JP6188805B2 - 酸素捕捉性プラスチック材料 - Google Patents
酸素捕捉性プラスチック材料 Download PDFInfo
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- JP6188805B2 JP6188805B2 JP2015531487A JP2015531487A JP6188805B2 JP 6188805 B2 JP6188805 B2 JP 6188805B2 JP 2015531487 A JP2015531487 A JP 2015531487A JP 2015531487 A JP2015531487 A JP 2015531487A JP 6188805 B2 JP6188805 B2 JP 6188805B2
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- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229920000007 Nylon MXD6 Polymers 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Natural products CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- ZIXVIWRPMFITIT-UHFFFAOYSA-N cadmium lead Chemical compound [Cd].[Pb] ZIXVIWRPMFITIT-UHFFFAOYSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000014171 carbonated beverage Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 1
- 239000001032 cobalt pigment Substances 0.000 description 1
- LHEFLUZWISWYSQ-CVBJKYQLSA-L cobalt(2+);(z)-octadec-9-enoate Chemical compound [Co+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LHEFLUZWISWYSQ-CVBJKYQLSA-L 0.000 description 1
- KDMCQAXHWIEEDE-UHFFFAOYSA-L cobalt(2+);7,7-dimethyloctanoate Chemical compound [Co+2].CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O KDMCQAXHWIEEDE-UHFFFAOYSA-L 0.000 description 1
- TZWGXFOSKIHUPW-UHFFFAOYSA-L cobalt(2+);propanoate Chemical compound [Co+2].CCC([O-])=O.CCC([O-])=O TZWGXFOSKIHUPW-UHFFFAOYSA-L 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical class O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 150000005125 dioxazines Chemical class 0.000 description 1
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000009459 flexible packaging Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000001035 lead pigment Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229920001526 metallocene linear low density polyethylene Polymers 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- ABMFBCRYHDZLRD-UHFFFAOYSA-N naphthalene-1,4-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1 ABMFBCRYHDZLRD-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 229920006285 olefinic elastomer Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000002979 perylenes Chemical class 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006131 poly(hexamethylene isophthalamide-co-terephthalamide) Polymers 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 1
- 229920006123 polyhexamethylene isophthalamide Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003763 resistance to breakage Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000011496 sports drink Nutrition 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920002397 thermoplastic olefin Polymers 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/008—Additives improving gas barrier properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/012—Additives improving oxygen scavenging properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Wrappers (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Description
(a)プラスチック材料が、ポリエステル、ポリオレフィン、ポリオレフィンコポリマーまたはポリスチレンであり、及び
添加剤が、(b)及び任意選択的に(c)である、
使用を提供する:
(b)式(I)、(1)、(2)、(5)、(8)、(9)及び/または(10)の化合物
Rcは、水素またはC1〜30アルキルであり;
Rdは、水素またはC1〜30アルキルであり、そしてRcに対しオルト(o)またはメタ(m)位置にあることができ;
pは、0、1または2の数であり;
式(8)中のXは、C(CH3)2、S=O、C=O、SO2から選択され;
nは、1〜20の数である;
(c)遷移金属触媒。
成分Aは、ポリエステル、ポリオレフィン、ポリオレフィンコポリマー及びポリスチレンからなる群から選択されるプラスチック材料であり、
成分Bは、式(I)、(1)、(2)、(5)、(8)、(9)及び/または(10)によって表される化合物から選択される添加剤であり、
Rcは、水素またはC1〜30アルキルであり;
Rdは、水素またはC1〜30アルキルであり、そしてRcに対しオルト(o)またはメタ(m)位置にあることができ;
pは、0、1または2の数であり;
式(8)中のXは、C(CH3)2、S=O、C=O、SO2から選択され;
nは、1〜20の数である]
及び
成分Cは、遷移金属触媒である。
−ポリエチレン(PE)、好ましくは高密度ポリエチレン(HDPE)、中密度ポリエチレン(MDPE)、低密度ポリエチレン(LDPE)、線状低密度ポリエチレン(LLDPE)、メタロセン低密度ポリエチレン(mLDPE)及びメタロセン線状低密度ポリエチレン(mLLDPE)からなる群から選択されるポリエチレン(PE)、
−ポリプロピレン(PP)、好ましくはポリプロピレンホモポリマー(PPH)、ポリプロピレンランダムコポリマー(PP−R)、及びポリプロピレンブロックコポリマー(PP−ブロック−COPO)からなる群から選択されるポリプロピレン(PP)、
−PEコポリマー、好ましくはエチレン−酢酸ビニルコポリマー(EVA)、エチレンとメチルアクリレートとのコポリマー(EMA)、エチレンとブチルアクリレートとのコポリマー(EBA)、エチレンとエチルアクリレートとのコポリマー(EEA)、及びシクロオレフィンコポリマー(COC)からなる群から選択されるPEコポリマー、
−汎用ポリスチレン(GPPS)及び耐衝撃性ポリスチレン(HIPS);
からなる群から選択され、より好ましくは、
−高密度ポリエチレン(HDPE)及び低密度ポリエチレン(LDPE)、
−ポリプロピレンホモポリマー(PPH)、
−汎用ポリスチレン(GPPS)、
からなる群から選択される。
植物または動物から誘導される天然の着色剤、及び合成着色剤、ここで好ましい合成着色剤は、合成有機もしくは無機染料及び顔料であり、
−好ましい合成有機顔料は、アゾまたはジスアゾ顔料、レーキ化アゾまたはジスアゾ顔料、または多環式顔料、特に好ましくはフタロシアニン、ジケトピロロピロール、キナクリドン、ペリレン、ジオキサジン、アントラキノン、チオインディゴ、ジアリールまたはキノフタロン顔料であり;
−好ましい合成無機顔料は、金属酸化物、混合酸化物、硫酸アルミニウム、クロム酸塩、金属粉、真珠光沢顔料(マイカ)、発光着色剤、酸化チタン、カドニウム鉛顔料、酸化鉄、カーボンブラック、ケイ酸塩、チタン酸ニッケル、コバルト顔料または酸化クロムであり;
−フィラー及びナノサイズフィラー、好ましくはシリカ、ゼオライト、ケイ酸塩、特に好ましくはケイ酸アルミニウム、ケイ酸ナトリウム、ケイ酸カルシウム;チョークまたはタルク;金属水和物;
−助剤、好ましくは酸捕捉剤、加工助剤、カップリング剤、滑剤、ステアレート、発泡剤、多価アルコール、成核剤、または酸化防止剤、例えばステアレート、または酸化物、例えば酸化マグネシウム;
−酸化防止剤、好ましくは一次または二次酸化防止剤;
−帯電防止剤;
−ポリエステル/ポリアミドブレンド用の相溶化剤;
UV吸収剤、スリップ剤、防曇剤(antifogging agent)、縮合防止剤、懸濁液安定化剤、ブロッキング防止剤、ワックス、及びこれらの物質の混合物、
からなる群から選択される。
14〜99.887重量%の成分A;
0.01〜70重量%の成分B;
0.003〜15重量%の成分C;
0〜80重量%の成分D及び/またはE;
を含み、ここで重量%は、それぞれ、組成物Zの全重量を基準とし;及び成分A、B、C及び任意選択的にD及びEの重量%は合計して常に100%である。
14〜94重量%の成分A;
5〜70重量%の成分B;
1〜15重量%の成分C;
0〜80重量%の一種または二種以上の他の物質、好ましくは成分D及び/またはE;
より好ましくは
14〜94重量%の成分A;
5〜50重量%の成分B;
1〜10重量%の成分C;
0〜80重量%の成分D及び/またはE;
を含み、ここで重量%は、それぞれ、組成物Zの全重量を基準とし;及び成分A、B、C及び任意選択的にD及びEの重量%は合計して常に100%である。
88〜99.887重量%の成分A;
0.01〜1.5重量%の成分B;
0.003〜0.5重量%の成分C;
0〜10重量%の一種または二種以上の他の物質、好ましくは成分D及び/またはE;
より好ましくは
90〜99.86重量%の成分A;
0.1〜0.8重量%の成分B;
0.04〜0.3重量%の成分C;
0〜8.9重量%の成分D及び/またはE;
を含み、ここで重量%は、それぞれ、組成物Zの全重量を基準とし;及び成分A、B、C及び任意選択的にD及びEの重量%は合計して常に100%である。
好ましくは、酸素を捕捉するために組成物Zが使用されている硬質容器、例えばボトル、または柔軟性フィルムは、単層である。
−包装品中に最初から存在する酸素の量、
−捕捉性の不在下に包装品中への酸素の侵入速度、及び
−包装品の意図される貯蔵寿命。
製品の性質は、他に記載がなければ次の方法で決定する:
密度値は、ASTM D792に従い決定する(g/cm3)。
酸素捕捉活性の測定方法
典型的な炭酸飲料貯蔵寿命試験の場合には、500mlのボトルを、(i)窒素循環グローブボックス内部で、上部空間が10mlとなるまで脱酸素した水で満たし、ここで、ボトル内の水の酸素レベルを50ppbよりも十分に低いレベルに安定化し、(ii)、2.8体積の炭酸化レベルまでCO2で炭酸化し(すなわち、水1cm3あたりに溶解したガスの量が2.8cm3である)、次いで蓋する。次いで、ボトルのフリーの上部空間中の酸素レベルの測定を、非侵襲的酸素測定センサ及びFibox(登録商標)トランスミッタを用いて行う。データを、一定の時間間隔で、同じ組成物の少なくとも二つのサンプルボトルについて並行して収集する。各々のサンプルボトルについて、或る時間での酸素侵入量を、その時に測定された酸素含有率と時間0で測定された酸素レベルとの間の差異として計算する。次いで、この酸素侵入量を、各々の組成物について測定されたサンプルボトルの数で平均化し、そして時間に対してプロットする。
食料品のための典型的なトレイの条件をシミュレートするために、20×20cm2の開放表面積を有する専売スチールセルを使用する。このセルは、窒素循環グローブボックス内で用意し、バリヤフィルムで覆い、そしてスチールフレームにより縁の所でシールする。次いで、セルのフリーの上部空間中の酸素レベルの測定を、非侵襲的酸素測定センサ及びFibox(登録商標)トランスミッタを用いて行う。データを、一定の時間間隔で収集する。各々のサンプルについて、或る時間での酸素侵入を、その時に測定された酸素含有率と時間0で測定された酸素レベルとの間の差異として計算する。次いで、酸素侵入量を時間に対してプロットする。
ヘイズの値は、ASTM D1003、手順Aに従い延伸ブロー成形ボトルの側壁について決定する(試料を通過する際に、前方散乱によって入射ビームから逸れる透過光の百分率)。
%ヘイズ=(T散乱/T合計)×100
ここでTは、透過率%である。
成分A1:
1.35〜1.45g/cm3の密度及び0.74〜0.78dl/g(ASTM D3236−88)の固有粘度を有するポリエチレンテレフタレート(PET)。
成分A2:
1.28〜1.32g/cm3の密度及び0.90〜1.00dl/g(ASTM D3236−88)の固有粘度を有するポリブチレンテレフタレート(PBT)。
Nylostab(登録商標)S−EED(登録商標)としてClariant社から商業的に入手可能な添加剤
成分C1:
ステアリン酸コバルト(9.5%コバルト濃度)
成分D1:
1.20〜1.30g/cm3の密度及び2g/10分のMFR(275℃/0.325kgで測定)を有するポリ(m−キシリレンアジパミド)(MXD6)。
成分D2:
比較製品:Amosorb(登録商標)4020Eポリエステル樹脂(ColorMatrix、US)、これは、元素状コバルト濃度が50ppmであるようにポリブタジエンセグメント及びコバルト塩を含むPETコポリマーである。
成分を、Leistritz(登録商標)ZSE18HP押出機で230℃の温度で一緒にホモジナイズして、固形マスターバッチMB1及びMB2を得た。表1にその詳細を示す。
成分A1を160℃で7時間乾燥し、次いで他の成分を表2に示す比率でホモジナイズ及び混合した。
デルタ=m・日
Y=1/(M・ヘイズ2)
である。
Claims (14)
- プラスチック材料中での酸素捕捉剤としての添加剤の使用であって、
(a)プラスチック材料が、ポリエステル、ポリオレフィン、ポリオレフィンコポリマーまたはポリスチレンであり、及び
添加剤が、(b)及び(c)である、前記使用:
(b)式(I)、(1)、(2)、(5)、(8)、(9)及び/または(10)の化合物:
各々のRaは、同一かまたは異なることができ、独立して、式(A)で表わされる基を表し、
pは、0、1または2の数であり;
式(8)中のXは、C(CH3)2、S=O、C=O、SO2から選択され;
nは、1〜20の数である]
(c)鉄、ニッケル、マンガン、コバルト及び銅より成る群から選ばれる遷移金属の塩の形態にある遷移金属触媒。 - プラスチック材料が、包装用物品であるかまたはそれの一部である、請求項1に記載の使用。
- 包装用物品が、容器、シートまたはフィルムである、請求項2に記載の使用。
- 添加剤b)が、プラスチック材料と添加剤との総重量を基準として、0.001〜5重量%の量で使用される、請求項2または3に記載の使用。
- 成分A、B、及びCを含む組成物Zであって、
成分Aは、ポリエステル、ポリオレフィン、ポリオレフィンコポリマー及びポリスチレンからなる群から選択されるプラスチック材料であり、
成分Bは、式(I)、(1)、(2)、(5)、(8)、(9)及び/または(10)によって表される化合物から選択される添加剤であり、
各々のRaは、同一かまたは異なることができ、独立して、式(A)で表わされる基を表し、
pは、0、1または2の数であり;
式(8)中のXは、C(CH3)2、S=O、C=O、SO2から選択され;
nは、1〜20の数である]
及び
成分Cは、鉄、ニッケル、マンガン、コバルト及び銅より成る群から選ばれる遷移金属の塩の形態にある遷移金属触媒である、
前記組成物Z。 - 14〜99.887重量%の成分A;
0.01〜70重量%の成分B;
0.003〜15重量%の成分C;
を含み、ここで重量%は、組成物Zの全重量を基準とし;及び成分A、B及びCの重量%は合計して常に100%である、請求項7に記載の組成物。 - 脂肪族ポリアミド及び部分的に芳香族のポリアミドからなる群から選択される成分Dを更に含む、請求項7または8に記載の組成物。
- 成分A、B、C、任意選択的に及び成分D及び任意選択的に成分Eからなる組成物Zであって、ここで成分A、B及びCは請求項7で定義した通りであり、
成分Dは、脂肪族ポリアミド及び部分的に芳香族のポリアミドからなる群から選択され、及び
成分Eは、植物もしくは動物より誘導される天然の着色剤、合成着色剤、フィラー、酸捕捉剤、加工助剤、カップリング剤、潤滑剤、ステアレート、発泡剤、多価アルコール、成核剤、酸化防止剤、帯電防止剤;ポリエステル/ポリアミドブレンド用の相溶化剤;UV吸収剤、スリップ剤、防曇剤、縮合防止剤、懸濁液安定化剤、ブロッキング防止剤、ワックス、及びこれらの物質の混合物からなる群から選択される、
前記組成物Z。 - 14〜99.887重量%の成分A;
0.01〜70重量%の成分B;
0.003〜15重量%の成分C;
0〜80重量%の成分D及び/またはE;
からなり、ここで重量%は、組成物Zの全重量を基準とし;及び成分A、B、C、D及びEの重量%は合計して常に100%である、
請求項10に記載の組成物。 - マスターバッチMBまたはコンパウンドCOである、請求項7〜13のいずれか一つに記載の組成物Z。
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RU2012110121A (ru) * | 2009-08-17 | 2013-09-27 | Басф Се | Применение термопластичных сополиэфирных или сополиамидных эластомеров для повышения поглощающей способности функционализированных полиолефиновых пленок по отношению к кислороду |
HUE025007T2 (en) * | 2010-06-30 | 2016-04-28 | Clariant Masterbatches (Italia) S P A | Oxygen Binding Plastic |
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2012
- 2012-09-18 EP EP12006550.3A patent/EP2708574A1/en not_active Withdrawn
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2013
- 2013-09-11 JP JP2015531487A patent/JP6188805B2/ja not_active Expired - Fee Related
- 2013-09-11 EP EP13759985.8A patent/EP2898012B1/en not_active Not-in-force
- 2013-09-11 CN CN201380048187.6A patent/CN105051098B/zh not_active Expired - Fee Related
- 2013-09-11 RU RU2015114592A patent/RU2015114592A/ru unknown
- 2013-09-11 CA CA2885206A patent/CA2885206A1/en not_active Abandoned
- 2013-09-11 ES ES13759985.8T patent/ES2640588T3/es active Active
- 2013-09-11 AU AU2013320646A patent/AU2013320646A1/en not_active Abandoned
- 2013-09-11 BR BR112015004863A patent/BR112015004863A2/pt not_active Application Discontinuation
- 2013-09-11 KR KR1020157006760A patent/KR20150058217A/ko not_active Application Discontinuation
- 2013-09-11 WO PCT/EP2013/002723 patent/WO2014044366A1/en active Application Filing
- 2013-09-11 US US14/429,289 patent/US20150240052A1/en not_active Abandoned
- 2013-09-11 MX MX2015003409A patent/MX2015003409A/es unknown
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Also Published As
Publication number | Publication date |
---|---|
CN105051098B (zh) | 2018-10-23 |
EP2898012B1 (en) | 2016-12-07 |
CN105051098A (zh) | 2015-11-11 |
AU2013320646A1 (en) | 2015-02-26 |
WO2014044366A1 (en) | 2014-03-27 |
EP2898012A1 (en) | 2015-07-29 |
BR112015004863A2 (pt) | 2020-04-22 |
CA2885206A1 (en) | 2014-03-27 |
NZ704471A (en) | 2018-02-23 |
JP2016500707A (ja) | 2016-01-14 |
KR20150058217A (ko) | 2015-05-28 |
RU2015114592A (ru) | 2016-11-10 |
EP2708574A1 (en) | 2014-03-19 |
US20150240052A1 (en) | 2015-08-27 |
MX2015003409A (es) | 2015-06-22 |
ES2640588T3 (es) | 2017-11-03 |
TW201425413A (zh) | 2014-07-01 |
ZA201500843B (en) | 2016-01-27 |
TWI571485B (zh) | 2017-02-21 |
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