JP6232289B2 - フレグランス化合物を放出することができる化合物 - Google Patents

フレグランス化合物を放出することができる化合物 Download PDF

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JP6232289B2
JP6232289B2 JP2013545436A JP2013545436A JP6232289B2 JP 6232289 B2 JP6232289 B2 JP 6232289B2 JP 2013545436 A JP2013545436 A JP 2013545436A JP 2013545436 A JP2013545436 A JP 2013545436A JP 6232289 B2 JP6232289 B2 JP 6232289B2
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enyl
alkyl
methyl
benzene
groups
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JP2014508121A5 (enExample
JP2014508121A (ja
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バウムガートナー,コリンネ
フラックスマン,フェリックス
クラフト,フィリップ
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ジボダン エス エー
ジボダン エス エー
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0007Aliphatic compounds
    • C11B9/0015Aliphatic compounds containing oxygen as the only heteroatom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/50Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic non-condensed
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/56Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic condensed
    • C07C15/58Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic condensed containing two rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/20Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/215Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring having unsaturation outside the six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/20Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/23Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing hydroxy or O-metal groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D317/00Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/44Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D317/46Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
    • C07D317/48Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
    • C07D317/50Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D317/00Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/44Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D317/46Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
    • C07D317/48Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
    • C07D317/50Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
    • C07D317/54Radicals substituted by oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0003Compounds of unspecified constitution defined by the chemical reaction for their preparation
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0042Essential oils; Perfumes compounds containing condensed hydrocarbon rings
    • C11B9/0046Essential oils; Perfumes compounds containing condensed hydrocarbon rings containing only two condensed rings
    • C11B9/0049Essential oils; Perfumes compounds containing condensed hydrocarbon rings containing only two condensed rings the condensed rings sharing two common C atoms
    • C11B9/0053Essential oils; Perfumes compounds containing condensed hydrocarbon rings containing only two condensed rings the condensed rings sharing two common C atoms both rings being six-membered
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0061Essential oils; Perfumes compounds containing a six-membered aromatic ring not condensed with another ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0069Heterocyclic compounds
    • C11B9/0073Heterocyclic compounds containing only O or S as heteroatoms
    • C11B9/0076Heterocyclic compounds containing only O or S as heteroatoms the hetero rings containing less than six atoms
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • C11D3/502Protected perfumes
    • C11D3/507Compounds releasing perfumes by thermal or chemical activation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fats And Perfumes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Cosmetics (AREA)
JP2013545436A 2010-12-23 2011-12-23 フレグランス化合物を放出することができる化合物 Active JP6232289B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1021864.2A GB201021864D0 (en) 2010-12-23 2010-12-23 Organic compounds
GB1021864.2 2010-12-23
PCT/EP2011/074003 WO2012085287A1 (en) 2010-12-23 2011-12-23 Compounds capable of releasing fragrant compounds

Publications (3)

Publication Number Publication Date
JP2014508121A JP2014508121A (ja) 2014-04-03
JP2014508121A5 JP2014508121A5 (enExample) 2017-10-12
JP6232289B2 true JP6232289B2 (ja) 2017-11-15

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ID=43598911

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JP2013545436A Active JP6232289B2 (ja) 2010-12-23 2011-12-23 フレグランス化合物を放出することができる化合物

Country Status (10)

Country Link
US (1) US9193935B2 (enExample)
EP (1) EP2655307B1 (enExample)
JP (1) JP6232289B2 (enExample)
CN (1) CN103261139B (enExample)
BR (1) BR112013016191B1 (enExample)
ES (1) ES2692179T3 (enExample)
GB (1) GB201021864D0 (enExample)
MX (1) MX341306B (enExample)
SG (1) SG190848A1 (enExample)
WO (1) WO2012085287A1 (enExample)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014180782A1 (en) * 2013-05-08 2014-11-13 Firmenich Sa Pro-fragrance compounds
WO2014180791A1 (en) * 2013-05-08 2014-11-13 Firmenich Sa Pro-fragrance compounds
EP3218458B1 (en) * 2014-11-10 2019-01-02 Givaudan S.A. Improvments in or relating to organic compounds
WO2016074698A1 (en) 2014-11-10 2016-05-19 Givaudan Sa Improvements in or relating to organic compounds
KR101609323B1 (ko) 2015-03-06 2016-04-05 충북대학교 산학협력단 2-메톡시-4-(3-(4-메톡시페닐)프로필-1-엔-1-일)페놀 및 이의 제조방법
GB201703706D0 (en) * 2017-03-08 2017-04-19 Givaudan Sa Improvements in or relating to organic compounds
EP3533786A1 (en) 2018-03-02 2019-09-04 Givaudan SA Thioether precursors for fragrant ketones and aldehydes
CN111936457B (zh) 2018-06-22 2025-02-25 弗门尼舍有限公司 烯醇醚香料前体
GB201817785D0 (en) 2018-10-31 2018-12-19 Givaudan Sa Organic compounds
CN113195697A (zh) * 2018-12-17 2021-07-30 奇华顿股份有限公司 加香方法
EP3898912A1 (en) 2018-12-17 2021-10-27 Givaudan SA A method of countering malodour in a washing machine comprising the addition of a fragrance precursor
CN112752744B (zh) * 2018-12-20 2025-02-18 弗门尼舍有限公司 烷基烯醇醚香料前体
EP4007748A1 (en) 2019-12-03 2022-06-08 Firmenich SA Enol ether properfume
WO2022018054A1 (en) * 2020-07-24 2022-01-27 Firmenich Sa Process for preparing indene acryladehyde derivatives
WO2022261956A1 (en) 2021-06-18 2022-12-22 Givaudan Sa Fragrance compounds
WO2023065200A1 (en) 2021-10-21 2023-04-27 Givaudan Sa Organic compounds
WO2023065203A1 (en) 2021-10-21 2023-04-27 Givaudan Sa Organic compounds
WO2024200404A1 (en) 2023-03-30 2024-10-03 Givaudan Sa Unsaturated ether fragrance precursors
WO2025003204A1 (en) 2023-06-27 2025-01-02 Givaudan Sa Organic compounds and their use for generating a fragrant alcohol
GB202405427D0 (en) 2024-04-18 2024-06-05 Givaudan Sa Process

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3115530A (en) 1960-05-13 1963-12-24 Exxon Research Engineering Co Preferred alkyl aryl sulfonate detergents
CH411836A (de) 1961-09-07 1966-04-30 Basf Ag Verfahren zur Herstellung von Mischoligomeren aus 1,3-Dienen und Verbindungen mit aktivierter olefinischer Doppelbindung
US3196174A (en) 1962-03-01 1965-07-20 Exxon Research Engineering Co Perhydro bis-(isoprenyl) alkyl aryl sulfonates
DE2301438A1 (de) 1973-01-12 1974-07-25 Hoechst Ag Verwendung von butadienderivaten als optische aufheller fuer waschmittel
FR2729661B1 (fr) * 1995-01-19 1997-04-04 Mane Fils V Procede de preparation de substances aromatiques par voie biochimique
JP3792450B2 (ja) 1999-09-03 2006-07-05 花王株式会社 機能性物質放出体
JP3840868B2 (ja) 2000-02-22 2006-11-01 株式会社ツムラ 新規な補骨脂の使用方法
EP1262473A1 (en) * 2001-05-30 2002-12-04 Givaudan SA Precursors for fragrant ketones and fragrant aldehydes
JP2008303159A (ja) * 2007-06-06 2008-12-18 Osaka Prefecture Univ カルボニル化合物の製造方法
GB0717485D0 (en) 2007-09-08 2007-10-17 Unilever Plc Improvements relating to fabric conditioners
JP2012502092A (ja) * 2008-09-12 2012-01-26 フイルメニツヒ ソシエテ アノニム 活性アルデヒドおよびケトンを放出できるジビニルエーテル誘導体および芳香表面への使用方法
US8669385B2 (en) * 2009-10-13 2014-03-11 University Of Central Florida Research Foundation, Inc. Oxidative cleavage of unsaturated carboxylic acids

Also Published As

Publication number Publication date
MX341306B (es) 2016-08-15
BR112013016191B1 (pt) 2021-02-09
SG190848A1 (en) 2013-07-31
MX2013006034A (es) 2013-07-03
BR112013016191A2 (pt) 2020-08-04
US20130316938A1 (en) 2013-11-28
US9193935B2 (en) 2015-11-24
GB201021864D0 (en) 2011-02-02
CN103261139B (zh) 2015-09-23
WO2012085287A1 (en) 2012-06-28
EP2655307A1 (en) 2013-10-30
EP2655307B1 (en) 2018-08-01
ES2692179T3 (es) 2018-11-30
CN103261139A (zh) 2013-08-21
JP2014508121A (ja) 2014-04-03

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