JP6026440B2 - ポリマー基材用耐候性および耐摩耗性コーティングシステム - Google Patents
ポリマー基材用耐候性および耐摩耗性コーティングシステム Download PDFInfo
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Description
繰り返し単位AおよびBは下記式:
(i)繰り返し単位AおよびBを含むコポリカーボネート、または(ii)ポリイソシアネートと、繰り返し単位AおよびBを含むコポリカーボネートジオールとの反応によって得られるポリウレタンのいずれかであってよく、繰り返し単位AおよびBは下記式:
CHDMおよびPPG425コポリカーボネートの合成を説明する例示的な反応スキームを以下に示す。
パートA CHDM−PPG coPCの調製
実施例2 CHDM−PEG coPC−CeO2系プライマー組成物
実施例3 TCDDM−PPG coPC−CeO2系プライマー組成物
実施例4 TCDDM−PEG coPC−CeO2系プライマー組成物
実施例5 CHDM−PPG coPCおよびTCDDM−PPG coPC−CeO2系プライマー組成物
実施例6 シリル化−CHDM−PPG coPC−CeO2系プライマー組成物
実施例7 シリル化−TCDDM−PPG coPC−CeO2系プライマー組成物
実施例8 シリル化−CHDM−PPG coPCおよびシリル化−TCDDM−PPG coPC−CeO2系プライマー組成物
比較例A PMMA/CeO2系プライマー組成物
比較例D PEG/CeO2系プライマー組成物
比較例E CHDMホモポリマー/CeO2系プライマー組成物
実施例9 CHDM−PPG coPC−CeO2系プライマー組成物のポリウレタン
実施例10 CHDM−PPG coPC−CeO2系プライマー組成物のシリル化ポリウレタン
実施例11 コーティング例1、2および比較コーティング例A
実施例12 コーティング例3および比較コーティング例BおよびC
Claims (27)
- (1)無機紫外線吸収剤;および(2)(i)繰り返し単位AおよびBを含むコポリカーボネートおよび(ii)ポリイソシアネートと、繰り返し単位AおよびBを含むコポリカーボネートジオールとの反応によって得られるポリウレタンから選択されるポリマーを含むプライマー組成物であって、
繰り返し単位AおよびBは下記式:
紫外線吸収剤は、プライマー組成物の合計重量に基づいて1〜80重量%の量である、プライマー組成物。 - 成分(2)(i)のコポリカーボネートの全ての末端基が式(I)のシリル基である、請求項2に記載のプライマー組成物。
- 成分(2)(i)のコポリカーボネートの全ての末端基が水酸基である、請求項1に記載のプライマー組成物。
- ポリウレタンが水酸基末端またはイソシアネート末端である、請求項1に記載のプライマー組成物。
- ポリウレタンがアミノシランおよびイソシアナートシランからなる群より選択される少なくとも一つの化合物でシリル化されている、請求項7に記載のプライマー組成物。
- 無機紫外線吸収剤が、CeOx、TiOx、ZnOx、ZrOx(式中、xは1〜2である)、およびそれらの組み合わせからなる群より選択される、請求項1に記載のプライマー組成物。
- ポリマー基材、該ポリマー基材の少なくとも片面に配置されているプライマー層、および該プライマー層上に配置されている耐摩耗層を含む塗装物品であり、プライマー層が請求項1に記載のプライマー組成物で作られている塗装物品。
- 耐摩耗層が有機系トップコートである、請求項11に記載の塗装物品。
- 耐摩耗層がシリコーンハードコートである、請求項11に記載の塗装物品。
- 耐摩耗層が水素化シリコンオキシカーバイド層である、請求項11に記載の塗装物品。
- 水素化シリコンオキシカーバイド層が、プライマー層上の蒸着層である、請求項14に記載の塗装物品。
- 基材が、ポリカーボネートおよびコポリカーボネート、アクリルポリマー、ポリエステル、ポリアミド、ポリイミド、アクリロニトリル−スチレンコポリマー、スチレン−アクリロニトリルーブタジエン三元重合体、ポリ塩化ビニル、ポリエチレン、およびそれらの組み合わせから選択される、請求項11に記載の塗装物品。
- 耐候性および耐摩耗性コーティングシステムで塗装されたポリマー基材を得る方法であって、
(i)請求項1に記載のプライマー組成物をポリマー基材に塗布するステップ;
(ii)プライマー層を得るためにプライマー組成物を硬化させるステップ;および
(iii)プライマー層上に耐摩耗層を配置することにより、耐候性および耐磨耗性コーティングシステムで塗装されたポリマー基材を作るステップ
を含む方法。 - 耐摩耗層が有機系トップコートである、請求項17に記載の方法。
- ステップ(iii)が、プライマー層に有機系トップコート組成物を塗布すること、およびプライマー層上に有機系トップコートを得るために組成物を硬化させることを含む、請求項17に記載の方法。
- 耐摩耗層がシリコーンハードコートである、請求項17に記載の方法。
- ステップ(iii)が、プライマー層にシリコーンハードコート組成物を塗布すること、およびプライマー層上にシリコーンハードコートを得るために組成物を硬化させることを含む、請求項17に記載の方法。
- 耐摩耗層が水素化シリコンオキシカーバイド層である、請求項17に記載の方法。
- ステップ(iii)がプラズマ蒸着および物理蒸着の一つにより、水素化シリコンオキシカーバイド層をプライマー層に蒸着することを含む、請求項17に記載の方法。
- プライマー組成物がフローコート、ディップコートまたはスピンコートによりポリマー基板上へ塗布される、請求項17に記載の方法。
- ポリマー基材がポリカーボネートおよびコポリカーボネート、アクリルポリマー、ポリエステル、ポリアミド、ポリイミド、アクリロニトリル−スチレン共重合体、スチレン−アクリロニトリル−ブタジエン三元共重合体、ポリ塩化ビニル、ポリエチレン、およびそれらの組み合せから選択される、請求項17に記載の方法。
- ステップ(iii)がプラズマ強化化学気相蒸着、拡張性熱プラズマ、マイクロ波プラズマ、誘導結合プラズマ、高密度プラズマ化学気相蒸着、およびそれらの組み合わせからなる群より選択される方法によって、水素化シリコンオキシカーバイド層をプライマー層に蒸着することを含む、請求項17に記載の方法。
- ステップ(iii)がスパッタリング、レーザーアブレーション、陰極アーク蒸着法、および電子ビーム蒸着の一つによって、水素化シリコンオキシカーバイド層をプライマー層に蒸着することを含む、請求項17に記載の方法。
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US13/036,348 | 2011-02-28 | ||
US13/036,348 US8940397B2 (en) | 2011-02-28 | 2011-02-28 | Weatherable and abrasion resistant coating systems for polymeric substrates |
PCT/US2012/026750 WO2012118741A1 (en) | 2011-02-28 | 2012-02-27 | Weatherable & abrasion resistant coating systems for polymeric substrates |
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EP (1) | EP2681285B1 (ja) |
JP (1) | JP6026440B2 (ja) |
KR (1) | KR20140010084A (ja) |
CN (1) | CN103492502B (ja) |
BR (1) | BR112013021992A2 (ja) |
ES (1) | ES2591008T3 (ja) |
MX (1) | MX352027B (ja) |
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CN103492502B (zh) | 2016-08-24 |
MX2013009823A (es) | 2014-01-08 |
WO2012118741A1 (en) | 2012-09-07 |
CN103492502A (zh) | 2014-01-01 |
JP2014511421A (ja) | 2014-05-15 |
MX352027B (es) | 2017-11-07 |
EP2681285A1 (en) | 2014-01-08 |
BR112013021992A2 (pt) | 2016-11-16 |
TW201239048A (en) | 2012-10-01 |
TWI530540B (zh) | 2016-04-21 |
US20120219803A1 (en) | 2012-08-30 |
ES2591008T3 (es) | 2016-11-24 |
US8940397B2 (en) | 2015-01-27 |
KR20140010084A (ko) | 2014-01-23 |
EP2681285B1 (en) | 2016-07-13 |
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