JP6749942B2 - 分極した強誘電ポリマーを使用するcvdグラフェンの無欠陥直接乾式剥離 - Google Patents

分極した強誘電ポリマーを使用するcvdグラフェンの無欠陥直接乾式剥離 Download PDF

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JP6749942B2
JP6749942B2 JP2017559270A JP2017559270A JP6749942B2 JP 6749942 B2 JP6749942 B2 JP 6749942B2 JP 2017559270 A JP2017559270 A JP 2017559270A JP 2017559270 A JP2017559270 A JP 2017559270A JP 6749942 B2 JP6749942 B2 JP 6749942B2
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graphene
ferroelectric polymer
layer
substrate
polymer layer
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JP2018512370A (ja
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バルバロス エツィイルマツ,
バルバロス エツィイルマツ,
フェルナンデス イニーゴ マルティン,
フェルナンデス イニーゴ マルティン,
チー タット トー,
チー タット トー,
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National University of Singapore
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • B32B37/025Transfer laminating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/16Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
    • B32B37/18Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/10Removing layers, or parts of layers, mechanically or chemically
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/10Interconnection of layers at least one layer having inter-reactive properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • C01B32/184Preparation
    • C01B32/19Preparation by exfoliation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • C01B32/194After-treatment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16Homopolymers or copolymers of vinylidene fluoride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/246Vapour deposition
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0223Vinyl resin fibres
    • B32B2262/0238Vinyl halide, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2313/00Elements other than metals
    • B32B2313/04Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Laminated Bodies (AREA)
JP2017559270A 2015-02-03 2016-02-03 分極した強誘電ポリマーを使用するcvdグラフェンの無欠陥直接乾式剥離 Active JP6749942B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562111195P 2015-02-03 2015-02-03
US62/111,195 2015-02-03
PCT/SG2016/050057 WO2016126208A1 (fr) 2015-02-03 2016-02-03 Délaminage direct par voie sèche sans défauts de graphène déposé par dépôt chimique en phase vapeur à l'aide d'un polymère ferroélectrique polarisé

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JP2018512370A JP2018512370A (ja) 2018-05-17
JP6749942B2 true JP6749942B2 (ja) 2020-09-02

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JP (1) JP6749942B2 (fr)
KR (1) KR102256000B1 (fr)
CN (2) CN112194120B (fr)
WO (1) WO2016126208A1 (fr)

Families Citing this family (7)

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Publication number Priority date Publication date Assignee Title
CN106587040B (zh) * 2016-12-29 2019-02-15 浙江合特光电有限公司 石墨烯薄膜的衬底转移方法
GB2570127B (en) * 2018-01-11 2022-06-22 Paragraf Ltd A method of making graphene structures
EP3887159A1 (fr) * 2018-11-30 2021-10-06 The Research Foundation for The State University of New York Procédé pour transférer du graphène émanant de substrats métalliques
KR102319610B1 (ko) 2020-04-10 2021-10-29 서울대학교산학협력단 잔류물 없이 그래핀을 전사하는 방법
WO2022086449A1 (fr) * 2020-10-22 2022-04-28 National University Of Singapore Photodétecteur à polymère ferroélectrique, points quantiques et graphène
US20240164948A1 (en) * 2021-03-12 2024-05-23 National University Of Singapore A multilayer composite
KR102703806B1 (ko) * 2023-12-08 2024-09-04 한국화학연구원 분극 처리된 강유전성 물질이 코팅 또는 혼합된 복합 양극 활물질을 포함하는 건식 전극 제조방법, 건식 전극 및 이를 포함하는 전기화학 소자

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CN103201106B (zh) * 2010-11-10 2015-07-08 新加坡国立大学 具有永久偶极层的透明石墨烯导体
SG10201607900XA (en) * 2012-03-23 2016-11-29 Univ Singapore Photovoltaic cell with graphene-ferroelectric electrode
US9184553B2 (en) * 2012-06-06 2015-11-10 National University Of Singapore Gate-tunable graphene-ferroelectric hybrid structure for photonics and plasmonics
WO2014055040A1 (fr) * 2012-10-03 2014-04-10 National University Of Singapore Dispositifs à écran tactile utilisant des réseaux de graphène avec des films de fluorure de polyvinylidène
CN103318879B (zh) * 2013-06-28 2015-09-09 重庆墨希科技有限公司 基于转移薄膜的石墨烯制备方法
US20160304352A1 (en) * 2013-12-05 2016-10-20 National University Of Singapore Graphene tape
CN104016335B (zh) * 2014-05-30 2016-01-20 无锡格菲电子薄膜科技有限公司 一种石墨烯的转移方法
CN104016340B (zh) * 2014-06-30 2017-01-11 上海集成电路研发中心有限公司 一种转移石墨烯薄膜的方法

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JP2018512370A (ja) 2018-05-17
WO2016126208A1 (fr) 2016-08-11
KR20170110133A (ko) 2017-10-10
CN107406258A (zh) 2017-11-28
CN112194120B (zh) 2022-06-10
KR102256000B1 (ko) 2021-05-25
CN112194120A (zh) 2021-01-08

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