBYCHTGQ-UHFFFAOYSA-N 0.000 description 2
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- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 description 2
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- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 description 1
- GWIIOMWMVVSZJE-UHFFFAOYSA-N tert-butyl 2-bromoprop-2-enoate Chemical compound CC(C)(C)OC(=O)C(Br)=C GWIIOMWMVVSZJE-UHFFFAOYSA-N 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
- 229940096522 trimethylolpropane triacrylate Drugs 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- QSGNKXDSTRDWKA-UHFFFAOYSA-N zirconium dihydride Chemical compound [ZrH2] QSGNKXDSTRDWKA-UHFFFAOYSA-N 0.000 description 1
- 229910000568 zirconium hydride Inorganic materials 0.000 description 1
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Description
本開示は、無機多孔質アグロメレートの組成物、並びに音響活性物品としての該組成物を作製及び使用する方法に関する。
[背景技術]
[発明の概要]
[詳細な記載]
ある特定の用語が、本明細書及び特許請求の範囲の全体を通して使用されており、これらの大部分については周知であるが、何らかの説明が必要とされる場合もある。以下が理解されるべきである。
構成成分1:フリーラジカル開始剤によって重合させることができる、1つ以上の炭素二重結合を有する化学物質を含む、モノマー(複数可)
を含み得る。構成成分1は、ビニルモノマーの混合物であってもよい。一部の実施形態において、構成成分1は、以下のモノマーのうちの1つ以上を含有してもよい。
構成成分2:例えば、水酸化アルミニウム、酸化アルミニウム、酸化ケイ素、シリケート、酸化ジルコニウム、水酸化ジルコニウム、鉄のフェリ水和物、又は他の金属酸化物、複合金属酸化物、複合酸化状態金属酸化物、水酸化物、及び水和物を含み得る、音響活性金属酸化物(複数可)
を含み得る。
構成成分3:無機バインダーのための供給源(複数可)
を含み得る。バインダー(複数可)は、炭素、シリカ、又は他の金属酸化物(複数可)を含み得る。
構成成分1:脱イオン水、及び
構成成分2:限定されるものではないが、ポリビニルアルコール(polyvinyl alcohol、PVA)、ポリビニルピロリドン(polyvinylpyrrolidone、PVP)、アルギン酸ナトリウム塩、ALKANOL(登録商標)189-S界面活性剤、Capstone(登録商標)FS-66、グリコール酸エトキシレート4-tert-ブチルフェニルエーテル、グリコール酸エトキシレートラウリルエーテル、グリコール酸エトキシレート4-ノニルフェニルエーテル、グリコール酸エトキシレートオレイルエーテル、ポリ(エチレングリコール)4-ノニルフェニル3-スルホプロピルエーテルカリウム塩、Adogen(登録商標)464、ALKANOL(登録商標)ファミリー界面活性剤、Brij(登録商標)ファミリー界面活性剤、ジ(エチレングリコール)ヘキシルエーテル、2,5-ジメチル-3-ヘキシン-2,5-ジオール、エチレンジアミンテトラキス(エトキシレート-ブロック-プロポキシレート)テトロール、IGEPAL(登録商標)ファミリー界面活性剤、MERPOL(登録商標)ファミリー界面活性剤、ポリ(エチレングリコール)-ブロック-ポリ(プロピレングリコール)-ブロック-ポリ(エチレングリコール)、ポリ(エチレングリコール)ソルビタンテトラオレエート、ポリ(エチレングリコール)ソルビトールヘキサオレエート、ポリ(エチレングリコール)トリデシルエーテル、ポリエチレン-ブロック-ポリ(エチレングリコール)、ソルビタンモノパルミテート、2,4,7,9-テトラメチル-5-デシン-4,7-ジオールエトキシレート、triton(商標)ファミリー界面活性剤、1-ドデカノイル-sn-グリセロ-3-ホスホコリン、3-(4-tert-ブチル-1-ピリジニオ)-1-プロパンスルホネート、3-(N,N-ジメチルミリスチルアンモニオ)プロパンスルホネート、3-(1-ピリジニオ)-1-プロパンスルホネート、3-(ベンジルジメチルアンモニオ)プロパンスルホネート、3-(デシルジメチルアンモニオ)-プロパン-スルホネート分子内塩、3-(N,N-ジメチルオクチルアンモニオ)プロパンスルホネート、及び3-[N,N-ジメチル(3-パルミトイルアミノプロピル)アンモニオ]-プロパンスルホネートなどの、イオン性であってもよくあるいは非イオン性であってもよい、0~15重量%の界面活性剤(複数可)又は安定化剤(複数可)(好ましくは、ポリビニルアルコール)
を含み得る。
実施形態1~14、15~19、20~30及び31~33のうちのいずれか1つを組み合わせることができることを理解されたい。
約50ミクロン~約2mmの範囲の平均寸法を有する、複数の多孔質無機アグロメレートを含み、多孔質アグロメレートが、それぞれ、炭素又はシリカのネットワークと、ネットワーク中に埋め込まれた金属酸化物粒子とを含む、物品である。
100nm~20ミクロンの範囲の平均粒子径を有する金属酸化物粉末を準備することと、
金属酸化物粉末を、炭素又はケイ素を含有する1つ以上の反応性モノマー又はポリマー及び水と混合して、混合物を形成することと、
混合物を重合させて、複数の複合ビーズを形成することであって、複合ビーズが、それぞれ、ポリマーバインダーの内部に分散された金属酸化物粉末を含み、かつ約50ミクロン~約2mmの範囲の平均サイズを有する、複合ビーズを形成することと、
複合ビーズを、約400~約1000℃の範囲の高温で加熱して、多孔質無機アグロメレートを形成することと、
を含む、方法である。
(i)5~30重量%の金属酸化物粉末、及び(ii)炭素又はケイ素を含有する5~95重量%の1つ以上の反応性モノマー又はポリマーの混合物を含む、油相と、
約85~約100重量%の水を含む、水相と、を含む、
音響活性アグロメレートビーズを形成するための組成物であって、
油相及び水相が混合されており、水相の油相に対する体積比が10:1~1:1である、組成物である。
インピーダンス試験の方法
共振周波数(resonance frequency、RF)のグラフは、0.93立方センチメートルのキャビティに接続されたKnowles Electronics 2403-260-00001 11×15×3.5mmのスピーカーの、標準的Thiele-Smallパラメーター解析(Small,R.H.,「Closed-Box Loudspeaker Systems」,J.Audio Eng.Soc.,vol.20,pp.798-808(1972年12月)に記載されている)を使用して得た。DATS V2 Dayton Audio Test System(Dayton Audio,Springboro,OH 45066から入手可能)をスピーカーに取り付け、オーディオ領域(20~20,000Hz)における共振周波数ピークを収集するために動作させた。この共振周波数は、未充填の0.93ccのキャビティと接続したスピーカーについて収集したものであり、これを、試験材料で充填したキャビティでのシステム共振と比較した。
各キャビティ充填材料の有効性を評価するために、音圧レベル(SPL)応答試験を、固定具に据え付けたKnowles Electronics 2403-260-00001モデルのスピーカーを駆動させて実行した。この固定具により、背後に空気キャビティの空間が提供された。空気キャビティの体積は、およそ0.93ccであった。駆動電圧は、0~3200Hzの帯域制限チャープの形態で供給された、およそ0.4mVrmであった。電圧プロファイルは、試験した各材料について同一であり、HP 35670モデルの周波数分析装置(Keysight Technologies,Santa Rosa,CAから入手可能)によって生成された。また、この周波数分析装置を使用して、固定具からおよそ2.54cmに位置決めした、Bruel and Kjaer 4188-A-03タイプのコンデンサーマイクロホン(Bruel&Kjaer,Norcross,GAから入手可能)からのSPLも記録した。
(3-アクリルオキシプロピル)トリメトキシシラン表面官能化アルミナ粉末の調製
1Lのジャーにおいて、125gのV-250を、5mmのイットリア安定化ジルコニア(yttria-stabilized zirconia、YSZ)粉砕媒体(1kg)を使用して、100rpmで4時間乾式粉砕して、平均粒子径が約1ミクロンのアルミナ粉末を得た。次いで、粉砕された粉末を、アルミナるつぼ内で1時間、750℃に加熱した。1リットルの一ツ口フラスコにおいて、加工したV-250のうちの100gを、100gの(3-アクリルオキシプロピル)トリメトキシシラン及び200gのトルエンに添加した。混合物を機械的に撹拌し、16時間50℃に加熱した。冷却した後、粉末を濾過によって収集し、メタノールで洗浄し、60℃の真空オーブン内で24時間乾燥させた。
3-(トリメトキシシリル)プロピルメタクリレート表面官能化アルミナ粉末の調製
1Lのジャーにおいて、125gのV-250を、5mmのイットリア安定化ジルコニア(YSZ)粉砕媒体(1kg)を使用して、100rpmで4時間乾式粉砕して、平均粒子径が約1μmのアルミナ粉末を得た。次いで、粉砕された粉末を、アルミナるつぼ内で1時間、750℃に加熱した。1リットルの一ツ口フラスコにおいて、加工したV-250のうちの100gを、100gの3-(トリメトキシシリル)プロピルメタクリレート及び200gのトルエンに添加した。混合物を機械的に撹拌し、16時間50℃に加熱した。冷却した後、粉末を濾過によって収集し、メタノールで洗浄し、60℃の真空オーブン内で24時間乾燥させた。
3-メタクリルオキシプロピルトリメトキシシラン表面官能化アルミナ粉末の調製
4Lのステンレス鋼ビーカーにおいて、1200gの酢酸エチルを、Ross Lab Model ME100L丸穴ローターステーター式ミキサーを使用して、速度設定3で混合し、VGL-25アルミナを、約1.5分間にわたってゆっくりと添加した。均一なスラリーが得られるまで、混合を継続した(総混合時間は4.0分間)。結果として得られたスラリーを、機械的撹拌及び温度プローブを備え付けた3Lの三ツ口丸底フラスコに移した。撹拌しながら(約150rpm)、99.6gのA-174NTをゆっくりと添加した。結果として得られた混合物を16時間70℃に加熱し、その後、室温まで冷却した。固形分を、ブフナー漏斗及びWhatman Qualitative 4濾紙を使用して、真空濾過によって収集した。この固形分を、メタノールで洗浄し、70℃のバッチ式オーブン内で13.5時間乾燥させた。
20x50GG炭素粒を、比較例として使用した。この炭素粒の密度は、0.37g/ccであった。
アルミナ/炭素ビーズの調製
機械的撹拌及び凝縮器を備える500mLの三ツ口フラスコにおいて、調製例1に由来する表面官能化アルミナ粉末10gを、12gのスチレン、8gのDVB、6gのAN、及び0.3gのAIBNとともに装入した。この油相を撹拌して、均質な分散体を形成し、次いで、0.225gのPVAを伴う150gの水溶液を添加した。この系の粘度が劇的に上昇し、撹拌速度を1400rpmに上げた。この系を、5時間80℃に加熱した。アグロメレートを沈殿させ、上清を取り除いた。アグロメレートを水で2回洗浄し、室温で一晩乾燥させた。その後、洗浄して乾燥させたアグロメレートを、N2流下のアルミナるつぼ内で2時間、900℃で焼成して、アルミナ/炭素複合ビーズを形成した。これらのビーズは、600~710ミクロンを保持するように篩にかけられ、0.35g/ccの嵩密度を有した。
アルミナ/シリカビーズの調製
機械的撹拌及び凝縮器を備える500mLの三ツ口フラスコにおいて、調製例1に由来する表面官能化アルミナ粉末12gを、17gのDVB、16gのトリメトキシ(4-ビニルフェニル)シラン、及び0.3gのAIBNとともに装入した。この油相を撹拌して、均質な分散体を形成し、次いで、0.225gのPVAを伴う150gの水溶液を添加した。この系の粘度が劇的に上昇し、撹拌速度を1000rpmに上げた。この系を、6時間80℃に加熱した。アグロメレートを沈殿させ、上清を取り除いた。アグロメレートを水で2回洗浄し、室温で一晩乾燥させた。その後、洗浄して乾燥させたアグロメレートを、空気流下のアルミナるつぼ内で2時間、700℃で焼成して、アルミナ/シリカ複合ビーズを形成した。これらのビーズは、600~710ミクロンを保持するように篩にかけられ、0.40g/ccの嵩密度を有した。
アルミナ/炭素/シリカビーズの調製
機械的撹拌及び凝縮器を備える500mLの三ツ口フラスコにおいて、調製例2に由来する表面官能化アルミナ粉末11.2gを、15gのDVB、0.8gのPOSS、12gのスチレン、6gのAN、及び0.5gのAIBNとともに装入した。この油相を撹拌して、均質な分散体を形成し、次いで、0.225gのPVAを伴う150gの水溶液を添加した。この系の粘度が劇的に上昇し、撹拌速度を1200rpmに上げた。この系を、6時間80℃に加熱した。アグロメレートを沈殿させ、上清を取り除いた。アグロメレートを水で2回洗浄し、室温で一晩乾燥させた。その後、洗浄して乾燥させたアグロメレートを、N2流下のアルミナるつぼ内で2時間、900℃で焼成して、アルミナ/炭素/シリカ複合ビーズを形成した。これらのビーズは、600~710ミクロンを保持するように篩にかけられ、0.34g/ccの嵩密度を有した。
アルミナ/炭素/シリカビーズの調製
脱イオン水(920g)と、100gの、PVOHの1%(w/w)水溶液と、5gの固体PVPとを半ガロンのジャーに装入し、PVPが溶解するまで、マグネチックスターラーで撹拌した。次いで、EcoSurf SA7(1g)をこのジャーに添加し、磁気撹拌によって混合した。2Lの分割樹脂フラスコに、28gのAN2、60gのスチレン2、59gのDVB2、3gのPOSS、2gのVAZO 67、及び調製例2aに由来する官能化アルミナ粉末56gを装入した。このフラスコに、オーバースターラー、熱電対、及び凝縮器を備え付けた三ツ口ヘッドを固定した。次いで、フラスコ中の油相に水性プレミックスを装入し、窒素パージの下で45分間、撹拌速度を500rpmに設定した。この系を、500rpmの下で、毎分摂氏1度の速度で25℃から80℃に加熱し、その後、80℃で2時間保持した。内容物が室温に冷めるまで放置し、アグロメレートを沈殿させた後、上清を取り除いた。アグロメレートを水で2回洗浄し、室温で一晩乾燥させた。その後、洗浄して乾燥させたアグロメレートを、N2流下のアルミナるつぼ内で2時間、900℃で焼成して、アルミナ/炭素/シリカ複合ビーズを形成した。これらのビーズは、250~850ミクロンを保持するように篩にかけられ、0.36g/ccの嵩密度を有した。
250mLのガラスジャーにおいて、0.41gの1-(トリメトキシシリル)オクタン、0.2mLの水酸化アンモニウム、40mLのエタノール、及び40mLの水を混合した。この混合物に、実施例5aのアルミナ/炭素/シリカビーズ1.5gを添加し、混合物を60℃に加熱し、一晩保持した。上清を取り除き、表面改質アルミナ/炭素/シリカビーズをエタノールで洗浄し、室温で一晩乾燥させた。これにより、活性のある表面部位のうち10%が、理論的には被覆された。
測定した周波数シフトを、スピーカーのバックキャビティ内における流体の有効体積弾性率に関して解析した。周波数シフトは、バックキャビティの寸法と、スピーカー振動板の機械的特性とに左右される。一方で、体積弾性率は、流体、この場合はバックキャビティを充填する流体固有の特性である。音響活性材料がこのバックキャビティに加えられた場合、有効体積弾性率は低下される。したがって、有効体積弾性率を計算することによって、測定した結果を他のスピーカー及びバックキャビティに適用することができる。
式中、
M=振動板の質量
B0=流体(通常は単なる空気)の体積弾性率
A=振動板の表面積
t=バックキャビティの深さ
factive=キャビティが充填された場合の共振周波数
fseal=キャビティが密封され、未充填の場合の共振周波数
式中、
fopen=単にキャビティが存在しないスピーカーの共振周波数
すべての引用した実施例に関して、fopen=468Hzであり、未充填の場合の固有周波数は841Hzであると測定され、上の式により、振動板の質量は0.088gであると計算された。
Claims (8)
- キャビティの存在下で、トランスデューサーと、前記キャビティによって受け入れられた、物品とを含む音響デバイスであって、
前記物品が、50ミクロン~2mmの範囲の平均寸法を有する、複数の多孔質無機アグロメレートを含み、
前記多孔質アグロメレートが、それぞれ、炭素又はシリカのネットワークと、前記ネットワーク中に埋め込まれた金属酸化物粒子とを含み、
前記多孔質無機アグロメレートが、前記音響デバイスの共振周波数が50Hz~1500Hzの範囲内にある場合に、前記共振周波数を低下させることが可能であり、かつ前記多孔質無機アグロメレートが、空気の体積弾性率未満又は100,000Pa未満の有効体積弾性率を有する、音響デバイス。 - 前記炭素又はシリカのネットワークが、400~1000℃の範囲の高温におけるポリマーバインダーの熱分解生成物である、請求項1に記載の音響デバイス。
- 前記金属酸化物粒子が、酸化アルミニウム又は水酸化アルミニウムを含む、請求項1または2に記載の音響デバイス。
- 前記物品が、5~25重量%の炭素又はシリカと、95~75重量%の金属酸化物粒子とを含む、請求項1ないし3のいずれか一項に記載の音響デバイス。
- 前記多孔質アグロメレートが、0.05~1.0g/ccの範囲の充填密度を有する、請求項1ないし4のいずれか一項に記載の音響デバイス。
- 前記物品が実質的量のゼオライトを含まない、請求項1ないし5のいずれか一項に記載の音響デバイス。
- キャビティの存在下で、トランスデューサーと、前記キャビティによって受け入れられた物品とを含む音響デバイスに含まれる、多孔質無機アグロメレートを含む物品を形成する方法であって、100nm~10ミクロンの範囲の平均粒子径を有する金属酸化物粉末を準備することと、前記金属酸化物粉末を、炭素又はケイ素を含有する1つ以上の反応性モノマー又はポリマー及び水と混合して、混合物を形成することと、前記混合物を重合させて、複数の複合ビーズを形成することであって、前記複合ビーズが、それぞれ、ポリマーバインダーの内部に分散された前記金属酸化物粉末を含み、かつ50ミクロン~2mmの範囲の平均サイズを有する、前記複合ビーズを形成することと、前記複合ビーズを、400~1000℃の範囲の高温で加熱して、前記多孔質無機アグロメレートを形成することと、を含み、
前記多孔質無機アグロメレートが、前記音響デバイスの共振周波数が50Hz~1500Hzの範囲内にある場合に、前記共振周波数を低下させることが可能であり、かつ前記多孔質無機アグロメレートが、空気の体積弾性率未満又は100,000Pa未満の有効体積弾性率を有する、
方法。 - 前記金属酸化物粉末を混合することが、前記金属酸化物粉末を混合して油相にすることを更に含み、前記油相が、(i)5~30重量%の金属酸化物粉末と、(ii)十分な量のフリーラジカル開始剤と、(iii)炭素又はケイ素を含有する5~95重量%の前記反応性モノマー又はポリマーとの混合物を含む、請求項7に記載の方法。
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WO2017116974A1 (en) | 2017-07-06 |
JP2019507086A (ja) | 2019-03-14 |
CN108430952A (zh) | 2018-08-21 |
US10669211B2 (en) | 2020-06-02 |
US20190016643A1 (en) | 2019-01-17 |
EP3397601A1 (en) | 2018-11-07 |
CN108430952B (zh) | 2022-06-21 |
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