JP6532664B2 - 高反応性オレフィン機能性ポリマーを作製する重合開始系および方法 - Google Patents

高反応性オレフィン機能性ポリマーを作製する重合開始系および方法 Download PDF

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JP6532664B2
JP6532664B2 JP2014208290A JP2014208290A JP6532664B2 JP 6532664 B2 JP6532664 B2 JP 6532664B2 JP 2014208290 A JP2014208290 A JP 2014208290A JP 2014208290 A JP2014208290 A JP 2014208290A JP 6532664 B2 JP6532664 B2 JP 6532664B2
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hydrocarbyl
lewis base
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JP2015074785A5 (enExample
JP2015074785A (ja
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ファウスト ルドルフ
ファウスト ルドルフ
クマール ラジーフ
クマール ラジーフ
エマート ヤコブ
エマート ヤコブ
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ユニバーシティ オブ マサチューセッツ
ユニバーシティ オブ マサチューセッツ
インフィニウム インターナショナル リミテッド
インフィニウム インターナショナル リミテッド
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
JP2014208290A 2013-10-11 2014-10-09 高反応性オレフィン機能性ポリマーを作製する重合開始系および方法 Active JP6532664B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/052,490 2013-10-11
US14/052,490 US9631038B2 (en) 2013-10-11 2013-10-11 Polymerization initiating system and method to produce highly reactive olefin functional polymers

Publications (3)

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JP2015074785A JP2015074785A (ja) 2015-04-20
JP2015074785A5 JP2015074785A5 (enExample) 2019-01-31
JP6532664B2 true JP6532664B2 (ja) 2019-06-19

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US (1) US9631038B2 (enExample)
EP (1) EP2860206B1 (enExample)
JP (1) JP6532664B2 (enExample)
KR (1) KR102065510B1 (enExample)
CN (1) CN104558304B (enExample)
CA (1) CA2866525C (enExample)
ES (1) ES2737074T3 (enExample)
SG (1) SG10201405955XA (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9156924B2 (en) * 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9771442B2 (en) * 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
SG11201806357PA (en) * 2016-02-16 2018-08-30 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CA3014685C (en) * 2016-02-16 2024-05-28 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
SG11201810402PA (en) * 2016-07-22 2018-12-28 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CN106496538B (zh) * 2016-10-19 2021-12-03 安徽红太阳新材料有限公司 一种高分子量聚己内酯的合成方法
US10167352B1 (en) * 2017-06-28 2019-01-01 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10047174B1 (en) 2017-06-28 2018-08-14 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10174138B1 (en) * 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers
KR102301668B1 (ko) 2018-07-27 2021-09-14 주식회사 엘지화학 폴리부텐 올리고머의 제조 방법
US10829573B1 (en) 2019-05-21 2020-11-10 Infineum International Limited Method for forming highly reactive olefin functional polymers
CN113661185B (zh) 2019-08-19 2023-12-29 株式会社Lg化学 有机硼酸盐类催化剂、使用它制备异丁烯低聚物的方法和由此制备的异丁烯低聚物
EP3943518A1 (en) 2020-07-22 2022-01-26 Indian Oil Corporation Limited Polymerization catalyst system and process to produce highly reactive polyisobutylene

Family Cites Families (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2682531A (en) 1951-03-31 1954-06-29 Standard Oil Dev Co Zirconium tetrachloride-ether complexes as low temperature polymerization catalyst
JPS4839599A (enExample) 1971-09-20 1973-06-11
US3850897A (en) 1971-11-26 1974-11-26 Snam Progetti Procedure for the production of polymers and copolymers of isobutylene
DE2702604C2 (de) 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
CA2019908A1 (en) 1989-12-28 1991-06-28 Rudolf Lukas Graft copolymers and the method and initiation system for preparation thereof
GB9025839D0 (en) 1990-11-28 1991-01-09 Bp Chem Int Ltd Cationic polymerisation of 1-olefins
US5286823A (en) 1991-06-22 1994-02-15 Basf Aktiengesellschaft Preparation of highly reactive polyisobutenes
US5350819A (en) 1993-02-19 1994-09-27 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts
WO1994028036A1 (en) 1993-05-20 1994-12-08 Exxon Chemical Patents Inc. Heterogeneous lewis acid-type catalysts
JP3203917B2 (ja) 1993-11-30 2001-09-04 ソニー株式会社 プロジェクタ用アクティブマトリクス液晶表示パネル
DE69513810T2 (de) 1994-03-31 2000-05-25 Infineum Usa Lp Polymerisationsreaktionen von kohlenwasserstoffen mit lewissäure enthaltende trägerkatalysatoren
US5710225A (en) 1996-08-23 1998-01-20 The Lubrizol Corporation Heteropolyacid catalyzed polymerization of olefins
DE19704482A1 (de) 1997-02-06 1998-08-13 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
DE19734176A1 (de) 1997-08-07 1999-02-11 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
US6407186B1 (en) 1997-12-12 2002-06-18 Basf Aktiengesellschaft Method for producing low-molecular, highly reactive polyisobutylene
CA2330529A1 (en) 1998-06-12 1999-12-16 Univation Technologies Llc Olefin polymerization process using activated lewis acid-base complexes
US6346585B1 (en) 1999-06-24 2002-02-12 The Lubrizol Corporation Ammonium heteropolyacid catalized polymerization of olefins
US6407170B1 (en) 1999-06-24 2002-06-18 The Lubrizol Corporation Dispersants prepared from high polydispersity olefin polymers
JP2001017864A (ja) * 1999-07-06 2001-01-23 Kawamura Inst Of Chem Res エポキシ化触媒及び該触媒を用いたオレフィン類のエポキシ化物の製造方法
US6562913B1 (en) 1999-09-16 2003-05-13 Texas Petrochemicals Lp Process for producing high vinylidene polyisobutylene
DE19952030A1 (de) 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung von hochreaktiven Polyisobutenen
US6858690B2 (en) 1999-11-15 2005-02-22 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
JP3735026B2 (ja) * 2000-02-17 2006-01-11 住友化学株式会社 シタロプラムの製造方法、およびその中間体とその製造方法
DE10035298A1 (de) 2000-07-18 2002-01-31 Basf Ag Verfahren zur Herstellung von Polysiobutenen
WO2002040553A1 (de) 2000-11-17 2002-05-23 Basf Aktiengesellschaft Verfahren zur desaktivierung und rückgewinnung von bortrifluorid bei der herstellung von polyisobutenen
DE10061715A1 (de) 2000-12-12 2002-06-13 Basf Ag Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens
DE10118182A1 (de) 2001-04-11 2002-10-17 Basf Ag Verfahren zur Aufarbeitung eines flüssigen Reaktionsaustrages der kationischen Polymerisation von Isobuten
DE10211418A1 (de) 2002-03-15 2003-09-25 Bayer Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
AU2003254173A1 (en) 2002-08-13 2004-02-25 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
AU2003297458A1 (en) 2002-12-20 2004-07-22 Exxonmobil Chemical Patents Inc. Polymerization processes
CN100402558C (zh) 2002-12-20 2008-07-16 埃克森美孚化学专利公司 聚合方法
DE10303212A1 (de) 2003-01-24 2004-08-05 Basf Ag Verfahren zur Herstellung von Polyisobuten
DE10356768A1 (de) 2003-12-04 2005-07-07 Universität Karlsruhe (TH) - Körperschaft des öffentlichen Rechts Verfahren zur Herstellung von Salzen schwach koordinierender Anionen, derartige Salze sowie deren Verwendung
US20080269440A1 (en) 2005-01-05 2008-10-30 Rudolf Faust Polymerization of Olefins
DE102005055818A1 (de) 2005-11-21 2007-05-24 Basf Ag Verfahren zur Herstellung von hochreaktiven Isobutenhomo- oder -copolymeren mittels metallhaltiger Katalysatorkomplexe
WO2008095933A1 (de) 2007-02-09 2008-08-14 Basf Se Verfahren zur polymerisation von ethylenisch ungesättigten monomeren
US8394897B2 (en) 2008-03-25 2013-03-12 Chevron Oronite Company Llc Production of vinylidene-terminated polyolefins via quenching with monosulfides
US20090258803A1 (en) 2008-04-14 2009-10-15 Harrison James J Copolymers made with quasi-living polyolefins and unsaturated acidic reagents, dispersants using same, and methods of making same
US8063154B2 (en) 2008-06-24 2011-11-22 The University Of Southern Mississippi Preparation of exo-olefin terminated polyolefins via quenching with alkoxysilanes or ethers
CN101613423B (zh) * 2008-06-27 2011-05-18 北京化工大学 一种用于合成高反应活性聚异丁烯的引发体系
US8530577B2 (en) 2008-06-30 2013-09-10 Fina Technology, Inc. Compatibilized polypropylene heterophasic copolymer and polylactic acid blends for injection molding applications
WO2010139684A1 (de) 2009-06-05 2010-12-09 Basf Se Verbindung aus einem protonierten aromaten und einem schwach koordinierenden anion als polymerisationskatalysator für isobuten oder ein isobuten-haltiges monomerengemisch
CN101955558B (zh) 2009-07-15 2013-03-13 北京化工大学 制备高反应活性聚异丁烯及其共聚物的引发体系
EP2496613B1 (de) 2009-11-04 2015-07-01 Basf Se Verfahren zur herstellung von homo- oder copolymeren
US8349977B2 (en) 2010-02-17 2013-01-08 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
BR112012020302B1 (pt) * 2010-02-17 2021-08-17 Basf Se Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade
US9562117B2 (en) 2010-11-30 2017-02-07 Basf Se Preparation of derivatives of isobutene copolymers
BR112014002551A2 (pt) 2011-08-11 2017-03-14 Basf Se processo para preparar homo ou copolímeros de isobuteno de alta reatividade, e, polímeros de isobuteno
US8697820B2 (en) * 2011-08-11 2014-04-15 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
US9034998B2 (en) 2011-12-16 2015-05-19 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9156924B2 (en) * 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9771442B2 (en) 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers

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CN104558304A (zh) 2015-04-29
CA2866525A1 (en) 2015-04-11
CA2866525C (en) 2020-03-24
KR20150042739A (ko) 2015-04-21
US9631038B2 (en) 2017-04-25
JP2015074785A (ja) 2015-04-20
US20150105525A1 (en) 2015-04-16
CN104558304B (zh) 2018-08-10
ES2737074T3 (es) 2020-01-10
EP2860206A1 (en) 2015-04-15
EP2860206B1 (en) 2019-04-17
KR102065510B1 (ko) 2020-01-13
SG10201405955XA (en) 2015-05-28

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