JP6800148B2 - Pvd金属効果顔料パウダー - Google Patents
Pvd金属効果顔料パウダー Download PDFInfo
- Publication number
- JP6800148B2 JP6800148B2 JP2017520985A JP2017520985A JP6800148B2 JP 6800148 B2 JP6800148 B2 JP 6800148B2 JP 2017520985 A JP2017520985 A JP 2017520985A JP 2017520985 A JP2017520985 A JP 2017520985A JP 6800148 B2 JP6800148 B2 JP 6800148B2
- Authority
- JP
- Japan
- Prior art keywords
- pvd
- effect pigment
- coated
- metal
- metal effect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000049 pigment Substances 0.000 title claims description 175
- 229910052751 metal Inorganic materials 0.000 title claims description 128
- 239000002184 metal Substances 0.000 title claims description 128
- 230000000694 effects Effects 0.000 title claims description 124
- 239000000843 powder Substances 0.000 title claims description 75
- 229910044991 metal oxide Inorganic materials 0.000 claims description 48
- 150000004706 metal oxides Chemical class 0.000 claims description 48
- 239000004033 plastic Substances 0.000 claims description 37
- 229920003023 plastic Polymers 0.000 claims description 37
- 238000000576 coating method Methods 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 32
- 239000000725 suspension Substances 0.000 claims description 32
- 239000011248 coating agent Substances 0.000 claims description 30
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 27
- 229910052782 aluminium Inorganic materials 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 14
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 13
- 239000003973 paint Substances 0.000 claims description 13
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 239000004743 Polypropylene Substances 0.000 claims description 9
- 238000010330 laser marking Methods 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 238000007639 printing Methods 0.000 claims description 8
- 238000003980 solgel method Methods 0.000 claims description 8
- 239000002537 cosmetic Substances 0.000 claims description 6
- -1 polypropylene Polymers 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 150000002894 organic compounds Chemical class 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 3
- 230000001588 bifunctional effect Effects 0.000 claims description 3
- 239000000976 ink Substances 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 230000001678 irradiating effect Effects 0.000 claims description 2
- 238000007704 wet chemistry method Methods 0.000 claims description 2
- 238000005240 physical vapour deposition Methods 0.000 description 100
- 239000000203 mixture Substances 0.000 description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 10
- 239000006072 paste Substances 0.000 description 10
- 239000002932 luster Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 239000011324 bead Substances 0.000 description 7
- 239000010408 film Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 5
- 230000002776 aggregation Effects 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 229910000077 silane Inorganic materials 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 150000004703 alkoxides Chemical class 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000004756 silanes Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011135 tin Substances 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- KBQVDAIIQCXKPI-UHFFFAOYSA-N 3-trimethoxysilylpropyl prop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C=C KBQVDAIIQCXKPI-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 241000209149 Zea Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 150000004770 chalcogenides Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- RSKGMYDENCAJEN-UHFFFAOYSA-N hexadecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OC)(OC)OC RSKGMYDENCAJEN-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- 238000001429 visible spectrum Methods 0.000 description 2
- IDXCKOANSQIPGX-UHFFFAOYSA-N (acetyloxy-ethenyl-methylsilyl) acetate Chemical compound CC(=O)O[Si](C)(C=C)OC(C)=O IDXCKOANSQIPGX-UHFFFAOYSA-N 0.000 description 1
- FGSFVBRPCKXYDI-UHFFFAOYSA-N 2-triethoxysilylethyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCOC(=O)C(C)=C FGSFVBRPCKXYDI-UHFFFAOYSA-N 0.000 description 1
- PSLRXNFNXYNXEK-UHFFFAOYSA-N 2-triethoxysilylethyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCOC(=O)C=C PSLRXNFNXYNXEK-UHFFFAOYSA-N 0.000 description 1
- BUJVPKZRXOTBGA-UHFFFAOYSA-N 2-trimethoxysilylethyl prop-2-enoate Chemical compound CO[Si](OC)(OC)CCOC(=O)C=C BUJVPKZRXOTBGA-UHFFFAOYSA-N 0.000 description 1
- LBIOWAJXQAGGBL-UHFFFAOYSA-N 3-[tris(2-butoxyethoxy)silyl]propyl prop-2-enoate Chemical compound CCCCOCCO[Si](CCCOC(=O)C=C)(OCCOCCCC)OCCOCCCC LBIOWAJXQAGGBL-UHFFFAOYSA-N 0.000 description 1
- DMZPTAFGSRVFIA-UHFFFAOYSA-N 3-[tris(2-methoxyethoxy)silyl]propyl 2-methylprop-2-enoate Chemical compound COCCO[Si](OCCOC)(OCCOC)CCCOC(=O)C(C)=C DMZPTAFGSRVFIA-UHFFFAOYSA-N 0.000 description 1
- PNZVYZIRTOVNKZ-UHFFFAOYSA-N 3-[tris(2-methoxyethoxy)silyl]propyl prop-2-enoate Chemical compound COCCO[Si](OCCOC)(OCCOC)CCCOC(=O)C=C PNZVYZIRTOVNKZ-UHFFFAOYSA-N 0.000 description 1
- ZJWCURYIRDLMTM-UHFFFAOYSA-N 3-tributoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCCOC(=O)C(C)=C ZJWCURYIRDLMTM-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- JZYAVTAENNQGJB-UHFFFAOYSA-N 3-tripropoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCCO[Si](OCCC)(OCCC)CCCOC(=O)C(C)=C JZYAVTAENNQGJB-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical group [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001343 alkyl silanes Chemical class 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- YHAYSVXJJPHCRO-UHFFFAOYSA-N but-3-enyl(dichloro)silane Chemical compound Cl[SiH](Cl)CCC=C YHAYSVXJJPHCRO-UHFFFAOYSA-N 0.000 description 1
- ZZHNUBIHHLQNHX-UHFFFAOYSA-N butoxysilane Chemical compound CCCCO[SiH3] ZZHNUBIHHLQNHX-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical group Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- YLJJAVFOBDSYAN-UHFFFAOYSA-N dichloro-ethenyl-methylsilane Chemical compound C[Si](Cl)(Cl)C=C YLJJAVFOBDSYAN-UHFFFAOYSA-N 0.000 description 1
- IGFFTOVGRACDBL-UHFFFAOYSA-N dichloro-phenyl-prop-2-enylsilane Chemical compound C=CC[Si](Cl)(Cl)C1=CC=CC=C1 IGFFTOVGRACDBL-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- MBGQQKKTDDNCSG-UHFFFAOYSA-N ethenyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(C=C)OCC MBGQQKKTDDNCSG-UHFFFAOYSA-N 0.000 description 1
- URZLRFGTFVPFDW-UHFFFAOYSA-N ethenyl-diethoxy-phenylsilane Chemical compound CCO[Si](OCC)(C=C)C1=CC=CC=C1 URZLRFGTFVPFDW-UHFFFAOYSA-N 0.000 description 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000006221 furniture coating Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- 238000001579 optical reflectometry Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical group [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Chemical group 0.000 description 1
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 1
- 239000004597 plastic additive Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000003351 stiffener Substances 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OYGYKEULCAINCL-UHFFFAOYSA-N triethoxy(hexadecyl)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC OYGYKEULCAINCL-UHFFFAOYSA-N 0.000 description 1
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/62—Metallic pigments or fillers
- C09C1/64—Aluminium
- C09C1/642—Aluminium treated with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0021—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/12—Treatment with organosilicon compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/031—Powdery paints characterised by particle size or shape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/032—Powdery paints characterised by a special effect of the produced film, e.g. wrinkle, pearlescence, matt finish
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
- C09D5/035—Coloring agents, e.g. pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
- C01P2004/86—Thin layer coatings, i.e. the coating thickness being less than 0.1 time the particle radius
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1054—Interference pigments characterized by the core material the core consisting of a metal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1054—Interference pigments characterized by the core material the core consisting of a metal
- C09C2200/1058—Interference pigments characterized by the core material the core consisting of a metal comprising a protective coating on the metallic layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/40—Interference pigments comprising an outermost surface coating
- C09C2200/402—Organic protective coating
- C09C2200/407—Organosilicon materials, e.g. silanes, silicones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2210/00—Special effects or uses of interference pigments
- C09C2210/60—Interference with laser-light, laser markable pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
a)ゾル−ゲルプロセスにおける、PVDプロセスによって製造された金属効果顔料の金属酸化物でのコーティング、当該金属酸化物層は、コーティングされたPVD金属効果顔料の合計重量に基づいて5〜45wt%である
b)反応混合液からの、コーティングされた金属効果顔料の固体−液体分離
c)得られたコーティングされた金属効果顔料の、100℃〜140℃での乾燥、それによりパウダーが得られる。
a)ゾル−ゲルプロセスにおける、PVDプロセスによって製造された金属効果顔料の金属酸化物でのコーティング、前記金属酸化物層の量はコーティングされたPVD金属効果顔料の合計重量に基づいて5〜45wt%である
b)反応混合物からのコーティングされた金属効果顔料の固体−液体分離
c)得られたコーティングされた金属効果顔料の100〜140℃での乾燥、粉末が得られる
Schlenk Metallic Pigments GmbH社製 Decomet 1002/10(固形分10%)200gが、イソプロパノール400gに懸濁される。テトラエトキシシラン47gがこの混合物に添加され、この混合物は60℃に加熱される。続いて、水100g、続いてアンモニア6gが添加され、混合物はさらに4時間攪拌される。混合物は続いて、ガラスフィルターを通して濾過される。続いて、得られたフィルターケーキがイソプロパノールで10%に調整される。金属酸化物層の量は、コーティングされたPVD金属効果顔料の合計重量に基づいて、40wt%である。
Schlenk Metallic Pigments GmbH社製 Decomet 1002/10 200gが、イソプロパノール400gに懸濁される。テトラエトキシシラン47gがこの混合物に添加され、この混合物は60℃に加熱される。続いて、水100g、続いて直ちにアンモニア6gが添加され、混合物はさらに4時間攪拌される。混合物は続いて、ガラスフィルターを通して濾過された。得られたフィルターケーキは、続いて、乾燥炉で120℃、12時間乾燥される。金属酸化物層の量は、コーティングされたPVD金属効果顔料の合計重量に基づいて、40wt%である。
Schlenk Metallic Pigments GmbH社製 Decomet 1002/10 200gが、イソプロパノール400gに懸濁される。テトラエトキシシラン47gがこの混合物に添加され、この混合物は60℃に加熱される。続いて、水100g、続いて直ちにアンモニア6gが混合物に添加され、混合物はさらに4時間攪拌される。混合物は続いて、ガラスフィルターを通して濾過される。得られたフィルターケーキは、続いて、乾燥炉で120℃、12時間乾燥される。金属酸化物層の量は、コーティングされたPVD金属効果顔料の合計重量に基づいて、40wt%である。
乾燥されたパウダー0.2gが1.8gイソプロパノールとともに25mLプラスチックビーカーに入れられる。この分散液にバインダーメディウムA(ニトロセルロースベースの塗料)3gが添加される。混合物は、Speedmixer(装置:DAC 250 SP)中で回転速度(1000rpm10秒;2000rpm15秒;2500rpm30秒;2000rpm10秒;1000rpm5秒)で分散され、スパチュラで再度短時間完全に混ぜられる。続いて、24μmスパイラルブレードを用いて、コーティング紙の上の基材上に塗布される。塗布物は5分後室温で乾燥され、続いて反射率計(Byk-Gardner社製Tri-Gloss)で測定される。凝集物の形成は、視覚的に確認される。
スラリー(10%)2gが、バインダーメディウムA3gに添加される。混合物はSpeedmixer(装置:DAC 250 SP)中で回転速度(1000rpm10秒;2000rpm15秒;2500rpm30秒;2000rpm10秒;1000rpm5秒)で分散され、スパチュラで再度短時間完全に混ぜられる。続いて、24μmスパイラルブレードを用いて、コーティング紙の上の基材上に塗布される。塗布物は5分後室温で乾燥され、続いて反射率計(Byk-Gardner社製Tri-Gloss)で測定される。凝集物の形成は、視覚的に確認される。
既知の体積のアルミニウムパウダーの重量を測定することによって、アルミニウムパウダーのバルク重量又はバルク密度が、g/mL又はg/cm3の単位で決定される。
真鍮製の測定シリンダ(50mL容量)がスケールに置かれ、0点が調節される。充分量のアルミニウムパウダーがオンス紙(Pergamyn Echo、35 g/m2、未漂白、光沢あり)上に置かれ、スパチュラを用いて注意深く横方向に(3回)延ばされた。パウダーはゆっくりと、紙の上に立っている金属シリンダーの中に導入され、金属のシートで表面を覆われて、重量測定される。
Claims (17)
- コーティングされたPVD金属効果顔料からなるパウダーであって、当該コーティングされたPVD金属効果顔料は、PVD金属効果顔料及び金属酸化物層を含み、前記PVD金属効果顔料がアルミニウム効果顔料であり、前記金属酸化物層がSiO2層であり、当該SiO2層は前記コーティングされたPVD金属効果顔料の合計重量に基づいて30〜45wt%であり、
前記コーティングされたPVD金属効果顔料の平均粒径(D50の値)が5〜50μmである、
パウダー。 - 前記金属酸化物層が湿式化学的に形成された、請求項1に記載のパウダー。
- 前記金属酸化物層が、前記コーティングされたPVD金属効果顔料の合計重量に基づいて30〜44wt%である、請求項1又は2に記載のパウダー。
- 二官能性又は一官能性の有機化合物が、前記金属酸化物層に結合している、
請求項1〜3のいずれか1項に記載のパウダー。 - 前記コーティングされたPVD金属効果顔料のBET表面積が15〜90m2/gの間である、請求項1〜4のいずれか1項に記載のパウダー。
- コーティングされたPVD金属効果顔料の溶媒懸濁液であって、前記コーティングされたPVD金属効果顔料はPVD金属効果顔料及び金属酸化物層を含み、前記PVD金属効果顔料がアルミニウム効果顔料であり、前記金属酸化物層がSiO2層であり、当該SiO2層は前記コーティングされたPVD金属効果顔料の合計重量に基づいて30〜45wt%であり、前記懸濁液は70wt%以上の前記コーティングされたPVD金属効果顔料を含有し、
前記コーティングされたPVD金属効果顔料の平均粒径(D50の値)が5〜50μmである、懸濁液。 - 前記コーティングされたPVD金属効果顔料の含量が、75wt%以上である、請求項6に記載の懸濁液。
- 粉末塗料における、請求項1〜5のいずれか1項に記載のパウダーの使用。
- ペイント、塗料、マスターバッチ、印刷インク、プラスチック、化粧品、証券類の偽造防止印刷又は有価証券印刷における、請求項1〜7のいずれか1項に記載のPVD金属効果顔料懸濁液又はPVD金属効果顔料パウダーの使用。
- 請求項1〜5のいずれか1項に記載のパウダーを含有する粉末塗料。
- 請求項1〜5のいずれか1項に記載のパウダー、又は、請求項6又は7に記載の懸濁液と、プラスチックとを含有するマスターバッチ。
- 前記プラスチックが、ポリプロピレン、ポリアミド及びポリカーボネートから選択される、請求項11に記載のマスターバッチ。
- 請求項1〜5のいずれか1項に記載のパウダー、又は、請求項6又は7に記載の懸濁液を含有するプラスチック材料。
- プラスチックのレーザーマーキングのための、請求項11又は12に記載のマスターバッチ、又は、請求項13に記載のプラスチック材料の使用。
- プラスチックのレーザーマーキングのための方法であって、
請求項11又は12に記載のマスターバッチ、又は、請求項13に記載のプラスチック材料を供給すること、及び、
前記プラスチックの選択されたエリアにレーザー光線を照射し、前記コーティングされたPVD金属効果顔料が少なくとも部分的にこのエリアで変性すること、を含む方法。 - PVD金属効果顔料パウダーの製造方法であって、次のステップを含み:
a)ゾル−ゲルプロセスにおいて、PVDプロセスによって製造された金属効果顔料を、金属酸化物でコーティングすること、前記金属酸化物の層は、コーティングされたPVD金属効果顔料の合計重量に基づいて30〜45wt%である、
b)反応混合物からコーティングされた金属効果顔料を固体−液体分離すること、
c)得られたコーティングされた金属効果顔料を100〜140℃で乾燥し、パウダーを得ること、
また、前記PVD金属効果顔料がアルミニウム効果顔料であり、前記金属酸化物層がSiO2層であり、
前記コーティングされたPVD金属効果顔料の平均粒径(D50の値)が5〜50μmである、
製造方法。 - 前記ステップc)における乾燥が、回転炉において120℃で実行される、請求項16に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102014015151.4 | 2014-10-13 | ||
DE102014015151.4A DE102014015151A1 (de) | 2014-10-13 | 2014-10-13 | PVD-Metalleffektpigmentpulver |
PCT/EP2015/073642 WO2016059033A1 (de) | 2014-10-13 | 2015-10-13 | Pvd-metalleffektpigmentpulver |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017533982A JP2017533982A (ja) | 2017-11-16 |
JP6800148B2 true JP6800148B2 (ja) | 2020-12-16 |
Family
ID=54292811
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017520985A Active JP6800148B2 (ja) | 2014-10-13 | 2015-10-13 | Pvd金属効果顔料パウダー |
Country Status (11)
Country | Link |
---|---|
US (1) | US20170306159A1 (ja) |
EP (1) | EP3207096A1 (ja) |
JP (1) | JP6800148B2 (ja) |
KR (1) | KR102448349B1 (ja) |
CN (1) | CN106795379A (ja) |
BR (1) | BR112017006824B1 (ja) |
CA (1) | CA2962010C (ja) |
DE (1) | DE102014015151A1 (ja) |
MX (1) | MX2017004734A (ja) |
RU (1) | RU2678656C2 (ja) |
WO (1) | WO2016059033A1 (ja) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SI3315563T1 (sl) * | 2016-10-28 | 2020-08-31 | Ewald Doerken Ag | Protikorozijski zaščitni pigment in njegova uporaba |
WO2019022003A1 (ja) * | 2017-07-24 | 2019-01-31 | 住友金属鉱山株式会社 | 赤外線吸収微粒子含有マスターバッチ粉砕物、赤外線吸収微粒子含有マスターバッチ粉砕物含有分散液、赤外線吸収材料含有インク、それらを用いた偽造防止インク、偽造防止用印刷膜、ならびに赤外線吸収微粒子含有マスターバッチ粉砕物の製造方法 |
EP3720912A1 (en) * | 2017-12-06 | 2020-10-14 | ECKART GmbH | Plate-like pvd aluminum pigment with a protective encapsulation and method for manufacturing a plate-like pvd aluminium pigment with a protective encapsulation |
US11920244B2 (en) | 2018-07-24 | 2024-03-05 | Hewlett-Packard Development Company, L.P. | Device housing with metallic luster |
JP2022521470A (ja) * | 2019-02-05 | 2022-04-08 | シルバーライン リミテッド | 新規製品 |
RU2730990C1 (ru) * | 2020-01-29 | 2020-08-26 | Александр Валентинович Чуфинев | Способ стабилизации пигментов в цветных фотосшиваемых гель-лаках |
EP3896130A1 (en) | 2020-04-17 | 2021-10-20 | Ferroglobe Innovation, S.L. | Method for obtaining coloured metal-containing powder, the powder obtained thereof and its use as metallic pigment |
KR20230025481A (ko) * | 2020-06-22 | 2023-02-21 | 에카르트 아메리카 코포레이션 | 반사성 코어를 갖는 효과 안료 |
CN113061356B (zh) * | 2021-03-26 | 2022-01-04 | 安徽诚易金属新材料有限公司 | 一种高光泽多用途磁性铝颜料及其制备方法 |
JP2022163850A (ja) * | 2021-04-15 | 2022-10-27 | 旭化成株式会社 | 複合金属顔料組成物及びその製造方法 |
WO2023152073A1 (en) * | 2022-02-09 | 2023-08-17 | Merck Patent Gmbh | Metal effect pigments with surface-treatments, preparing method and use of same |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2941894A (en) | 1955-03-16 | 1960-06-21 | American Marietta Co | Metallized coating compositions |
US2839378A (en) | 1955-04-15 | 1958-06-17 | American Marietta Co | Method of making metal flakes |
US4321087A (en) | 1978-12-21 | 1982-03-23 | Revlon, Inc. | Process for making metallic leafing pigments |
RU2093533C1 (ru) * | 1992-06-10 | 1997-10-20 | Акционерное общество "Порхим" | Способ получения пигментных паст с металлическим эффектом |
US6013370A (en) * | 1998-01-09 | 2000-01-11 | Flex Products, Inc. | Bright metal flake |
DE19836810A1 (de) * | 1998-08-14 | 2000-02-17 | Merck Patent Gmbh | Mehrschichtpigmente auf Basis beschichteter Metallplättchen |
GB0221697D0 (en) * | 2002-09-18 | 2002-10-30 | Unilever Plc | Novel compouds and their uses |
DE102004063433A1 (de) | 2004-12-23 | 2006-07-06 | Eckart Gmbh & Co. Kg | Mehrschichtiges Effektpigment mit zentraler Absorberschicht, Verfahren zu deren Herstellung, Verwendung derselben, Beschichtungsmittel und beschichteter Gegenstand |
DE102005030242A1 (de) * | 2005-06-29 | 2007-01-04 | Merck Patent Gmbh | Semitransparente Interferenzpigmente |
DE102008031901A1 (de) * | 2008-07-08 | 2010-01-14 | Eckart Gmbh | Metalleffektpigmente, Verfahren zu deren Herstellung sowie Verwendung derselben und Pulverlack |
RU2011141886A (ru) * | 2009-03-18 | 2013-04-27 | Мерк Патент Гмбх | Пигмент для лазерной маркировки |
DE102010007147A1 (de) * | 2010-02-05 | 2011-08-11 | Eckart GmbH, 91235 | Mit SiO2 beschichtete Metalleffektpigmente, Verfahren zur Herstellung dieser Metalleffektpigmente und Verwendung |
JP5626520B2 (ja) * | 2010-10-04 | 2014-11-19 | セイコーエプソン株式会社 | 紫外線硬化型インクジェット用インク組成物 |
DE102011103882A1 (de) * | 2011-03-25 | 2012-09-27 | Eckart Gmbh | Kupferhaltige Metallpigmente mit Metalloxidschicht und Kunststoffschicht, Verfahren zu deren Herstellung, Beschichtungsmittel und beschichteter Gegenstand |
DE102011055072A1 (de) * | 2011-11-04 | 2013-05-08 | Eckart Gmbh | Beschichtete, nasschemisch oxidierte Aluminiumeffektpigmente, Verfahren zu deren Herstellung, Beschichtungsmittel und beschichteter Gegenstand |
CN104136550B (zh) * | 2012-03-02 | 2016-11-16 | 巴斯夫欧洲公司 | 薄铝片 |
DE102012109055A1 (de) | 2012-09-25 | 2014-03-27 | Eckart Gmbh | Beschichtete ferromagnetische Metallpigmente, Verfahren zu deren Herstellung und deren Verwendung |
CN104026342A (zh) * | 2014-05-22 | 2014-09-10 | 王海兴 | 一种精制海藻鸡饲料 |
-
2014
- 2014-10-13 DE DE102014015151.4A patent/DE102014015151A1/de active Pending
-
2015
- 2015-10-13 BR BR112017006824-9A patent/BR112017006824B1/pt active IP Right Grant
- 2015-10-13 CN CN201580055279.6A patent/CN106795379A/zh active Pending
- 2015-10-13 MX MX2017004734A patent/MX2017004734A/es unknown
- 2015-10-13 JP JP2017520985A patent/JP6800148B2/ja active Active
- 2015-10-13 US US15/518,268 patent/US20170306159A1/en not_active Abandoned
- 2015-10-13 WO PCT/EP2015/073642 patent/WO2016059033A1/de active Application Filing
- 2015-10-13 CA CA2962010A patent/CA2962010C/en active Active
- 2015-10-13 KR KR1020177009839A patent/KR102448349B1/ko active IP Right Grant
- 2015-10-13 RU RU2017111326A patent/RU2678656C2/ru active
- 2015-10-13 EP EP15778688.0A patent/EP3207096A1/de active Pending
Also Published As
Publication number | Publication date |
---|---|
BR112017006824A2 (pt) | 2017-12-12 |
CA2962010C (en) | 2023-03-21 |
WO2016059033A1 (de) | 2016-04-21 |
KR102448349B1 (ko) | 2022-09-27 |
MX2017004734A (es) | 2017-11-30 |
RU2678656C2 (ru) | 2019-01-30 |
RU2017111326A (ru) | 2018-11-15 |
CA2962010A1 (en) | 2016-04-21 |
BR112017006824B1 (pt) | 2022-08-09 |
EP3207096A1 (de) | 2017-08-23 |
RU2017111326A3 (ja) | 2018-11-15 |
US20170306159A1 (en) | 2017-10-26 |
CN106795379A (zh) | 2017-05-31 |
KR20170070045A (ko) | 2017-06-21 |
JP2017533982A (ja) | 2017-11-16 |
DE102014015151A1 (de) | 2016-04-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6800148B2 (ja) | Pvd金属効果顔料パウダー | |
TWI604020B (zh) | 效果顏料 | |
CN102844384B (zh) | 涂有SiO2的金属效应颜料,生产所述金属效应颜料的方法及用途 | |
JP5475210B2 (ja) | 高耐腐食性薄片状金属顔料、その製造方法、およびそれをベースとする金属光沢干渉発色顔料 | |
US20110197782A1 (en) | Gold colored metallic pigments that include manganese oxide nanoparticles | |
JP6752802B2 (ja) | コーティングされた顔料、その製造および使用、コーティング剤および物品 | |
JP6956642B2 (ja) | 酸化鉄で被覆された赤色の一次干渉色を有するアルミニウムフレークの被覆における使用 | |
KR102107608B1 (ko) | 금속 산화물 코팅된 알루미늄 효과 안료의 제조 방법 | |
CN107614627B (zh) | 光亮性颜料及其制造方法、含颜料组合物、以及含颜料涂装体 | |
KR102612343B1 (ko) | 67° 78°의 범위의 색상 (h15) 및 90 이상의 채도 (c*15)를 갖는 금색 효과 안료 | |
JPWO2007116769A1 (ja) | 金色調を有する光輝性顔料、これを含有する化粧料、塗料、インク、または樹脂組成物 | |
JP5288085B2 (ja) | 有機無機複合粒子粉末の製造法、該有機無機複合粒子粉末からなる有機無機複合顔料並びに該有機無機複合顔料を用いた塗料及び樹脂組成物、該有機無機複合顔料を含む顔料分散体及びマスターバッチペレット | |
JP2023065342A (ja) | 顔料粉末 | |
JP6526683B2 (ja) | 非磁性化可能な効果顔料 | |
JP5955853B2 (ja) | ブリリアントブラック顔料 | |
EP3617275A1 (en) | Lustrous pigment, pigment-containing composition, and pigment-containing coated article | |
JP5177333B2 (ja) | 微細なオレンジ色系顔料並びに該微細なオレンジ色系顔料を用いた塗料及び樹脂組成物 | |
JP4862976B2 (ja) | 緑色系顔料並びに該緑色系顔料を用いた塗料及び樹脂組成物 | |
Yan et al. | Performance Test And Heat Resistance Of Physical And Chemical Coated Iron Oxide Black Pigment |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20180817 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20190426 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190529 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190827 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20200205 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200501 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20201104 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20201124 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6800148 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |