JP6321543B2 - ナノ粒子をガラスに結合する方法 - Google Patents
ナノ粒子をガラスに結合する方法 Download PDFInfo
- Publication number
- JP6321543B2 JP6321543B2 JP2014541218A JP2014541218A JP6321543B2 JP 6321543 B2 JP6321543 B2 JP 6321543B2 JP 2014541218 A JP2014541218 A JP 2014541218A JP 2014541218 A JP2014541218 A JP 2014541218A JP 6321543 B2 JP6321543 B2 JP 6321543B2
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- Prior art keywords
- binder
- glass
- alkali
- nanoparticle
- layer
- Prior art date
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Images
Classifications
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- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/068—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of particles
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
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- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
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- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
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- C—CHEMISTRY; METALLURGY
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
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- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
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Description
本明細書および以下のクレーム中においては、多くの用語が言及されており、これらの用語は以下の意味を有するものとして定義される。
可溶性ケイ酸塩は、概してさまざまな割合のアルカリ金属とSiO2から製造された水溶性ガラスである。表1および2に示されているのは、SiO2:Na2O比が2.00〜3.22で変動しているケイ酸ナトリウム(「NaSil」)である(PQ Corporation、Sigma−Aldrich)。約2.5以上のSiO2/Na2O比を有するNaSilは、ナノ粒子接着力に関し優れた性能を示した。26.5%のSiO2百分率と2.5のSiO2/Na2O比を有するケイ酸ナトリウム(5−xシリーズ)は、Sigma Aldrich製であり、27.2%のSiO2百分率と3.2のSiO2/Na2O比を有するケイ酸ナトリウムE(56−Xシリーズ)は、PQ製である。恒常で安定したpH(11〜12)を確保しながら異なるNaSilを異なる濃度まで希釈し、コーティング方法の中で使用する。
図4は、100〜250nmのシリカナノ粒子でコーティングされた表面について使用された異なる重量百分率のアルカリ結合剤(調合物5−2〜5−5)を示す(例えばIPA ST−ZL(70〜100nm)Nissan Chemical USA;250nmのシリカ粉末、Fiber optic center;約120〜150nmの水中シリカ分散、microspheres−nanospheres.com製)。一次シリカナノ粒子層は典型的に、1〜5重量%のシリカ/水またはIPA分散液を用いてディップ/スピンコーティングする。濃度、引抜速度およびスピン速度などを変動させることにより、単層コーティングを得る。一次層の乾燥後、結合剤を表面上にディップコーティングする。さまざまな濃度およびディップ引抜速度およびコーティング時間を用いて、結合剤の厚みを変動させる。図1Aおよび1Bは、同じ速度でディップコーティングした2つの異なる濃度の結合剤のSEMを示し、図5はこれらの試料についての対応するデータを示す。
次に、試料を500℃から630℃まで変動する温度で1時間熱処理する。Dow Corning(登録商標)DC2634を用いてキャッピング層で表面をコーティングした後に、耐久性を測定する。ナノ粒子/結合剤コーティングは、疎油性(>90°)でなければならず、コーティングが拭取試験を乗り切った場合疎油性を保ち続けなければならない。接触角測定のために使用されるゴニオメータは、Drop Shape analyzer DSA100、Kruss GmbH、Germanyとして公知である。
ナノ粒子および結合剤の被着および熱処理の後、試料を、その特定的ガラス組成について確立されたIOX手順に付す。図5は、ナノ粒子/結合剤組成物のイオン交換能を表わすコーティング側と非コーティング側上のCSおよびDOLデータを示す。CSおよびDOLの値は、KNO3を用いてイオン交換されている基準2318に匹敵するものである。
図7は、HAZE−GARD PLUS(登録商標)(BYK Additives and Instruments,Inc)由来の異なる直径のナノ粒子/結合剤コーティングについて得た曇り度および透過率%を列挙する。この実施例中で使用されたNaSil結合剤は、SiO2/Na2O比が3.2の異なるケイ酸ナトリウムである。図は同様に、耐スクラッチ性データも列挙している。耐スクラッチ性は、鉛筆硬度キットを用いて測定し、典型的に耐スクラッチ性は、5B<4B<3B<…B<HB<1H<2H…<9Hの通りに増大する。耐スクラッチ性は、透過率%に不利な影響を及ぼさないような形でより大きな粒子サイズ上により厚い結合剤を付加することによって改善されている。図2および3は、鉛筆スクラッチ試験を行った場合の画像を示す。図2は、3B鉛筆(軟質)の使用を示す画像であり、ここで黒鉛のマークは構造上に転写されているが、スクラッチの形跡は全く無く、図3は5H鉛筆での画像を示し、ここでははっきりとスクラッチマークが見える。
ナノ粒子の表面上にアルカリケイ酸塩の結合剤と共にペルフルオロポリエーテルシランのキャッピング層(例えばDow Corning(登録商標)DC2634)を使用することにより、図8で示されている通り、鉛筆スクラッチデータが著しく改善されるように思われた。この実施例では、NaSil結合剤は、キャッピング層に対するプライマ層として作用した。アルカリケイ酸塩を単独で使用すると、鉛筆硬度試験においてナノ粒子層上で測定された場合に、「hb」硬度を用いた時に見られるスクラッチが結果としてもたらされた。しかしながら、アルカリケイ酸塩とキャッピング層を組合せると、結果として、はるかに高い硬度でのスクラッチ発生がもたらされ、表面は8hの鉛筆硬度での試験に合格している。このような実験で使用された有機結合剤は、キャッピング層のように作用するかもしれず、一次層中にナトリウムを添加することで、さらに急速に硬化されるかもしれない。この方法は、試料のイオン交換の前後いずれにおいて使用してもよい。
Claims (5)
- a.ガラスまたはガラスセラミックを含む支持要素と、
b.ナノ粒子層と、
c.結合剤と、
d.前記結合剤および前記ナノ粒子層の上に配置され、ペルフルオロポリエーテルシランを有するキャッピング層と、
を含む構造であって、
前記結合剤は本質的に、二酸化ケイ素およびアルカリケイ酸塩、アルカリホウ酸塩、アルカリリン酸塩またはその組合せを含む無機網状組織構造から成り、
前記網状組織構造はガラスとして固結するものであり、
前記網状組織構造の前記ガラスはイオン交換プロセスによる圧縮応力層を有するものである、
ことを特徴とする、構造。 - 二酸化ケイ素と、アルカリケイ酸塩、アルカリホウ酸塩またはアルカリリン酸塩との比が0.05:1〜20.0:1であることを特徴とする請求項1に記載の構造。
- 前記結合剤が0.1〜40.0重量パーセントの二酸化ケイ素を含むことを特徴とする請求項1または2に記載の構造。
- a)ガラスまたはガラスセラミックを含む支持要素を提供するステップと、
b)前記支持要素上にナノ粒子層を形成するステップと、
c)前記支持要素上に、二酸化ケイ素とアルカリケイ酸塩、アルカリホウ酸塩またはアルカリリン酸塩とを含む結合剤を形成するステップと、
d)前記結合剤および前記ナノ粒子層上に、ペルフルオロポリエーテルシランを有するキャッピング層を形成するステップと、
e)前記ナノ粒子層、前記結合剤および必要に応じて前記キャッピング層を含む前記支持要素を、前記結合剤が網状組織構造を形成できる温度まで加熱するステップであって、当該網状組織構造は、本質的に二酸化ケイ素並びに、アルカリケイ酸塩、アルカリホウ酸塩、またはアルカリリン酸塩から成り、ガラスとして固結するものである、ステップと、
f)前記網状組織構造の前記ガラスを、当該ガラスが圧縮応力層を有するようにイオン交換プロセスに付すステップ、
を含むことを特徴とする請求項1に記載の構造を形成する方法。 - 前記結合剤の形成ステップまたは前記ナノ粒子層の形成ステップが、ディップコーティング、スピンコーティング、スロットコーティング、ラングミュア・ブロジェット被着、エレクトロスプレーイオン化、直接ナノ粒子被着、蒸着、化学蒸着、真空濾過、フレーム溶射、エレクトロスプレー、噴霧堆積法、電着、スクリーン印刷、クローズスペース昇華法、ナノインプリントリソグラフィ、インサイチュ成長法、マイクロ波援用化学蒸着、レーザーアブレーション、アーク放電または化学エッチングを含むことを特徴とする請求項4に記載の方法。
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US9206322B2 (en) * | 2013-09-27 | 2015-12-08 | National Taiwan University Of Science And Technology | Non-fluorinated coating materials with anti-fingerprint property, and evaluation method thereof |
US20150099110A1 (en) * | 2013-10-07 | 2015-04-09 | Corning Incorporated | Glass articles and methods for controlled bonding of glass sheets with carriers |
JP6469108B2 (ja) | 2013-11-19 | 2019-02-13 | 三星電子株式会社Samsung Electronics Co.,Ltd. | ルミネッセンス粒子、これを含む材料および製品、ならびに方法 |
SG11201608442TA (en) | 2014-04-09 | 2016-11-29 | Corning Inc | Device modified substrate article and methods for making |
US10126485B2 (en) | 2014-05-21 | 2018-11-13 | Samsung Electronics Co., Ltd. | Optical film and lighting and display products including same |
DE102014013528B4 (de) * | 2014-09-12 | 2022-06-23 | Schott Ag | Beschichtetes Glas-oder Glaskeramiksubstrat mit beständigen multifunktionellen Oberflächeneigenschaften, Verfahren zu dessen Herstellung und dessen Verwendung |
US10338276B2 (en) | 2014-09-12 | 2019-07-02 | Fujifilm Corporation | Antireflective film, polarizing plate, cover glass, image display device, and method of manufacturing antireflective film |
CN104464119A (zh) * | 2014-12-10 | 2015-03-25 | 福建联迪商用设备有限公司 | 一种防指纹残留的pos机及制备方法 |
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JPWO2018025818A1 (ja) | 2016-08-02 | 2019-02-28 | 富士フイルム株式会社 | 積層体、反射防止物品、及びそれらの製造方法 |
TW201825623A (zh) | 2016-08-30 | 2018-07-16 | 美商康寧公司 | 用於片材接合的矽氧烷電漿聚合物 |
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WO2019036710A1 (en) | 2017-08-18 | 2019-02-21 | Corning Incorporated | TEMPORARY BINDING USING POLYCATIONIC POLYMERS |
US11084100B2 (en) * | 2017-08-23 | 2021-08-10 | University Of Central Florida Research Foundation, Inc. | Laser-assisted manufacturing system and associated method of use |
JP7431160B2 (ja) | 2017-12-15 | 2024-02-14 | コーニング インコーポレイテッド | 基板を処理するための方法および結合されたシートを含む物品を製造するための方法 |
WO2019126245A1 (en) * | 2017-12-20 | 2019-06-27 | University Of Florida Research Foundation | Methods of forming an antireflective layer on a complex substrate and complex substrates having the antireflective layer |
CN110132668B (zh) * | 2019-04-28 | 2022-02-15 | 西安培华学院 | 一种常规载玻片超疏水处理方法 |
CN110183113B (zh) * | 2019-05-22 | 2022-03-22 | 湖南天羿领航科技有限公司 | 防眩光玻璃的制备方法 |
PL242694B1 (pl) * | 2019-10-29 | 2023-04-11 | Ml System Spolka Akcyjna | Sposób otrzymywania selektywnej warstwy ognioodpornej modyfikowanej nanocząsteczkami półprzewodnikowymi oraz wypełniania tą aktywną warstwą komory lub komór szyby zespolonej i szyba zespolona zawierająca tą lub te warstwy |
CN112853313A (zh) * | 2019-11-28 | 2021-05-28 | 康宁股份有限公司 | 耐久的高接触角易清洁涂层 |
CN111039572A (zh) * | 2019-12-30 | 2020-04-21 | 华南理工大学 | 一种纳米颗粒薄膜及其制备方法与应用 |
US20220194590A1 (en) * | 2020-12-18 | 2022-06-23 | B/E Aerospace, Inc. | Copper plated touch surfaces |
US20230133694A1 (en) * | 2021-10-28 | 2023-05-04 | Kismet Technologies Llc | Electronic device with self-disinfecting touch screen and method of manufacture |
DE102022121667A1 (de) * | 2022-08-26 | 2024-02-29 | MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. | Fixierung und/oder Schutz von Strukturen mittels Aufbringung einer optisch transparenten Deckschicht auf einer Oberfläche eines Substrats, welches eine Komponente eines Mikroskops oder einer ein Mikroskop umfassenden Vorrichtung ist |
Family Cites Families (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3630704A (en) | 1969-03-10 | 1971-12-28 | Corning Glass Works | Method for strengthening glass articles |
US3630730A (en) | 1970-06-01 | 1971-12-28 | Eastman Kodak Co | Diffusion transfer processes and elements comprising dye developers and bis-sulfonyl alkane speed-increasing agents |
US3804650A (en) * | 1970-06-12 | 1974-04-16 | Corning Glass Works | Silicate binders |
JPS5491514A (en) * | 1977-12-29 | 1979-07-20 | Matsushita Electric Works Ltd | Production of milky glass |
JPS58145642A (ja) | 1982-02-22 | 1983-08-30 | Hoya Corp | ガラス強化法 |
JPH05170488A (ja) | 1991-12-25 | 1993-07-09 | Toyota Motor Corp | 撥水ガラス |
US5717031A (en) * | 1995-06-21 | 1998-02-10 | Lord Corporation | Aqueous adhesive compositions |
US5863322A (en) | 1996-09-26 | 1999-01-26 | Akzo-Pq Silica Vof | Adhesive compositions comprising water glass, an oligosaccharide, and a mono-, di- or tri-saccharide |
DE10016485A1 (de) | 2000-04-01 | 2001-10-11 | Dmc2 Degussa Metals Catalysts | Glas-, Keramik- und Metall-Substrate mit selbstreinigender Oberfläche, Verfahren zu deren Herstellung und deren Verwendung |
JP4788852B2 (ja) | 2000-07-25 | 2011-10-05 | 住友金属鉱山株式会社 | 透明導電性基材とその製造方法およびこの製造方法に用いられる透明コート層形成用塗布液と透明導電性基材が適用された表示装置 |
DE10063739B4 (de) | 2000-12-21 | 2009-04-02 | Ferro Gmbh | Substrate mit selbstreinigender Oberfläche, Verfahren zu deren Herstellung und deren Verwendung |
JP2002234754A (ja) | 2001-02-02 | 2002-08-23 | Nippon Sheet Glass Co Ltd | 強化された機能性膜被覆ガラス物品の製造方法 |
US6706551B2 (en) | 2001-02-07 | 2004-03-16 | Agfa-Gevaert | Thin film inorganic light emitting diode |
US6737293B2 (en) | 2001-02-07 | 2004-05-18 | Agfa-Gevaert | Manufacturing of a thin film inorganic light emitting diode |
JP4149924B2 (ja) * | 2001-09-11 | 2008-09-17 | スリーエム イノベイティブ プロパティズ カンパニー | 耐汚染性ナノ複合材ハードコートおよびその製造方法 |
US6682872B2 (en) | 2002-01-22 | 2004-01-27 | International Business Machines Corporation | UV-curable compositions and method of use thereof in microelectronics |
US20060147699A1 (en) | 2002-10-03 | 2006-07-06 | Alberta Research Council Inc. | Protective ceramic coating |
DE10256265A1 (de) | 2002-12-03 | 2004-06-24 | Basf Coatings Ag | Beschichtungsstoff, Verfahren zu seiner Herstellung und seine Verwendung zur Herstellung haftfester, korrosionshemmender Beschichtungen |
DE10301984B4 (de) | 2003-01-15 | 2008-07-03 | Hahn-Meitner-Institut Berlin Gmbh | Flexible, atmungsaktive Polymerfolie |
DE10313630A1 (de) * | 2003-03-26 | 2004-10-07 | BSH Bosch und Siemens Hausgeräte GmbH | Glasartige Bedruckung mittels Siebdruck |
DE10325768A1 (de) | 2003-06-05 | 2004-12-23 | Chemetall Gmbh | Beschichtungssystem für Glasoberflächen, Verfahren zu dessen Herstellung und dessen Anwendung |
US7052618B2 (en) | 2004-01-28 | 2006-05-30 | Agilent Technologies, Inc. | Nanostructures and methods of making the same |
EP1776196A2 (de) | 2004-08-03 | 2007-04-25 | Chemetall GmbH | Verfahren zum schützen einer metallischen oberfläche mit einer korrosions-inhibierenden beschichtung |
JP2006076829A (ja) | 2004-09-09 | 2006-03-23 | Nippon Sheet Glass Co Ltd | 防曇物品及びその製造方法 |
KR20060047146A (ko) | 2004-11-15 | 2006-05-18 | 삼성에스디아이 주식회사 | 감광성 도체 그린 시트 |
EP1670079B1 (en) | 2004-12-08 | 2010-12-01 | Samsung Mobile Display Co., Ltd. | Method of forming a conductive pattern of a thin film transistor |
JP2007052345A (ja) | 2005-08-19 | 2007-03-01 | Oji Paper Co Ltd | 屈折率傾斜多層薄膜構造体及びその製造方法 |
JP4651098B2 (ja) | 2005-09-07 | 2011-03-16 | 国立大学法人 名古屋工業大学 | シリカ殻からなるナノ中空粒子を用いた防食膜及びシリカ殻からなるナノ中空粒子を用いた防食塗料 |
DE112006002940T5 (de) | 2005-11-05 | 2008-12-11 | 3M Innovative Properties Co., St. Paul | Optische Filme, umfassend einen hohen Brechungsindex aufweisende und antireflektierende Beschichtungen |
DE502005011016D1 (de) * | 2005-11-10 | 2011-04-07 | Henkel Ag & Co Kgaa | Kleb-, dicht- und beschichtungsstoffe mit glaspartikeln als füllstoff |
EP1818694A1 (en) | 2006-02-14 | 2007-08-15 | DSMIP Assets B.V. | Picture frame with an anti reflective glass plate |
FR2908406B1 (fr) | 2006-11-14 | 2012-08-24 | Saint Gobain | Couche poreuse, son procede de fabrication et ses applications. |
KR101207124B1 (ko) | 2006-11-24 | 2012-11-30 | 주식회사 엘지화학 | 친수기로 개질된 아크릴계 수지를 포함하는 무기 나노 입자 코팅액, 및 상기 코팅액으로 제조된 무기 나노 입자 필름 |
JP2009070812A (ja) | 2007-08-17 | 2009-04-02 | Sosuke Naito | 放熱膜を用いた熱放射加熱調理器 |
JP2009059666A (ja) | 2007-09-03 | 2009-03-19 | Sumitomo Metal Mining Co Ltd | 透明導電層付フィルムとフレキシブル機能性素子、およびそれらの製造方法 |
KR20100098498A (ko) | 2007-09-28 | 2010-09-07 | 에이일이삼 시스템즈 인코포레이티드 | 무기/유기 다공성 필름을 갖는 배터리 |
US8319095B2 (en) * | 2007-11-27 | 2012-11-27 | Guardian Industries Corp. | Method of making an antireflective silica coating, resulting product, and photovoltaic device comprising same |
CN101910079A (zh) * | 2007-11-29 | 2010-12-08 | 康宁股份有限公司 | 具有改进的韧性和抗刮性的玻璃 |
US20090197048A1 (en) | 2008-02-05 | 2009-08-06 | Jaymin Amin | Damage resistant glass article for use as a cover plate in electronic devices |
JP5288841B2 (ja) | 2008-03-18 | 2013-09-11 | 株式会社きもと | 光拡散フィルム及びそれを用いた表示部材 |
KR101061970B1 (ko) | 2009-05-25 | 2011-09-05 | 한국과학기술연구원 | 전도성 비금속 필름을 이용한 광전극 및 이를 포함하는 염료감응 태양전지 |
KR101064986B1 (ko) | 2009-06-04 | 2011-09-15 | 강원대학교산학협력단 | 세라믹 다공성 지지체, 그를 이용한 강화 복합 전해질 막 및 그를 구비한 막-전극 어셈블리 |
KR101171827B1 (ko) | 2009-07-28 | 2012-08-14 | 도레이첨단소재 주식회사 | 반사방지층을 포함하는 광학용 폴리에스테르계 이접착 필름 |
US9085484B2 (en) | 2010-04-30 | 2015-07-21 | Corning Incorporated | Anti-glare surface treatment method and articles thereof |
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JP2014533233A (ja) | 2014-12-11 |
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CN104105675B (zh) | 2017-11-17 |
US20130115441A1 (en) | 2013-05-09 |
WO2013070830A3 (en) | 2013-07-04 |
KR102013922B1 (ko) | 2019-08-23 |
JP2018140933A (ja) | 2018-09-13 |
TW201733952A (zh) | 2017-10-01 |
KR20140093259A (ko) | 2014-07-25 |
EP2776373B1 (en) | 2020-08-19 |
TWI644877B (zh) | 2018-12-21 |
US10155361B2 (en) | 2018-12-18 |
CN107500565A (zh) | 2017-12-22 |
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