JP6247213B2 - Gmawハイブリッドレーザアーク溶接用の電極 - Google Patents
Gmawハイブリッドレーザアーク溶接用の電極 Download PDFInfo
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- JP6247213B2 JP6247213B2 JP2014532488A JP2014532488A JP6247213B2 JP 6247213 B2 JP6247213 B2 JP 6247213B2 JP 2014532488 A JP2014532488 A JP 2014532488A JP 2014532488 A JP2014532488 A JP 2014532488A JP 6247213 B2 JP6247213 B2 JP 6247213B2
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- 238000003466 welding Methods 0.000 title claims description 67
- 229910052799 carbon Inorganic materials 0.000 claims description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 22
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 21
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 21
- 229910052698 phosphorus Inorganic materials 0.000 claims description 21
- 239000011574 phosphorus Substances 0.000 claims description 21
- 229910052710 silicon Inorganic materials 0.000 claims description 21
- 229910052717 sulfur Inorganic materials 0.000 claims description 21
- 239000011593 sulfur Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000010703 silicon Substances 0.000 claims description 18
- 239000011572 manganese Substances 0.000 claims description 16
- 229910052748 manganese Inorganic materials 0.000 claims description 12
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 10
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 239000011162 core material Substances 0.000 description 20
- 239000000203 mixture Substances 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000007711 solidification Methods 0.000 description 7
- 230000008023 solidification Effects 0.000 description 7
- 239000007787 solid Substances 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- -1 are reduced too much Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- SBEQWOXEGHQIMW-UHFFFAOYSA-N silicon Chemical compound [Si].[Si] SBEQWOXEGHQIMW-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
- B23K35/0255—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
- B23K35/0261—Rods, electrodes, wires
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/21—Bonding by welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/346—Working by laser beam, e.g. welding, cutting or boring in combination with welding or cutting covered by groups B23K5/00 - B23K25/00, e.g. in combination with resistance welding
- B23K26/348—Working by laser beam, e.g. welding, cutting or boring in combination with welding or cutting covered by groups B23K5/00 - B23K25/00, e.g. in combination with resistance welding in combination with arc heating, e.g. TIG [tungsten inert gas], MIG [metal inert gas] or plasma welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K28/00—Welding or cutting not covered by any of the preceding groups, e.g. electrolytic welding
- B23K28/02—Combined welding or cutting procedures or apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/3073—Fe as the principal constituent with Mn as next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/40—Making wire or rods for soldering or welding
- B23K35/406—Filled tubular wire or rods
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Plasma & Fusion (AREA)
- Laser Beam Processing (AREA)
- Nonmetallic Welding Materials (AREA)
Description
炭素(C)=0.06〜0.15%
マンガン(Mn)=0.9〜1.40%
ケイ素(Si)=0.45〜0.75%
硫黄(S)=0.035%以下
燐(P)=0.025%以下
炭素(C)=0.02%以下
マンガン(Mn)=0.6〜1.2%
ケイ素(Si)=0.3〜0.6%
硫黄(S)=0.01%以下
燐(P)=0.01%以下
炭素(C)=0.005〜0.015%
マンガン(Mn)=0.6〜0.90%
ケイ素(Si)=0.3〜0.45%
硫黄(S)=0.002〜0.007%
燐(P)=0.002〜0.007%
101 ビーム
103 レーザ装置
105 レーザ電源
111 溶接電源
113 接触先端
115 源源
201 外側シース
203 コア
W 被加工物
Claims (15)
- ハイブリッドレーザアーク溶接のための溶接電極であって、
コアと、該コアを取り囲む外側シースとで構成される、電極本体を含み、
該電極本体は、該電極本体の質量%において、
0.02%以下の炭素、
0.6〜1.2%の範囲内のマンガン、
0.3〜0.6%の範囲内のケイ素、
0.01%以下の硫黄、及び
0.01%以下の燐
があるように、炭素、マンガン、ケイ素、硫黄、及び燐を含み、
前記炭素、マンガン、ケイ素、硫黄、及び燐の各々は、前記コア内にあり、前記コアは、粉末又は粒状形態にある、
溶接電極。 - 前記電極本体は、質量%において、0.15%以下のクロムを含む、請求項1に記載の溶接電極。
- 前記炭素は、前記電極本体の質量において、0.005〜0.015%の範囲内にある、請求項1又は2に記載の溶接電極。
- 前記マンガンは、前記電極本体の質量において、0.6〜0.9%の範囲内にある、請求項1乃至3のうちのいずれか1項に記載の溶接電極。
- 前記ケイ素は、前記電極本体の質量において、0.3〜0.45%の範囲内にある、請求項1乃至4のうちのいずれか1項に記載の溶接電極。
- 前記硫黄は、前記電極本体の質量において、0.002〜0.007%の範囲内にある、請求項1乃至5のうちのいずれか1項に記載の溶接電極。
- 前記燐は、前記電極本体の質量において、0.002〜0.007%の範囲内にある、請求項1乃至6のうちのいずれか1項に記載の溶接電極。
- 前記炭素は、前記電極本体の質量において、0.005〜0.015%の範囲内にあり、前記硫黄及び燐の各々は、前記電極本体の質量において、0.002〜0.007%の範囲内にある、請求項1乃至7のうちのいずれか1項に記載の溶接電極。
- 前記コアは、外側シース内に配置されており、前記コアは、前記外側シースによって閉じられている、請求項1乃至8のうちのいずれか1項に記載の溶接電極。
- 前記炭素、マンガン、ケイ素、硫黄、及び燐の各々は、前記コア内にある、請求項1乃至9のうちのいずれか1項に記載の溶接電極。
- 前記コアは、前記電極本体の質量の5〜35%である、請求項1乃至10のうちのいずれか1項に記載の溶接電極。
- 前記コアは、前記電極本体の質量の10〜25%である、請求項1乃至11のうちのいずれか1項に記載の溶接電極。
- ハイブリッドレーザアーク溶接のための溶接電極を作製する方法であって、
コアと、該コアを取り囲む外側シースとで構成される、電極本体を形成することを含み、該電極本体は、少なくとも炭素、マンガン、ケイ素、硫黄、及び燐を有し、
前記電極本体の質量%において、
0.02%以下の炭素、
0.6〜1.2%の範囲内のマンガン、
0.3〜0.6%の範囲内のケイ素、
0.01%以下の硫黄、及び
0.01%以下の燐があり、
前記炭素、マンガン、ケイ素、硫黄、及び燐の各々は、前記コア内にあり、前記コアは、粉末又は粒状形態にある、
方法。 - 被加工物の少なくとも一部を溶解させるようレーザビームを前記被加工物に向けること、
コアと、該コアを取り囲む外側シースとで構成される、電極本体を含む、溶接電極を、前記被加工物に供給すること、及び
アーク溶接プロセスを使用して溶解部分内に前記溶接電極を配置することを含み、
前記電極本体は、前記電極本体の質量%において、
0.02%以下の炭素、
0.6〜1.2%の範囲内のマンガン、
0.3〜0.6%の範囲内のケイ素、
0.01%以下の硫黄、及び
0.01%以下の燐があるように、
炭素、マンガン、ケイ素、硫黄、及び燐を含み、
前記炭素、マンガン、ケイ素、硫黄、及び燐の各々は、前記コア内にあり、前記コアは、粉末又は粒状形態にある、
溶接方法。 - 前記炭素は、前記電極本体の質量において、0.005〜0.015%の範囲内にあり、前記硫黄及び燐の各々は、前記電極本体の質量において、0.002〜0.007%の範囲内にある、請求項14に記載の溶接方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US13/249,139 | 2011-09-29 | ||
US13/249,139 US9180553B2 (en) | 2011-09-29 | 2011-09-29 | Electrode for GMAW hybrid laser arc welding |
PCT/IB2012/001903 WO2013046002A1 (en) | 2011-09-29 | 2012-09-28 | Electrode for gmaw hybrid laser arc welding |
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Publication Number | Publication Date |
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JP2014534072A JP2014534072A (ja) | 2014-12-18 |
JP6247213B2 true JP6247213B2 (ja) | 2017-12-13 |
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US (1) | US9180553B2 (ja) |
JP (1) | JP6247213B2 (ja) |
CN (1) | CN103958119B (ja) |
BR (1) | BR112014007618A2 (ja) |
DE (2) | DE212012000180U1 (ja) |
WO (1) | WO2013046002A1 (ja) |
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US10112268B2 (en) | 2013-10-09 | 2018-10-30 | Hobart Brothers Company | Systems and methods for corrosion-resistant welding electrodes |
US10300565B2 (en) | 2014-10-17 | 2019-05-28 | Hobart Brothers Company | Systems and methods for welding mill scaled workpieces |
US20160312377A1 (en) * | 2015-04-21 | 2016-10-27 | Siemens Energy, Inc. | Laser Deposit Surface Control Using Select Fluxes and Electrochemistry |
US10688596B2 (en) | 2015-12-18 | 2020-06-23 | Illinois Tool Works Inc. | Wire manufactured by additive manufacturing methods |
RU2668625C1 (ru) * | 2017-08-16 | 2018-10-02 | Публичное акционерное общество "Челябинский трубопрокатный завод" (ПАО "ЧТПЗ") | Способ лазерно-дуговой сварки плавящимся электродом в среде защитного газа стыкового соединения сформованной трубной заготовки |
JP7284014B2 (ja) * | 2019-07-10 | 2023-05-30 | 株式会社ダイヘン | レーザ・アークハイブリッド溶接装置 |
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JP3657127B2 (ja) * | 1998-09-25 | 2005-06-08 | 株式会社神戸製鋼所 | ガスシールドアーク溶接用フラックス入りワイヤ |
US6242113B1 (en) | 1999-06-10 | 2001-06-05 | Inco Alloys International, Inc. | Welding alloy and articles for use in welding, weldments and methods for producing weldments |
US6608284B1 (en) * | 2000-05-17 | 2003-08-19 | Illinois Tool Works Inc. | Weld wire with enhanced slag removal |
JP3762676B2 (ja) * | 2001-09-17 | 2006-04-05 | 本田技研工業株式会社 | ワークの溶接方法 |
FR2865152B1 (fr) * | 2004-01-21 | 2007-02-02 | Air Liquide | Procede de soudage hybride arc-laser des aciers ferritiques |
JP2005219062A (ja) | 2004-02-03 | 2005-08-18 | Jfe Steel Kk | Yagレーザアークハイブリッド溶接方法 |
KR101021397B1 (ko) * | 2006-02-17 | 2011-03-14 | 가부시키가이샤 고베 세이코쇼 | 이재 접합용 플럭스 코어드 와이어, 이재 접합 방법 및 그 접합 방법을 이용한 알루미늄재 또는 알루미늄 합금재와, 강재와의 접합 이음 구조체 |
FR2897549B1 (fr) * | 2006-02-20 | 2009-02-06 | Air Liquide | Procede de fabrication de tubes remplis de poudres, tels des fils fourres de soudage |
US8563897B2 (en) * | 2007-04-30 | 2013-10-22 | Illinois Tool Works Inc. | Sheathed welding wire |
CN101549442B (zh) * | 2008-03-31 | 2012-09-26 | 鞍钢股份有限公司 | 一种高韧性金属芯气体保护焊丝及其制造方法 |
CN101549440A (zh) * | 2009-05-11 | 2009-10-07 | 深圳市大族激光科技股份有限公司 | 一种激光-电弧复合热源焊接方法及焊接装置 |
FR2955795A1 (fr) | 2010-02-01 | 2011-08-05 | Air Liquide | Procede et consommables de soudage des aciers au nickel |
-
2011
- 2011-09-29 US US13/249,139 patent/US9180553B2/en active Active
-
2012
- 2012-09-28 CN CN201280058514.1A patent/CN103958119B/zh active Active
- 2012-09-28 BR BR112014007618A patent/BR112014007618A2/pt not_active Application Discontinuation
- 2012-09-28 DE DE212012000180.8U patent/DE212012000180U1/de not_active Expired - Lifetime
- 2012-09-28 JP JP2014532488A patent/JP6247213B2/ja active Active
- 2012-09-28 WO PCT/IB2012/001903 patent/WO2013046002A1/en active Application Filing
- 2012-09-28 DE DE112012004067.8T patent/DE112012004067T5/de not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
US9180553B2 (en) | 2015-11-10 |
US20130082036A1 (en) | 2013-04-04 |
CN103958119B (zh) | 2018-01-12 |
DE212012000180U1 (de) | 2014-06-24 |
DE112012004067T5 (de) | 2014-10-23 |
CN103958119A (zh) | 2014-07-30 |
JP2014534072A (ja) | 2014-12-18 |
WO2013046002A1 (en) | 2013-04-04 |
BR112014007618A2 (pt) | 2017-04-11 |
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