JP6372840B2 - 脱水素触媒及びその製造方法 - Google Patents

脱水素触媒及びその製造方法 Download PDF

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JP6372840B2
JP6372840B2 JP2017505224A JP2017505224A JP6372840B2 JP 6372840 B2 JP6372840 B2 JP 6372840B2 JP 2017505224 A JP2017505224 A JP 2017505224A JP 2017505224 A JP2017505224 A JP 2017505224A JP 6372840 B2 JP6372840 B2 JP 6372840B2
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catalyst
alumina
weight
parts
zinc oxide
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JP2017523910A5 (enExample
JP2017523910A (ja
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ジェヨン リ
ジェヨン リ
イネ キム
イネ キム
スンヒ カン
スンヒ カン
ヨンジョン ソ
ヨンジョン ソ
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ロッテ ケミカル コーポレーション
ロッテ ケミカル コーポレーション
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/63—Platinum group metals with rare earths or actinides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2017505224A 2014-07-28 2015-07-23 脱水素触媒及びその製造方法 Expired - Fee Related JP6372840B2 (ja)

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Application Number Priority Date Filing Date Title
KR1020140095906A KR101644695B1 (ko) 2014-07-28 2014-07-28 탈수소 촉매 및 그 제조방법
KR10-2014-0095906 2014-07-28
PCT/KR2015/007671 WO2016017994A1 (ko) 2014-07-28 2015-07-23 탈수소 촉매 및 그 제조방법

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JP2017523910A JP2017523910A (ja) 2017-08-24
JP2017523910A5 JP2017523910A5 (enExample) 2018-06-14
JP6372840B2 true JP6372840B2 (ja) 2018-08-15

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US (1) US20170151553A1 (enExample)
EP (1) EP3175918A4 (enExample)
JP (1) JP6372840B2 (enExample)
KR (1) KR101644695B1 (enExample)
CN (1) CN106660015A (enExample)
WO (1) WO2016017994A1 (enExample)

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KR101716170B1 (ko) * 2015-11-10 2017-03-14 희성촉매 주식회사 안정화 활성금속 복합체를 이용한 직쇄형 경질탄화수소류 탈수소화 촉매 제조방법
RU2705574C1 (ru) 2018-02-27 2019-11-08 Индийская Нефтяная Корпорация Лимитэд Каталитическая композиция для превращения алканов в алкены и способ ее получения
JP2019189585A (ja) * 2018-04-27 2019-10-31 Ｊｘｔｇエネルギー株式会社 不飽和炭化水素の製造方法
CN110496634B (zh) * 2018-05-17 2021-09-21 中国石油化工股份有限公司 异丁烷脱氢催化剂及其制备方法以及异丁烷脱氢制异丁烯的方法
CN110496630B (zh) * 2018-05-17 2021-10-19 中国石油化工股份有限公司 异丁烷脱氢催化剂及其制备方法以及异丁烷脱氢制异丁烯的方法
CN110813284A (zh) * 2018-08-14 2020-02-21 中国石油化工股份有限公司 载体为硅胶的异丁烷脱氢催化剂及其制备方法和应用
CN111408370B (zh) * 2019-01-08 2022-03-22 天津大学 一种负载型PtZn金属间合金催化剂及其制备方法和应用
CN109761734A (zh) * 2019-01-21 2019-05-17 中石化上海工程有限公司 石脑油及乙烷裂解前脱乙烷与pdh耦合的方法
CN110142044B (zh) * 2019-06-03 2022-07-26 北京柯通科技有限公司 一种石油树脂加氢催化剂及其制备方法和应用
US20210053034A1 (en) * 2019-08-23 2021-02-25 Uop Llc Dehydrogenation catalyst composition
CN112473720A (zh) * 2019-09-12 2021-03-12 中国石油化工股份有限公司 异丁烷脱氢制异丁烯催化剂及其制备方法和应用
EP3858478A1 (en) * 2020-01-31 2021-08-04 SCG Chemicals Co., Ltd. Stable, high selectivity catalysts and catalyst systems, and processes for their use
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KR102332406B1 (ko) * 2020-03-10 2021-11-26 에스케이가스 주식회사 알칸족 가스로부터 올레핀 제조용 탈수소촉매 및 그 제조방법
US11000832B1 (en) * 2020-03-13 2021-05-11 Uop Llc Dehydrogenation catalyst with minimized aromatic production
CN113877577B (zh) * 2020-07-02 2024-01-30 中国石油化工股份有限公司 催化剂及其制备方法和提高烷烃转化率的方法
CN115337955B (zh) * 2021-05-12 2024-02-20 中国石油化工股份有限公司 新型脱氢催化剂及其制备方法以及在异丁烷脱氢制异丁烯中的应用
CN115999532B (zh) * 2021-10-21 2025-02-14 中国石油化工股份有限公司 丙烷脱氢制丙烯催化剂及其制备方法
CN114733521B (zh) * 2022-04-11 2024-06-14 恩索(苏州)科技有限公司 一种双晶型载体的烷烃非氧化脱氢催化剂
KR102757431B1 (ko) 2022-06-15 2025-01-21 충북대학교 산학협력단 프로판 탈수소화 반응을 위한 Pt가 담지된 아연-실리케이트 촉매의 제조방법 및 이에 따라 제조된 촉매
CN115254136A (zh) * 2022-07-08 2022-11-01 润和科华催化剂(上海)有限公司 稀土金属和碱土金属改性的低碳烷烃脱氢催化剂及其制备方法和应用
CN115155613B (zh) * 2022-08-04 2023-12-05 西南化工研究设计院有限公司 一种环境友好型丙烷脱氢新型催化剂的制备方法及其应用
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KR101644695B1 (ko) 2016-08-01
US20170151553A1 (en) 2017-06-01
WO2016017994A1 (ko) 2016-02-04
EP3175918A1 (en) 2017-06-07
EP3175918A4 (en) 2018-04-18
KR20160013722A (ko) 2016-02-05
JP2017523910A (ja) 2017-08-24
CN106660015A (zh) 2017-05-10

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