JP6700444B2 - プラスチック光学レンズ用ポリチオール組成物 - Google Patents

プラスチック光学レンズ用ポリチオール組成物 Download PDF

Info

Publication number
JP6700444B2
JP6700444B2 JP2019006000A JP2019006000A JP6700444B2 JP 6700444 B2 JP6700444 B2 JP 6700444B2 JP 2019006000 A JP2019006000 A JP 2019006000A JP 2019006000 A JP2019006000 A JP 2019006000A JP 6700444 B2 JP6700444 B2 JP 6700444B2
Authority
JP
Japan
Prior art keywords
polythiol
compound
polythiol compound
composition
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2019006000A
Other languages
English (en)
Japanese (ja)
Other versions
JP2019128596A (ja
JP2019128596A5 (enExample
Inventor
▲じょん▼▲みん▼ 沈
▲じょん▼▲みん▼ 沈
正煥 明
正煥 明
承模 洪
承模 洪
▲ひゅく▼熙 韓
▲ひゅく▼熙 韓
政煥 慎
政煥 慎
賢明 徐
賢明 徐
Original Assignee
エスケーシー カンパニー，リミテッド
エスケーシー カンパニー，リミテッド
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by エスケーシー カンパニー，リミテッド, エスケーシー カンパニー，リミテッド filed Critical エスケーシー カンパニー，リミテッド
Publication of JP2019128596A publication Critical patent/JP2019128596A/ja
Publication of JP2019128596A5 publication Critical patent/JP2019128596A5/ja
Application granted granted Critical
Publication of JP6700444B2 publication Critical patent/JP6700444B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3876—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/04—Polythioethers from mercapto compounds or metallic derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/12—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms
    • C07C321/14—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
    • C08G18/7642—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group containing at least two isocyanate or isothiocyanate groups linked to the aromatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate groups, e.g. xylylene diisocyanate or homologues substituted on the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041—Lenses
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/248—Catalysts containing metal compounds of tin inorganic compounds of tin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Eyeglasses (AREA)
JP2019006000A 2018-01-19 2019-01-17 プラスチック光学レンズ用ポリチオール組成物 Active JP6700444B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020180007050A KR101894921B1 (ko) 2018-01-19 2018-01-19 플라스틱 광학 렌즈용 폴리티올 조성물
KR10-2018-0007050 2018-01-19

Publications (3)

Publication Number Publication Date
JP2019128596A JP2019128596A (ja) 2019-08-01
JP2019128596A5 JP2019128596A5 (enExample) 2019-09-26
JP6700444B2 true JP6700444B2 (ja) 2020-05-27

Family

ID=63598262

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2019006000A Active JP6700444B2 (ja) 2018-01-19 2019-01-17 プラスチック光学レンズ用ポリチオール組成物

Country Status (6)

Country Link
US (1) US10435512B2 (enExample)
EP (1) EP3514187B1 (enExample)
JP (1) JP6700444B2 (enExample)
KR (1) KR101894921B1 (enExample)
CN (1) CN109627419B (enExample)
TW (1) TWI675821B (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101935031B1 (ko) * 2017-12-28 2019-01-03 에스케이씨 주식회사 플라스틱 광학 렌즈용 폴리티올 조성물
EP4209525A4 (en) * 2020-09-01 2025-06-25 SK pucore co., ltd. POLYTHIOL COMPOSITION, OPTICAL COMPOSITION AND OPTICAL PRODUCTS
KR102564990B1 (ko) * 2020-12-01 2023-08-07 에스케이씨 주식회사 폴리티올 조성물 및 이를 포함하는 중합성 조성물
KR102707088B1 (ko) * 2020-11-27 2024-09-19 에스케이피유코어 주식회사 폴리티올 조성물, 광학 조성물 및 광학 제품
GB2615967B (en) * 2020-11-27 2024-09-11 Sk Pucore Co Ltd Polythiol composition, optical composition and optical product
WO2022114719A1 (ko) * 2020-11-27 2022-06-02 에스케이씨 주식회사 폴리티올 조성물, 광학 조성물 및 광학 제품
CN114605605B (zh) * 2022-03-08 2023-03-24 益丰新材料股份有限公司 一种含有多硫醇组合物的光学材料组合物

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0351073B1 (en) * 1988-07-14 1994-09-21 MITSUI TOATSU CHEMICALS, Inc. Lens comprising a resin having a large refractive index and process for preparing the lens
FR2649711B1 (fr) * 1989-07-13 1993-01-22 Essilor Int Compositions de polymeres a base de polythiourethanes pour la fabrication de verres organiques
JPH0768326B2 (ja) * 1989-10-09 1995-07-26 三井東圧化学株式会社 ウレタン系レンズ用樹脂の製造方法
KR920007246B1 (ko) 1990-11-10 1992-08-28 현대자동차 주식회사 직접분사식 디이젤기관의 연소실
JP2695599B2 (ja) * 1993-09-29 1997-12-24 ホーヤ株式会社 ポリウレタンレンズの製造方法
US5608115A (en) * 1994-01-26 1997-03-04 Mitsui Toatsu Chemicals, Inc. Polythiol useful for preparing sulfur-containing urethane-based resin and process for producing the same
JPH09194558A (ja) 1996-01-23 1997-07-29 Mitsui Toatsu Chem Inc 含硫ウレタン系プラスチックレンズ
US5942158A (en) * 1998-03-09 1999-08-24 Ppg Industries Ohio, Inc. One-component optical resin composition
JP3974404B2 (ja) * 2002-01-15 2007-09-12 三井化学株式会社 ポリチオール、その製造方法、これを含有する重合性組成物、並びに樹脂及びレンズ
EP1878758B1 (en) * 2005-04-11 2013-06-05 Mitsui Chemicals, Inc. Polythiourethane polymerizable composition and method for producing optical resin by using same
AU2007246616B2 (en) * 2006-04-19 2012-01-19 Mitsui Chemicals, Inc. Process for production of (poly)thiol compound for use as optical material, and polymerizable composition comprising the compound
US7553925B2 (en) * 2006-05-05 2009-06-30 Ppg Industries Ohio, Inc. Thioether functional oligomeric polythiols and articles prepared therefrom
KR101400358B1 (ko) * 2012-05-23 2014-05-27 주식회사 케이오씨솔루션 신규한 폴리티올 화합물의 제조방법 및 이를 포함하는 광학재료용 중합성 조성물
JP5373226B1 (ja) 2012-08-14 2013-12-18 三井化学株式会社 ポリチオール組成物、光学材料用重合性組成物およびその用途
TW201506083A (zh) * 2013-06-18 2015-02-16 Mitsubishi Gas Chemical Co 光學材料用組成物
CN106458876B (zh) * 2014-06-09 2018-06-05 可奥熙搜路司有限公司 新的硫醇化合物和包含其的聚合性组合物
US20180016415A1 (en) * 2015-02-02 2018-01-18 Mitsui Chemicals, Inc. Polymerizable composition for optical material, optical material, and use thereof
CN107207339B (zh) * 2015-02-05 2021-02-19 积水化学工业株式会社 夹层玻璃用中间膜及夹层玻璃
KR102512167B1 (ko) * 2015-03-10 2023-03-21 가부시끼가이샤 도꾸야마 포토크로믹 경화체의 제조 방법
JP6335392B2 (ja) * 2015-06-24 2018-05-30 三井化学株式会社 ペンタエリスリトールメルカプトカルボン酸エステルの製造方法、重合性組成物、樹脂、光学材料およびレンズ
KR101831892B1 (ko) * 2016-06-30 2018-02-26 에스케이씨 주식회사 폴리티오우레탄계 광학 재료용 중합성 조성물
US11279673B2 (en) * 2016-07-14 2022-03-22 Skc Co., Ltd. Aromatic polythiol compound for optical material
JP6632493B2 (ja) * 2016-08-05 2020-01-22 ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ ポリチオール化合物の製造方法、硬化性組成物の製造方法、および硬化物の製造方法
JP6633990B2 (ja) * 2016-08-08 2020-01-22 ホヤ レンズ タイランド リミテッドＨＯＹＡ Ｌｅｎｓ Ｔｈａｉｌａｎｄ Ｌｔｄ ポリチオール化合物の製造方法、硬化性組成物の製造方法、および硬化物の製造方法

Also Published As

Publication number Publication date
JP2019128596A (ja) 2019-08-01
EP3514187B1 (en) 2020-07-29
TWI675821B (zh) 2019-11-01
US10435512B2 (en) 2019-10-08
KR101894921B1 (ko) 2018-09-04
EP3514187A1 (en) 2019-07-24
US20190225755A1 (en) 2019-07-25
CN109627419A (zh) 2019-04-16
TW201932449A (zh) 2019-08-16
CN109627419B (zh) 2020-04-14

Similar Documents

Publication Publication Date Title
TWI675821B (zh) 用於塑膠光學透鏡之多元硫醇組成物
KR101807584B1 (ko) 폴리티올화합물의 제조방법과 이를 이용한 우레탄계 광학재료용 수지 조성물
KR101946181B1 (ko) 중합성 조성물, 투명 수지, 광학 재료, 플라스틱 렌즈 및 투명 수지의 제조 방법
JP6324286B2 (ja) 重合性組成物、透明樹脂、光学材料、プラスチックレンズおよび透明樹脂の製造方法
BR112014025570B1 (pt) composição de politiol, composição polimerizável para material óptico e uso das mesmas
EP0329386A2 (en) S-alkyl thiocarbamate base resin, plastic lens comprising the resin, and process for making the lens
TWI698420B (zh) 用於塑膠光學透鏡之多元硫醇組成物
KR101802479B1 (ko) 고리개환을 통해 사슬연장된 폴리티올화합물과 그 제조 방법 및 이를 이용한 우레탄계 광학재료용 수지 조성물
CN104321308A (zh) 新聚硫醇化合物的制造方法及包括此的光学材料用聚合性组合物
JPWO2007052329A1 (ja) ペンタエリスリトールメルカプトカルボン酸エステルの製造方法、それにより得られたペンタエリスリトールメルカプトカルボン酸エステル、およびその用途
JP2019524725A (ja) 光学材料のための芳香族ポリチオール化合物
JPH0912663A (ja) 光重合含硫ウレタン系プラスチックレンズ
JP6957445B2 (ja) 光学材料用重合性組成物
JPH05208950A (ja) メルカプト化合物、その製造方法、及びそれを用いた含硫ウレタン系樹脂及びレンズ
KR101922168B1 (ko) 플라스틱 렌즈용 중합성 조성물
KR101996981B1 (ko) 플라스틱 렌즈용 중합성 조성물
JP2018058922A (ja) 光学材料の製造方法
KR20210121873A (ko) 티오우레탄계 광학재료용 수지 조성물과 티오우레탄계 광학재료용 수지의 제조방법
KR20190042190A (ko) 공정성이 개선된 폴리티오우레탄계 화합물의 제조방법

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20190306

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20190306

A871 Explanation of circumstances concerning accelerated examination

Free format text: JAPANESE INTERMEDIATE CODE: A871

Effective date: 20190306

A975 Report on accelerated examination

Free format text: JAPANESE INTERMEDIATE CODE: A971005

Effective date: 20190425

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20190514

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20190813

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20191105

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20200205

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20200407

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20200430

R150 Certificate of patent or registration of utility model

Ref document number: 6700444

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250