JP2014511421A - ポリマー基材用耐候性および耐摩耗性コーティングシステム - Google Patents
ポリマー基材用耐候性および耐摩耗性コーティングシステム Download PDFInfo
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Abstract
無機紫外線吸収剤、および(i)コポリカーボネートおよび(ii)ポリイソシアネートとコポリカーボネートジオールとの反応によって得られるポリウレタンから選択されるポリマーを含むプライマー組成物が開示される。また、ポリマー基材、該ポリマー基材の少なくとも片面に配置されているプライマー層、および該プライマー層に配置されている耐摩耗層を含む塗装物品を開示され、ここで、プライマー層は、本発明のプライマー組成物で作られる。
【選択図】なし
Description
繰り返し単位AおよびBは下記式:
(i)繰り返し単位AおよびBを含むコポリカーボネート、または(ii)ポリイソシアネートと、繰り返し単位AおよびBを含むコポリカーボネートジオールとの反応によって得られるポリウレタンのいずれかであってよく、繰り返し単位AおよびBは下記式:
で表され、
である。
CHDMおよびPPG425コポリカーボネートの合成を説明する例示的な反応スキームを以下に示す。
のものである。
より選択される)で表されるジイソシアネートである。
の一級または二級アミノシランである。
パートA CHDM−PPG coPCの調製
実施例3 TCDDM−PPG coPC−CeO2系プライマー組成物
実施例4 TCDDM−PEG coPC−CeO2系プライマー組成物
実施例5 CHDM−PPG coPCおよびTCDDM−PPG coPC−CeO2系プライマー組成物
実施例6 シリル化−CHDM−PPG coPC−CeO2系プライマー組成物
実施例7 シリル化−TCDDM−PPG coPC−CeO2系プライマー組成物
実施例8 シリル化−CHDM−PPG coPCおよびシリル化−TCDDM−PPG coPC−CeO2系プライマー組成物
比較例A PMMA/CeO2系プライマー組成物
比較例D PEG/CeO2系プライマー組成物
比較例E CHDMホモポリマー/CeO2系プライマー組成物
実施例9 CHDM−PPG coPC−CeO2系プライマー組成物のポリウレタン
実施例10 CHDM−PPG coPC−CeO2系プライマー組成物のシリル化ポリウレタン
実施例11 コーティング例1、2および比較コーティング例A
実施例12 コーティング例3および比較コーティング例BおよびC
Claims (27)
- (1)無機紫外線吸収剤;および(2)(i)繰り返し単位AおよびBを含むコポリカーボネートおよび(ii)ポリイソシアネートと、繰り返し単位AおよびBを含むコポリカーボネートジオールとの反応によって得られるポリウレタンから選択されるポリマーを含むプライマー組成物であって、
繰り返し単位AおよびBは下記式:
(式中、単位(B)に対する単位(A)のモル比は、およそ9:1〜およそ1:9の範囲であり、R1は、二価C8〜C12脂環式基であり、R2は、エチレン、プロピレンおよびそれらの組み合わせからなる群より選択される二価の基であり、nは、4〜40の整数である)で表され、
紫外線吸収剤は、プライマー組成物の合計重量に基づいておよそ1〜およそ80重量%の量である。 - 成分(2)(i)のコポリカーボネートの実質的に全ての末端基が式(I)のシリル基である、請求項2に記載のプライマー組成物。
- 成分(2)(i)のコポリカーボネートの実質的に全ての末端基が水酸基である、請求項1に記載のプライマー組成物。
- ポリウレタンが水酸基末端またはイソシアネート末端である、請求項1に記載のプライマー組成物。
- ポリウレタンがアミノシランおよびイソシアナートシランからなる群より選択される少なくとも一つの化合物でシリル化されている、請求項7に記載のプライマー組成物。
- アミノシランが、一般式:
(式中、R6は、水素またはおよそ1〜およそ10の炭素原子のアルキル基であり、R7は、およそ1〜およそ10の炭素原子の二価アルキレン基であり、R2およびR3の各々は、独立して、およそ1〜およそ6の炭素原子のアルキル基またはおよそ6〜およそ8の炭素原子のアリール基であり、bは、0、1または2の数値を持つ)であり、イソシアナートシランが、一般式:
(式中、R8は、およそ1〜およそ10の炭素原子の二価アルキレン基であり、R4およびR5の各々は、独立して、およそ1〜およそ6の炭素原子のアルキル基またはおよそ6〜およそ8の炭素原子のアリール基であり、cは、0、1または2の数値を持つ)である、請求項8に記載のプライマー組成物。 - 無機紫外線吸収剤が、CeOx、TiOx、ZnOx、ZrOx(式中、xは1〜2である)、およびそれらの組み合わせからなる群より選択される、請求項1に記載のプライマー組成物。
- ポリマー基材、該ポリマー基材の少なくとも片面に配置されているプライマー層、および耐摩耗層を含む塗装物品であり、プライマー層が請求項1に記載のプライマー組成物で作られている。
- 耐摩耗層が有機系トップコートである、請求項11に記載の塗装物品。
- 耐摩耗層がシリコーンハードコートである、請求項11に記載の塗装物品。
- 耐摩耗層が水素化シリコンオキシカーバイド層である、請求項11に記載の塗装物品。
- 水素化シリコンオキシカーバイド層が、プラズマ蒸着または物理蒸着により、プライマー層に蒸着される、請求項14に記載の塗装物品。
- 水素化シリコンオキシカーバイド層が、プラズマ強化化学気相蒸着、拡張性熱プラズマ、マイクロ波プラズマ、融合結合プラズマ、高密度プラズマ化学気相蒸着、およびそれらの組み合わせからなる群より選択される方法によって、プライマー層に蒸着される、請求項14に記載の塗装物品。
- 水素化シリコンオキシカーバイド層が、スパッタリング、レーザーアブレーション、陰極アーク蒸着法、および電子ビーム蒸着の一つによって蒸着される、請求項14に記載の塗装物品。
- 基材が、ポリカーボネートおよびコポリカーボネート、アクリルポリマー、ポリエステル、ポリアミド、ポリイミド、アクリロニトリル−スチレンコポリマー、スチレン−アクリロニトリルーブタジエン三元重合体、ポリ塩化ビニル、ポリエチレン、およびそれらの組み合わせから選択される、請求項11に記載の塗装物品。
- 耐候性および耐摩耗性コーティングシステムで塗装されたポリマー基材を得る方法であって、
(i)請求項1に記載のプライマー組成物をポリマー基材に塗布するステップ;
(ii)プライマー層を得るためにプライマー組成物を硬化させるステップ;および
(iii)プライマー層上に耐摩耗層を配置することにより、耐候性および耐磨耗性コーティングシステムで塗装されたポリマー基材を作るステップ
を含む。 - 耐摩耗層が有機系トップコートである、請求項19に記載の方法。
- ステップ(iii)が、プライマー層に有機系トップコート組成物を塗布すること、およびプライマー層上に有機系トップコートを得るために組成物を硬化させることを含む、請求項19に記載の方法。
- 耐摩耗層がシリコーンハードコートである、請求項19に記載の方法。
- ステップ(iii)が、プライマー層にシリコーンハードコート組成物を塗布すること、およびプライマー層上にシリコーンハードコートを得るために組成物を硬化させることを含む、請求項19に記載の方法。
- 耐摩耗層が水素化シリコンオキシカーバイド層である、請求項19に記載の方法。
- ステップ(iii)がプラズマ蒸着および物理蒸着の一つにより、水素化シリコンオキシカーバイド層をプライマー層に蒸着することを含む、請求項19に記載の方法。
- プライマー組成物がフローコート、ディップコートまたはスピンコートによりポリマー基板上へ塗布される、請求項19に記載の方法。
- ポリマー基材がポリカーボネートおよびコポリカーボネート、アクリルポリマー、ポリエステル、ポリアミド、ポリイミド、アクリロニトリル−スチレン共重合体、スチレン−アクリロニトリル−ブタジエン三元共重合体、ポリ塩化ビニル、ポリエチレン、およびそれらの組み合せから選択される、請求項19に記載の方法。
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PCT/US2012/026750 WO2012118741A1 (en) | 2011-02-28 | 2012-02-27 | Weatherable & abrasion resistant coating systems for polymeric substrates |
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CN103492502B (zh) | 2016-08-24 |
EP2681285B1 (en) | 2016-07-13 |
TW201239048A (en) | 2012-10-01 |
US20120219803A1 (en) | 2012-08-30 |
TWI530540B (zh) | 2016-04-21 |
EP2681285A1 (en) | 2014-01-08 |
CN103492502A (zh) | 2014-01-01 |
JP6026440B2 (ja) | 2016-11-16 |
KR20140010084A (ko) | 2014-01-23 |
US8940397B2 (en) | 2015-01-27 |
BR112013021992A2 (pt) | 2016-11-16 |
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