JP6062417B2 - エチレンをエチレンオキシドに酸化するための触媒の製造方法 - Google Patents

エチレンをエチレンオキシドに酸化するための触媒の製造方法 Download PDF

Info

Publication number
JP6062417B2
JP6062417B2 JP2014504439A JP2014504439A JP6062417B2 JP 6062417 B2 JP6062417 B2 JP 6062417B2 JP 2014504439 A JP2014504439 A JP 2014504439A JP 2014504439 A JP2014504439 A JP 2014504439A JP 6062417 B2 JP6062417 B2 JP 6062417B2
Authority
JP
Japan
Prior art keywords
temperature
range
support
carrier
heating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2014504439A
Other languages
English (en)
Japanese (ja)
Other versions
JP2014516310A5 (https=
JP2014516310A (ja
Inventor
ローゼンダール，トビアス
モイレル，トルシュテン
カタリナ ドブネル，コルネリア
カタリナ ドブネル，コルネリア
ガイゲル，トーマス
グリッチュ，アヒム
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of JP2014516310A publication Critical patent/JP2014516310A/ja
Publication of JP2014516310A5 publication Critical patent/JP2014516310A5/ja
Application granted granted Critical
Publication of JP6062417B2 publication Critical patent/JP6062417B2/ja
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2014504439A 2011-04-14 2012-04-13 エチレンをエチレンオキシドに酸化するための触媒の製造方法 Expired - Fee Related JP6062417B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11162377.3 2011-04-14
EP11162377 2011-04-14
PCT/IB2012/051834 WO2012140614A1 (de) 2011-04-14 2012-04-13 Verfahren zur herstellung eines katalysators zur oxidation von ethen zu ethylenoxid

Publications (3)

Publication Number Publication Date
JP2014516310A JP2014516310A (ja) 2014-07-10
JP2014516310A5 JP2014516310A5 (https=) 2015-06-11
JP6062417B2 true JP6062417B2 (ja) 2017-01-18

Family

ID=47008898

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2014504439A Expired - Fee Related JP6062417B2 (ja) 2011-04-14 2012-04-13 エチレンをエチレンオキシドに酸化するための触媒の製造方法

Country Status (4)

Country Link
EP (1) EP2696971A4 (https=)
JP (1) JP6062417B2 (https=)
CN (1) CN103608107B (https=)
WO (1) WO2012140614A1 (https=)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013066557A1 (en) * 2011-10-31 2013-05-10 Dow Technology Investments, Llc Methods for producing epoxidation catalysts and epoxidation methods utilizing these
TWI808125B (zh) 2018-02-07 2023-07-11 德商巴斯夫歐洲公司 有效地將乙烯氧化轉化為環氧乙烷之催化劑
DK3749449T3 (da) 2018-02-07 2022-04-19 Basf Se Fremgangsmåde til fremstilling af en sølvimprægnerings-opløsning
EP3639923A1 (en) 2018-10-15 2020-04-22 Basf Se Process for producing ethylene oxide by gas-phase oxidation of ethylene
EP3639924A1 (en) 2018-10-15 2020-04-22 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3659703A1 (en) 2018-11-28 2020-06-03 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
WO2021038027A1 (en) 2019-08-28 2021-03-04 Basf Se Process for preparing an epoxidation catalyst
EP3885038A1 (en) 2020-03-27 2021-09-29 Basf Se Process for producing an epoxidation catalyst
US20230256415A1 (en) 2020-06-26 2023-08-17 Basf Se Production of porous alpha-alumina supports from boehmitic derived aluminas
WO2021260138A1 (en) 2020-06-26 2021-12-30 Basf Se Shaped catalyst body for the production of ethylene oxide
WO2021259427A1 (de) 2020-06-26 2021-12-30 Basf Se Poröser katalysatorträger-formkörper
EP4284552A1 (en) 2021-01-26 2023-12-06 Basf Se Epoxidation catalyst
EP4359123A1 (en) 2021-06-25 2024-05-01 Basf Se High purity tableted alpha-alumina catalyst support
EP4601789A1 (en) 2022-10-12 2025-08-20 Basf Se Epoxidation catalyst
WO2026027443A1 (en) 2024-07-29 2026-02-05 Basf Se Blended catalyst mix for epoxidation

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL84232A (en) * 1986-10-31 1992-06-21 Shell Int Research Catalyst and process for the catalytic production of ethylene oxide
US5070058A (en) * 1990-01-22 1991-12-03 Texaco, Inc. Method for making a catalyst composition used in the production of lower aliphatic alcohols
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
JPH0677685B2 (ja) * 1992-09-25 1994-10-05 三菱油化株式会社 エチレンからエチレンオキシドの製造方法
US5525740A (en) * 1993-03-01 1996-06-11 Scientific Design Company, Inc. Process for preparing silver catalyst and process of using same to produce ethylene oxide
US5504052A (en) * 1994-12-02 1996-04-02 Scientific Design Company, Inc. Silver catalyst preparation
TW408034B (en) * 1997-12-16 2000-10-11 Nippon Catalytic Chem Ind Silver catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide
JP4001429B2 (ja) * 1998-02-20 2007-10-31 株式会社日本触媒 エチレンオキシド製造用銀触媒、その製造方法およびエチレンオキシドの製造方法
EP1002575B1 (en) * 1998-11-17 2005-03-30 Nippon Shokubai Co., Ltd. Catalyst carrier for use in production of ethylene oxide
JP2002320855A (ja) * 2001-04-25 2002-11-05 Scientific Design Co Inc 酸化エチレン用触媒
RU2342190C2 (ru) * 2002-02-25 2008-12-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализатор и способ его применения
EP1624964B1 (en) * 2003-05-07 2019-07-31 Shell International Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
MX2008013433A (es) * 2006-04-18 2009-03-06 Dow Global Technologies Inc Catalizador de oxido de alquileno y uso del mismo.
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof

Also Published As

Publication number Publication date
EP2696971A4 (de) 2014-11-26
CN103608107A (zh) 2014-02-26
CN103608107B (zh) 2015-11-25
EP2696971A1 (de) 2014-02-19
WO2012140614A1 (de) 2012-10-18
JP2014516310A (ja) 2014-07-10

Similar Documents

Publication Publication Date Title
JP6062417B2 (ja) エチレンをエチレンオキシドに酸化するための触媒の製造方法
US9067198B2 (en) Calcination process for producing an improved ethylene oxide catalyst
TWI596091B (zh) 用於使高選擇性環氧乙烷觸媒啟動的方法
JP2014514960A (ja) エチレンオキシド製造用触媒
KR102203848B1 (ko) 에틸렌 옥사이드의 제조 방법
JP2017501864A (ja) アルケンのエポキシ化用触媒
US20120264953A1 (en) Zinc-comprising catalyst for preparing ethylene oxide
CN106311230B (zh) 用于烯烃环氧化的银催化剂的制备方法、催化剂及应用
JP2014512949A (ja) エチレンをエチレンオキシドに酸化するための触媒の製造方法
KR102197292B1 (ko) 에틸렌 옥사이드 촉매의 촉매적 성능 향상을 위한 담체 처리
US8629079B2 (en) Process for producing a catalyst for the oxidation of ethylene to ethylene oxide
TWI643671B (zh) 用於乙烯之環氧化的鋅促進觸媒
KR102232620B1 (ko) 감소된 소듐 함량을 가지는, 에틸렌 옥사이드 제조를 위한 은-기반 촉매
TW202239471A (zh) 環氧化催化劑
CN103608106B (zh) 用于制备氧化乙烯的含锌催化剂
CN107530688A (zh) 具有改进的银颗粒尺寸和分布密度的银催化剂
JP2015518421A (ja) アルケンのエポキシ化のための触媒

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20150413

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20150413

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20160224

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20160315

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20160609

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20160805

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20160907

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20161115

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20161214

R150 Certificate of patent or registration of utility model

Ref document number: 6062417

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees