JP6019034B2 - 多価不飽和化合物の金属触媒モノヒドロシリル化 - Google Patents
多価不飽和化合物の金属触媒モノヒドロシリル化 Download PDFInfo
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- JP6019034B2 JP6019034B2 JP2013541003A JP2013541003A JP6019034B2 JP 6019034 B2 JP6019034 B2 JP 6019034B2 JP 2013541003 A JP2013541003 A JP 2013541003A JP 2013541003 A JP2013541003 A JP 2013541003A JP 6019034 B2 JP6019034 B2 JP 6019034B2
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- Prior art keywords
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- trivinylcyclohexane
- group
- alkyl
- independently
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 0 CCC(CC)CC(C(*=C1[Cn])OC*C*)=C(*(CC)N)C=C1O* Chemical compound CCC(CC)CC(C(*=C1[Cn])OC*C*)=C(*(CC)N)C=C1O* 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41706110P | 2010-11-24 | 2010-11-24 | |
| US61/417,061 | 2010-11-24 | ||
| PCT/US2011/061752 WO2012071360A1 (en) | 2010-11-24 | 2011-11-22 | Metal - catalyzed mono - hydrosilylation of polyunsaturated compounds |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014502271A JP2014502271A (ja) | 2014-01-30 |
| JP2014502271A5 JP2014502271A5 (OSRAM) | 2015-01-29 |
| JP6019034B2 true JP6019034B2 (ja) | 2016-11-02 |
Family
ID=45319392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013541003A Active JP6019034B2 (ja) | 2010-11-24 | 2011-11-22 | 多価不飽和化合物の金属触媒モノヒドロシリル化 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8895770B2 (OSRAM) |
| EP (1) | EP2643330B1 (OSRAM) |
| JP (1) | JP6019034B2 (OSRAM) |
| KR (1) | KR101896423B1 (OSRAM) |
| CN (1) | CN103732599B (OSRAM) |
| BR (1) | BR112013012734A2 (OSRAM) |
| TW (1) | TWI457176B (OSRAM) |
| WO (1) | WO2012071360A1 (OSRAM) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2643335B1 (en) * | 2010-11-24 | 2015-03-11 | Momentive Performance Materials Inc. | Hydrosilylation catalyst |
| JP6101695B2 (ja) | 2011-09-20 | 2017-03-22 | ダウ コーニング コーポレーションDow Corning Corporation | ニッケル含有ヒドロシリル化触媒及びその触媒を含有する組成物 |
| WO2013081794A1 (en) | 2011-12-01 | 2013-06-06 | Dow Corning Corporation | Hydrosilylation reaction catalysts and curable compositions and methods for their preparation and use |
| US9782763B2 (en) * | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
| US9447125B2 (en) | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
| US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
| US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
| WO2014182670A2 (en) | 2013-05-06 | 2014-11-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
| JP2016520083A (ja) | 2013-05-15 | 2016-07-11 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | シリルヒドリドによる金属塩の活性化およびヒドロシリル化反応におけるその使用 |
| US9387468B2 (en) | 2013-11-19 | 2016-07-12 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| TW201524603A (zh) * | 2013-11-19 | 2015-07-01 | Momentive Performance Mat Inc | 鈷觸媒及其於矽氫化與脫氫甲矽烷化之用途 |
| WO2015077306A1 (en) | 2013-11-19 | 2015-05-28 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| WO2015171881A1 (en) * | 2014-05-08 | 2015-11-12 | Momentive Performance Materials Inc. | Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| JP2015231965A (ja) * | 2014-06-10 | 2015-12-24 | 国立研究開発法人産業技術総合研究所 | 有機ケイ素化合物の製造方法及び触媒組成物 |
| WO2016024611A1 (ja) | 2014-08-12 | 2016-02-18 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
| WO2016024607A1 (ja) | 2014-08-12 | 2016-02-18 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
| JP6761997B2 (ja) | 2014-08-19 | 2020-09-30 | 国立大学法人九州大学 | ヒドロシリル化鉄触媒 |
| CN107847921B (zh) | 2015-07-14 | 2022-01-14 | 国立大学法人九州大学 | 氢化硅烷化反应催化剂 |
| US10717752B2 (en) * | 2015-07-24 | 2020-07-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using pyridinediimine cobalt carboxylate catalysts |
| KR101728308B1 (ko) | 2015-09-14 | 2017-04-19 | 기초과학연구원 | 비전이금속 촉매법 수소규소화 반응을 이용한 규소 고분자 제조방법 |
| EP3406616B1 (en) | 2016-01-22 | 2022-06-29 | Shin-Etsu Chemical Co., Ltd. | Novel isocyanide compound and hydrosilylation reaction catalyst |
| CN110366449B (zh) | 2017-02-28 | 2022-10-21 | 国立大学法人九州大学 | 氢化硅烷化反应、氢化反应和氢硅烷还原反应用催化剂 |
| JP2019064950A (ja) | 2017-09-29 | 2019-04-25 | 国立大学法人九州大学 | コバルト錯体、その製造方法およびヒドロシリル化反応用触媒 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2641785B1 (fr) | 1989-01-19 | 1992-07-31 | Essilor Int | Composition de polymeres transparents pour lentilles de contact de type rigide, permeables a l'oxygene |
| US5691435A (en) * | 1996-01-25 | 1997-11-25 | Wacker-Chemie Gmbh | Crosslinkable compositions |
| US5756795A (en) * | 1996-12-30 | 1998-05-26 | Dow Corning Corporation | Unsaturated accelerators for hydrosilation |
| US5986022A (en) * | 1998-04-01 | 1999-11-16 | Witco Corporation | Continuous manufacture of silicone coploymers |
| GB9819847D0 (en) | 1998-09-12 | 1998-11-04 | Bp Chem Int Ltd | Novel compounds |
| DE19856115A1 (de) | 1998-12-04 | 2000-06-21 | Wacker Chemie Gmbh | Alkenylgruppen aufweisende Siloxancopolymere |
| US6278011B1 (en) | 1999-08-30 | 2001-08-21 | The University Of Dayton | Polysilahydrocarbons as lubricants for aerospace application |
| US7429672B2 (en) | 2006-06-09 | 2008-09-30 | Momentive Performance Materials Inc. | Process for the direct synthesis of trialkoxysilane |
| US7696269B2 (en) * | 2006-12-28 | 2010-04-13 | Momentive Performance Materials Inc. | Silated core polysulfides, their preparation and use in filled elastomer compositions |
| US8415443B2 (en) * | 2009-07-10 | 2013-04-09 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| US8236915B2 (en) * | 2009-07-10 | 2012-08-07 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| BR112013012733A2 (pt) * | 2010-11-24 | 2016-09-13 | Univ Cornell | ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação |
-
2011
- 2011-11-22 EP EP11794591.5A patent/EP2643330B1/en active Active
- 2011-11-22 US US13/302,506 patent/US8895770B2/en active Active
- 2011-11-22 JP JP2013541003A patent/JP6019034B2/ja active Active
- 2011-11-22 WO PCT/US2011/061752 patent/WO2012071360A1/en not_active Ceased
- 2011-11-22 CN CN201180065872.0A patent/CN103732599B/zh active Active
- 2011-11-22 BR BR112013012734A patent/BR112013012734A2/pt not_active Application Discontinuation
- 2011-11-22 KR KR1020137016391A patent/KR101896423B1/ko active Active
- 2011-11-23 TW TW100142961A patent/TWI457176B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| US8895770B2 (en) | 2014-11-25 |
| TW201235102A (en) | 2012-09-01 |
| TWI457176B (zh) | 2014-10-21 |
| CN103732599A (zh) | 2014-04-16 |
| KR20140035318A (ko) | 2014-03-21 |
| WO2012071360A1 (en) | 2012-05-31 |
| CN103732599B (zh) | 2016-09-14 |
| JP2014502271A (ja) | 2014-01-30 |
| EP2643330B1 (en) | 2017-01-04 |
| BR112013012734A2 (pt) | 2016-09-13 |
| KR101896423B1 (ko) | 2018-10-04 |
| US20120130105A1 (en) | 2012-05-24 |
| EP2643330A1 (en) | 2013-10-02 |
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