BR112013012734A2 - mono-hidrossililação catalisada por metal não-precioso seletivo de compostos polinsaturados - Google Patents

mono-hidrossililação catalisada por metal não-precioso seletivo de compostos polinsaturados

Info

Publication number
BR112013012734A2
BR112013012734A2 BR112013012734A BR112013012734A BR112013012734A2 BR 112013012734 A2 BR112013012734 A2 BR 112013012734A2 BR 112013012734 A BR112013012734 A BR 112013012734A BR 112013012734 A BR112013012734 A BR 112013012734A BR 112013012734 A2 BR112013012734 A2 BR 112013012734A2
Authority
BR
Brazil
Prior art keywords
monohydrosilylation
polyunsaturated compounds
precious metal
metal catalyzed
selective non
Prior art date
Application number
BR112013012734A
Other languages
English (en)
Inventor
Aaron M Tondreau
Johannnes G P Delis
Keith J Weller
Kenrick M Lewis
Paul J Chirik
Richard W Cruse
Susan A Nye
Original Assignee
Univ Cornell
Momentive Performance Mat Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Cornell, Momentive Performance Mat Inc filed Critical Univ Cornell
Publication of BR112013012734A2 publication Critical patent/BR112013012734A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

mono-hidrossililação catalisada por metal não-precioso seletivo de compostos polinsaturados. a presente invenção refere-se a sínteses seletivados monohidrossilados de compostos poliinsaturados, tal como trivinilciclohexano usando metal não preciso à base de complexo de terpiridina e limina piridinada como catalisadores de hidrolisação seletiva.
BR112013012734A 2010-11-24 2011-11-22 mono-hidrossililação catalisada por metal não-precioso seletivo de compostos polinsaturados BR112013012734A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US41706110P 2010-11-24 2010-11-24
PCT/US2011/061752 WO2012071360A1 (en) 2010-11-24 2011-11-22 Metal - catalyzed mono - hydrosilylation of polyunsaturated compounds

Publications (1)

Publication Number Publication Date
BR112013012734A2 true BR112013012734A2 (pt) 2016-09-13

Family

ID=45319392

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013012734A BR112013012734A2 (pt) 2010-11-24 2011-11-22 mono-hidrossililação catalisada por metal não-precioso seletivo de compostos polinsaturados

Country Status (8)

Country Link
US (1) US8895770B2 (pt)
EP (1) EP2643330B1 (pt)
JP (1) JP6019034B2 (pt)
KR (1) KR101896423B1 (pt)
CN (1) CN103732599B (pt)
BR (1) BR112013012734A2 (pt)
TW (1) TWI457176B (pt)
WO (1) WO2012071360A1 (pt)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112013012742A2 (pt) * 2010-11-24 2016-09-13 Univ Cornell catalisadores de hidrossililação
WO2013043785A2 (en) 2011-09-20 2013-03-28 Dow Corning Corporation Nickel containing hydrosilylation catalysts and compositions containing the catalysts
CN103958059B (zh) 2011-12-01 2017-04-26 道康宁公司 硅氢加成反应催化剂和可固化组合物及它们的制备和使用方法
US9782763B2 (en) * 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
US9447125B2 (en) 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
WO2014182670A2 (en) 2013-05-06 2014-11-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
US9440999B2 (en) 2013-05-15 2016-09-13 Momentive Performance Materials Inc. Activation of metal salts with silylhydrides and their use in hydrosilylation reactions
JP6486925B2 (ja) 2013-11-19 2019-03-20 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用
US9381506B2 (en) 2013-11-19 2016-07-05 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP6486924B2 (ja) * 2013-11-19 2019-03-20 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用
WO2015171881A1 (en) * 2014-05-08 2015-11-12 Momentive Performance Materials Inc. Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP2015231965A (ja) * 2014-06-10 2015-12-24 国立研究開発法人産業技術総合研究所 有機ケイ素化合物の製造方法及び触媒組成物
EP3181226B1 (en) 2014-08-12 2024-08-07 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
CN106660030A (zh) 2014-08-12 2017-05-10 国立大学法人九州大学 氢化硅烷化反应催化剂
JP6761997B2 (ja) 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
EP3323505B1 (en) 2015-07-14 2024-07-17 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
CN108026126B (zh) * 2015-07-24 2021-04-20 莫门蒂夫性能材料股份有限公司 使用吡啶二亚胺羧酸钴催化剂的脱氢硅烷化、氢化硅烷化和交联
KR101728308B1 (ko) 2015-09-14 2017-04-19 기초과학연구원 비전이금속 촉매법 수소규소화 반응을 이용한 규소 고분자 제조방법
WO2017126562A1 (ja) 2016-01-22 2017-07-27 信越化学工業株式会社 新規イソシアニド化合物及びヒドロシリル化反応触媒
US20200001285A1 (en) 2017-02-28 2020-01-02 Kyushu University, National University Corporation Catalyst for hydrosilylation reaction, hydrogenation reaction, and hydrosilane reduction reaction
JP2019064950A (ja) 2017-09-29 2019-04-25 国立大学法人九州大学 コバルト錯体、その製造方法およびヒドロシリル化反応用触媒

Family Cites Families (12)

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Publication number Priority date Publication date Assignee Title
FR2641785B1 (fr) 1989-01-19 1992-07-31 Essilor Int Composition de polymeres transparents pour lentilles de contact de type rigide, permeables a l'oxygene
US5691435A (en) * 1996-01-25 1997-11-25 Wacker-Chemie Gmbh Crosslinkable compositions
US5756795A (en) * 1996-12-30 1998-05-26 Dow Corning Corporation Unsaturated accelerators for hydrosilation
US5986022A (en) * 1998-04-01 1999-11-16 Witco Corporation Continuous manufacture of silicone coploymers
GB9819847D0 (en) * 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
DE19856115A1 (de) 1998-12-04 2000-06-21 Wacker Chemie Gmbh Alkenylgruppen aufweisende Siloxancopolymere
US6278011B1 (en) 1999-08-30 2001-08-21 The University Of Dayton Polysilahydrocarbons as lubricants for aerospace application
US7429672B2 (en) 2006-06-09 2008-09-30 Momentive Performance Materials Inc. Process for the direct synthesis of trialkoxysilane
US7696269B2 (en) * 2006-12-28 2010-04-13 Momentive Performance Materials Inc. Silated core polysulfides, their preparation and use in filled elastomer compositions
US8415443B2 (en) 2009-07-10 2013-04-09 Momentive Performance Materials Inc. Hydrosilylation catalysts
US8236915B2 (en) 2009-07-10 2012-08-07 Momentive Performance Materials Inc. Hydrosilylation catalysts
WO2012071358A2 (en) * 2010-11-24 2012-05-31 Momentive Performance Materials Inc. In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts

Also Published As

Publication number Publication date
KR101896423B1 (ko) 2018-10-04
KR20140035318A (ko) 2014-03-21
WO2012071360A1 (en) 2012-05-31
CN103732599B (zh) 2016-09-14
JP6019034B2 (ja) 2016-11-02
EP2643330B1 (en) 2017-01-04
JP2014502271A (ja) 2014-01-30
CN103732599A (zh) 2014-04-16
EP2643330A1 (en) 2013-10-02
US8895770B2 (en) 2014-11-25
TWI457176B (zh) 2014-10-21
US20120130105A1 (en) 2012-05-24
TW201235102A (en) 2012-09-01

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

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