JP6107139B2 - イソブタノールからメタクロレイン及びメタクリル酸を製造する方法、並びにその製造装置 - Google Patents

イソブタノールからメタクロレイン及びメタクリル酸を製造する方法、並びにその製造装置 Download PDF

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JP6107139B2
JP6107139B2 JP2012552183A JP2012552183A JP6107139B2 JP 6107139 B2 JP6107139 B2 JP 6107139B2 JP 2012552183 A JP2012552183 A JP 2012552183A JP 2012552183 A JP2012552183 A JP 2012552183A JP 6107139 B2 JP6107139 B2 JP 6107139B2
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isobutanol
catalyst
methacrylic acid
butenes
methacrolein
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JPWO2013069630A1 (ja
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大谷内　健
健 大谷内
隼也 安川
隼也 安川
秀治 秋原
秀治 秋原
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Mitsubishi Chemical Corp
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Mitsubishi Chemical Corp
Mitsubishi Rayon Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0046—Sequential or parallel reactions, e.g. for the synthesis of polypeptides or polynucleotides; Apparatus and devices for combinatorial chemistry or for making molecular arrays
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00277—Apparatus
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2012552183A 2011-11-07 2012-11-06 イソブタノールからメタクロレイン及びメタクリル酸を製造する方法、並びにその製造装置 Active JP6107139B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2011243518 2011-11-07
JP2011243518 2011-11-07
PCT/JP2012/078714 WO2013069630A1 (ja) 2011-11-07 2012-11-06 イソブタノールからｔ－ブタノールを製造する方法、イソブタノールからメタクロレイン及びメタクリル酸を製造する方法、並びにそれらの製造装置

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JPWO2013069630A1 JPWO2013069630A1 (ja) 2015-04-02
JP6107139B2 true JP6107139B2 (ja) 2017-04-05

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US (1) US9346735B2 (enExample)
JP (1) JP6107139B2 (enExample)
KR (1) KR101979475B1 (enExample)
CN (1) CN103917508A (enExample)
IN (1) IN2014KN00748A (enExample)
MY (1) MY167695A (enExample)
WO (1) WO2013069630A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6081949B2 (ja) * 2014-03-25 2017-02-15 Ｊｘエネルギー株式会社 脱水触媒、及び共役ジエンの製造方法
JP6081950B2 (ja) * 2014-03-25 2017-02-15 Ｊｘエネルギー株式会社 脱水触媒、及び共役ジエンの製造方法
SG11201610414QA (en) * 2014-07-02 2017-02-27 Mitsubishi Rayon Co Method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate
CN111004116A (zh) * 2019-12-19 2020-04-14 湖北美和科技有限公司 一种用于制备结焦抑制剂组份的甲基丙烯酸酯单体
WO2021200795A1 (ja) * 2020-03-31 2021-10-07 三菱ケミカル株式会社 イソブチレンの製造方法、メタクリル酸の製造方法及びメタクリル酸メチルの製造方法
CN118742533A (zh) 2022-02-17 2024-10-01 三菱化学株式会社 甲基丙烯醛和/或甲基丙烯酸的制造方法、以及甲基丙烯酸酯的制造方法
WO2025226576A1 (en) * 2024-04-25 2025-10-30 ExxonMobil Technology and Engineering Company Processes for producing isobutylene and isobutylene-based polymers

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5112605B2 (enExample) * 1971-09-01 1976-04-21
JPS5324403B2 (enExample) 1973-06-11 1978-07-20
JPS6130538A (ja) 1984-07-20 1986-02-12 Mitsubishi Rayon Co Ltd メタクロレイン及びメタクリル酸の製造法
EP1000923B1 (en) * 1997-06-30 2003-12-03 Takara Bio Inc. Cyclopentenone derivatives
JPH11193255A (ja) * 1997-12-26 1999-07-21 Mitsubishi Rayon Co Ltd 第３級ブチルアルコールの製造方法
JP4197771B2 (ja) 1998-07-30 2008-12-17 旭化成ケミカルズ株式会社 オレフィン混合物より第３級ブチルアルコールの回収方法
CN1108283C (zh) * 2000-09-28 2003-05-14 中国石油天然气股份有限公司兰州石化分公司 一种异丁烯水合制叔丁醇的方法
KR100579678B1 (ko) * 2001-12-21 2006-05-15 아사히 가세이 케미칼즈 가부시키가이샤 산화물 촉매 조성물
CN1511815A (zh) * 2002-12-31 2004-07-14 中国石化集团齐鲁石油化工公司 一种叔丁醇的制备方法

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Publication number Publication date
JPWO2013069630A1 (ja) 2015-04-02
MY167695A (en) 2018-09-21
KR101979475B1 (ko) 2019-05-16
US9346735B2 (en) 2016-05-24
WO2013069630A1 (ja) 2013-05-16
US20140357890A1 (en) 2014-12-04
IN2014KN00748A (enExample) 2015-10-02
KR20140090650A (ko) 2014-07-17
CN103917508A (zh) 2014-07-09

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