JP6901968B2 - 有機重合体微粒子 - Google Patents
有機重合体微粒子 Download PDFInfo
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- JP6901968B2 JP6901968B2 JP2017522240A JP2017522240A JP6901968B2 JP 6901968 B2 JP6901968 B2 JP 6901968B2 JP 2017522240 A JP2017522240 A JP 2017522240A JP 2017522240 A JP2017522240 A JP 2017522240A JP 6901968 B2 JP6901968 B2 JP 6901968B2
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|---|---|---|---|---|
| JPS6123628A (ja) | 1984-07-11 | 1986-02-01 | Nippon Paint Co Ltd | 高耐候性機能を有する微小樹脂粒子 |
| JPS6295301A (ja) | 1985-10-21 | 1987-05-01 | Dainippon Ink & Chem Inc | 化粧品以外に用いられる非造膜性樹脂エマルジヨンの製法及びその粉末化法 |
| JPH02149509A (ja) | 1988-12-01 | 1990-06-08 | Nippon Oil & Fats Co Ltd | 化粧用微粒子粉体 |
| JPH04363303A (ja) | 1991-02-05 | 1992-12-16 | Nippon Paint Co Ltd | 連続重合方法および装置 |
| JP3149487B2 (ja) | 1991-12-10 | 2001-03-26 | 住友化学工業株式会社 | メタアクリル系樹脂粒子の製造方法 |
| JP2790595B2 (ja) | 1992-06-16 | 1998-08-27 | 株式会社日本触媒 | 樹脂粒子、その製造方法および用途 |
| JP3179044B2 (ja) | 1992-06-16 | 2001-06-25 | 株式会社日本触媒 | 樹脂粒子およびその用途 |
| US5683501A (en) * | 1993-11-09 | 1997-11-04 | Nippon Shokubai Co., Ltd. | Compound fine particles and composition for forming film |
| KR960007660A (ko) * | 1994-08-12 | 1996-03-22 | 아크릴계 시트, 아크릴계 접착시트 및 이들의 제조방법 | |
| JP4172601B2 (ja) | 1997-06-26 | 2008-10-29 | 東セロ株式会社 | 単分散性メタクリレート系樹脂粒子および該樹脂粒子を配合、製膜したフィルム |
| JP2000038455A (ja) * | 1998-07-23 | 2000-02-08 | Soken Chem & Eng Co Ltd | アクリル系アンチブロッキング粒子群およびその製造法 |
| JP4107627B2 (ja) | 1999-11-22 | 2008-06-25 | ガンツ化成株式会社 | メイクアップまたは固液多層式化粧料 |
| JP4034157B2 (ja) | 2001-09-28 | 2008-01-16 | 株式会社日本触媒 | (メタ)アクリル系架橋微粒子の製造方法 |
| TWI254719B (en) * | 2001-09-28 | 2006-05-11 | Nippon Catalytic Chem Ind | (Meth)acrylic crosslinked fine particles and method of manufacturing the same |
| DE102004006115A1 (de) | 2004-02-06 | 2005-08-25 | Bayer Chemicals Ag | Verfahren zur Herstellung von monodispersen acrylhaltigen Perlpolymerisaten |
| KR100607250B1 (ko) * | 2004-09-16 | 2006-08-01 | 엘지전자 주식회사 | 인버스 구조의 플라즈마 디스플레이 패널 |
| JP4711796B2 (ja) | 2005-03-29 | 2011-06-29 | 積水化成品工業株式会社 | 光拡散性ポリカーボネート系樹脂組成物及び光拡散剤 |
| WO2008133147A1 (ja) | 2007-04-16 | 2008-11-06 | Nippon Shokubai Co., Ltd. | 耐熱性に優れた有機重合体微粒子およびその製造方法、並びにこれを用いた光学用部材 |
| JP5602992B2 (ja) | 2008-03-04 | 2014-10-08 | 帝人株式会社 | 光拡散性芳香族ポリカーボネート樹脂組成物 |
| JP5436833B2 (ja) * | 2008-10-15 | 2014-03-05 | 株式会社日本触媒 | 重合体微粒子およびその製造方法 |
| JP5427437B2 (ja) * | 2009-02-26 | 2014-02-26 | 株式会社日本触媒 | 重合体微粒子、その製造方法および導電性微粒子並びに異方導電性材料 |
| JP2010275356A (ja) | 2009-05-26 | 2010-12-09 | Jx Nippon Oil & Energy Corp | 押出成形時のメヤニ発生を抑制するポリマー微粒子、これを用いたアンチブロッキング剤マスターバッチ並びにそれを用いて成形した樹脂フィルム |
| JP5703567B2 (ja) * | 2010-02-16 | 2015-04-22 | 東亞合成株式会社 | 架橋重合体微粒子の製造方法 |
| JP5444066B2 (ja) * | 2010-03-19 | 2014-03-19 | 積水化成品工業株式会社 | 湿式ブラスト加工用研磨材及びその製造方法 |
| JP5555213B2 (ja) * | 2010-09-30 | 2014-07-23 | 積水化成品工業株式会社 | 光拡散性樹脂組成物、光拡散性部材、および照明カバー |
| KR101588226B1 (ko) * | 2011-08-31 | 2016-01-25 | 세키스이가세이힝코교가부시키가이샤 | 수지 입자 집합체, 그 제조 방법 및 그 용도 |
| CN104011085B (zh) * | 2011-12-16 | 2016-01-20 | 综研化学株式会社 | 树脂颗粒团及其制造方法以及树脂颗粒团的颗粒的粒度调整方法 |
| JP6029507B2 (ja) | 2012-03-27 | 2016-11-24 | 積水化成品工業株式会社 | 多孔質樹脂粒子、多孔質樹脂粒子の製造方法、及び、その用途 |
| KR101447775B1 (ko) | 2012-05-08 | 2014-10-06 | (주)엘지하우시스 | 감촉 특성이 우수한 코팅 조성물, 그 제조방법 및 이를 이용한 전사시트 |
| JP6137446B2 (ja) | 2012-11-06 | 2017-05-31 | 川崎化成工業株式会社 | 縮合多環芳香族骨格を有する連鎖移動剤並びに該縮合多環芳香族骨格を有するポリマーおよびポリマーの製造方法 |
| JP2014231546A (ja) | 2013-05-28 | 2014-12-11 | Jx日鉱日石エネルギー株式会社 | ポリマー微粒子の製造方法 |
| JP6134592B2 (ja) * | 2013-06-21 | 2017-05-24 | 積水化成品工業株式会社 | 樹脂粒子溶剤分散体及びその用途 |
| JP2015067694A (ja) | 2013-09-27 | 2015-04-13 | 株式会社日本触媒 | (メタ)アクリル系架橋微粒子およびその製造方法 |
| JP2015067803A (ja) | 2013-09-30 | 2015-04-13 | 株式会社日本触媒 | 多孔質樹脂粒子 |
| EP3070106B1 (en) | 2013-11-13 | 2019-01-09 | Sekisui Plastics Co., Ltd. | Composite particles, method for producing same, and use thereof |
| KR102382184B1 (ko) * | 2015-09-30 | 2022-04-04 | 세키스이가세이힝코교가부시키가이샤 | 중합체 입자 및 그 용도 |
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- 2016-06-02 JP JP2017522240A patent/JP6901968B2/ja active Active
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- 2016-06-02 WO PCT/JP2016/066372 patent/WO2016195006A1/ja not_active Ceased
- 2016-06-02 CN CN201680032307.7A patent/CN107614550B/zh active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2016195006A1 (ja) | 2018-02-22 |
| EP3305816A4 (en) | 2019-02-27 |
| KR20180015665A (ko) | 2018-02-13 |
| WO2016195006A9 (ja) | 2017-10-26 |
| EP3305816A1 (en) | 2018-04-11 |
| WO2016195006A1 (ja) | 2016-12-08 |
| US11104753B2 (en) | 2021-08-31 |
| JP2020172656A (ja) | 2020-10-22 |
| CN107614550A (zh) | 2018-01-19 |
| US20180171050A1 (en) | 2018-06-21 |
| KR102454100B1 (ko) | 2022-10-12 |
| CN107614550B (zh) | 2021-10-22 |
| JP7348974B2 (ja) | 2023-09-21 |
| JP2022066218A (ja) | 2022-04-28 |
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